• Title/Summary/Keyword: Nonlinear optical properties

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Theoretical Study of the N-(2,5-Methylphenyl)salicylaldimine Schiff Base Ligand: Atomic Charges, Molecular Electrostatic Potential, Nonlinear Optical (NLO) Effects and Thermodynamic Properties

  • Zeyrek, Tugrul C.
    • Journal of the Korean Chemical Society
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    • v.57 no.4
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    • pp.461-471
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    • 2013
  • Optimized geometrical structure, atomic charges, molecular electrostatic potential, nonlinear optical (NLO) effects and thermodynamic properties of the title compound N-(2,5-methylphenyl)salicylaldimine (I) have been investigated by using ab initio quantum chemical computational studies. Calculated results showed that the enol form of (I) is more stable than keto form. The solvent effect was investigated for obtained molecular energies, hardneses and the atomic charge distributions of (I). Natural bond orbital and frontier molecular orbital analysis of the title compound were also performed. The total molecular dipole moment (${\mu}$), linear polarizability (${\alpha}$), and first-order hyperpolarizability (${\beta}$) were calculated by B3LYP method with 6-31G(d), 6-31+G(d,p), 6-31++G(d,p), 6-311+G(d) and 6-311++G(d,p) basis sets to investigate the NLO properties of the compound (I). The standard thermodynamic functions were obtained for the title compound with the temperature ranging from 200 to 450 K.

Synthesis and Nonlinear Optical Properties of 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene Derivatives

  • Cho, Bong-Rae;Kim, Young-Hoon;Son, Kyung-Wha;Khalil, Chajara;Kim, Yong-Ho;Jeon, Seung-Joon
    • Bulletin of the Korean Chemical Society
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    • v.23 no.9
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    • pp.1253-1309
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    • 2002
  • 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene derivatives have been synthesized as a new type of octupolar nonlinear optical molecules and their linear and nonlinear optical properties were determined. The λmax values increa sed with the conjugation length and as the conjugation bridge was changed from phenyl to thienyl group. For phenyl and thiophene derivatives, the b value increased with conjugation length. In contrast, the $\beta$ values of the thiophene derivatives were much smaller than the corresponding phenyl derivatives.

All-Optical Binary Full Adder Using Logic Operations Based on the Nonlinear Properties of a Semiconductor Optical Amplifier

  • Kaur, Sanmukh;Kaler, Rajinder-Singh;Kamal, Tara-Singh
    • Journal of the Optical Society of Korea
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    • v.19 no.3
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    • pp.222-227
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    • 2015
  • We propose a new and potentially integrable scheme for the realization of an all-optical binary full adder employing two XOR gates, two AND gates, and one OR gate. The XOR gate is realized using a Mach-Zehnder interferometer (MZI) based on a semiconductor optical amplifier (SOA). The AND and OR gates are based on the nonlinear properties of a semiconductor optical amplifier. The proposed scheme is driven by two input data streams and a carry bit from the previous less-significant bit order position. In our proposed design, we achieve extinction ratios for Sum and Carry output signals of 10 dB and 12 dB respectively. Successful operation of the system is demonstrated at 10 Gb/s with return-to-zero modulated signals.

Synthesis of Side-Chain Nonlinear Optical Polymers with Carbazolylnitrostilbene Chromophores

  • 김동욱;홍성일;박수영;김낙중
    • Bulletin of the Korean Chemical Society
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    • v.18 no.2
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    • pp.198-203
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    • 1997
  • Two different carbazolylnitrostilbene chromophores with second-order nonlinear optical (NLO) activity were newly synthesized by the reaction of 9-(2-hydroxyethyl)-9H-carbazol-3-carbaldehyde with 4-nitrophenylacetonitrile or 4-nitrophenylacetic acid. The NLO monomers were obtained by reaction of these chromophores with methacryloyl chloride. The side-chain nonlinear optical polymers were synthesized by the copolymerization of NLO monomer with methylmethacrylate using a free radical initiator. The chemical structures of the polymers were identified by spectroscopic means and the polymer properties such as molecular weight, Tg, solubility, UV-visible absorption, and second-harmonic generation (SHG) coefficients were investigated.

Optical Properties of Silver Particle Containing Glass (은 입자 함유 유리의 광학적 특성)

  • Choe Mun Gu;Jeong Eun Hui;Thierry Cardinal;Park Seung Han
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.10-11
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    • 2003
  • Metal nanoparticle doped glasses have various applications such as use as photochromic media for optical disk data storage, the fabrication of optical waveguides and waveguide lasers, use as all-optical switches due to their nonlinear optical properties, as well as use in the color glass recycling industry. Recently, an ultrashort pulsed laser has been used as a powerful tool to make microscopic modifications to transparent Metal nano particle doped glasses. (omitted)

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