• Title/Summary/Keyword: No water exchange

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Evaluation of Groundwater Quality in Crystalline Bedrock Site for Disposal of Radioactive Waste (방사성폐기물 처분을 위한 결정질 기반암의 지하수 수질 평가)

  • Lee, Jeong-Hwan;Jung, Haeryong;Cheong, Jae-Yeol;Park, Joo-Wan;Yun, Si-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.4
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    • pp.275-286
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    • 2014
  • This study evaluated the evolution stage and origin of chemical components of 12 boreholes at crystalline bedrock using multivariate statistical and groundwater quality analyses. Groundwater types are mostly belonged to Na(Ca)-$HCO_3$ and Ca-$HCO_3$ types, indicating that directly reaction of cation exchange ($Ca^{2+}{\rightarrow}Na^+$) prevailed. The degree of groundwater evolution is included the range from low to intermediate stage based on field and laboratory analytical conditions. As a result of multivariate statistical analysis, a typical indicator of groundwater contamination, $NO_3$-, has the positive correlation with $Na^+$ and $Cl^-$. The origin of sea spary ($Cl^-$) has the positive correlation with $Na^+$, $SO{_4}^{2-}$, $Mg^{2+}$, and $K^+$, while not correlation with $Ca^{2+}$, $Fe^{2+}$, $HCO_3{^-}$, $F^-$, and $SiO_2$. The concentration of $Cl^-$ and $NO_3{^-}$ belongs to general quality of groundwater and not exceeds over the Korean standard for drinking water. And the negative values of saturation index of minerals are calculated with chemical components in groundwater. Therefore, most of chemical components of groundwater in the study area are originated from natural process between rock and groundwater, whereas some of components are derived from sea spary and anthropogenic sources related to agricultural activities.

Antioxidant Effects of Fermented Anchovy (멸치액젓의 항산화효과)

  • Park, Jong-Ok;Yoon, Mi-Sun;Cho, Eun-Jung;Kim, Hee-Sook;Ryu, Byung-Ho
    • Korean Journal of Food Science and Technology
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    • v.31 no.5
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    • pp.1378-1385
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    • 1999
  • The antioxidative activity of Fermented Anchovy on linoleic acid autooxidation was investigated in an aqueous system at pH 7.0. All solvent fractions from Fermented Anchovy were exhibited the strong antioxidative activity. Especially, BuOH and aqueous fractions were gained large amounts with strong antioxidative activity. Ultrafiltration, dialysis, heat treatment of aqueous fraction indicated that water-soluble antioxidants of Fermented Anchovy were heat-resistant, amino acid related compounds with smaller molecular weights than 1,000. Unbound fractions from DE-52 anion exchange chromatography were exhibited antioxidative activity with or without $15\;{\mu}M\;Fe^{+++}\;ion$. We were able to purify one methionine derivative from lots of antioxidative substances in Fermented Anchovy aqueous fraction by gel filtration, anion-exchange chromatography, TLC and HPLC, successfully. These data suggest that Fermented Anchovy aqueous fraction is a mixture of fermented small molecules with strong antioxidative activities.

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Chloride Penetration Properties of Portland Cement Mortar Substituted with Anion Exchange Resin Powder (음이온교환수지 분말이 치환된 포틀랜드 시멘트 모르타르의 염소이온 침투 특성)

  • Lee, Yun-Su;Lim, Seung-Min;Park, Jang-Hyun;Jung, Do-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.1
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    • pp.1-9
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    • 2020
  • Chloride ion, which penetrates into the cement composites from the outside, generally diffuses by the concentration gradient. Chloride ions are adsorbed by the chemical reaction with cement hydrates. Recent studies have shown that anion exchange resin (AER) powder can effectively adsorb the chloride ion in the cement composites, and thus, the cement composites containing AER have a high chloride adsorption capacity and a good resistance for chloride penetration. In this study, the chloride adsorption ability of the AER powder was investigated under the conditions of distilled water and calcium hydroxide saturated solution to determine if the AER powder is less effective to increase the chloride adsorption ability after grinding process. The chloride adsorption ability of AER powder was compared with the previous research about the chloride adsorption of AER bead. In addition, the compressive strength, chloride diffusion coefficient (using NT Build 492 method), and the chloride profile of cement mortar substituted with AER powder were investigated. There was no decrease in the chloride adsorption capacity of AER powder but increase in the kinetic property for chloride adsorption after the grinding process. The AER powder could absorb the chloride ion in the mortar quickly, and showed better chloride ion adsorption ability than the cement hydrates.

