• 한국자동차공학회논문집
• /
• 제17권1호
• /
• pp.137-145
• /
• 2009

The steady-state kinetics of the selective catalytic reduction (SCR) of $NO_X$ with $NH_3$ has been investigated over a commercial ${V_2}{O_5}/TiO_2$ catalyst. In order to account for the influence of transport effects the kinetics are coupled with a fully transient two-phase 1D+1D monolith channel model. The Langmuir-Hinshelwood (L-H) mechanism is adopted to describe the steady-state kinetic behavior of the ${V_2}{O_5}/TiO_2$ catalyst. The reaction rate expressions are based on previously reported papers and are modified to fit the experimental data. The steady-state chemical reaction scheme used in the present mathematical model has been validated extensively with experimental data of selective $NO_X$ reduction efficiency for a wide range of inlet conditions such as space velocity, oxygen concentrations, water concentration, and $NO_2/NO$ ratio. The parametric investigations are performed to examine how the $NH_3$ slip from a SCR $DeNO_X$ catalyst and the conversion of $NO_X$ are affected by the reaction temperature, $NH_3/NO_X$ feed ratio, and space velocity for feed gas compositions with $NO_2/NO_X$ ratios of 0 and 0.5.

• 공업화학
• /
• 제18권3호
• /
• pp.255-261
• /
• 2007

망간계 금속산화물을 이용한 저온 선택적 촉매 환원 반응에 대하여 연구하였다. 망간계 금속산화물은 $200^{\circ}C$ 이하의 저온에서 우수한 탈질 특성을 보인다. 온도에 따른 $NH_3/NOx$ 몰비 변화 실험을 통하여 미반응 암모니아의 배출은 몰비가 증가하고 온도가 감소할수록 증가하였으며, $NO_2$의 발생은 반대의 현상을 보였다. $NO_2$는 NO가 촉매 표면에 흡착된 후 nitrate종으로 산화되어 생성되는 것으로 보인다. 촉매 표면에 생성된 nitrate종과 흡착된 암모니아가 반응하기 때문에 $NH_3/NOx$ 몰비 1.0 이상에서도 미반응 암모니아의 배출이 없었다. 담지된 금속산화물의 영향은 Zr은 산화상태를 증가시켜 $NO_2$의 배출이 증가하였으며, Ce를 첨가시킨 경우 $NO_2$ 발생량이 감소하였다. 그러나 금속산화물의 첨가는 전체적으로 NOx 전환율을 감소시켰다

• 한국대기환경학회지
• /
• 제33권6호
• /
• pp.605-615
• /
• 2017

Efficient simultaneous reduction conditions for $NO_x$ and $NH_3$-slip was investigated in SCR (Selective Catalytic Reduction) process with load variation by applying dual catalysts (SCR catalyst, $NH_3$ decomposition catalyst) system. $N_2O$ formation characteristics were analyzed to look into possible undesirable reaction pathways. In the experiments of catalyst characteristics, various operational variables were tested for the combined catalytic system, such as $NH_3/NO_x$ ratio, temperature, oxygen concentration and $H_2O$. The reaction characteristics of $NO_x$, $NH_3$ and $N_2O$ were analyzed and optimal conditions could be evaluated for the combustion facility with varied load. In terms of $NO_x/NH_3$ simultaneous reduction and $N_2O$ formation suppression, optimal condition was considered NSR 1.2 and temperature $300^{\circ}C$. At this operational condition, $NO_x$ conversion was 98%, $NH_3$ reduction efficiency was 95%, generated $N_2O$ concentration 9.5 ppm with inlet $NO_x$ concentration of 100 ppm. In $NH_3-SCR$ process with $NH_3$ decomposition catalyst, $NO_x$ and $NH_3$ can be considered to be reduced simultaneously at limited conditions. The results of this study may be utilized as basic data at facilities requiring simultaneous $NO_x$ and $NH_3$ reduction for facilities with load variation.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회B
• /
• pp.2874-2879
• /
• 2008

The Selective catalytic reduction(SCR) system is a highly-effective device of $NO_x$ reduction for diesel engines. Generally, the ammonia($NH_3$) generated from a liquid urea-water solution is used for the reductant. The ideal ratio of $NH_3$ molecules to $NO_x$ molecules is 1:1 based on $NH_3$ consumption and having $NH_3$ available for reaction of all of the exhaust $NO_x$. However, under the too low and too high temperature condition, the $NO_x$ reduction efficiency becomes lower, due to temperature window. And space velocity also affects to $NO_x$ conversion efficiency. This paper reviews a laboratory study to evaluate the effects of $NO_x$ and $NH_3$ concentrations, gas temperature and space velocity on the $NO_x$ conversion efficiency of the SCR system. The maximum conversion efficiency of $NO_x$ was indicated when the $NH_3$ to $NO_x$ ratio was 1.2 and the space velocity was $60,000\;h^{-1}$. The results of this paper contribute to improve overall $NO_x$ reduction efficiency and $NH_3$ slip.

