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질소와 노벡 혼합가스를 이용한 청정소화약제의 소화성능에 관한 연구 (A Study on Clean Agent Fire Extinguishing Ability Using Nitrogen and Novec Mixtures Gas)

  • 임우섭;정종진;남동군;사공성호;김종원;최근주
    • 한국안전학회지
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    • 제23권6호
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    • pp.76-83
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    • 2008
  • In the course of increasing in human and material damage caused by fire, it is an important research field to develop clean extinguishing agent which does no harm to global environment as well as has a good extinguishing efficiency. This research is a basic step to develop a new clean extinguishing agent. In order to get a satisfactory result, we tested fire extinguishing ability using nitrogen and Novec mixtures gas which are inert gas and new clean extinguishing agent. We used Cup Burner Test made by international standard ISO-14520 regulations of gaseous extinguishing agent ability test, and the fuels used in the test are n-heptane, methanol, ethanol, iso-propanol and 1-butanol. The experimental results of flame extinguishing concentration are n-heptane 6.54%, methanol 8.47%, ethanol 6.98%, isopropanol 6.10% and butanol 6.54% by pure Novec agent. So the finding is that a new clean agent, Novec has an efficient extinguishing ability in a state of gas. Also, in a test as to mixtures gas of nitrogen and Novec, it has a good result for minimum oxygen concentration is under 16%.

인도네시아 저등급 석탄의 스팀 가스화 반응성 비교 평가 (Comparative Evaluation of Steam Gasification Reactivity of Indonesian Low Rank Coals)

  • 김수현;;유지호;이시훈;임영준;임정환;김상도;전동혁;최호경
    • 한국수소및신에너지학회논문집
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    • 제27권6호
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    • pp.693-701
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    • 2016
  • Steam gasification of low rank coals is possible at relatively low temperature and low pressure, and thus shows higher efficiency compared to high rank coals. In this study, the gasification reactivity of four different Indonesian low rank coals (Samhwa, Eco, Roto, Kideco-L) was evaluated in $T=700-800^{\circ}C$. The low rank coals containing $53.8{\pm}3.4$ wt% volatile matter in proximate analysis and $71.6{\pm}1.2$ wt% carbon in ultimate analysis showed comparable gasification reactivity. In addition, $K_2CO_3$ catalyst rapidly accelerated the reaction rate at $700^{\circ}C$, and all of the coals were converted over 90% within 1 hour. The XRD analysis showed no significant difference in carbonization between the coals, and the FT-IR spectrum showed similar functional groups except for differences due to moisture and minerals. TGA results in pyrolysis ($N_2$) and $CO_2$ gasification atmosphere showed very similar behavior up to $800^{\circ}C$ regardless of the coal species, which is consistent with the steam gasification results. This confirms that the indirect evaluation of the reactivity can be made by the above instrumental analyses.

Effect of Alkali Metal Nitrates on the Ru/C-catalyzed Ring Hydrogenation of m-Xylylenediamine to 1,3-Cyclohexanebis(methylamine)

  • Kim, Young Jin;Lee, Jae Hyeok;Widyaya, Vania Tanda;Kim, Hoon Sik;Lee, Hyunjoo
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1117-1120
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    • 2014
  • Ru/C-catalyzed hydrogenation of m-xylylene diamine into 1,3-cyclohexanebis(methylamine) was greatly accelerated by the presence of $LiNO_3$, $NaNO_2$, or $NaNO_3$. It was found that the effect of the nitrate salt was significantly affected by the size of cation. The promoting effect of the nitrate salt increased with the decrease of the cation size: $LiNO_3$ ~ $NaNO_2$ > $KNO_3$ > $CsNO_3$ >> [1-butyl-3-methylimidazolium]$NO_3$. XRD analysis of the recovered catalysts after the hydrogenation reactions showed that $LiNO_3$ and $NaNO_2$ were completely transformed into LiOH and NaOH, respectively, along with the evolution of $NH_3$, while $KNO_3$ and $CsNO_3$ remained unchanged.

식품제조공장 내 공중부유미생물 오염도와 오염진균동정 (Identification and Concentration of Airborne Microbes in Food Manufacturing Plants)