Water Quality Improvement by Natural Wetland (습지에 의한 수질개선 효과)

  • Kim, Bom-Chul;Kim, Ho-Sub;Jun, Man-Sig;Hwang, Gil-Son
    • Korean Journal of Ecology and Environment
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    • v.33 no.3 s.91
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    • pp.295-303
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    • 2000
  • The water clarification efficiency was examined in a shallow wetland where dense vegetation was formed naturally in an abandoned paddy field. And, also two enclosure experiments were carried out to measure the effects of materials exchange between sediment and the overlying water with the existence of vegetation and accumulated litter. The hydraulic retention time of wetland was regulated in 1.2 day. The removal rates of SS (56%) and $NO_3-N$ (61%) were high, considering its short retention time. However, removal efficiencies of VSS (28%), COD (14%), DOC (1%),and TP (0.2%) were relatively lower. This low removal efficiencies were thought to be due to the release of dissolved form of organic matter and phosphorus from the sediment. Most of constituents except nitrate were higher in the enclosure at the beginning of enclosure installation than that of the outflowing water from wetland. And then, it has fluctuated and decreased with time. The wetland was in equilibrium state of settling, accumulation of organic debris, and regeneration of dissolved material from sediment. So ultimately high primary production by dense vegetation in the wetland may be the reason of unfavorable or low treatment efficiency of wetland after many years of operation for wastewater treatment. However, the water quality of effluent from the wetland showed smaller variation and better condition than that of inflow, especially during storm events. It can be concluded that this wetland is suitable for the improvement of water quality from nonpoint sources.

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Genesis of Iron Ore Deposits in the south-eastern Part of Gyeongnam Porvince, Korea (경남(慶南) 동남부지역(東南部地域) 철광상(鐵鑛床)의 성인(成因)에 관(關)한 연구(硏究))

  • Woo, Young-Kyun
    • Economic and Environmental Geology
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    • v.21 no.1
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    • pp.45-56
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    • 1988
  • Many hydrothermal skarn-type iron ore deposits inchiding Mulgeum, Yangseong, Maeri and Kimhae mines are distributed in the south-eastern Gyeongnam Province, Korea. The deposits are magnetite veins which occurred in propylitized andesitic rock near the contact with late Cretaceous Masanite. Symmetrical zoned skarns are commonly developed around the magnetite veins. The order of the skarn zones from the vein is garnet-quartz skarn, epidote skarn, and epidote-orthoclase skarn. The garnets include isotropic or anisotropic andradite($Ad_{100{\sim}70}$), and the epidotes are composed of pistacite($Ps_{21-31}$). Fe contents of the epidotes generally increase toward the magnetite veins. Epidotes and garnets often show compositional variations from grain to grain, that is, their Fe and Al contents vary inversely. This suggests that the variations depend mainly upon $fo_2$ during the skarnization. Oxygen and carbon isotope analyses of minerals from andesitic rock, micrographic granite, major skarn zones and post-mineralization zones were conducted to provide the information on the formation temperature, the origin and the evolution of the hydrothermal solution forming the iron ore deposits. Becoming more distant from the ore vein, temperatures of skarn zones represent the decreasing tendency, but most ${\delta}O^{18}$ and ${\delta}O^{18}_{H_2O}$ values of skarn minerals represent no variation trend, and also the values are relatively low. Judging from all the isotopic data from the ore deposits, the major source of hydrothemal solution altering the skarn zones and precipitating the ore bodies was magmatic water derived from the more deeply seated micrographic granite. This high temperature hydrothermal solution rising through the fissures of propylitized andesitic rock was mixed with some meteoric water, and the extensive isotopic exchange occurred with the propylitized andesitic rock. During this process, the temperature and ${\delta}O^{18}_{H_2O}$ value of hydrothermal solution were lowered gradually. At the stage of iron ore precipitation, because after all the alteration was already finished, the oxygen isotopic exchange with the wall rock was nearly not taken. The relatively high ${\delta}O^{18}$ and ${\delta}O^{18}_{H_2O}$, and relatively low ${\delta}C^{13}$ values of calcites of post mineralization stage, are the results of leaching of the high ${\delta}O^{18}$ chert xenolith in the andesitic rock and low ${\delta}C^{13}$ andesitic rock.

