• 한국주조공학회지
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• 제27권4호
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• pp.167-172
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• 2007

In the present study, the microstructural evolution and mechanical properties of $Al_{71.6}Ge_{28.4}$ eutectic alloy have been investigated. Stable (fcc ${\alpha}$-Al and diamond cubic ${\beta}$-Ge) and various metastable crystalline (monoclinic, rhombohedral) phases were produced by competitive phase selection during non-equilibrium processing methods i.e. melt spinning and injection casting. The as-injection casted samples containing metastable-equilibrium eutectic (${\alpha}$-Al + monoclinic) structure showed much higher strength than samples with equilibrium eutectic (${\alpha}-Al+{\beta}-Ge$) structure but plasticity disappointingly diminished. In order to endow the enhanced ductility without significant strength drop, the alloys was heat-treated at transition temperature from metastable phase to stable phase. The annealed specimen displayed the phase transformed microstructural evolution and enhanced macroscopic plasticity.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2000년도 추계학술대회 및 발표대회 강연 및 발표논문 초록집
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• pp.10-10
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• 2000

Mechanical alloying (MA) is a powder metallurgy processing technique involving cold welding, fracturing, and rewelding of powder particles in a high-energy ball mill. This has now become an established commercial technique in producing oxide dispersion strengthened (ODS) nickel- and iron-based materials. The technique of MA is also capable of synthesizing non-equilibrium phases such as supersaturated solid solutions, metastable crystalline and quasicrystalline intermetallic phases, nanostructures, and amorphous alloys. In this respect, the capabilities of MA are similar to those of another important non-equilibrium processing technique, viz, rapid quenching of metallic melts. however, the science of MA is being investigated only during the past ten years or so. The technique of mechanochemistry, on the other hand, has had a long history and the materials produced this way have found a number of technological applications, e.g., in areas such as hydrogen storage materials, heaters, gas absorber, fertilizers. catalysts, cosmetics, and waste management. The present talk will concentrate on the basic mechanisms of formation of non-equilibrium phases by the technique of MA and these aspects will be compared with those of rapid quenching of metallic melts. Additionally, the variety of technological applications of mechanically alloyed products will be highlighted.

• 소성∙가공
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• 제8권3호
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• pp.252-261
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• 1999

The 3-dimensional finite element program is developed to analyze the non-isothermal forming processes of aluminum-alloy sheet metals. Bishop's method is introduced to solve the heat balance and force equilibrium equations. Also, Barlat's non-quadratic anisotropic yield function depicts the planar anisotropy of the aluminum-alloy sheet. To find an appropriate constitutive equation, four different forms are reviewed. For the verification of the reliability of the developed program, the computational try-outs of the non-isothermal cylindrical cupping processes of AL5052-H32 and Al1050-H16 are carried out. As results, the constitutive equation relating to strain and strain-rate, in which the constants are represented by the 5th-degree polynomials of temperature, is in good agreement with measurement. The computational try-outs can predict optimal forming conditions in non-isothermal forming processes.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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• pp.5-18
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• 1996

The solid state cesium ion source os alumino-silicate based zeolite which contains cerium. The material is an ionic conductor. Cesiums are stably stored in the material and one can extract the cesiums by applying electric field across the electrolyte. Cesium ion bombardment has the unique property of producing high negative ion yield. This ion source is used as the primary source for the production of a negative ion without any gas discharge or the need for a carrier gas. The deposition of materials as an ionic species in the energy range of 1.0 to 300eV is recently recognized as a very promising new thin film technique. This energetic non-thermal equilibrium deposition process produces films by “Kinetic Bonding / Energetic Condensation" mechansim not governed by the common place thermo-mechanical reaction. Under these highly non-equilibrium conditions meta-stable materials are realized and the negative ion is considered to be an optimum paeticle or tool for the purpose. This process differs fundamentally from the conventional ion beam assisted deposition (IBAD) technique such that the ion beam energy transfer to the deposition process is directly coupled the process. Since cesium ion beam sputter deposition process is forming materials with high kinetic energy of metal ion beams, the process provider following unique advantages:(1) to synthesize non thermal-equilibrium materials, (2) to form materials at lower processing temperature than used for conventional chemical of physical vapor deposition, (3) to deposit very uniform, dense, and good adhesive films (4) to make higher doposition rate, (5) to control the ion flux and ion energy independently. Solid state cesium ion beam sputter deposition system has been developed. This source is capable of producing variety of metal ion beams such as C, Si, W, Ta, Mo, Al, Au, Ag, Cr etc. Using this deposition system, several researches have been performed. (1) To produce superior quality amorphous diamond films (2) to produce carbon nitirde hard coatings(Carbon nitride is a new material whose hardness is comparable to the diamond and also has a very high thermal stability.) (3) to produce cesiated amorphous diamond thin film coated Si surface exhibiting negative electron affinity characteristics. In this presentation, the principles of solid state cesium ion beam sputter deposition and several applications of negative metal ion source will be introduced.

