• Title/Summary/Keyword: Nitrous oxide ($N_2O$)

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Effect of Biochar Application on Nitrous Oxide Emission in the Soil with Different Types of Nitrogen Fertilizer During Corn (Zea may) Cultivation (옥수수 재배지 아산화질소 배출에 대한 질소비료와 바이오차 시용 효과)

  • Lee, Sun-il;Kim, Gun-yeob;Choi, Eun-jung;Lee, Jong-sik;Gwon, Hyo-Suk;Shin, Joung-du
    • Korean Journal of Environmental Agriculture
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    • v.39 no.4
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    • pp.297-304
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    • 2020
  • BACKGROUND: Emission of nitrous oxide (N2O) from the soil is expected to depend on the types of nitrogen fertilizer used. Biochar has recently been proposed as a potential mitigation of climate change by reducing the N2O emission. Although laboratory studies reported that biochar applications could reduce N2O emission, the number of field-based studies is still limited. Therefore, a field experiment was conducted to investigate the effect of biochar on N2O emission when different nitrogen fertilizers were applied in corn cultivated field. METHODS AND RESULTS: The field experiment consisted of six treatments: urea fertilizer without biochar (U), ammonium sulfate fertilizer without biochar (A), oil cake fertilizer without biochar (O), urea fertilizer with biochar (U+B), ammonium sulfate fertilizer with biochar (A+B), and oil cake fertilizer with biochar (O+B). Biochar was applied at a rate of 10 t/ha. Greenhouse gas fluxes were measured during growing seasons using static vented chambers. The cumulative N2O emissions were 0.99 kg/ha in the U, 1.23 kg/ha in the A, 3.25 kg/ha in the O, 1.19 kg/ha in the U+B, 0.86 kg/ha in the A+B, and 1.55 kg/ha in the O+B. CONCLUSION: It was found that N2O emission was related to application of both nitrogen fertilizer type and biochar. In particular, the N2O reduction effect was the highest in the corn field incorporated with biochar when oil cake was applied to the soil.

[ $N_2O-O_2$ ] INHALATION SEDATION WITH SUCTION CATHETER IN FULL MOUTH BREATHING PATIENTS (구호흡 소아환자에서 흡인도관을 이용한 $N_2O-O_2$ 진정)

  • Yoon, Hyung-Bae
    • Journal of the korean academy of Pediatric Dentistry
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    • v.26 no.4
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    • pp.589-594
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    • 1999
  • There are some problems in inhalation sedation of non-cooperative pediatric patients. Usually the pediatric patients reject the nasal hood and there's no cooperation for administration of nitrous oxide gas. In mouth breathing patient, other technics of sedation such as intravenous or oral sedation or general anesthesia were recommended. Common causes of mouth breathing are common cold, allergic rhinitis, sinus problem, anatomical disorder, and habitual mouth-breathing. However in some patient not indicated the general anesthesia and high failure rate in oral and intravenous sedation. Administration of $N_2O-O_2$ with suction catheter was applied in full mouth breathing patient. Clinically effective sedation were occurred during procedure about 45 to 55 minutes. There's no any side effects by $N_2O-O_2$ inhalation sedation. The patients awoke at the end of the procedure and received 100% oxygen for 2-3 minutes. There's still some problems in use of the suction catheter such as air pollution of operation theater and elevate arterial carbon dioxide tension.

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A Comparative Study of Gate Oxides Grown in $10%-N_2O$ and in Dry Oxygen on N-type 4H SiC

  • Cheong, Kuan-Yew;Bahng, Wook;Kim, Nam-Kyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.17-19
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    • 2004
  • The electrical properties of gate oxides grown in two different processes, which are in 10% nitrous oxide($N_2O$) and in dry oxygen, have been experimentally investigated and compared. It has been observed that the $SiC-SiO_2$ interface-trap density(Dit) measured in nitrided gate oxide has been tremendously reduced, compared to the density obtained from gate oxide grown in dry oxygen. The beneficial effects of nitridation on gate oxides also have been demonstrated in the values of total near interface-trap density and of forward-bias breakdown field. The reasons of these improvements have been explained.