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An evaluation of empirical regression models for predicting temporal variations in soil respiration in a cool-temperate deciduous broad-leaved forest

  • Lee, Na-Yeon
    • Journal of Ecology and Environment
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    • v.33 no.2
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    • pp.165-173
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    • 2010
  • Soil respiration ($R_S$) is a critical component of the annual carbon balance of forests, but few studies thus far have attempted to evaluate empirical regression models in $R_S$. The principal objectives of this study were to evaluate the relationship between $R_S$ rates and soil temperature (ST) and soil water content (SWC) in soil from a cool-temperate deciduous broad-leaved forest, and to evaluate empirical regression models for the prediction of $R_S$ using ST and SWC. We have been measuring $R_S$, using an open-flow gas-exchange system with an infrared gas analyzer during the snowfree season from 1999 to 2001 at the Takayama Forest, Japan. To evaluate the empirical regression models used for the prediction of $R_S$, we compared a simple exponential regression (flux = $ae^{bt}$Eq. [1]) and two polynomial multiple-regression models (flux = $ae^{bt}{\times}({\theta}{\nu}-c){\times}(d-{\theta}{\nu})^f:$ Eq. [2] and flux = $ae^{bt}{\times}(1-(1-({\theta}{\nu}/c))^2)$: Eq. [3]) that included two variables (ST: t and SWC: ${\theta}{\nu}$) and that utilized hourly data for $R_S$. In general, daily mean $R_S$ rates were positively well-correlated with ST, but no significant correlations were observed with any significant frequency between the ST and $R_S$ rates on periods of a day based on the hourly $R_S$ data. Eq. (2) has many more site-specific parameters than Eq. (3) and resulted in some significant underestimation. The empirical regression, Eq. (3) was best explained by temporal variations, as it provided a more unbiased fit to the data compared to Eq. (2). The Eq. (3) (ST $\times$ SWC function) also increased the predictive ability as compared to Eq. (1) (only ST exponential function), increasing the $R^2$ from 0.71 to 0.78.

AN ATTEMPT TO IMPROVE TIDELANDS FOR MARINE BIVALVES (1) Soil textures and chemical properties of tidelands in Kyunggi Bay (해산패류 증식을 위한 간석지 개척에 관한 연구 (1) 경기만 간석지의 토성과 화학적 조성에 관하여)

  • LEE Choonkoo;CHANG Nam Kee;LEE Jung Jae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.1 no.2
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    • pp.115-119
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    • 1968
  • 1. The basic investigations on soil textures, water holding capacity, pH, exchangeable calcium, and organic matter contents in four species bed were conducted in order to improve the natural flat for the bivalve beds. 2. It was statistically significant that there were differences in the soil textures among all beds of four species, D. japonica, C. sinensis, M. veneriformis, and T. philippin-arum. 3. There was no significant difference in water holding capacity, pH, and exchange-able calcium contents among different bivalve beds statistically, 4. It was highly significant that there were diffences in soil organic matter content among all groups of beds except that of D. japonica - C. sinensis. 5. It is considered that that soil textures and soil organic matter contents are most important factors to restrict the distribution of each species bivalve within a certain limited area of tidelands.

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Biochemical characterization of cotton stalks biochar suggests its role in soil as amendment and decontamination

