• Title/Summary/Keyword: Nitrogen recovery

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Growth and Yield of Rice Affected by Slow Release Nitrogen Fertilizer Mixed with Soil in Seedling Box and Incorporated into Paddy Soil (육묘상자와 본답에 전층시비한 완효성 질소비료가 벼의 생육과 수량에 미치는 영향)

  • Lee, Suk-Soon;Lee, Dong-Wook
    • Korean Journal of Environmental Agriculture
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    • v.20 no.4
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    • pp.218-224
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    • 2001
  • To find out the optimum level of slow release N fertilizers (MS 10, MS S10, LCU 80, and LCU 100), total amount of nitrogen required throughout the growing season were applied in the seedling box or incorporated into paddy soil. Four levels of the slow release N fertilizers (0, 6, 9 and 12 kg N/10 a) were mixed with commercial rice nursery bed soil. N release rate and electrical conductivity(EC) of the slow release fertilizers were greater in the order of MS 10 > LCU 80 ${\fallingdotseq}$ LCU 100 > MS S10 and higher as temperature increased. No seedlings were emerged in all MS 10 plots. The seedling emergence rate of LCU 80 and LCU 100 decreased as the N level increased and seedlings were wilted severely on the 13th day after sowing at 9 and 12 kg N/10 a. In MS S10 plots the emergence rate was higher than 80% at all N levels and seedling growth was normal until 30 days after sowing. Yield of rice was similar between seedling box application and soil incorporation in paddy of MS S10. Yield of rice among the 6, 9, 12 kg N/10 a of MS S10 and conventional 12 kg N/10 a of urea split application was similar, but it was significantly higher compared with no N plot. Fertilizer N recovery of MS S10 decreased as fertilizer level increased and it was significantly higher compared with conventional urea split application.

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Improved Radiochemical Yields, Reliability and Improvement of Domestic $^{18}F$-FDG Auto Synthesizer (국산 $^{18}F$-FDG Auto Sysnthesizer의 수율 향상과 성능 개선)

  • Park, Jun-Hyung;Im, Ki-Seop;Lee, Hong-Jin;Jeong, Kyung-Il;Lee, Byung-Chul;Lee, In-Won
    • The Korean Journal of Nuclear Medicine Technology
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    • v.13 no.3
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    • pp.147-151
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    • 2009
  • Purpose: 2-[$^{18}F$]Fluoro-2-deoxy-D-glucose ([$^{18}F$]FDG) particularly plays as a important role in Positron Emission Tomography (PET) imaging in nuclear medicine. Domestic [$^{18}F$]FDG auto synthesizers are installed in Seoul National University Bundang Hospital (SNUBH) at June 2008, these modules were known that it's synthetic yields were guaranteed in average $45{\pm}5%$ so far. To improve yields and convenience of domestic [$^{18}F$]FDG auto synthesizer, numerous trials in reaction time, base concentration, pressure and temperature were performed to increase [$^{18}F$]FDG yields. Materials and Methods: Several synthetic factors (temperature, time and pressure) and shortcoming were corrected based on many evaporation test. Syringe dispensing of tetra-butylammonium bicarbonate (TBAB) was replaced with micro pipette to prepare tetrabutyl ammonium fluoride salt ([$^{18}F$]TBAF). Troublesome refill of liquid nitrogen every 2 hours which was used to protect vacuum system was changed to charcoal cartridge, base guard filter. To monitor the volume of delivered $[^{18}O]OH_2$ from cyclotron by surveillance camera, we set up the volumetric vial on the cover of the module. In addition to, the recovery vial was added in [$^{18}F$]FDG production system to recover [$^{18}F$]FDG loss due to the leak of valve ($V_{13,14}$) in [$^{18}F$]FDG purification process. Results: When we used micro pipette for adding TBAB ($30\;{\mu}L$ in 12% $H_2O$ in acetonitrile), this quantitative dispensation has enabled to improve $5.5{\pm}1.7%$ residual fluorine-18 activity in fluorine separation cartridge compared to syringe adding. Besides, the synthetic yields of [$^{18}F$]FDG has increased $58{\pm}2.6%$ (n=19), $58{\pm}2.9%$ (n=14), $60%{\pm}2.5%$ (n=17) for 3 months. The life cycle of charcoal cartridge and base vacuum was 3 months prior to filling liquid nitrogen every 2 hours and additional side separator can prevent pump corrosion by organic solvent. After setting of volumetric indicator vial, the operator can easily monitor the total volume of irradiated $[^{18}O]OH_2$ from cyclotron. The recovery vial can be used for the stabilizer when an irregular [$^{18}F$]FDG loss was generated by the leak of valves ($V_{13,14}$). Conclusions: We has optimized appropriate synthetic conditions (temperature, time, pressure) in domestic [$^{18}F$]FDG auto synthesizer. In addition to, the remodeling with several accessories improve yields of domestic [$^{18}F$]FDG auto synthesizer with reliable reproducibility.

