• Title/Summary/Keyword: Non-destructive determination

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Data intercomparison and determination of toxic and trace elements in Algae using Instrumental Neutron Activation Analysis (중성자방사화분석에 의한 Algae중의 독성미량원소의 정량 및 실험실간 비교검증)

  • Chung, Yong-Sam;Moon, Jong-Hwa;Park, Kwang-Won;Lee, KiI-Yong;Yoon, Yoon-Yeol
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.346-353
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    • 1999
  • For the non-destructive multi-elemental analysis of environmental and biological materials, instrumental neutron activation analysis (INAA) was applied for the determination of toxic and trace elements in a set of three Algae samples provided by the International Atomic Energy Agency (IAEA). The analytical quality control was evaluated by comparing the analytical results of two standard reference materials of the National Institute of Standards and Technology (NIST); Oyster Tissue (SRM 1566a) and Citrus Leaves (SRM 1572). According to given analytical procedure, the concentration of 15-25 elements including spiked elements such as As, Cd, Cr and Hg in Algae samples were determined. To identify and validate these results, a data intercomparison program using more than 35 analytical methods in 150 laboratories was carried out and the estimated statistical data are summarized. Result of INAA is favorable, therefore, it is illustrated that can be applied for routine analysis of essential and toxic elements in algae samples as well as analytical quality assurance.

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Gamma-Ray Spectrometric Determination of Burnup Distribution and Cooling Time of Spent PWR Fuel Assemblies (감마선 분광분석에 의한 조사후 핵연료 집합체(PWR)의 연소분포 및 냉각시간 결정)

  • Young-Gil Lee;Jae-Shik Jun
    • Nuclear Engineering and Technology
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    • v.17 no.1
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    • pp.1-7
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    • 1985
  • Non-destructive gamma-ray spectrometry was carried out on the spent PWR fuel assemblies at the spent fuel pool of reactor-site. Attention was focused on the determination of burnup distribution and cooling time. For the measurement of burnup distribution, the concentration ratio of $^{134}$ Cs$^{137}$ Cs was used and the results showed these ratios varied with the positions of assemblies in the core during their irradiation. For the measurement of cooling time, $^{144}$ Ce$^{137}$ Cs was used and the results were agreed considerably well with the operator declared cooling time.

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Applications of piezoelectric sensors in geotechnical engineering

  • Zeng, Xiangwu
    • Smart Structures and Systems
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    • v.2 no.3
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    • pp.237-251
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    • 2006
  • Piezoelectric sensors have many applications in geotechnical engineering, especially in characterizing soils through measurement of wave velocities. Since mechanical properties of a material are closely associated with wave velocities, piezoelectric sensors provide a reliable and non-destructive method for the determination of soil properties. This paper presents results of recent research on measuring stiffness of a wide range of soils such as clay, sand, and gravel, characterizing anisotropic properties of soil induced by external loading, measuring stiffness of base and subgrade materials in the pavement, determining soil properties in a centrifuge model during the flight of a centrifuge, and understanding wave propagation in granular materials under micro-gravity environment using this technique.

Estimation of Aging Effects on Determination of Compressive Strength of Concrete by Non-Destructive Tests (비파괴 시험에 의한 콘크리트 압축강도 및 반발도의 재령계수 추정)

  • 김민수;윤영호;김진근;권영웅;이승석
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.782-788
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    • 2002
  • Several non-destructive test methods have been developed to estimate compressive strength of concrete in other countries. However, their applications are limited in domestic concrete due to their inaccuracies. The purpose of this study is to propose an aging coefficient of compressive strength of structural concrete in rebound number method and ultrasonic pulse velocity method for domestic concrete. The test variables include type of aggregate, curing condition, and compressive strength. Two approaches are used to estimate aging coefficient. One is evaluated by uniform linear regression equation for all ages and shows uniform strength reduction coefficient regardless of material properties and the other is evaluated by individual regression equation for each ages and shows nonuniform strength reduction and rebound increasing coefficients which decrease with increasing of rebound number and compressive strength. The latter result which can include the effect of rebound number and compressive strength is more resonable than the former.

