• Title/Summary/Keyword: Nox4

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Study on Characteristics of Change of Urea and Biuret Content by Temperature Variation in Urea Solution (요소수(Urea solution)의 온도변화에 따른 요소 및 뷰렛함량 변화 특성 연구)

  • Doe, Jin-woo;Park, Tae-sung;Lee, Yu-rim;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1307-1319
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    • 2018
  • As interests in the air pollution increases, many kinds of researches are underway on the reduction of air pollutants. The removal of nitrogen oxides from the emission gas of diesel vehicles using urea solution has shown a great effect. The quality of urea solution is strictly defined by domestic law, but the increase of impurities in urea solution reduces the effect of reducing nitrogen oxides. Therefore, in this study, the change of physical properties of urea solution was analyzed after heating the urea solution for a certain temperature and time. Also, the changes of physical properties of urea solution were analyzed according to kinds of storage container and temperature for storing the urea solution. After heating the urea solution for a certain period of time, the biuret content in urea solution increased and the content of urea decreased. As the urea content decreased, both density and refractive index decreased. In the storage stability test carried out at a constant temperature with iron and PET containers, no change in physical properties was observed.

A Study on Prediction Model Conformity of Line Source in Urban Area (도시지역에서의 선오염원 예측모델 적합성에 관한 연구)

  • Kim, Jin Hong;Park, Sun hwan;Chang, Yoon young
    • Journal of the Korean Society of Urban Environment
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    • v.18 no.4
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    • pp.511-521
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    • 2018
  • Despite the limitations and difficulty in the application of CALINE3 model for air dispersion prediction of roads and tunnels construction businesses in South Korea, the model is being used in all roads construction projects. This study compared the predicted values of CALINE3 and AERMOD model that is suggested by the US EPA, to the values of GRAL model, a Lagrangian particle tracking model developed in Europe, by applying the models to the existing roads of the urban areas. The result showed low relevance to the actual measurement value in the case of CALINE3 model, thus displaying a low trusted value when applying to the urban areas. In the case of using AERMOD model, the predicted values were overly expressed compared to the actual measurement value, thus leading to the need of adding a No2 conversion method to the model in the future. In the case of GRAL model, a Lagrangian particle tracking model, the relevance between the actual and predicted values were high as the model considers the surrounding topography and the buildings all together, thus confirming that the model can be used for air dispersion prediction of the roads in the urban areas. Lastly, the result of this study testing the air prediction models in Jeongneung Measuring Station points that it is necessary for the future studies to expand the testing areas and test the validity of the models continuously.

Effects of a mixture of Citri Pericarpium and Scutellariae Radix on acute reflux esophagitis in rats (진피-황금 혼합물이 급성 역류성 식도염 흰쥐에 미치는 효과)

  • Lee, Jin A;Shin, Mi-Rae;Roh, Seong-Soo;Park, Hae-Jin
    • Journal of Nutrition and Health
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    • v.54 no.3
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    • pp.321-333
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    • 2021
  • Purpose: Reflux esophagitis is a disease caused by the reflux of stomach contents and stomach acid etc. into the esophagus due to defect in the lower esophageal sphincter and is currently increasing worldwide. This study was conducted to evaluate the effect of a mixture of Citrus Reticulata and Scutellariae Radix (CS) extract on acute reflux esophagitis in rats. Methods: Rats were divided into five groups for examination: normal group (Normal, n = 8), water-treated acute reflux esophagitis rats (Control, n = 8), tocopherol 30 mg/kg body weight-treated acute reflux esophagitis rats (Toco, n = 8), CS 100 mg/kg body weight-treated acute reflux esophagitis rats (CS100, n = 8), CS 200 mg/kg body weight-treated acute reflux esophagitis rats (CS200, n = 8). The experimental groups were administrated of each treatment compounds and after 90 min, acute reflux esophagitis was induced through surgery. Rats were sacrificed 5 h after surgery. We measured the level of reactive oxygen species (ROS) in serum and analyzed the expression of nicotinamide adenine dinucleotide phosphate, inflammatory, and tight junction-related proteins by western blot in the esophageal tissues. Results: CS administration significantly protected the esophageal mucosal damage due to reflux esophagitis, and the level of ROS in the serum was significantly reduced with CS administration as compared to Control. In addition, CS administration significantly suppressed mitogen-activated protein kinase (MAPK or MAP kinase) and nuclear factor-kappa B (NF-κB) pathways and increased protein expressions of tight junction protein. Conclusion: These results suggest that the CS not only regulates the expression of inflammatory proteins by inhibiting oxidative stress, but also reduces damage to the esophageal mucosa by inhibiting the expression of tight junction proteins.

