• Title/Summary/Keyword: Nitrogen storage

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Evaluation of Hydrogen Storage Performance of Nanotube Materials Using Molecular Dynamics (고체수소저장용 나노튜브 소재의 분자동역학 해석 기반 성능 평가)

  • Jinwoo Park;Hyungbum Park
    • Composites Research
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    • v.37 no.1
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    • pp.32-39
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    • 2024
  • Solid-state hydrogen storage is gaining prominence as a crucial subject in advancing the hydrogen-based economy and innovating energy storage technology. This storage method shows superior characteristics in terms of safety, storage, and operational efficiency compared to existing methods such as compression and liquefied hydrogen storage. In this study, we aim to evaluate the solid hydrogen storage performance on the nanotube surface by various structural design factors. This is accomplished through molecular dynamics simulations (MD) with the aim of uncovering the underlying ism. The simulation incorporates diverse carbon nanotubes (CNTs) - encompassing various diameters, multi-walled structures (MWNT), single-walled structures (SWNT), and boron-nitrogen nanotubes (BNNT). Analyzing the storage and effective release of hydrogen under different conditions via the radial density function (RDF) revealed that a reduction in radius and the implementation of a double-wall configuration contribute to heightened solid hydrogen storage. While the hydrogen storage capacity of boron-nitrogen nanotubes falls short of that of carbon nanotubes, they notably surpass carbon nanotubes in terms of effective hydrogen storage capacity.

The Energy Flow and Mineral Cycles in a Zoysia japonica and a Miscanthus sinensis Ecosystem on Mt. Kwanak 3. The Cycles of Nitrogen (관악산의 잔디와 억새 생태계에 있어서 에너지의 흐름과 무기물의 순환 3.질소의 순환)

  • 장남기;김정석;강경미
    • Asian Journal of Turfgrass Science
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    • v.9 no.4
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    • pp.265-273
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    • 1995
  • This investigation is carried out to clarify the cycles of nitrogen in the grassland ecosystems of Zoysia japonica and a Miscanthus sinensis on Mt. Kwanak. The hasic differential equation for the rate of change of nitrogen storage is illustrated hy huild-up and turnover of organic nitrogen, particularly in the ecosystems. The turnover velocity fractions of nitrogen for the Z. japonica and M .sinensis grasslands were k= 0. 181 and k=0. 166, respectively. The times required to reach 50, 95 and 99 percent of the steady state levels and turnover values of nitrogen on the grassland floors were 3.85, 16.67 and 27.78 years in the Z japonica grassland and 4.08, 17.65 and 29.41 years in the M sinensis grassland. The amount of annual cycles of nitrogen are 560.2 g /$m^2$ in the Z.japonica grassland and 654.1 g /$m^2$ in the M. sinensis grassland. Key words : Zsysia japonica Alisca nthus sinensis, Mt. Kivanak, Nitrogen cycle.

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Relationship between the Concentration of Biogenic Amines and Volatile Basic Nitrogen in Fresh Beef, Pork, and Chicken Meat

  • Min, J.S.;Lee, S.O.;Jang, A.;Jo, C.;Park, C.S.;Lee, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.8
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    • pp.1278-1284
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    • 2007
  • Changes in the concentrations of biogenic amines (BAs) in fresh beef, pork, and chicken breast and leg were investigated during storage, and the relationship between the content of volatile basic nitrogen (VBN) and BAs was evaluated. As the storage period increased, the levels of putrescine (PUT), cadaverine (CAD) and tyramine (TYM) increased in all the meat samples, except for TYM in beef (p<0.001). The level of BAs in beef, pork and chicken changed but the extent of these changes was different among the kinds of BAs and meats. Measurement of the VBN content was confirmed as a good index for interpreting the specific BAs content in general, such as PUT, CAD, and TYM, as well as evaluating a meat's freshness during storage. However, the kinds of BAs which can be predicted from the VBN content varied in different meats (p<0.05).

