• 한국연소학회지
• /
• 제20권4호
• /
• pp.34-41
• /
• 2015

Oxy-methane nonpremixed flames diluted with $CO_2$ were investigated to clarify impact of radiation heat loss and chemical effects of additional $CO_2$ to oxidizer stream on flame extinction. Flame stability maps were presented with functional dependencies of critical diluents mole fraction upon global strain rate at several oxidizer stream temperatures in $CH_4-O_2/N_2$, $CH_4-O_2/CO_2$, and $CH_4-O_2/CO_2/N_2$ counterflow flames. The effects of radiation heat loss on the critical diluent mole fractions for flame extinction are not significant even at low strain rate in nonpremixed $CH_4-O_2/N_2$ diffusion flame, whereas those are significant at low strain rate and are negligible at high strain rate (> $200s^{-1}$) in $CH_4-O_2/CO_2$ and $CH_4-O_2/CO_2/N_2$ counterflow flames. Chemical effects of additional $CO_2$ to oxidizer stream on the flame extinction curves were appreciable in both $CH_4-O_2/CO_2$ and $CH_4-O_2/CO_2/N_2$ flames. A scaling analysis based on asymptotic solution of stretched flame extinction was applied. A specific radical index, which could reflect the OH population in main reaction zone via controlling the mixture composition in the oxidizer stream, was identified to quantify the chemical kinetic contribution to flame extinction. A good correlation of predicted extinction limits to those calculated numerically were obtained via the ratio between radical indices and oxidizer Lewis numbers for the target and baseline flames. This offered an effective approach to estimate extinction strain rate of nonpremixed oxy-methane flames permitting air infiltration when the baseline flame was taken to nonpremixed $CH_4-O_2/N_2$ flame.

• 대한기계학회논문집B
• /
• 제26권1호
• /
• pp.125-132
• /
• 2002

An experimental study on the characteristics of stability of propane turbulent nonpremixed jet flames discharged normal to air free-streams with uniform velocity profile is conducted. Experimental observations are focused on the flame shape, the stability considering two kinds of flame, lift-off distance, and the flame length according to velocity ratio. In order to investigate the mixing structure of the flame base at the lower limit, we employ the RMS technique and measure the species concentration by a gas chromatography. In the results of the stability curve and lifted flame, it is fecund that the dependency of nozzle diameter is closely related to the large-scale vortical structure representing counter-rotating vortices pair. Also, the detailed discussion on the phenomenon of blowout due to this large vortical motion, is provided.

• 한국연소학회지
• /
• 제16권4호
• /
• pp.38-45
• /
• 2011

Coal-derived syngas has been utilized by main fuel at IGCC power plant. Research efforts for investigating the characteristics of premixed and nonpremixed flames at gas-turbine condition have been conducted. The present study has been mainly motivated to evaluate the capability of the detailed chemical kinetics to predict the syngas laminar flame speed. Special emphasis is given to the effects of pressure, temperature, syngas composition, and dilution level on the characteristics of premixed and nonpremixed flames. The predicative capability of a number of detailed mechanism for laminar flame speed is compared to experimental data. From these results, detailed kinetics of Davis et al. and Li et al. have the best conformity with the experiments in the all the case of parametric studies.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2007년도 춘계학술대회
• /
• pp.775-778
• /
• 2007

The present study numerically investigate the detailed structure of the syngas diffusion flames. In order to realistically represent the turbulence-chemistry interaction, the transient flamelet model has been applied to simulate the combustion processes and $NO_X$ formation in the syngas turbulent nonpremixed flames. The single mixture fraction formulation is extended to account for the effects of the secondary inlet mixture. Computations are the wide range of syngas compositions and oxidizer dilutions. Based on numerical results, the detailed discussion has been made for the effects of syngas composition and oxidizer dilution on the structure of the syngas-air and syngas-oxygen turbulent nonpremixed flames.