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A Prospective, Randomized and Controlled Study for the Efficacy and Safety of Sedation Technique for Implant Surgery by Combining Nitrous Oxide and Intravenous Midazolam (임플란트 수술을 위한 미다졸람 정주와 아산화질소 흡입 병용 진정법의 효과와 안전성에 대한 전향적 무작위 대조군 연구)

  • Jeon, Seung-Hwan;Chung, Shin-Hye;Kim, Kwang-Soo;Jun, Sang-Ho;Hwang, Kyung-Gyun;Park, Chang-Joo
    • Journal of The Korean Dental Society of Anesthesiology
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    • v.12 no.2
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    • pp.69-74
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    • 2012
  • Background: The purpose of this study is to investigate the efficacy and safety of the sedation technique for implant surgery by combining the use of inhalation of nitrous oxide/oxygen with intravenous midazolam. Methods: Patients requiring surgery for the placement of dental implants were randomly allocated to two groups receiving intravenous midazolam or a combined technique using nitrous oxide/oxide and intravenous midazolam. Safety parameters, cooperation scores, anxiety scales, total amount of midazolam administered and recovery time were recorded and compared. Results: There were a statistically significant reduction in the amount of midazolam required to achieve optimal sedation (P<0.01), an overall significant reduction in recovery time (P<0.01), a significant reduction in anxiety scales (P<0.05), and a significant improvement in cooperation (P<0.05) and peripheral oxygen saturation (P<0.05) when a combined technique of inhalational $N_2O/O_2$ and midazolam was used. Conclusions: For implant surgery, this combining sedation technique could be safe and reliable, demonstrating reduction of total dose of midazolam and level of patient's anxiety and improvement in patient's recovery and cooperation.

Emission of Greenhouse Gases from Upland Rice and Soybean (밭벼와 콩 재배지의 온실가스 배출)

  • Shin, Yong-Kwang;Ahn, Jong-Woong;Koh, Mun-Hwan;Shim, Jae-Chun
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.4
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    • pp.256-262
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    • 2003
  • The emission of methane and nitrous oxide was measured from fields of upland rice and soybean. Rice cultivar, Daejinbyeo, was seeded in a row of 30 cm space in upland soil on April 28, 2001. The fields were irrigated with sprinkler irrigation or natural precipitation. Three soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong, were sown with seeding space of $60{\times}15cm$ on June 16, 2001. Gas samples were collected twice a week during the growth period, and methane and nitrous oxide were analyzed. Methane emission from upland rice field of sprinkler irrigation was $3.5kg\;CH_4\;ha^{-1}$. However, negative emission of methane, $-1.7kg\;CH_4\;ha^{-1}$, was observed in upland rice field of natural precipitation. Total nitrous oxide emission from upland rice field of sprinkler irrigation was $50.8kg\;N_2O\;ha^{-1}$, while the emission in the field of natural precipitation was $8.3kg\;N_2O\;ha^{-1}$. Global warming potentials (GWP) in the upland rice fields of sprinkler irrigation and natural precipitation were 15,822 and $2,216kg\;CO_2\;ha^{-1}$, respectively. Methane emissions from fields of soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong were -14.7, -4.3 and $4.8kg\;CH_4\;ha^{-1}$, respectively. Total nitrous oxide emissions from fields of soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong were 4.7, 4.6 and $3.0kg\;N_2O\;ha^{-1}$, respectively. Total GWPs for soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong were 1152, 1323 and $1027kg\;CO_2\;ha^{-1}$, respectively.

A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas (고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구)

  • Lee, Han Min;Yun, Jae Geun;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

Nitrogen Dynamics in Soil Amended with Different Rate of Nitrogen Fertilizer

  • Kim, Sung Un;Choi, Eun-Jung;Jeong, Hyun-Cheol;Lee, Jong-Sik;Lee, Hyun Ho;Park, Hye Jin;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.574-587
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    • 2017
  • Excessive application of nitrogen (N) fertilizer to support switchgrass growth for bioenergy production may cause adverse environmental effects. The objective of this study was to determine optimum N application rate to increase biomass yield of switchgrass and to reduce adverse environmental effects related to N. Switchgrass was planted in May 2008 and biomass yield, N uses of switchgrass, nitrate ($NO_3$) leaching, and nitrous oxide ($N_2O$) emission were evaluated from 2010 through 2011. Total N removal significantly increased with N rate despite the fact that yield did not increased with above $56kg\;N\;ha^{-1}$ of N rate. Apparent nitrogen recoveries were 4.81 and 5.48% at 56 and $112kg\;N\;ha^{-1}$ of N rate, respectively. Nitrogen use efficiency decreased into half with increasing N rate from 56 to $112kg\;N\;ha^{-1}$. Nitrate leaching and $N_2O$ emission were related to N use of switchgrass. There was no significant difference of cumulative $NO_3$ leaching between 0 and $56kg\;N\;ha^{-1}$ but, it significantly increased at $112kg\;N\;ha^{-1}$. There was no significant difference of cumulative $N_2O$ emission among N rates in crest, but it significantly increased at $112kg\;N\;ha^{-1}$ in toe. Excessive N application rate (above $56kg\;N\;ha^{-1}$) beyond plant requirement could accelerate $NO_3$ leaching and $N_2O$ emission in switchgrass field. Overall, $56kg\;N\;ha^{-1}$ might be optimum N application rate in reducing economic waste on N fertilizer and adverse environmental impacts.