  • Younis, Uzma;Athar, Mohammad;Malik, Saeed Ahmad;Bokhari, Tasveer Zahra;Shah, M. Hasnain Raza
    • Advances in environmental research
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    • v.6 no.2
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    • pp.127-137
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    • 2017
  • Cotton is the major fiber crop in Pakistan that accounts for 2% of total national gross domestic product (GDP). After picking of cotton, the dry stalks are major organic waste that has no fate except burning to cook food in villages. Present research focuses use of cotton stalks as feedstock for biochar production, its characterization and effects on soil characteristics. Dry cotton stalks collected from agricultural field of Bahauddin Zakariya University, Multan, Pakistan were combusted under anaerobic conditions at $450^{\circ}C$. The physicochemical analysis of biochar and cotton stalks show higher values of % total carbon, phosphorus and potassium concentrations in biochar as compared to cotton stalks. The concentration of nitrogen was decreased in biochar. Similarly biochar had greater values of fixed carbon that suggest its role for carbon sequestration and as a soil amendment. The fourier transformation infrared spectroscopic spectra (FTIR) of cotton stalks and biochar exposed more acidic groups in biochar as compared to cotton stalks. The newly developed functional groups in biochar have vital role in increasing surface properties, cation exchange capacity, and water holding capacity, and are responsible for heavy metal remediation in contaminated soil. In a further test, results show increase in the water holding capacity and nutrient retention by a sandy soil amended with biochar. It is concluded that cotton stalks can be effectively used to prepare biochar.

Heating Performance Characteristics of Heat Pump with VI cycle using Re-Heater and Solar-Assisted (태양열과 재열기를 사용한 VI heat pump의 성능 특성에 관한 연구)

  • Lee, Jin-Kook;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.35 no.6
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    • pp.25-33
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    • 2015
  • In this study, heating performance of the air-cooled heat pump with vapor-injection (VI) cycles, re-heater and solar heat storage tank was investigated experimentally. Devices used in the experiment were comprised of a VI compressor, re-heater, economizer, variable evaporator, flat-plate solar collector for hot water, thermal storage tank, etc. As working fluid, refrigerant R410A for heat pump and propylene glycol (PG) for solar collector were used. In this experiment, heating performance was compared by three cycles, A, B and C. In case of Cycle B, heat exchange was conducted between VI suction refrigerant and inlet refrigerant of condenser by re-heater (Re-heater in Fig. 3, No. 3) (Cycle B), and Cycle A was not use re-heater on the same operating conditions. In case of Cycle C, outlet refrigerant from evaporator go to thermal storage tank for getting a thermal energy from solar thermal storage tank while re-heater also used. As a result, Cycle C reached the target temperature of water in a shorter time than Cycle B and Cycle A. In addition, it was founded that, as for the coefficient of heating performance($COP_h$), the performance in Cycle C was improved by 13.6% higher than the performance of Cycle B shown the average $COP_h$ of 3.0 and by 18.9% higher than the performance of Cycle A shown the average $COP_h$ of 2.86. From this results, It was confirmed that the performance of heat pump system with refrigerant re-heater and VI cycle can be improved by applying solar thermal energy as an auxiliary heat source.

Effect of Ultrasonic Bath in Preparing Specimens for Transmission Electron Microscopy (전자현미경 시료 제작에 있어 Ultrasonic bath의 유용성에 관한 연구)

  • Lim, Byung-Soo;Choi, Jeung-Mok;Kang, Dae-Young
    • Applied Microscopy
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    • v.28 no.3
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    • pp.315-328
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    • 1998
  • The present study was carried out to investigate the effect of ultrasonic bath in tissue preparation for transmission electron microscopy. The method used standard reagents and media, and employed ultrasonic bath agitation to accelerate fluid exchange. The liver kidney, stomach and cardiac muscle tissues of male Sprague-Dawley rats were used for the experiment, and the experimental design was divided into 4 groups; The control group using rotators (Traditional method, 1,625 mins) and the three experimental groups using ultrasonic bath (UB) in the primary fixation through the infiltration processes (UB I; 62.5 mins, UB II; 125 mins, UB III; 250 mins). The results were as follows; 1. In the control group, tissues were easily sectioned, and showed well preserved intact membranes, and cell organelles such as mitochondria, lysosome, peroxisome, rough endoplasmic reticulum and smooth endoplasmic reticulum. 2. In the UB treated group I, tissues showed holes due to the inadequate removal of both water and fluids used in the dehydration process. Also the mitochondria of cell organelles, especially, showed swollen intracristal spaces and dense matrices due to poor fixation. 3. In the UB treated group II, tissues showed good preservation of cell organelles and specimen slice sections. Also, no holes were observed. 4. In the UB treated group III, tissues showed leaching of structural components in the cytoplasm, but no holes were observed. In conclusion, the ultrasonic bath procedure takes approximately 120 minutes from specimen fixation to resin infiltration and gives excellent results.

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