  • 곽현정;이헌준;이상호;나혜진
    • 한국식품위생안전성학회지
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    • 제26권4호
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    • pp.361-365
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    • 2011
  • To evaluate the indoor air quality of food manufacturing plants, the presence of viable bacteria and fungi was assessed in the indoor air of the facilities at which 9 food items were manufactured. Air samples were collected from the general zone, low clean zone and clean zone of each factory with an air sampler, in combination with plate counts agar using for bacteria, and dichloran-glycerol agar for fungi. The samples were incubated at $25^{\circ}C$ for 4 to 7 days. After culture, the colony forming units (CFU) on each plate were counted and corrected with a positive hole conversion table. The average concentration of bacteria was $2.2{\times}10^3\;CFU/m^3$ in the general zone, $1.2{\times}10^3\;CFU/m^3$ in the low clean zone and $7.3{\times}10^2\;CFU/m^3$ in the clean zone. The average concentration of fungal microbes was $2.5{\times}10^3\;CFU/m^3$ in the general zone, $2.6{\times}10^3\;CFU/m^3$ in the low clean zone, and $2.0{\times}10^2\;CFU/m^3$ in the clean zone. No meaningful differences were detected between the general zone and the low clean zone, but the clean zone had significantly lower concentrations than the other zones. Additionally, the identification of the fungi was performed according to morphological method using a giant culture and slide culture. The fungi were identified as belonging to 18 genera, and the genera Cladosporium(33%), Penicillium(29%) and Aspergillus(26%), predominated. Aspergillus isolates were identified to species level, and A. ochraceus, a mycotoxigenic species, was identified. As part of the effort to control the quality of the indoor air of food manufacturing plants, our results show that continued studies are clearly warranted.

Effect of slag and bentonite on shear strength parameters of sandy soil

  • Sabbar, Ayad Salih;Chegenizadeh, Amin;Nikraz, Hamid
    • Geomechanics and Engineering
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    • 제15권1호
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    • pp.659-668
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    • 2018
  • A series of direct shear tests were implemented on three different types of specimens (i.e., clean Perth sand, sand containing 10, 20 and 30% bentonite, sand containing 1, 3 and 5% slag, and sand containing 10, 20 and 30% bentonite with increasing percentages of added slag (1%, 3% and 5%). This paper focuses on the shear stress characteristics of clean sand and sand mixtures. The samples were tested under different three normal stresses (100, 150 and 200 kPa) and three curing periods of no curing time, 7 and 14 days. It was observed that the shear stresses of clean sand and mixtures were increased with increasing normal stresses. In addition, the use of slag has improved the shear strength of the sand-slag mixtures; the shear stresses rose from 128.642 kPa in the clean sand at normal stress of 200 kPa to 146.89 kPa, 154 kPa and 161.14 kPa when sand was mixed with 1%, 3% and 5% slag respectively and tested at the same normal stress. Internal friction angle increased from $32.74^{\circ}$ in the clean sand to $34.87^{\circ}$, $37.12^{\circ}$ and $39.4^{\circ}$ when sand was mixed with 1%, 3% and 5% slag respectively and tested at 100, 150, and 200 kPa normal stresses. The cohesion of sand-bentonite mixtures increased from 3.34 kPa in 10% bentonite to 22.9 kPa, 70.6 kPa when sand was mixed with 20% and 30% bentonite respectively. All the mixtures of clean sand, different bentonite and slag contents showed different behaviour; some mixtures exhibited shear stress more than clean sand whereas others showed less than clean sand. The internal friction angle increased, and cohesion decreased with increasing curing time.

메탄-공기 예혼합 선회화염에서 수소첨가와 선회강도 영향에 관한 연구 (A Study on the Effects of Hydrogen Addition and Swirl Intensity in CH4-Air Premixed Swriling Flames)

  • 김한석;조주형;김민국;황정재;이원준
    • 한국수소및신에너지학회논문집
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    • 제30권6호
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    • pp.593-600
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    • 2019
  • The combustion characteristics of methane/hydrogen pre-mixed flame have been investigated with swirl stabilized flame in a laboratory-scale pre-mixed combustor with constant heat load of 5.81 kW. Hydrogen/methane fuel and air were mixed in a pre-mixer and introduced to the combustor through a burner nozzle with different degrees of swirl angle. The effects of hydrogen addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using particle image velocimetry (PIV), micro-thermocouples, various optical interference filters and gas analyzers to provide information about flow velocity, temperature distributions, and species concentrations of the reaction field. The results show that higher swirl intensity creates more recirculation flow, which reduces the temperature of the reaction zone and, consequently, reduces the thermal NO production. The distributions of flame radicals (OH, CH, C2) are dependent more on the swirl intensity than the percentage of hydrogen added to methane fuel. The NO concentration at the upper part of the reaction zone is increased with an increase in hydrogen content in the fuel mixture because higher combustibility of hydrogen assists to promote faster chemical reaction, enabling more expansion of the gases at the upper part of the reaction zone, which reduces the recirculation flow. The CO concentration in the reaction zone is reduced with an increase in hydrogen content because the amount of C content is relatively decreased.