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Effects of Cooling Rates and Plunging Temperatures on Survival of Hamster Embryos (동결속도와 침지온도가 Hamster 수정란의 생존성에 미치는 영향)

  • 윤도중;이규승;박창식;서길웅
    • Korean Journal of Animal Reproduction
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    • v.11 no.3
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    • pp.161-169
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    • 1987
  • This experiment was carried out to investigate the optimal cooling rate and the plunging temperature into liquid nitrogen of the 8-cell hamster embryos. The female hamsters were induced to superovulate by intraperitoneal injection of 30 i.u. PMSG. Embryos were flushed from oviduct and uterine horn. Embryos were frozen and incubated with a modified Dulbecco's phosphate buffered saline, and equilibrated with 1.5M-dimethyl sulfoxide by a 3-step procedure. The cooling rate of samples was 1$^{\circ}C$/min from room temperature to -5$^{\circ}C$ and the samples were seeded at -5$^{\circ}C$. The plunging temperatures into liquid nitrogen were -20, -25, -30, -35, -40, -45, -50 and -55$^{\circ}C$ at 0.3$^{\circ}C$/min, 0.5$^{\circ}C$/min and 1$^{\circ}C$/min cooling rates, respectively. This mean numbers of ovulation points and recovered embryos were 59.4 and 48.4 appearing 81.6% recovery rate. The percentage of 8-cell embryos in recovered embryos was 68.2. The survival rates of embryos plunged at -45$^{\circ}C$ were 73.5% at 0.3$^{\circ}C$/min, 44.8% at 0.5$^{\circ}C$/min and 30.3% at 1$^{\circ}C$/min cooling rates, respectively. This mean numbers of ovulation points and recovered embryos were 59.4 and 48.4 appearing 81.6% recovery rate. The percentage of 8-cell embryos in recovered embryos was 68.2. The survival rates of embryos plunged at -45$^{\circ}C$ were 73.5% at 0.3$^{\circ}C$/min, 44.8% at 0.5$^{\circ}C$/min and 30.3% at 1$^{\circ}C$/min cooling rates, respectively. The survival rates at 0.3$^{\circ}C$/min were significantly high. Under the condition of 0.3$^{\circ}C$/min cooling rate, the survival rates of embryos according to the plunging temperature were 70.0% and 73.5% at -40 and -45$^{\circ}C$, and those were higher than other plunging temperatures. Under the condition of 0.5$^{\circ}C$/min and 1$^{\circ}C$/min cooling rates, the survival rates according to the plunging temperatures were lower than the cooling rate of 0.3$^{\circ}C$/min, showing the similar tendency at all the plunging temperatures. In conclusion, 8-cell hamster embryos showed the best survival rates at 0.3$^{\circ}C$/min cooling rate and -45$^{\circ}C$ plunging temperature.