Preparation of Nitrogen-doped Carbon Nanowire Arrays by Carbonization of Mussel-inspired Polydopamine

  • Oh, Youngseok;Lee, Jea Uk;Lee, Wonoh
    • Composites Research
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    • v.29 no.4
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    • pp.132-137
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    • 2016
  • Based on mussel-inspired polydopamine (PDA), a novel technique to fabricate carbon nanowire (CNW) arrays is presented for a possible use of porous carbon electrode in electrochemical energy storage applications. PDA can give more porosity and nitrogen-doping effect to carbon electrodes, since it has high graphitic carbon yield characteristic and rich amine functionalities. Using such outstanding properties, the applicability of PDA for electrochemical energy storage devices was investigated. To achieve this, the decoration of the CNW arrays on carbon fiber surface was performed to increase the surface area for storage of electrical charge and the chemical active sites. Here, zinc oxide (ZnO) nanowire (NW) arrays were hydrothermally grown on the carbon fiber surface and then, PDA was coated on ZnO NWs. Finally, high temperature annealing was performed to carbonize PDA coating layers. For higher energy density, manganese oxide ($MnO_x$) nanoparticles (NPs), were deposited on the carbonized PDA NW arrays. The enlarged surface area induced by carbon nanowire arrays led to a 4.7-fold enhancement in areal capacitance compared to that of bare carbon fibers. The capacitance of nanowire-decorated electrodes reached up to $105.7mF/cm^2$, which is 59 times higher than that of pristine carbon fibers.

Hydrogen Storage Properties of Microporous Carbon Nitride Spheres (구형의 질화탄소 마이크로세공체의 수소저장 특성)

  • Kim, Se-Yun;Suh, Won-Hyuk;Choi, Jung-Hoon;Yi, Yoo-Soo;Lee, Sung-Keun;Stucky, Galen D.;Kang, Jeung-Ku
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.744-744
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    • 2009
  • The development of safe and suitable hydrogen storage materials is one of key issues for commercializing hydrogen as an energy carrier. Carbon based materials have been investigated for many years to store hydrogen by the adsorption of the gas on the surface of the carbon structure. Recently, it is reported that carbon nitride nanobells have high hydrogen storage capacity since the nitrogen atom plays an important role on attracting hydrogen molecules. Here we report carbon nitride microporous spheres (CNMS) which have the maximum surface area of 995.3 $m^2/g$. Melamine-Formaldehyde resin is the source of carbon and nitrogen in CNMS. Most of the CNMS pores have diameters in the range of 6 to 8 A which could give a penetration energy barrier to a certain molecule. In addition, the maximum hydrogen storage capacities of carbon nitride spheres are 1.9 wt% under 77 K and 1 atm.

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Effects of Storage Duration and Temperature on the Chemical Composition, Microorganism Density, and In vitro Rumen Fermentation of Wet Brewers Grains

  • Wang, B.;Luo, Y.;Myung, K.H.;Liu, J.X.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.6
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    • pp.832-840
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    • 2014
  • This study aimed to investigate the effects of storage duration and temperature on the characteristics of wet brewers grains (WBG) as feeds for ruminant animals. Four storage temperatures ($5^{\circ}C$, $15^{\circ}C$, $25^{\circ}C$, and $35^{\circ}C$) and four durations (0, 1, 2, and 3 d) were arranged in a $4{\times}4$ factorial design. Surface spoilage, chemical composition and microorganism density were analyzed. An in vitro gas test was also conducted to determine the pH, ammonia-nitrogen and volatile fatty acid (VFA) concentrations after 24 h incubation. Surface spoilage was apparent at higher temperatures such as $25^{\circ}C$ and $35^{\circ}C$. Nutrients contents decreased concomitantly with prolonged storage times (p<0.01) and increasing temperatures (p<0.01). The amount of yeast and mold increased (p<0.05) with increasing storage times and temperatures. As storage temperature increased, gas production, in vitro disappearance of organic matter, pH, ammonia nitrogen and total VFA from the WBG in the rumen decreased (p<0.01). Our results indicate that lower storage temperature promotes longer beneficial use period. However, when storage temperature exceeds $35^{\circ}C$, WBG should be used within a day to prevent impairment of rumen fermentation in the subtropics such as Southeast China, where the temperature is typically above $35^{\circ}C$ during summer.