Investigation on the Preparation Method of TiO2-mayenite for NOx Removal (질소산화물 제거를 위한 TiO2-mayenite 제조 방법에 관한 연구)

  • Park, Ji Hye;Park, Jung Jun;Park, Hee Ju;Yi, Kwang Bok
    • Clean Technology
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    • v.26 no.4
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    • pp.304-310
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    • 2020
  • In order to apply a photocatalyst (TiO2) to various building materials, TiO2-mayenite was prepared in this study. The TiO2 was synthesized using the sol-gel method by fixing titanium isopropoxide (TTIP) and urea at a ratio of 1 : 1. Later, they were calcined in a temperature range of 400-700 ℃ to analyze the properties according to temperature. BET, TGA, and XRD were used to analyze the physical and chemical properties of TiO2. The nitrogen oxide removal test was confirmed by measuring the change in the concentration of NO for 1 h according to KS L ISO 22197-1. The prepared TiO2 samples exhibited an anatase crystal structure below 600 ℃, and TiO2 (urea)-400 showed the highest nitrogen oxide removal rate at 2.35 µmol h-1. TiO2-mayenite was prepared using two methods: spraying TiO2 dispersion solution (s/s) and sol-gel solution (g/s). Through BET and XRD analysis, it was found that 5-TiO2 (g/s) prepared by spraying a sol-gel solution has maintained its crystallinity even after heat treatment. Also, 5-TiO2 (g/s)-500 showed the highest removal rate of 0.55 µmol h-1 in the nitrogen oxide removal test. To prepare TiO2-mayenite, it was confirmed that mayenite should be blended with TiO2 in a sol-gel state to maintain the crystal structure and exhibit a high nitrogen oxide removal rate.

A Study on Estimating Ship's Emission in the Port Area of Mokpo Port (목포항 항만구역 내 선박 배기가스 배출량 산정에 대한 연구)

  • Bui, Hai-Dang;Kim, Hwayoung
    • Journal of Korea Port Economic Association
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    • v.39 no.3
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    • pp.47-60
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    • 2023
  • A thorough inventory of ship emissions, particularly ship's emission of in-port area is necessary to identify significant sources of exhaust gases such as NOx, SOx, PM, and CO2 and trends in emission levels over time, and reduce their serious effects on the environment and human health. Therefore, the goal of this study is to assess the volume of emissions from ships in Mokpo port, which serves as a gateway to the southwest coast of Korea, using a bottom-up methodology and data from the automatic identification system (AIS) and the Korean Port Management Information System (Port-MIS). In this work, an analysis of ship movement utilizing AIS data and an actual set of data on ship specification were gathered. By examining ship movement using AIS data, We also proposed a new approach for identifying cruising/maneuvering mode. Finally, the results were classified by ship operating mode, by exhaust gas, by ship type, and by berth, which provides a thorough and in-depth analysis of the air pollution caused by ships in Mokpo port.

Numerical Investigation of Urea Freezing and Melting Characteristics Using Coolant Heater (냉각수 순환 가열 방식을 이용한 요소수의 동결 및 해동 특성에 관한 수치적 연구)

  • Lee, Seung Yeop;Kim, Nam Il;Park, Yun Beom;Kim, Man Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.8
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    • pp.717-724
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    • 2013
  • Urea-SCR technology is known as one of the powerful NOx reduction systems for vehicles as well as stationary applications. For its consistent and reliable operation in vehicle applications, however, the freezing and melting of the urea solution in cold environments have to be resolved. In this study, therefore, a numerical study of three-dimensional unsteady problems was analyzed to understand the urea freezing and heating phenomena and heat transfer characteristics in terms of urea liquid volume fraction, temperature profiles, and phase change behavior in urea solutions with time by using the commercial software Fluent 6.3. As a result, it was found that the freezing phenomenon proceeds with a phase change from the tank wall to the center, whereas the melting phenomenon occurs faster in the upper part of the storage tank by natural convection and in the adjacent part of the coolant pipe than in other parts. Furthermore, approximately 190 s were required to obtain 1L of urea solution using a 4-coiled coolant heater under conditions of $70^{\circ}C$ and 200 L/h.