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Soil Nitrogen Dynamics in Two Black Locust Stands Established on Volcano Mt. Showa-Shinzan, Northern Japan (일본(日本) 북부(北部)의 소화신산(昭和新山)의 분화후(噴火後)에 성립(成立)한 두 아카시아나무 임분(林分)의 토양중(土壤中) 질소동태(窒素動態))

  • Moon, Hyun-Shik
    • Journal of Korean Society of Forest Science
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    • v.88 no.3
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    • pp.419-427
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    • 1999
  • To clarify the soil N dynamics, the relationship between soil N and vegetation recovery after volcanic eruptions was investigated in two stands dominated by black locust(Robinia pseudo-acacia L.) on volcano Mt. Showa-Shinzan, northern Japan, from August 1999 to July 1996. No significant differences were observed between the two stands with respect to soil chemical properties and soil extractable N. At both stands, total N concentration were high in spring and declined through the summer and fall. The peaks in concentrations of extractable $NH_4{^+}$ and $NO_3{^-}$ occurred in July at both stands. $NH_4{^+}$ mineralization showed a conspicuous peak in June and July throughout the study period. Extractable $NO_3{^-}$ concentration and nitrification rates at the two stands during the study period were relatively high. Negative values for $NH_4{^+}$ mineralization at both stands were found in August. Extractable $NH_4{^+}$ and $NO_3{^-}$ concentrations were correlated positively with soil organic matter, and nitrification rates were controlled by $NH_4{^+}$ mineralization and extractable $NH_4{^+}$ concentration at both stands.

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Model Verification of Decision Assisting Nitrogen Expert System NES to Illinois Cornfields (일리노이주의 옥수수 포장에서 질소질 비료의 적정시용에 대한 전문가체계의 검증)

  • Kim, Won-Il;Jung, Goo-Bok;Huck, M.G.;Kim, Kil-Yong;Park, Ro-Dong
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.1
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    • pp.64-70
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    • 2001
  • To verify the newly developed decision assisting expert system for nitrogen fertilizer application NES to Illinois cornfields, a couple of N rate studies from Dr. Howard and five Illinois Agricultural Experiment Stations were applied. Four types of recommendations including the current Illinois recommendation, Hoeft recommendation, NES, and maximum economic recommendation were compared with each other for the crop yields, profits, recovery rate, and N losses to cornfields. The N rate of NES recommendation, considering productivity index (PI), soil organic matter content (SOM), and pre-sidedressing nitrate concentration (PSNT) level, was the lowest in comparison to those of other recommendations. However, N recovery rate in NES was generally higher and the resulting N loss was lower than others. But, adherence to the recommendations may also reduce farmers income if environmental expense did not considered. Therefore, NES will be more effective by adding the factors including environmental expense, tillage systems, crop rotation, and other agricultural management parameters.

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Urease and nitrification inhibitors with pig slurry effects on ammonia and nitrous oxide emissions, nitrate leaching, and nitrogen use efficiency in perennial ryegrass sward

  • Park, Sang Hyun;Lee, Bok Rye;Kim, Tae Hwan
    • Animal Bioscience
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    • v.34 no.12
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    • pp.2023-2033
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    • 2021
  • Objective: The present study was conducted to assess the effect of urease inhibitor (hydroquinone [HQ]) and nitrification inhibitor (dicyandiamide [DCD]) on nitrogen (N) use efficiency of pig slurry for perennial ryegrass regrowth yield and its environmental impacts. Methods: A micro-plot experiment was conducted using pig slurry-urea 15N treated with HQ and/or DCD and applied at a rate of 200 kg N/ha. The flows of N derived from the pig slurry urea to herbage regrowth and soils as well as soil N mineralization were estimated by tracing pig slurry-urea 15N, and the N losses via ammonia (NH3), nitrous oxide (N2O) emission, and nitrate (NO3-) leaching were quantified for a 56 d regrowth of perennial ryegrass (Lolium perenne) sward. Results: Herbage dry matter at the final regrowth at 56 d was significantly higher in the HQ and/or DCD applied plots, with a 24.5% to 42.2% increase in 15N recovery by herbage compared with the control. Significant increases in soil 15N recovery were also observed in the plots applied with the inhibitors, accompanied by the increased N content converted to soil inorganic N (NH4++NO3-) (17.3% to 28.8% higher than that of the control). The estimated loss, which was not accounted for in the herbage-soil system, was lower in the plots applied with the inhibitors (25.6% on average) than that of control (38.0%). Positive effects of urease and/or nitrification inhibitors on reducing N losses to the environment were observed at the final regrowth (56 d), at which cumulative NH3 emission was reduced by 26.8% (on average 3 inhibitor treatments), N2O emission by 50.2% and NO3- leaching by 10.6% compared to those of the control. Conclusion: The proper application of urease and nitrification inhibitors would be an efficient strategy to improve the N use efficiency of pig slurry while mitigating hazardous environmental impacts.