The Effect of Package Material and Moisture Content on Storage of Dried Persimmons at Room Temperature (포장방법 및 수분 함량이 곶감의 상온 장기 저장에 미치는 영향)

  • 이무호;이숙희
    • Food Science and Preservation
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    • v.2 no.2
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    • pp.285-291
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    • 1995
  • This study was performed to investigate the optimum moisture content and the best packaging method of dried persimmons for long term storage at room temperature. The package material to be used were 0.05mm polyethylene film, Wrap film, 0.08mm LDPE film exchanged nitrogen gas, and non package for untreated control. Before the storage, the initial moisture contents of dried persimmons were treated with 40%, 35% and 30%, respectively; 40% as traditional dryness, 35% as extending dry period one more week, and 30% as for two more weeks. The best package method was 0.08mm LDPE film exchanged nitrogen gas, and the optimum moisture control was 35%

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Investigation on the Self-Pressurization in Cryogenic Liquid Storage System (극저온 유체 저장 시스템의 압력 증가에 대한 연구)

  • Seo, Man-Su;Kim, Young-Kwon;In, Se-Hwan;Jeong, Sang-Kwon
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.142-147
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    • 2008
  • This paper reports an analysis of self-pressurization in a closed cryogenic liquid storage system and its comparison with experimental data using liquid nitrogen. Partial equilibrium model(PEM), revised thermodynamic analysis of homogeneous model, has been applied for the pressurization in a closed tank. The vapor and liquid bulk temperature and the liquid-vapor interface temperature are separately calculated as their own representative values in this analysis. The analysis results of the partial equilibrium model are compared with the experimental data and other preceding homogeneous temperature models for validation.

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Effects of Artificial Filaments Equipped in the Aeration Tank of Aerobic Fermentation System on the Removal Efficiency of Nitrogen of Swine Wastewater Containing High Nitrogen (담체설치가 고질소함유 양돈폐수의 호기발효에 미치는 영향)

  • 손경호;이상락;안정제;권윤정;정태영
    • Journal of Animal Environmental Science
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    • v.6 no.2
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    • pp.65-72
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    • 2000
  • This study was conducted to investigate the effects of artificial filaments equipped in the aeration tank of aerobic·fermentation system on the removal efficiency of swine wastes which were fermented an aerobically and thus containing high nitrogen. Two aerobic fermentation system each consist4s of 4 tanks ; storage tank, 1st and 2nd aeration tank and settling tank were run before and one or three weeks after equipment of artificial filament in the aeration tanks. Total solids concentration tended to increase by aerobic fermentation in all running periods. However, decreased(P<0.05) total nitrogen concentration was shown three weeks after the equipment of artificial filament. Ammonia nitrogen concentration also largely decreased(p<0.05) in both running periods of one and three weeks after equipment of artificial filaments. These results suggest that the artificial filaments may improve the removal efficiency of nitrogen in swine wastewater containing high nitrogen during aerobic fermentation.

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Effect of Storage Conditions on the Chemical Characteristics of Traditional Kochujang (저장조건에 따른 전통고추장의 성분 특성 변화)

  • Kim, Dong-Han;Lee, Jung-Seung;Lee, Sang-Bok
    • Korean Journal of Food Science and Technology
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    • v.34 no.3
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    • pp.466-471
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    • 2002
  • Effect of anti-microbial agents, such as alcohol, garlic, chitosan, K-sorbate, mustard, or pasteurization on the quality of traditional kochujang was investigated during storage at $30^{\circ}C$ for 24 weeks. The pH of kochujang decreased during storage and titratable acidity changed little in the group of mustard and garlic addition. Reducing sugar increased during storage, with higher values for K-sorbate of alcohol added groups than the other groups. Alcohol contents increased during storage with higher values in control or chitosan added group. Amino nitrogen contents of kochujang decreased gradually during storage and were lower in control or chitosan added group. Ammonia nitrogen contents were lower in alcohol, garlic, K-sorbate or mustard added kochujang. The content of total free amino acid increased slightly during storage and were higher in pasteurized, garlic or alcohol added kochujang. After 24 weeks of storage, the results of sensory evaluation showed K-sorbate, garlic or alcohol added kochujang were more acceptable than control in the sense of taste.