The Studies of Stability for Volatile Organic Compounds(VOCs) Generated from the Adhesives (접착제에서 발생하는 휘발성유기화합물(VOCs)에 대한 안정성 연구)

  • Lee, Hyeon Kyeong;Wi, Koang Chul
    • Journal of Conservation Science
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    • v.31 no.3
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    • pp.243-254
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    • 2015
  • In this study, the stability of the adhesive was determined through the Oddy Test that is Verification Test for potential damage by various materials. And to find the factor causing the corrosion of the metal samples, the adhesives and coatings those are usually used in the metal preservation process were selected and treated on the samples. Six kinds of adhesives and four kinds of metal specimens Fe, Pb, Cu, Ag were used. As results, the weight change showed high increasement in the rate of weight change 29.87% of Fe sample. The chromaticity measurement showed the high change value of the Cellulose-based adhesive. In case of the VOCs test from adhesive by using GC-MS, Acetic acid was detected from all six kinds of the adhesives. Compared to cellulose-based adhesives and the other adhesives, the amount of VOCs per 1mg concentration is higher than 900 times and was detected small amount of Formic acid. This is assumed to be facilitated by acid impurities and the light. This reaction was considered as the result of reducing a large amount of molecular and of generating a large amount of Nox. And thus the reacted sulfur changes was considered as the factor for causing corrosion.

Implementation of a QoS routing path control based on KREONET OpenFlow Network Test-bed (KREONET OpenFlow 네트워크 테스트베드 기반의 QoS 라우팅 경로 제어 구현)

  • Kim, Seung-Ju;Min, Seok-Hong;Kim, Byung-Chul;Lee, Jae-Yong;Hong, Won-Taek
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.48 no.9
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    • pp.35-46
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    • 2011
  • Future Internet should support more efficient mobility management, flexible traffic engineering and various emerging new services. So, lots of traffic engineering techniques have been suggested and developed, but it's impossible to apply them on the current running commercial Internet. To overcome this problem, OpenFlow protocol was proposed as a technique to control network equipments using network controller with various networking applications. It is a software defined network, so researchers can verify their own traffic engineering techniques by applying them on the controller. In addition, for high-speed packet processing in the OpenFlow network, programmable NetFPGA card with four 1G-interfaces and commercial Procurve OpenFlow switches can be used. In this paper, we implement an OpenFlow test-bed using hardware-accelerated NetFPGA cards and Procurve switches on the KREONET, and implement CSPF (Constraint-based Shortest Path First) algorithm, which is one of popular QoS routing algorithms, and apply it on the large-scale testbed to verify performance and efficiency of multimedia traffic engineering scheme in Future Internet.

A Study on Capacity of Electric Propulsion System by Load Analysis of 6,800TEU Container Ship (6,800TEU 컨테이너선의 부하분석을 통한 전기추진시스템 용량 연구)

  • Jang, Jae-Hee;Son, Na-Young;Oh, Jin-Seok
    • Journal of Navigation and Port Research
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    • v.42 no.6
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    • pp.437-445
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    • 2018
  • IMO (International Maritime Organization) has been strengthening the regulations of ship emission gas such as sulfur oxides (SOX), nitrogen oxides (NOX) and carbon dioxides (CO2) to protect the marine environment. Especially, ECA (Emission Control Area) has been set and operated in the USA and US. As a countermeasure against these environmental regulations, the demand for environmentally, friendly and highly efficient vessels has led to a growing interest in technology related research with respect to electric propulsion systems capable of reducing exhaust gas. Container ships were excluded from the application coverage of the electric propulsion systems for reasons of operation at economical speed. However, in the future, the need for electric propulsion system is expected to rise, because it is easy to monitor and control so that it can be an applicate to smart ship which are represented by fourth industrial revolution technology. In this study, research was carried out to design a generator and battery capacity through the load analysis of the 6,800TEU container ship to apply the electric propulsion system of the container ship. A capacity design based on the load analysis has an advantage that the generator can be operated in a high efficiency section through the load distribution control using the battery.

A Study on the Emission and Particulate Matter of a Heavy Duty Natural Gas Engine According to Gas Composition under certification tests (인증시험 조건에서 가스조성 변화에 따른 대형 천연가스 엔진 배기가스 및 입자상 물질 배출 특성에 관한 연구)

  • Choi, Ji-Seon;Park, Cheol-Woong;Jang, Hyoung-Jun;Kim, Chang-Gi
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.66-73
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    • 2021
  • In this study, The full load test and WHTC mode test were performed to examine the effect on a heavy duty natural gas engine according to the type of standard gas for certification to check engine performance and exhaust characteristics. Two types of standard gas (Gr, G23) and commercially available natural gas were applied as the fuel used. As a result of the test results of three natural gases with different fuel compositions, G23 with a high nitrogen content was inferior in torque, fuel consumption, and thermal efficiency conditions. In addition, when evaluated in the WHTC mode it was possible to obtain a result that satisfies the EURO VI regulation. However, compared to the other two fuels, the emission characteristics of G23 decreased CO2 and CO, but increased CH4, NOx and PN emissions.