Mechanisms on Struvite Production for Nitrogen and Phosphorus Recovery (질소/인 회수를 위한 Struvite 생성 메커니즘)

  • Lee, Sang-hun
    • Resources Recycling
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    • v.28 no.3
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    • pp.15-20
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    • 2019
  • The recovery of struvite using nitrogen and phosphorus in wastewaters is useful for prevention of eutrophication and use as fertilizer, but there are theoretical and technical issues to be resolved. Through the detailed literature review, this study discusses the possible reasonable prediction of struvite formation reaction by setting a feasible reaction equation with some theoretical considerations. In a technical aspect, the purity of struvite in solid precipitates can be promoted by excluding Ca in an effective way. As for the struvite reaction prediction issue, selection of proper equilibrium reaction as well as its reaction equilibrium coefficient is significant in the neutral and basic pH regions. The equilibrium reaction agrees well with the experimental batch test results. Considering the charge balance of the ions, the pH drop along struvite formation in a diluted solution can be predicted. Also, improvement of struvite purity through elimination of Ca can be expected by providing a highly concentrated ${NH_4}^+-N$ relative to ${HPO_4}^{2-}-P$ because ${NH_4}^+$ can enhance the thermodynamic driving force toward favorable struvite formation. Even though the phosphate reacts rapidly with Ca to form a solid precipitate, the thermodynamic driving force due to the high ${NH_4}^+$ activity can dissociate the phosphate-calcium precipitates and produce struvite.

Effect of supplementary lighting on nutrient recovery of Ocimum basilicum and fishes in a polyculture aquaponic system

  • Azeezat Adenike Junaid;Mohd Salleh Kamarudin;Wahab Puteri Edaroyati;Quazim Olawale Junaid;Victor Tosin Okomoda;Mohammed Sani Isyaka;Yusuf Adewale Adejola;Danladi Mohammed Umar;Sarker Mohd Nurul Amin
    • Fisheries and Aquatic Sciences
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    • v.26 no.8
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    • pp.500-513
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    • 2023
  • The effects of prolonged photoperiod (additional night lighting) were investigated on the production of Ocimum basilicum (lemon basil) and fish/crayfish raised in a nutrient film technique aquaponic system. Hybrid lemon fin barb and red claw crayfish juveniles were co-cultured with O. basilicum and subjected to 12 h of ambient natural daylight and additional 0, 4, 8, and 12 h of night lighting for 14 weeks (two batches of 7 weeks each). The water quality parameters and the performance characteristics of the fish/crayfish/plant were evaluated, and the nutri- ent uptake (nitrogen, phosphorus, and potassium) in the system by the three organisms was also measured. The fish growth performance showed no significant differences (p > 0.05) in all the growth parameters measured across the treatments. The body proximate and nitrogen, phosphate, and potassium (NPK) composition of the fish and crayfish were not significantly (p > 0.05) different across the treatments. Similarly, there was no significant difference (p > 0.05) in the NPK uptake by the fish and crayfish across the treatments. The plant growth performance showed that there were no significant (p > 0.05) differences in the plant growth parameters measured, except for % plant height gained in the 12 h-light treatment (403.2 ± 26.0%) which was significantly (p < 0.05) higher than other treatments and cycles. Hence, this study demonstrat- ed that varying supplementary night lighting has no significant effect on the growth performance of O. basilicum, hybrid lemon fin barb, and red claw crayfish. This study, therefore, suggests that supplementary night lighting should not be considered for O. basilicum production as it does not significantly improve the performance characteristics of the plant nor the fish co-cultured with it in a polyculture aquaponic system.

