• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.4
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• pp.275-286
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• 2014

This study evaluated the evolution stage and origin of chemical components of 12 boreholes at crystalline bedrock using multivariate statistical and groundwater quality analyses. Groundwater types are mostly belonged to Na(Ca)-$HCO_3$ and Ca-$HCO_3$ types, indicating that directly reaction of cation exchange ($Ca^{2+}{\rightarrow}Na^+$) prevailed. The degree of groundwater evolution is included the range from low to intermediate stage based on field and laboratory analytical conditions. As a result of multivariate statistical analysis, a typical indicator of groundwater contamination, $NO_3$-, has the positive correlation with $Na^+$ and $Cl^-$. The origin of sea spary ($Cl^-$) has the positive correlation with $Na^+$, $SO{_4}^{2-}$, $Mg^{2+}$, and $K^+$, while not correlation with $Ca^{2+}$, $Fe^{2+}$, $HCO_3{^-}$, $F^-$, and $SiO_2$. The concentration of $Cl^-$ and $NO_3{^-}$ belongs to general quality of groundwater and not exceeds over the Korean standard for drinking water. And the negative values of saturation index of minerals are calculated with chemical components in groundwater. Therefore, most of chemical components of groundwater in the study area are originated from natural process between rock and groundwater, whereas some of components are derived from sea spary and anthropogenic sources related to agricultural activities.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.4
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• pp.267-274
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• 2014

The first Low- and Intermediate-Level Waste (LILW) disposal facility with 6 silos has been constructed in granite host rock saturated with groundwater in Korea. A two-dimensional numerical modeling on gas migration was carried out using TOUGH2 with EOS5 module in the disposal facility. Laboratory-scale experiments were also performed to measure the important properties of silo concrete related with gas migration. The gas entry pressure and relative gas permeability of the concrete was determined to be $0.97{\pm}0.15bar$ and $2.44{\times}10^{-17}m^2$, respectively. The results of the numerical modeling showed that hydrogen gas generated from radioactive wastes was dissolved in groundwater and migrated to biosphere as an aqueous phase. Only a small portion of hydrogen appeared as a gas phase after 1,000 years of gas generation. The results strongly suggested that hydrogen gas does not accumulate inside the disposal facility as a gas phase. Therefore, it is expected that there would be no harmful effects on the integrity of the silo concrete due to gas generation.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.4
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• pp.311-324
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• 2013

To ensure the reliability of computer programs used for the post-closure safety assessment in the Wolsong LILW Center, the results from MASCOT, SAFE-ROCK and GOLDSIM programs are compared with a problem for degradation. Advantages and disadvantages of each computer programs are individually analyzed. Effects on the individual dose are assessed with each computer programs. MASCOT and SAFE-ROCK showed similar results for $^{129}I$ and $^3H$. However, GOLDSIM represented different results for $^{129}I$ and $^3H$. It is analyzed further and compared with the fluxes in each barrier of the disposal system. Througout the benchmarking testing of the computer program, the limitation of computer program can be continuously found out for the mature post-closure safety of Korean radwaste disposal system.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.4
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• pp.281-291
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• 2013

A hypothetical repository was assumed to be located at the KURT (KAERI Underground Research Tunnel) site, and the travel times of radionuclides released from three source positions were calculated. The groundwater flow around the KURT site was simulated and the groundwater pathways from the hypothetical source positions to the shallow groundwater were identified. Of the pathways, three pathways were selected because they had highly water-conductive features. The transport travel times of the radionuclides were calculated by a TDRW (Time-Domain Random Walk) method. Diffusion and sorption mechanisms in a host rock matrix as well as advection-dispersion mechanisms under the KURT field condition were considered. To reflect the radioactive decay, four decay chains with the radionuclides included in the high-level radioactive wastes were selected. From the simulation results, the half-life and distribution coefficient in the rock matrix, as well as multiple pathways, had an influence on the mass flux of the radionuclides. For enhancing the reliability of safety assessment, this reveals that identifying the history of the radionuclides contained in the high-level wastes and investigating the sorption processes between the radionuclides and the rock matrix in the field condition are preferentially necessary.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.3
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• pp.347-357
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• 2018

The applicability of room temperature ionic liquids (RTILs), 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([$C_nmim$] [$Tf_2N$]), was investigated for the extraction of Am(III) and Eu(III) from nitric acid using n-octyl(phenyl)-N,N-diisobutyl carbamoylmethyl phosphine oxide (CMPO) and tri-n-butylphosphate (TBP) as extractants. The distribution ratios of Am(III) and Eu(III) in CMPO-TBP/[$C_nmim$][$Tf_2N$] were measured as a function of various parameters such as the concentrations of nitric acid, CMPO, and TBP. The results were compared with those obtained in CMPO-TBP/n-dodecane (n-DD). With comparable concentrations of the extractants, the distribution ratios obtained with RTILs were much higher than those obtained with n-DD. It was observed that the extraction efficiency was less for Eu(III) than for Am(III). The extraction of Am(III) and Eu(III) decreased with increases in the feed acidity for all three RTILs. The results suggest that the extraction of Am(III) and Eu(III) by CMPO in RTILs from nitric acid proceeds through the cation-exchange mechanism. The distribution ratios of Am(III) and Eu(III) increased with increases in the concentration of CMPO for all three RTILs. A linear regression analysis of the extraction data resulted in a straight line with a slope of about 3, suggesting the involvement of 3 molecules of CMPO during the extraction process.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.2
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• pp.179-194
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• 2020