• Journal of Advanced Marine Engineering and Technology
• /
• 제29권3호
• /
• pp.306-312
• /
• 2005

IMO $NO_x$ levels are generally possible to meet by means of primary on-engine measures. Further significant follow-on reductions are likely to require a secondary after-treatment technique. SCR(Selective Catalytic Reduction) technology is used almost exclusively for $NO_x$ removal in stationary combustion systems. In order to develop a practical SCR system for marine application on board ship, a primary SCR system using urea was made. The SCR system was set up on the ship, 'HANNARA' as a test vessel. employed a two-stroke cycle diesel engine as main propulsion, which is a training ship of Korea Maritime University. The purpose of this paper is to report the results about the basic effects of the below system parameters, The degree of $NO_x$ removal depends on some parameters, such as the amount of urea solution added, space velocity, reaction gas temperature and activity of catalyst.

• 대한치과보철학회지
• /
• 제36권6호
• /
• pp.832-845
• /
• 1998

The purpose of this study was to compare the marginal fit of all ceramic crowns prepared from alumina slip casting, which is consistent with the conventional In-ceram system, and those fabricated from alumina tapes which is currently under development in an effort to alleviate complexities involved in the forming procedure of the In-ceram crown core. All ceramic crowns, made of In-ceram(slip casting) and alumina tapes(Doctor blade casting), were prepared with $90^{\circ}\;and\;135^{\circ}$ shoulder margins. The crowns were cemented with a glass ionomer cement and embeded in epoxy resin. The embedded crowns were sectioned faciolingually and mesiodistally and marginal discrepancies and marginal gaps were measured under the Measurescope MM II. The measurements were analyzed using Wilcoxon rank sum test and Kruskal-Wallis test and the results were as follows: 1. In the case of $90^{\circ}$ shoulder margin, the combined marginal discrepancies and marginal gaps were $78.3{\mu}m\;and\;44.4{\mu}m$ respectively, for the all ceramic crowns fabricated using the alumina tapes. In comparison, the values were $65{\mu}m\;and\;25.5{\mu}m$ for the In-ceram crowns. For the marginal gaps a statistical difference existed (p<0.05) but no significant difference was observed for the marginal discrepancy (p>0.05). 2. In the case of $135^{\circ}$ shoulder margin, the combined marginal discrepancy and marginal gaps were $82.1{\mu}m\;and\;40.2{\mu}m$ respectively, for the all ceramic crowns formed with the tapes. As compared with the marginal discrepancy and gaps of the $90^{\circ}$ shoulder margin in the fabricated from the alumina tapes, no significant statistical differencies were discerned in both cases (p>0.05). 3. There was no statistically significant difference in the fits among four locations around the margins of the all ceramic crowns fabricated using the alumina tapes. The results obtained in this study showed that the marginal fits of the glass infiltrated alumina cores fabricated from the alumina tapes are slightly higher value than those prepared using the In-ceram but the difference is within a clinically acceptable range.

• 한국자동차공학회논문집
• /
• 제22권1호
• /
• pp.174-182
• /
• 2014

Recently, not only common types of hybrid electric vehicle (HEV) such as series or parallel but many other types of HEVs including 4WD hybrid electric vehicle have been developed and released. In this study, analysis of fuel economy and driving performance for 2WD and 4WD HEV are conducted using backward simulation based on dynamic programming. To analyze the characteristics of 4WD HEV, tire slip model based on vehicle dynamics was applied to the backward simulation program. As a result, 2WD HEV shows better fuel economy than 4WD HEV because of relatively simple configuration. However, in a severe road condition, 4WD HEV shows better driving performance that 2WD HEV had about 6% of impossible time to follow the driving cycle though the 4WD HEV had no impossible time.

