• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.261-262
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• 2002

산업용 보일러나 발전설비와 같은 대규모 고정원에서 다량 배출되는 NOx의 제거를 위한 여러 기술 중에서 현재 암모니아를 환원제로 사용하는 선택적 촉매 환원법(Selective Catalytic Reduction : SCR)이 가장 유망하며, 많은 연구와 더불어 선진국가에서 상업화되어 조업되고 있다. SCR 공정은 시설투자와 운전비가 비교적 저렴하고 높은 NOx 전환율(90%이상)과 폐수처리 등의 후처리 공정이 필요하지 않은 장점이 있다. (중략)

• Journal of Advanced Marine Engineering and Technology
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• v.23 no.6
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• pp.755-760
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• 1999

To remove nitrogen oxides(NOx) in exhaust gas of diesel engine three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conver-sion to $NO_2$ and /or $HNO_3$ due to high activation energies for NO oxidation and reduction, NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

• Proceedings of the KIEE Conference
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• 1997.11a
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• pp.709-712
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• 1997

Selective removal of NOx by binary oxide systems of Ba-Cu and Mn-Zr was investigated. These mixed oxides were effective in removing NOx at $400^{\circ}C$ by absorption in or on the solid as nitrate. The reaction was investigated by oxidation of NO which was promoted in the presence of $O_2$ on Mn or Cu sites. Then, the oxidized species were stored in the solid as nitrate ions on Ba or Zr sites.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.434-435
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• 2000

SCR 공정은 고정원에서 발생하는 질소 화합물을 90% 이상 제거할 수 있는 방법으로 현재로서는 기술성, 경제성 및 법규제치의 만족이라는 측면에서 NOx 제거를 위한 BACT(Best Available Control Technology)로 인식되고 있다. 하지만 먼지를 포함한 배가스는 전처리를 해야하는 한계가 있다$^{3)}$ . 이에 본 연구에서는 이미 확인된 고효율의 CuO 담지 섬유형 세라믹 필터를 이용하여 먼지 주입에 따른 NOx 제거실험을 수행하였다. (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2001.11a
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• pp.411-412
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• 2001

산업용 보일러나 발전설비와 같은 대규모 고정원에서 다량 배출되는 NOx는 시정장애, 온실효과뿐만 아니라 산성비의 원인으로 작용하며, 자외선 존재 하에 산소와 결합하여 광화학 smog를 유발시키는 등 문제를 초래하고 있다. NOx 저감기술은 크게 연소전 처리와 연소후처리로 나눌 수 있는데, 연소전 처리에 의해서는 40-70% 저감효과를 얻는 것으로 알려져 있어 어떤 형태로든 연소후 처리기술의 도입이 불가피하다. (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.473-474
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• 1999

일반적으로 NOx배출은 연소과정에 의해 강력하게 지배되고 있으며, NOx 저감 기술은 1970년대 후반부터 많은 연구들이 수행되어, 그 이론들이 확립되고 있다. 석탄 연소시스템에서는 공기 다단(air staging, OFA), 연료다단(fuel staging, reburning) 및 배기가스 재순환(FGR) 등이 대표적인 NOx 저감 기술이며 [1∼4], 그 중 배기가스 재순환법은 저산소 배기가스를 연소용 공기에 재혼입시키므로써 NO의 생성속도를 저하시켜 NOx를 저감시키는 기법이다.(중략)

• 한국연소학회:학술대회논문집
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• 1998.10a
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• pp.155-164
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• 1998

Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymetric 2-D CH4 jet diffusion, partial premixed, premixed flame. Calculations were carried out twice with C2-Full Mechanism including prompt NO reaction in addition to the above C2-Thermal NO Mechanism. The role of thermal NO mechanism and prompt NO mechanism on each flame's NO production is investigated by using the numerical result. The NOx production of each flame were evaluated Quantitatively in terms of the NOx emission index

• Journal of the Korean Applied Science and Technology
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• v.37 no.4
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• pp.723-732
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• 2020

The spent RHDS (Residue HydroDeSulfurization) catalyst is deactivated mainly by deposition of various contaminants such as coke, sulfur and vanadium on the surface of catalyst. To eliminate those contaminants, the following remanufacturing process was conducted. The first, heavy oil on the surface of the spent RHDS catalyst was removed by kerosene and dehydrated. The second, the high temperature incineration was carried out to eliminate coke and sulfur components deposited on the surface of spent RHDS catalyst. The third, the excessive quantity of Vanadium deposited on the surface of catalyst was removed by leaching process as follows: ultrasonic agitation was carried out at 50℃, for 10 seconds with 0.5% and 1% oxalic acid solution. The purpose of this process is to find out regenerated RHDS catalyst can be used as SCR catalyst for NOx reduction by controlling the vanadium residual content of the regenerated RHDS catalyst through leaching process. The composition of regenerated RHDS catalyst was analyzed by XRF and the NOx reduction efficiency was also measured by continuous catalytic fixed bed reactor. As the result, regenerated catalyst, with 0.5% oxalic acid, ultrasonic agitation in 10 seconds, showed the most stable NOx reduction efficiency. Also, in comparison with commercial SCR catalyst, the NOx reduction performance of regenerated catalyst was similar to that of commercial SCR catalyst at the temperature 375℃ and higher whereas was lower than commercial SCR catalyst at the temperature range between 200~250℃. Therefore, it was confirmed that the regenerated catalyst as powder form wash coated on the surface of metal corrugated substrate can be used for commercial SCR catalyst.

• Clean Technology
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• v.29 no.4
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• pp.313-320
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• 2023

In order to increase the usability of H₂-SCR, the NOx removal characteristics with catalyst powder of PtNi/CeO₂-W-TiO₂ using Ce as a co-catalyst was synthesized and coated on a porous metal structure (PMS) were evaluated. Catalyst powder of PtNi/CeO₂-W-TiO₂(PtNi nanoparticles onto W-TiO₂, with the incorporation of ceria (CeO₂) as a co-catalysts) was synthesized and coated onto a porous metal structure (PMS) to produce a Selective Catalytic Reduction (SCR) catalyst. H₂-SCR with CeO₂ as a co-catalyst exhibited higher NOx removal efficiency compared to H₂-SCR without CeO₂. Particularly, at a 10wt% CeO₂ loading ratio, the NOx removal efficiency was highest at 90℃. As the amount of catalyst coating on PMS increased, the NOx removal efficiency was improved below 90℃, but it was decreased above 120℃. When the space velocity was changed from 4,000 h^-1 to 20,000 h^-1, the NOx removal efficiency improved at temperatures above 120℃. It was expected that the use of the catalyst could be reduced by applying the PMS with excellent specific surface area as a support.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.4
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• pp.413-418
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• 2012

A modified VIStA (Vortex Inertial Staged Air) burner has been developed and applied to a once-through type boiler. The secondary air is supplied through a swirler instead of nozzles, which stabilizes the flame and reduces carbon monoxide (CO) emissions. However, the modification increases the emission of nitrogen oxides (NOx). To balance emissions of the two pollutants, a divided flame was adopted. An air damper was installed to control the distribution of air to each combustion chamber, and three types of flame dividers were studied. The effects of the air-fuel ratio and combustion load on the NOx formation were investigated. The divided flame was found to reduce the NOx emission up to 25%, while keeping the CO to less than 10 ppm.