고출력 SOEC 시스템의 매개변수 연구 (Parametric Study on High Power SOEC System)

  • 뚜안앵;김영상;잡반티엔;이동근;안국영
    • 한국수소및신에너지학회논문집
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    • 제32권6호
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    • pp.470-476
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    • 2021
  • In the near future, with the urgent requirement of environmental protection, hydrogen based energy system is essential. However, at the present time, most of the hydrogen is produced by reforming, which still produces carbon dioxide. This study proposes a high-power electrolytic hydrogen production system based on solid oxide electrolysis cell with no harmful emissions to the environment. Besides that, the parametric study and optimization are also carried to examine the effect of individual parameter and their combination on system efficiency. The result shows that the increase in steam conversion rate and hydrogen molar fraction in incoming stream reduces system efficiency because of the fuel heater power increase. Besides, the higher Faraday efficiency does not always result a higher system efficiency.

8주간 속도 기반 트레이닝이 전문 운동선수의 근력과 근 파워 능력에 미치는 영향 (The Effect of an 8-weeks Velocity-based Training on Strength and Mechanical Power of Professional Athletes)

  • Jae Ho Kim;Sukhoon Yoon
    • 한국운동역학회지
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    • 제34권1호
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    • pp.9-17
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    • 2024
  • Objective: The purpose of this study is to apply 8-week velocity-based training to domestic professional athletes and the kinematic and kinetic analysis of the 1-RM improvement of back squat and power clean, which can represent strength-power ability, to verify the effectiveness of velocity-based training in Korea and to establish a basic basis. Method: The subjects who participated in this study were 10 professional athletes from K University (age: 21.40 ± 0.97 yrs., height: 179.90 ± 3.54 cm., body mass: 71.298 ± 2.98 kg). All subjects performed back squat and power clean 1-RM before and after 8-weeks of velocity-based training. A 3-dimensional motion analysis with 8 infrared cameras and 4 channels of EMG was performed in this study. A paired t-test was used for statistical verification. The significant level was set at α=.05. Results: Both Back squat and Power Clean 1-RM showed statistically significant increases (p<.05). In the case of back squat, there was no statistically significant difference in both kinematic and kinetic variables (p>.05). In the case of Power Clean, only the quadriceps of Phase 1 showed a statistically significant decrease (p<.05). Conclusion: Domestic professional athletes can improve their strength-power ability through velocity-based training, and such training for at least 8-weeks is considered a way to improve their performance.

동이 담지된 모더나이트 상에서 NO의 분해 및 환원 반응 (Decomposition and Reduction of Nitrogen Oxide on Copper Loaded Mordenites)

  • 이창용;모용기;최고열
    • 청정기술
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    • 제8권3호
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    • pp.111-117
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    • 2002
  • 동을 담지한 모더나이트를 이용하여 고정층 연속흐름 반응기에서 NO 분해와 CO에 의한 NO 환원을 실시하였다. NO 분해에서는 많은 동함량에서 $Cu^{\circ}/HM$이 CuO/HM보다 높은 분해 활성을 나타내었다. 이것은 $Cu^{\circ}/HM$과 CuO/HM에 존재하는 $Cu^{2+}$이온의 양과 CuO의 환원성 등의 차이에 관련된다고 보인다. NO 환원에서는 적은 동함량에서 Cuo/HM이 CuO/HM보다 높은 환원 활성을 나타내었다. 이것은 $Cu^{\circ}/HM$과 CuO/HM에 존재하는 CuO의 환원성과 입자 크기 등의 차이에 관련된다고 보인다.

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빈그릇교육을 통한 대학 기숙사의 음식물쓰레기 감량효과에 대한 연구 (Effect of Clean Plate Education on Food Wastes Reduction in University Dormitory)

  • 이은경;김덕길;김승우;정신영;최광수
    • 한국환경과학회지
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    • 제21권7호
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    • pp.865-873
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    • 2012
  • Clean plate education program was applied to change students' perception on food waste in the dormitory cafeteria of T campus G university that is located in Tongyeong, in which 408 students joined the program. From survey and food waste monitoring, it was found that clean plate education program was effective to change students' perception as well as action. Half students (50.5%) answered that their eating habit changed, and among them 30.1 % students left a little food on the plate and 13.1% students left no food behind. Many students become aware of the seriousness of food waste issue (84.5%), and 44.2% students were trying to reduce leftover. Food waste generation in cafeteria was 341.9, 576.1, 344.3g/capita/day in 2005, 2007 and 2008, respectively. And this shows that food waste generations were much less than national average data except 2007. Therefore we could conclude that clean plate education program was satisfactory to change students' perception on food and to change their action, and it could be an excellent new approach to resolve a social issue caused by food waste. In order to reduce food waste generation at dormitory cafeteria, food taste and diet should be improved and students' eating habits also should be changed. For this, a practical program like clean plate education should be organized.