A Bayesian approach was introduced to improve the belief of prior distributions of input parameters for the probabilistic safety assessment of radioactive waste repository. A GoldSim-based module was developed using the Markov chain Monte Carlo algorithm and implemented through GSTSPA (GoldSim Total System Performance Assessment), a GoldSim template for generic/site-specific safety assessment of the radioactive repository system. In this study, sequential Bayesian updating of prior distributions was comprehensively explained and used as a basis to conduct a reliable safety assessment of the repository. The prior distribution to three sequential posterior distributions for several selected parameters associated with nuclide transport in the fractured rock medium was updated with assumed likelihood functions. The process was demonstrated through a probabilistic safety assessment of the conceptual repository for illustrative purposes. Through this study, it was shown that insufficient observed data could enhance the belief of prior distributions for input parameter values commonly available, which are usually uncertain. This is particularly applicable for nuclide behavior in and around the repository system, which typically exhibited a long time span and wide modeling domain.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.2
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• pp.133-141
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• 2020

A geological repository comprises a natural barrier and an engineered barrier system. Its design components consist of canisters, buffers, backfill, and near-field rock. Among the engineered barrier system components, bentonite buffers minimize the groundwater flow from near-field rock and prevent the release of nuclide. Investigation of the hydraulic conductivity of the buffer to groundwater flow is an important factor in the performance evaluation of the stability and integrity of the engineered barrier of the repository. In this study, saturated hydraulic conductivity tests were performed using Gyeongju bentonite at various dry densities and temperatures, and a hydraulic conductivity prediction model was developed through multiple regression analysis using the 120 result sets of hydraulic conductivity. The test results showed that the hydraulic conductivity tends to decrease as the dry density increases. In addition, the hydraulic conductivity increased with increasing temperature. The multiple regression analysis results showed that the coefficient of determination (R²) of the hydraulic conductivity prediction equation was as high as 0.93. The hydraulic conductivity prediction equation presented in this study could be used for the design of engineered barrier systems.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.3
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• pp.183-192
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• 2005

Natural ventilation in radioactive waste repositories is considered to be less efficient than mechanically forced ventilation for the repository working environment and hygiene & safety of the public at large, for example, controlling the exposure of airborne radioactive particulate matter. It is, however, considered to play an important role and may be fairly efficient for maintaining environmental conditions of the repository over the duration of its lifetime, for example, moisture content and radon (Rn) gas elimination in repository. This paper describes the feasibility of using natural ventilation which can be generated in the repository itself, depending on the conditions of the natural environment during the periods of repository construction and operation. Evidences from natural cave analogues, actual measurements of natural ventilation pressures in mountain traffic tunnels with vertical shafts, and calculations of airflow rates with given natural ventilation pressures indicate possible benefits from passive ventilation for the prospective Korean radioactive waste repository. Natural ventilation may provide engineers with a cost-efficient method for heat and moisture transfer, and radon (Rn) gas elimination in a radioactive waste repository. The overall thermal performance of the repository may be improved. The dry-out period may be extended, and the seepage flux likely would be decreased.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.3
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• pp.249-256
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• 2005

Thermal decomposition and stabilization characteristics of the solid cake after the dissolution of nitrate of the lagoon sludge was investigated. Most of the nitrates were dissolved in the water and removed to the filtrate, but small amount of nitrates, calcium carbonate and uranium were remained in the solid cake. The solid cake was thermally decomposed in the muffle furnace at $900^{\circ}C$ for 5 hours. Uranium, which is in the lagoon 1, was stabilized with $NaNO_3$ decomposition to $Na_{2}O{\cdot}2UO_3$ form. For the lagoon 2, it is confirmed that CaO, which was created by thermal decomposition of the $Ca(NO_3)_2$ and $CaCO_3$, was transferred to $Ca(OH)_2$ in the air with water. Because it is known that $Ca(OH)_2$ is stable material, further additives did not need to the stabilization of the thermal decomposition of the lagoons.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.4 no.2
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• pp.103-116
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• 2006

By executing corrosion experiment on Inconel 600, 690 used to material of S/G tube in domestic NPP, this paper show estimation of amount of product such as Co-58, Co-60, Cr-51, Mn-54, Fe-59 which are main exposure cause to the workers in NPP. Therefore, Making the 12 samples consisted of Inconel 600, 690, whole corrosion experiment was carried out for 60 days(each pH by 20 days). The conditions of those tests were similar or more harsh than actual conditions of domestic NPP. The Glow Discharge Spectrometer(GDS) was used for quantitative analysis of results. The results of using GDS, the Inconel 600 corrodes more than Inconel 690 at pH 7 and pH 9. However, it is observed that Inconel 690 corrodes more than Inconel 600 at pH 4. Those results is estimated that test sections had the effect of transient. The long terms of experiment is required to minimize and solve the problem.