• 한국연소학회지
• /
• 제3권2호
• /
• pp.41-50
• /
• 1998

Numerical simulations of nonpremixed $CH_4/C_2HCl_3$(Trichloroethylene, TCE)/Air flames are conducted at atmospheric pressure in order to understand the effect of hydrocabon bound chlorine on methane/air flames. A chemical kinetic mechanism is employed, the adopted scheme involving 48 gas-phase species and 445 elementray reaction steps containing 223 backward reactions. The calculated temperature, velocity, and critical strain rate are compared with the experiments for the flame (16.1% TCE by Vol.) estabilished at a strain rate of $175s^{-1}$. Whereas there is overall good agreement between predictions and the measurements, it appears that the critical strain rate is higher than measured, and some areas of further refinement in the kinetic mechanism are required.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2002년도 제24회 KOSCO SYMPOSIUM 논문집
• /
• pp.52-60
• /
• 2002

A two-dimensional direct numerical simulation is performed to investigate the flame structure of $CH_4/N_2-Air$ counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman's detailed reaction mechanism are adopted in this calculation. To quantify the strain on flame induced by a vortex, a scalar dissipation rate (SDR) is introduced. Results show that the fuel and air-side vortex cause an unsteady extinction. In this case, the flame interacting with a vortex is extinguished at much larger SDR than steady flame. It is also found that air-side vortex extinguishes a flame more rapidly than fuel-side vortex. The unsteady effect induced by flame-vortex interaction does not lead to a transient OH overshoot of the maximum steady concentration observed in experiment, while $HO_2$ radical increases more than the maximum steady concentration with increasing SDR. In addition, it is seen that NO and $NO_2$ are not sensitive to the unsteady variation of SDR.

• 한국연소학회지
• /
• 제9권2호
• /
• pp.10-17
• /
• 2004

A two-dimensional direct numerical simulation is performed to investigate the flame structure of $CH_4/N_2-Air$ counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman#s detailed reaction mechanism are adopted in this calculation. To quantify the strain on flame induced by a vortex, a scalar dissipation rate (SDR) is introduced. The results show that fuel-side and air-side vortex cause an unsteady extinction. In this case, the flame interacting with a vortex is extinguished at much larger SDR than steady flame. It is also found that air-side vortex extinguishes a flame more rapidly than fuel-side vortex. The unsteady effect induced by flame-vortex interaction does not lead to a transient OH overshoot of the maximum steady concentration observed in experiment, while $HO_2$ radical increases more than the maximum steady concentration with increasing SDR. In addition, it is seen that NO and $NO_2$ are not sensitive to the unsteady variation of SDR.

• 대한기계학회논문집B
• /
• 제26권1호
• /
• pp.94-100
• /
• 2002

The effects of periodic fuel supply on the nonpremixed flame stability and soot formation were experimentally studied. A solenoid valve was used to control the period of fuel supply. The laser induced incandescence technique was used to visualize cool: volume fraction profile. The flame base shape was changed significantly by the fuel supply period and partially by the fuel flowrates. The portion of bluish flame near the flame base became larger as the period increased. When the period was long, two flames coexisted within one period. It seemed that the characteristic of flame stability were repeated with 4.68m change of fuel supply line length. The soot mass measurements and soot volume fraction measurements revealed that the maximum suppression of soot by the perioic fuel supply was approximately 75% , which occurred when the occurred when the fuel supply period was relatively long.

• 대한기계학회논문집B
• /
• 제28권11호
• /
• pp.1407-1416
• /
• 2004

A two-dimensional direct numerical simulation was performed to investigate the flame structure of CH$_4$/$N_2$-Air counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman's detailed chemistry were adopted in this computation. The results showed that an initially flat stagnation plane, on which an axial velocity was zero, was deformed into a complex-shaped plane, and an initial stagnation point was moved far away from a vortex head when the counterflow field was perturbed by the vortex. It was noted that the movement of stagnation point could alter the species transport mechanism to the flame surface. It was also identified that the altered species transport mechanism affected the distributions of the mixture fraction and the scalar dissipation rate.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
• /
• pp.169-174
• /
• 2004

The NOx emission characteristics with oxygen enrichment in nonpremixed counterflow and coflow jet flame of $CH_4$ fuel have been investigated numerically. A small amount of nitrogen is included in oxygen-enriched combustion, in order to consider the inevitable $N_2$ contamination by air infiltration. The results show that the initial increase of NO with increasing oxygen enrichment is due to increasing temperature and residence time, while its subsequent decrease above 75% oxygen is due to decreasing the consumption rate of nitrogen. When oxygen addition exceeds 30%, Thermal NO gradually becomes the dominant production pathway and Prompt NO becomes negative pathway for net NO production rate. It is also seen that Thermal NO plays an important role in NO reduction when strain rate increase in oxygen-enriched combustion. Finally, the results of EINOx with oxygen enrichment in coflow jet flame show the similar profile with those of conterflow flame. It is confirmed that, with leakage of 1% nitrogen in the oxidizer stream, the corresponding EINOx is eight times of that emitted from regular $CH_4$/Air flame.