• 소성∙가공
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• 제7권6호
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• pp.594-602
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• 1998

The design analysis of axisymmetric, multi-stage deep drawing dies was performed using the rigid-viscoplastic finite element formulation. In the formulation the axisymmetric CFS algorithm was employed. Hill's non-quadratic normal anisotropic yield criterion and isotropic hardening rule were considered. For trial initial displacements and tool contact points. the geometric force equilibrium method was adopted. In order to see the validity of the formulation, the multi-stage deep drawing processes of shell-cylinder front part of hydraulic booster were simulated. The simulation showed good agreements with measurments and PAM-STAMP results.

• 한국표면공학회지
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• 제34권5호
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• pp.395-402
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• 2001

An induction thermal plasma system have been newly designed for advanced operation with a pulse modulated mode to control the plasma power in time domain and to create non-equilibrium effects such as fast quenching of the plasma to produce new functional materials in high rate. The system consists of MOSFET power supply with a maximum power of 50 kW with a frequency of 460 kHz, an induction plasma torch with a 10-turns coil of 80 mm diameter and 150 mm length and a vacuum chamber. The pulse modulated plasma was successfully generated at a plasma power of 30 kW and a high pressure of 100 kPa, with taking the on and off time as 10 ms, respectively. Measurements were carried out on the time-dependent spectral lines emitted from Ar species. The dynamic behavior of plasma temperature in a pulse cycle was estimated by the Boltzmann plot and the excitation temperature of Ar atom was found to be changed periodically from around 0.5 to 1.7 eV during the cycle. Two application regions of the induction thermal plasma newly generated were introduced to material processing with high rate synthesis based on non equilibrium effects, and to the finding of new arc quenching gases coming necessary for power circuit breaker, which is friendly with earth circumstance alternative to SF6 gas.

• Steel and Composite Structures
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• 제6권5호
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• pp.417-433
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• 2006

In this paper, a non-linear structural analysis software with pro-processing and post-recessing function is proposed by the author. The software incorporating the functions of the structural analysis and geometrical design of Tensegrity structures. Using this software, Cable Dome is analyzed as a prototype, a comprehensive study on the structural behavior of Tensegrity domes is presented in detail. Design methods of Tensegrity domes were proposed. Based on the analysis, optimizing design was performed. Several new Tensegrity domes with different geometrical design scheme are proposed, the structural analysis of the new schemes is also conducted. The analysis result shows that the proposed new forms of the Tensegrity domes are reasonable for practical applications.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1292-1293
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• 2006

A non-equilibrium powder metallurgy processing such as an MA/SPS (Mechanical Alloying / Spark Plasma Sintering) process is examined in a Ti-48moll%Al. TiAl intermetallic compound is a potential light-weight/high-temperature structural material. One of the major problems, however, limiting the practical use of the material is its poor workability. From this point, the powder metallurgy (PM) processing route has been attractive alternative of the conventional processing for such material The MA/SPS process is able to apply to a LIGA process. Optimization of the pseudo-superplasticity enables to fabricate micro-parts made of fine grained ceramics composites of TiAl by the LIGA process.

• 한국레이저가공학회지
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• 제5권3호
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• pp.15-20
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• 2002

The principal obstacle to selection of a laser processing method in production is its relatively high equipment cost and the natural unwillingness of production supervision to try something new until it is thoroughly proven. The major objective of this work is focused on the combined features of gas tungsten arc and a low-power cold laser beam. In this work, the laser beam from a 7 watts carbon monoxide laser was combined with electrical discharges from a short-pulsed capacitive discharge GTA welding power supply. When the low power CO laser beam passes through a special composition shielding gas, the CO molecules in the gas absorbs the radiation, and ionizes through a process blown as non-equilibrium, vibration-vibration pumping. The resulting laser-induced plasma(LIP) was positioned between various configurations of electrodes. The high-voltage impulse applied to the electrodes forced rapid electrical breakdown between the electrodes. Electrical discharges between tungsten electrodes and aluminum sheet specimens followed the ionized path provided by LIP. The result was well-focused melted spots.

• 한국세라믹학회지
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• 제54권2호
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• pp.75-85
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• 2017

Thermoelectric is a key technology for energy harvesting and solid-state cooling by direct thermal-to-electric energy conversion (or vice versa); however, the relatively low efficiency has limited thermoelectric systems to niche applications such as space power generation and small-scale or high-density cooling. To expand into larger scale power generation and cooling applications such as ATEG (automotive thermoelectric generators) and HVAC (heating, ventilation, and air conditioning), high-performance bulk thermoelectric materials and their low-cost processing are essential prerequisites. Recently, the performance of commercial thermoelectric materials including $Bi_2Te_3$-, PbTe-, skutterudite-, and half-Heusler-based compounds has been significantly improved through non-equilibrium processing technologies for defect engineering. This review summarizes material design approaches for the formation of multi-dimensional and multi-scale defect structures that can be used to manipulate both the electronic and thermal transport properties, and our recent progress in the synthesis of conventional thermoelectric materials with defect structures is described.