Reliability Evaluation for Prediction of Concrete Compressive Strength through Impact Resonance Method and Ultra Pulse Velocity Method (충격공진법과 초음파속도법을 통한 콘크리트 압축강도 예측의 신뢰성 평가)

  • Lee, Han-Kyul;Lee, Byung-Jae;Oh, Kwang-Chin;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.4
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    • pp.18-24
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    • 2015
  • Non-destructive testing (NDT) methods are widely used in the construction industry to diagnose the defects/strength of the concrete structure. However, it has been reported that the results obtained from NDT are having low reliability. In order to resolve this issue, four kinds of NDT test (ultrasonic velocity measurements by P-wave and S-wave and the impact resonance methods by longitudinal vibration and deformation vibration) were carried out on 180 concrete cylinders made with two kinds of mix proportions. The reliability of the NDT results was analyzed and compared through the measurement of the actual compressive strength of the concrete cylinders. The statistical analysis of the results was revealed that the ultrasonic velocity method by S-wave is having lowest coefficient of variation and also most capable of stable observation. Analytical equations were established to estimate the compressive strength of the concrete from the obtained NDT results by relating the actual compressive strength. Moreover the equation established by the ultrasonic velocity method by S-wave had the highest coefficient of determination. Further studies on the stability of non-destructive testing depending on various mixing conditions will be necessary in the future.

Development of Models for the Prediction of Domestic Red Pepper (Capsicum annuum L.) Powder Capsaicinoid Content using Visible and Near-infrared Spectroscopy

  • Lim, Jongguk;Mo, Changyeun;Kim, Giyoung;Kim, Moon S.;Lee, Hoyoung
    • Journal of Biosystems Engineering
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    • v.40 no.1
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    • pp.47-60
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    • 2015
  • Purpose: The purpose of this study was to non-destructively and quickly predict the capsaicinoid content of domestic red pepper powders from various areas of Korea using a pungency measurement system in combination with visible and near-infrared (VNIR) spectroscopic techniques. Methods: The reflectance spectra of 149 red pepper powder samples from 14 areas of Korea were obtained in the wavelength range of 450-950 nm and partial least squares regression (PLSR) models for the prediction of capsaicinoid content were developed using area models. Results: The determination coefficient of validation (RV2), standard error of prediction (SEP), and residual prediction deviation (RPD) for the capsaicinoid content prediction model for the Namyoungyang area were 0.985, ${\pm}2.17mg/100g$, and 7.94, respectively. Conclusions: These results show the possibility of VNIR spectroscopy combined with PLSR models in the non-destructive and facile prediction of capsaicinoid content of red pepper powders from Korea.

High sensitivity determination of iridium contents in ultra-basic rocks by INAA with coincidence gamma-ray detection

  • Ebihara, Mitsuru;Shirai, Naoki;Kuwayama, Jin;Toh, Yosuke
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.423-428
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    • 2022
  • Very low contents (in the range of 10-9 g/g) of Ir in mantle-derived rock samples (komatiites) were non-destructively determined by INAA coupled with coincidence gamma-ray spectrometry using 16 Ge detectors. Aliquots of the same samples were analyzed by NiS fire-assay ICP-MS for Ir and other platinum group elements. Because the INAA procedure used in this study is non-destructive and is almost free from spectral interference in gamma-ray spectrometry, the INAA values of Ir contents obtained in this study can be highly reliable. Iridium values obtained by ICP-MS were consistent with the INAA values, implying that the ICP-MS values of Ir obtained in this study are equally reliable. Under the present experimental conditions, detection limits were estimated to be 1 pg/g, which corresponds to 0.1 pg for a sample mass of 0.1 g. These levels can be even lowered by an order of magnitude, if necessary, which cannot be achieved by ICP-MS carried out in this study.

