• Elastomers and Composites
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• v.41 no.3
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• pp.172-181
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• 2006

Flame retardant synergism of phyllite was studied in ABS resins containing brominated flame retardant(tetrabromobisphenol A(TBBA) or brominated epoxy oligomer(BEO)) and antimony trioxide($Sb_2O_3)$. Talc was used for the comparison purpose. ABS compounds were manufactured by a twin-screw co-rotating extruder and subsequently injection molded into several specimen for mechanical and thermal properties. Flame retardancy of ABS compounds measured by UL 94 vertical test with 1.6 mm thick bar specimen was enhanced by the replacement of antimony trioxide into phyllite or talc in the range of 12.5%(0.5 wt%) to 37.5%(1.5 wt%). Phyllite showed better synergistic effect comparing with talc especially for BEO. Only phyllite enhanced the flowability of ABS compounds. Notched Izod impact strength decreased with the proportion of phyllite or talc content. Phyllite could replace the antimony trioxide up to the content of 25%(1 wt%) to give better flame retardancy and flowability without darkening problem.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.2
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• pp.1216-1221
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• 2014

Poly(ethylene-co-isosorbide terephthalate) (PEIT) is interest in polymer which has isosorbide monomer that is renewable resources such as corn. However, there is important drawback which is low mechnical properties as increasing isosorbide contents. In this study, polycarbonate used to make up for drawback of mechanical properties of PEIT. In addition, PEIT used to improve the tensile elongation of polycarbonate because PEIT has good sheet proccessability. The effect of polycarbonate on morphology, thermal and mechanical properties were investigated using FE-SEM, DMA, TGA, UTM, and notched izod impact strength tester. As a result of this study, PEIT/PC blends were in compatible system and polycarbonate can act as an improvement of thermal stability and mechanical properties in the blends.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.7
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• pp.4081-4086
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• 2014

Cellulose acetate butyrate (CAB) is a biodegradable resin with excellent optical properties, but it is difficult to apply film process. In this study, an attempt was made to improve the processability of CAB using polyactic acid and the mechanical properties using an impact modifier. Polylacitc acid (PLA)/Cellulose acetate butyrate (CAB) blends with an impact modifier were prepared using a twin screw extruder. The temperature range was $140^{\circ}C$ to $200^{\circ}C$, and the screw speed was fixed to 200 rpm. To evaluate the miscibility of impact modified CAB/PLA, the glass transition behavior and morphology were observed by DSC and FE-SEM. The mechanical properties were investigated by dynamic mechanical analysis (DMA) and a Universal Testing Machine (UTM). In addition, the effect of an impact modifier in the polymer matrix was determined using a notched Izod impact strength tester. Finally, the PLA/CAB/impact modifier 75/25/10 ratio was found to be a compatible system. In the 10wt.% impact modifier, the sample had a 4 times higher izod impact strength than the non-toughening composition.

• Elastomers and Composites
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• v.46 no.4
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• pp.335-342
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• 2011

The virgin and recycled polyethylene composites with various ratio of fly ash were manufactured by using a fully intermeshing co-rotating twin screw extruder for the reuse of fly ash from power plant and post-consumed polyethylene. Fly ash were blended with virgin HDPE and recycled polyethylene at the weight fraction of 0 to 40 wt.%. Mechanical properties such as yield strength, abrasion resistance, and slow crack resistance were measured with ISO and ASTM standards. The experimental results for the various composites showed that the elongation at break and the yield stress of the composites decreased with increasing fly ash contents. Generally, the abrasion resistance of PEs decreased with increasing sandpaper grits but the abrasion resistance of the composites increased with fly ash content at finer abrasive surface. The slow crack growth resistance of virgin HDPE, recycled JRPE and the JRPE composite showed higher slow crack growth resistance up to 50% of load at notch depth of 20% and 30%, but KRPE and the KRPE composite showed much lower resistance than virgin HDPE, JRPE and the JRPE composite. Time to break, measured with NCLS test method, of all PEs and the composites satisfies the regulation of Korean Industrial Specification for sewer pipe and support application.