• Journal of the Korean Society for Industrial and Applied Mathematics
• /
• 제21권2호
• /
• pp.89-107
• /
• 2017

In this paper, we have proposed a modified Marker-And-Cell (MAC) method to investigate the problem of an unsteady 2-D incompressible flow with heat and mass transfer at low, moderate, and high Reynolds numbers with no-slip and slip boundary conditions. We have used this method to solve the governing equations along with the boundary conditions and thereby to compute the flow variables, viz. u-velocity, v-velocity, P, T, and C. We have used the staggered grid approach of this method to discretize the governing equations of the problem. A modified MAC algorithm was proposed and used to compute the numerical solutions of the flow variables for Reynolds numbers Re = 10, 500, and 50000 in consonance with low, moderate, and high Reynolds numbers. We have also used appropriate Prandtl (Pr) and Schmidt (Sc) numbers in consistence with relevancy of the physical problem considered. We have executed this modified MAC algorithm with the aid of a computer program developed and run in C compiler. We have also computed numerical solutions of local Nusselt (Nu) and Sherwood (Sh) numbers along the horizontal line through the geometric center at low, moderate, and high Reynolds numbers for fixed Pr = 6.62 and Sc = 340 for two grid systems at time t = 0.0001s. Our numerical solutions for u and v velocities along the vertical and horizontal line through the geometric center of the square cavity for Re = 100 has been compared with benchmark solutions available in the literature and it has been found that they are in good agreement. The present numerical results indicate that, as we move along the horizontal line through the geometric center of the domain, we observed that, the heat and mass transfer decreases up to the geometric center. It, then, increases symmetrically.

• Steel and Composite Structures
• /
• 제18권6호
• /
• pp.1369-1389
• /
• 2015

In order to investigate the behaviour of lying multi-stud connectors in cable-pylon anchorage zone, twenty-four push-out tests are carried out with different stud numbers and diameters. The effect of concrete block width and tensile force on shear strength is investigated using the developed and verified finite element model. The results show that the shear strength of the lying multi-stud connectors is reduced in comparison with the lying single-stud connector. The reduction increases with the increasing of the number of studs in the vertical direction. The influence of the stud number on the strength reduction of the lying multi-stud connectors is decreased under combined shear and tension loads compared with under pure shear. Yet, due to multi-stud effect, they still can't be ignored. The concrete block width has a non-negligible effect on the shear strength of the lying multi-stud connectors and therefore should be chosen properly when designing push-out specimens. No obvious difference is observed between the strength reductions of the studs with 22 mm and 25 mm diameters. The shear strengths obtained from the tests are compared with those predicted by AASHTO LRFD and Eurocode 4. Eurocode 4 generally gives conservative predictions of the shear strength, while AASHTO LRFD overestimates the shear strength. In addition, the lying multi-stud connectors with the diameters of 22 m and 25 mm both exhibit adequate ductility according to Eurocode 4. An expression of load-slip curve is proposed for the lying multi-stud connectors and shows good agreement with the test results.

• 한국지반공학회논문집
• /
• 제16권1호
• /
• pp.51-64
• /
• 2000

본 연구는 강우의 침투로 인한 불포화 토사사면의 안정 해석을 위한 절차를 제시한다. 강우 침투로 인한 사면의 거동은 흐름과 변형이 연관된 이차원 유한요소해석을 통하여 해석된다. 시간에 따른 안전율을 계산하기 위하여 유한요소 해석법을 통한 응력장(stress field)으로부터 가상활동면에 대한 안전율을 산정할 수 있도록 하는 정교한 응력적분기법을 적용하였고 기하학적으로 허용가능한 활동단면의 형상을 유지하면서 합리적으로 임계단면을 찾아가는 최적화방법을 적용함으로써 강우에 의한 토사사면의 안정성 평가 절차를 개발하였다. 또한 이를 이용하여 강우침투시 투수계수의 공간적인 변화가 불포화토사사면의 파괴 거동에 미치는 영향을 보다 공학적이고 합리적인 방법으로 연구하였다. 연구결과에 의하면 투수계수의 불균질한 분포로 인하여 강우에 의한 사면표면의 국부적인 파괴영역이 발생할 수 있고 이러한 영역이 점점 확대되어 전체적인 파괴에 이르게 된다. 그러므로 시간의존적 인 사면안정해석 문제의 경우 이러한 국부적인 파괴 영역의 영향을 더 이상 무시할 수 없다.