Influence of oxytetracycline on the fate of Nitrogen species in a recirculating aquaculture system

  • Medriano, Carl A.D.;Yoon, Hyojik;Chandran, Kartik;Khanal, Samir.K.;Lee, Jaewoo;Cho, Yunchul;Kim, Sungpyo
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.123-128
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    • 2018
  • Common aquaculture practices include the use of certain pharmaceuticals such as antibiotics in avoiding diseases and promoting a healthier growth of the culture. The aim of this study is to monitor and assess the influence of different low oxytetracycline concentrations on the transformation of nitrogen compounds under aeration condition in a lab-scale recirculating aquaculture system (RAS). Over $1mg\;L^{-1}$ dose of oxytetracycline to aquaculture had induced ammonia($NH_4-N$), nitrate($NO_3-N$), soluble COD accumulation in RAS. In addition, nitrous oxide ($N_2O$) emission from RAS was significantly reduced during the oxytetracycline dose periods. After ceasing the dose of oxytetracycline, ammonia oxidation and nitrous oxide re-emission were observed. This observation indicated that low concentrations of oxytetracycline could affect the nitrogen species in RAS. Also, the emission mechanisms of $N_2O$ may not be only dependent on nitrification process but also dependent on denitrification process in our RAS system.

The Effect of Intracuff Pressure Adjustment on Postoperative Sore Throat and Hoarseness after Nitrous Oxide and Air Anesthesia (아산화질소(N2O)와 공기(Air)를 사용한 마취 수술의 기낭압 조정이 수술 후 인후통과 쉰목소리에 미치는 영향)

  • Gu, An Na;Yu, Mi
    • Journal of Korean Academy of Nursing
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    • v.49 no.2
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    • pp.215-224
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    • 2019
  • Purpose: To investigate the differences in postoperative sore throat and hoarseness by adjustment of endotracheal tube cuff pressure (CP) during nitrous oxide ($N_2O$) and air anesthesia. Methods: A one-equivalent control group pretest-posttest design was used. Data were collected from August 8 to October 19, 2017 and analyzed using the independent t-test and repeated measures ANOVA. Eighty-four participants were enrolled and divided into three groups: 28 in the Control Group (CP adjusted every 30 minutes using $N_2O$), 28 in Experimental Group 1 (CP adjusted every 10 minutes using $N_2O$), and 28 in Experimental Group 2 (non-adjusted CP using air), all of whom underwent urologic, gynecologic, and orthopedic surgeries at the G University hospital. Sore throat was assessed using a numeric rating scale; hoarseness was evaluate using the Stout classification at 1, 6, and 24 hours after surgery. Results: Scores for sore throat and hoarseness were significantly different between the groups at each measurement time, and scores were consistently higher in the control group. During subsequent measurements, sore throat and hoarseness scores were significantly lower at 6 hours. Cuff pressure changed significantly using air anesthesia (${\chi}^2=10.41$, p=.015) up to 2 hours after induction. Severe sore throat and hoarseness was observed for up to 6 hours after surgery. Conclusion: Cuff pressure adjustment at short time intervals would be helpful in reducing postoperative sore throat and hoarseness. Nursing intervention focused on prevention of sore throat and hoarseness should be required up to 6 hours postoperatively in patients undergoing endotracheal intubation.

Theoretical Study of the Interaction of N2O with Pd(110)

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2369-2376
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    • 2007
  • N2O has been found from experimental and theoretical considerations to bind on-top to the Pd(110) surface in a tilted end-on fashion via its terminal N atom. We use a frontier orbital description of the bonding interactions in the Pd-N2O system to obtain molecular insight into the catalytic mechanism of the activation of N2O by the Pd(110) surface giving rise to the formation of N2 and O on the surface. For the tilted end-on N2O binding mode, the LUMO 3π of N2O has good overlap with the Pd dσ and dπ orbitals which can serve as the electron donors. The donor-acceptor orbital overlap is favorable for electron transfer from Pd to N2O and is expected to dominate the surface reaction pathway of N2O decomposition.