Estimation of Moisture Content in Comminuted Miscanthus based on the Intensity of Reflected Light

  • Cho, Yongjin;Lee, Dong Hoon
    • Journal of Biosystems Engineering
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    • v.40 no.3
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    • pp.296-304
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    • 2015
  • Purpose: The balance between miscanthus production and its cost effectiveness depends greatly on its moisture content during post processing. The objective of this research was to measure the moisture content using a non-destructive and non-contact methodology for in situ applications. Methods: The moisture content of comminuted miscanthus was controlled using a closed chamber, a humidifier, a precision weigher, and a real-time monitoring software developed in this research. A CMOS sensor equipped with $50{\times}$ magnifier lens was used to capture magnified images of the conditioned materials with moisture content level from 5 to 30%. The hypothesis is that when light is incident on the comminuted particles in an inclined manner, higher moisture content results in light being reflected with a higher intensity. Results: A linear regression analysis for an initiative hypothesis based on general histogram analysis yielded insufficient correlations with low significance level (<0.31) for the determination coefficient. A significant relationship (94% confidence level) was determined at level 108 in a reverse accumulative histogram proposed based on a revised hypothesis. A linear regression model with the value at level 108 in the reverse accumulative histogram for a magnified image as the independent variable and the moisture content of comminuted miscanthus as the dependent variable was proposed as the estimation model. The calibrated linear regression model with a slope of 92.054 and an offset of 32.752 yielded 0.94 for the determination coefficient (RMSE = 0.2%). The validation test showed a significant relationship at the 74% confidence level with RMSE 6.4% (n = 36). Conclusions: To compensate the inconsistent significance between calibration and validation, an estimation model robust against various systematic interferences is necessary. The economic efficiency of miscanthus, which is a promising energy resource, can be improved by the real-time measurement of its crucial material properties.

Development of Automatic Peach Grading System using NIR Spectroscopy

  • Lee, Kang-J.;Choi, Kyu H.;Choi, Dong S.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1267-1267
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    • 2001
  • The existing fruit sorter has the method of tilting tray and extracting fruits by the action of solenoid or springs. In peaches, the most sort processing is supported by man because the sorter make fatal damage to peaches. In order to sustain commodity and quality of peach non-destructive, non-contact and real time based sorter was needed. This study was performed to develop peach sorter using near-infrared spectroscopy in real time and nondestructively. The prototype was developed to decrease internal and external damage of peach caused by the sorter, which had a way of extracting tray with it. To decrease positioning error of measuring sugar contents in peaches, fiber optic with two direction diverged was developed and attached to the prototype. The program for sorting and operating the prototype was developed using visual basic 6.0 language to measure several quality index such as chlorophyll, some defect, sugar contents. The all sorting result was saved to return farmers for being index of good quality production. Using the prototype, program and MLR(multiple linear regression) model, it was possible to estimate sugar content of peaches with the determination coefficient of 0.71 and SEC of 0.42bx using 16 wavelengths. The developed MLR model had determination coefficient of 0.69, and SEP of 0.49bx, it was better result than single point measurement of 1999's. The peach sweetness grading system based on NIR reflectance method, which consists of photodiode-array sensor, quartz-halogen lamp and fiber optic diverged two bundles for transmitting the light and detecting the reflected light, was developed and evaluated. It was possible to predict the soluble solid contents of peaches in real time and nondestructively using the system which had the accuracy of 91 percentage and the capacity of 7,200 peaches per an hour for grading 2 classes by sugar contents. Draining is one of important factors for production peaches having good qualities. The reason why one farm's product belows others could be estimated for bad draining, over-much nitrogen fertilizer, soil characteristics, etc. After this, the report saved by the peach grading system will have to be good materials to farmers for production high quality peaches. They could share the result or compare with others and diagnose their cultural practice.

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