Alleviation Technology of Cold Stress of Maize(Zea mays L.) by Low Temperatures Damage

  • Youngchul Yoo;Mi-jin Chae;Jeong Ju Kim;Seuk Ki Lee;AReum Han;Won Tae Jeon;Dae-Woo Lee;Beom-Young Son
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.95-95
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    • 2022
  • Maize is one of the world's three largest crops and has a long cultivation history, and is an important crop used for various purposes such as food, feed, and industrial raw materials. Recently, the agricultural environment is changing, in which the limit of cultivation of crops is shifted to the north due to the rise in temperature due to climate change. This study was conducted in experimental field of Suwon in 2022 by setting a seeding period earlier than the sowing time to establish the North Korean agricultural climatic zone and meteorological conditions. The test cultivars were silage cultivars, Kwangpyeongok and Dacheongok. As a priming test method, it was used to directly plant seeds in the field through immersion using 4mM zinc (Zn) and 2.5mM manganese (Mn), which are trace elements for seeds. The planting season was early on March 15th, April 1st, and April 15th. The number of days from sowing to silk stage of the two cultivars sown on March 15, April 1, and April 15 was 107, 93, and 85 days for Kwangpyeongok and 109, 95, and 87 days for Dacheongok, respectively. The seed priming test did not show any difference from the control group in the growth survey up to the middle stage of growth. In another test, low-temperature recovery was confirmed through nitrogen (2-5%) foliar fertilization after 3 days, 5 days, and 7 days in refrigeration (0 degrees), a selective low temperature treatment for com in the third leaf stage. As a result of this study, it was confirmed that the low-temperature damaged com treated at 0℃ showed the same growth as that of the untreated com through nitrogen foliar fertilization. These results suggest that urea foliar fertilization for low-temperature damage reduction of corn for silage in high-latitude climates will be helpful. In addition, through the results of the study, additional studies are needed on the recovery mechanism and field application through urea foliar fertilization.

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Overall Performance characteristic for 300MW Taean IGCC Plant (300MW 태안 IGCC 플랜트 종합성능 특성)

  • Kim, Hakyong;Kim, Jaehwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.129.2-129.2
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    • 2010
  • As a part of the government renewable energy policy, KOWEPO is constructing 300MW IGCC plant in Taean. IGCC plant consists of gasification block, air separation unit and power block, which performance test is separately conducted. Overall performance test for IGCC plant is peformed to comply with ASME PTC 46. Major factors affected on the overall efficiency for IGCC plant are external conditions, each block performance(gasification, ASU, power block), water/steam integration and air integration. Performance parameters of IGCC plant are cold gas efficiency, oxygen consumption, sensible heat recovery of syngas cooler for gasification block and purity of oxygen, flow amount of oxygen and nitrogen, power consumption for air separation unit and steam/water integration among the each block. The gas turbine capacity applied to the IGCC plant is 20 percent higher than NGCC gas turbine due to the low caloric heating value of syngas, therefor it is possible to utilize air integration between gas turbine and air separation unit to improve overall efficiency of the IGCC plant and there is a little impact on the ambient condition. It is very important to optimize the air integration design with consideration to the optimized integration ratio and the reliable operation. Optimized steam/water integration between power block and gasification block can improve overall efficiency of IGCC plant where the optimized heat recovery from gasification block should be considered. Finally, It is possibile to achieve the target efficiency above 42 percent(HHV, Net) for 300MW Taean IGCC plant by optimized design and integration.

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