• Title/Summary/Keyword: Nitrogen pressure

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Transport properties of polycrystalline TaNx thin films prepared by DC reactive magnetron sputtering method

  • Hwang, Tae Jong;Jung, Soon-Gil
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.2
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    • pp.1-5
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    • 2021
  • We have investigated the electrical transport properties of polycrystalline tantalum nitride (TaNx) films. Various compositions of tantalum (nitride) thin films have been deposited on SiO2 substrates by reactive DC magnetron sputtering while changing the ratio of nitrogen partial pressure. The substrate temperature was maintained at 283 K during deposition. X-ray diffraction analyses indicated the presence of α-Ta and β-Ta phases in the Ta film deposited in pure argon atmosphere, while fcc-TaNx phases appeared in the sputtering gas mixture of argon and nitrogen. The N/Ta atomic ratio in the film increased ranging from 0.36 to 1.07 for nitrogen partial pressure from 7 to 20.7%. The superconducting transition temperatures of the TaNx thin films were measured to be greater than 3.86 K with a maximum of 5.34 K. The electrical resistivity of TaNx thin film was in the range of 177-577 𝜇Ωcm and increased with an increase in nitrogen content. The upper critical filed at zero temperature for a TaN0.87 thin film was estimated to exceed 11.3 T, while it showed the lowest Tc = 3.86 K among the measured superconducting TaNx thin films. We try to explain the behavior of the increase of the residual resistivity and the upper critical field for TaNx thin films with the nitrogen content by using the combined role of the intergrain Coulomb effect and disorder effect by grain boundaries.

Effects of Fuel-Side dilution and Pressure on Structure and Extinction Scalar Dissipation Rate of Syngas Nonpremixed Flames (질소희석과 압력이 석탄가스 비예혼합 화염구조와 소염 스칼라 소산율에 미치는 영향 해석)

  • Park, Sangwoon;Shin, Youngjun;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.61-62
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    • 2012
  • The present study has numerically investigated the effects of fuel-side dilution and pressure on flame structure and extinction scalar dissipation rate of turbulent syngas nonpremixedd flames. Numerical results indicate that for highly diluted case, peak temperature is decreased and stoichiometric mixture fraction is increased. By decreasing the pressure and the nitrgen dilution levelcreased, the extinction scalar dissipation rate is increased.

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Effect of Opening Pressure and Ambient Pressure on the Characteristics of Atomization in Early Stage of Diesel Spray (개변압 및 배압 변화가 디젤부문의 초기 미립화 특성에 미치는 영향)

  • 김종현;이봉수;이장희;구자예
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.9
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    • pp.56-62
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    • 1999
  • The disintegration of transient diesel spray in early was investigated at different opening pressure and chamber pressure by measns of shadowgraph method using nanolite and still camera. Diesel spary was injected into the spray chamber which was charged with high pressure nitrogen gas. Atthe begining of injection, a liquid column that was almost the same diameter as the nozzle hole was observed . Spray tip penetration and spray angle were always increased with an increase in opening pressure.

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Open-Loop Responses of Droplet Vaporization to Linear Normal Acoustic Modes

  • Kim, S.Y.;W.S. Yoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.155-164
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    • 2004
  • In order for studying pressure-coupled dynamic responses of droplet vaporization, open-loop experiment of an isolated droplet vaporization exposed to pressure perturbations in stagnant gaseous environment is numerically conducted, Governing equations are solved for flow parameters at gas and liquid phases separately and thermodynamic parameters at the interfacial boundary are matched for problem closure. For high-pressure effects, vapor-liquid interfacial thermodynamics is rigorously treated. A series of parametric calculations in terms of mean pressure level and wave frequencies are carried out employing a n-pentane droplet in stagnant gaseous nitrogen. Results show that wave instability in view of pressure-coupled vaporization response seems more susceptible at higher pressures and higher wave frequencies. Mass evaporation rate responding to pressure waves is amplified with increase in pressure due to substantial reduction in latent heat of vaporization. Augmentation of perturbation frequency also enhances amplification due to the reduction of phase differences between pressure perturbation and surface temperature fluctuation.

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Characteristics of Sub-cooled Nitrogen Cryogenic System for Applied High-Tc Superconducting Devices (고온초전도 응용기기용 과냉질소 냉각시스템의 냉각특성)

  • 강형구;김형진;배덕권;안민철;윤용수;장호명;고태국
    • Progress in Superconductivity and Cryogenics
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    • v.6 no.1
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    • pp.38-42
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    • 2004
  • The cryogenic system for 6.6 kV/200 A inductive superconducting fault current limiter (SFCL) was developed at Yonsei university in 2003. The sub-cooled nitrogen cryogenic system could be applied to not only SFCL but also many other applied high-Tc superconducting (HTS) devices like superconducting motor, superconducting generator and superconducting magnetic energy storage (SMES). Generally, the cooling capacity of GM-cryocooler depends on the load temperature. Therefore it is necessary to perform the cooling capacity test at no load condition to calculate the exact cooling power and heat load of cryogenic system. In this research, the cooling capacity test of GM-cryocooler was executed and the heat load of developed cryogenic system was calculated. The long run operation test results of sub-cooled nitrogen cryogenic system were successful in pressure and temperature condition. Moreover, the design and fabrication method of cryogenic system were introduced and the test results were described.

Symbiotic Nitrogen Fixation Activity and Environmental Factors of Robinia Pseudo-acacia L. (아까시나무 ( Robinia pseudo - acacia L. ) 의 공생적 질소고정 활성과 환경요인)

  • Hong, Sung-Jin;Song, Seung-Del
    • The Korean Journal of Ecology
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    • v.13 no.2
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    • pp.93-100
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    • 1990
  • The activity of symbiotic -fixation and environmental factors of Robinia pseudo-acacia L., bearing root nodules, were quantitatively analyzed during the growing period. Among changes of total nitrogen and phosphorus contents of each organ, leaves showed prominent decreases from the highest quantity of the early growing period to the lowest of the late period. The rhizosphere showed acidic pH and low level of nitrogen, phosphorus and organic matter contents during the growing period. -fixation activity of nodules initiated from April and showed the maximum value of 190 $\mu$/g DW/hr in late June and than decreased to 50$\mu$M/g DW/hr during the rainy and dry season. Another peak of the activity attained 246$\mu$M/g DW/hr in the late growing stage of September. The maximum value of nitrogen fixation activity was observed at the conditions of pH7, $25\{\circ}C$ of temperature and 20 Kpa of oxygen partial pressure.

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Breakdown Characteristics of Liquid Nitrogen in the Environment to Restrain Vapor Bubbles (비등 기포를 억제한 환경에서 액체 질소의 절연파괴 특성)

  • 백승명;정종만;김영석;곽동순;한철수;김상현
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.02a
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    • pp.228-231
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    • 2003
  • Experimental investigations of AC breakdown characteristics of liquid nitrogen in the environment to restrain boil bubbles are presented in this paper. The environment to restrain vapor bubble in the liquid nitrogen is both increasing pressure and decreasing temperature. Measurements of the breakdown voltage of liquid nitrogen in the environment to restrain vapor bubbles are investigated under AC high voltage in a quasi-uniform and non-uniform electrical field for pressures and temperatures ranging from 0 to 0.5 MPa and 77 K to 65 K respectively.

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A Study on the Dielectric Characteristics of Insulation Gases for a Sub-cooled Liquid Nitrogen System (이용률을 이용한 과냉질소 냉각시스템용 절연가스의 절연특성에 관한 연구)

  • Kang, Hyoung-Ku;Ko, Tae-Kuk
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.1
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    • pp.52-55
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    • 2010
  • A sub-cooled liquid nitrogen system is known as a promising method to develop high voltage superconducting apparatuses such as superconducting fault current limiters (SFCLs) and superconducting cables. To develop a high voltage superconducting machine adopting the sub-cooled liquid nitrogen system with a constant pressure. injecting a non-condensable gas is indispensable. In this study. the dielectric characteristics of insulation gases are investigated and analyzed by using electric utilization factors ($\xi$). It is found that the maximum electric field at sparkover that occurs with 50 % probability. $E_{MAX.50%}$ exponentially decreases as the S increases. This means that the $E_{MAX.50%}$ at sparkover can be estimated with the $E_{MAX.50%}$

Evaporation Heat Transfer Characteristics of Liquid Nitrogen in Horizontal Plain Tubes with Wire Coil Inserts (평활관 및 열전달촉진관에서 액체질소의 관내 증발열전달 특성에 대한 연구)

  • Hwang, Jee-Sang;Chung, Jin-Taek;Yun, Rin;Kim, Yong-Chan;Moon, Young-June;Kim, Dong-Hyuk
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1359-1364
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    • 2004
  • An experiment was performed to study the evaporation heat transfer and the pressure drop characteristics of liquid nitrogen in a horizontal stainless steel tube with wire coil inserts. The inner diameter of test tube is 4.3mm and the length is 1.5m. Four wire coils having different pitch and thickness were inserted into the plain test tube. The wire coil length is 1.5m and the diameter is 3.65mm with thickness of 0.5mm and 0.9mm. Experiments were conducted at saturation temperature of $-191^{\circ}C$ mass flux from 200 to 370 $kg/m^{2}s$ and heat flux of 62 $kW/m^{2}$. Direct heating method was used to apply heat to the test section. Boiling heat transfer coefficients of both the plain and the enhanced tubes were calculated. Pressure drops between inlet and outlet side of test section were also measured, and they are used to estimate EPR(Enhancement Performance Ratio).

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AlN preparation by Self-propagation High-temperature Synthesis (SHS) in Al-N2 and Al-N2-AIN system (Al-N2와 Al-N2-AlN계에서 고온자전연소법에 의한 AlN 합성)

  • 이재령;이익규;안종관;김동진;안양규;정헌생
    • Journal of Powder Materials
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    • v.11 no.4
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    • pp.294-300
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    • 2004
  • This study for preparation of aluminum nitride (AlN) with high purity was carried out by self-propagating high-temperature synthesis method in two different systems, $Al-N_{2}$ and $Al-N_{2}$-AlN, with the change of nitrogen gas pressure and dilution factor. On the occasion of $Al-N_{2}$ system, unreacted aluminum was detected in the product in spite of high nitrogen pressure, 10 MPa, This may be caused by obstructing nitrogen gas flow to inner part of molten and agglomerate of aluminum, formed in pre-heating zone. In $Al-N_{2}$-AlN system, AlN with a purity of 95% or ever can be prepared in the condition of $f_{Dil}\geq0.5$, $P_{N_{2}}\geq$ 1 MPa, and the purity can be elevated to 98% over in the condition of $f_{Dil}$ = 0.7 and $P_{N_{2}}$ = 10 MPa.