• Title/Summary/Keyword: Nitrogen dioxide($NO_2$)

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Damage Characteristics of Korean Traditional Textiles by Nitrogen Dioxide (NO2) Concentrations (이산화질소(NO2) 농도에 따른 전통직물의 손상 특성)

  • Kim, Myoung Nam;Lim, Bo A;Kim, Seojin;Lee, Sun Myung
    • Journal of Conservation Science
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    • v.29 no.3
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    • pp.197-207
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    • 2013
  • The gas acceleration test was conducted to identify the deterioration of Korean traditional textiles caused by $NO_2$. Total 20 specimens were prepared using 4 different materials (silk, cotton, ramie, hemp) after dyeing with 5 colors (undyed, red, yellow, blue, black). The specimens were exposed to 0.01, 0.1, 1, 10, 100, and 1000 ppm $NO_2$ gas in the test chamber at $20^{\circ}C$, 50% RH for 1 day. Optical, chemical, and physical evaluation was carried out after the exposure. In the case of Korean traditional textile, color difference increased at 1 ppm/day, $NO_3{^-}$ concentration, carbonyl and C-$NO_2$ functional group increased while pH decreased at 10 ppm/day and tensile strength weakened at 100 ppm/day. when it comes to undyed textile, alteration of color difference on silk and hemp cloth, $NO_3{^-}$ concentration and tensile strength on hemp cloth was remarkable. In addition, color difference on blue and yellow textile, $NO_3{^-}$ concentration increase of yellow textile and tensile strength decrease of hemp cloth & ramie cloth were significant. The results suggest that critical $NO_2$ concentration of optical, chemical, and physical damage on Korean traditional textiles are 1ppm/day, 10 ppm/day, 100 ppm/day respectively.

Synthesis and Antimicrobial Properties of Surfactants Contaning Phenazine Ring (Ⅱ) (Phenazine Ring을 가진 界面活性劑의 合成과 그 抗菌性 (제2보))

  • Jong Dae Kim;Dong Soo Kim;Sang Jik Lee;Sung Wook Han
    • Journal of the Korean Chemical Society
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    • v.27 no.6
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    • pp.457-463
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    • 1983
  • -Alkyl-2-hydroxyphenazine-5,10-dioxides were synthesized from hydroquinone, and alkyl benzofuroxanes which were previously obtained through five reaction steps starting from aniline. Infrared, nuclear mangnetic resonance spectrometry and elemental analysis were employed to identify the products concerned in the synthetic processes. It was observed that these alkylated phenazine oxides lowered the surface tension of water substantially. These derivatives showed stronger antimicrobial activity against both gram positive and negative microbes than 1-carboxyphenazine which had no alkyl side chain. It was also found that the antimicrobial activity of the phenazine compound increased when the nitrogen of the ring was bound to the oxygen atom.

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Adverse Effects of Air Pollution on Pulmonary Diseases

  • Ko, Ui Won;Kyung, Sun Young
    • Tuberculosis and Respiratory Diseases
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    • v.85 no.4
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    • pp.313-319
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    • 2022
  • Environmental exposure to air pollution is known to have adverse effects on various organs. Air pollution has greater effects on the pulmonary system as the lungs are directly exposed to contaminants in the air. Here, we review the associations of air pollution with the development, morbidity, and mortality of pulmonary diseases. Short-and long-term exposure to air pollution have been shown to increase mortality risk even at concentrations below the current national guidelines. Ambient air pollution has been shown to be associated with lung cancer. Particularly long-term exposure to particulate matter with a diameter <2.5 ㎛ (PM2.5) has been reported to be associated with lung cancer even at low concentrations. In addition, exposure to air pollution has been shown to increase the incidence risk of chronic obstructive pulmonary disease (COPD) and has been correlated with exacerbation and mortality of COPD. Air pollution has also been linked to exacerbation, mortality, and development of asthma. Exposure to nitrogen dioxide (NO2) has been demonstrated to be related to increased mortality in patients with idiopathic pulmonary fibrosis. Additionally, air pollution increases the incidence of infectious diseases, such as pneumonia, bronchitis, and tuberculosis. Furthermore, emerging evidence supports a link between air pollution and coronavirus disease 2019 transmission, susceptibility, severity and mortality. In conclusion, the stringency of air quality guidelines should be increased and further therapeutic trials are required in patients at high risk of adverse health effects of air pollution.

Satellite (SCIAMACHY) Measurements of Tropospheric SO2 and NO2: Seasonal Trends of SO2 and NO2 Levels over Northeast Asia in 2006 (인공위성 (SCIAMACHY) 데이터를 이용한 대류권 SO2, NO2 측정: 2006년 동북아시아 지역의 계절적 SO2, NO2 변화 추세)

  • Lee, Chul-Kyu;Richter, Andreas;Burrows, John P.;Kim, Young-J.
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.2
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    • pp.176-188
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    • 2008
  • Anthropogenic emissions of nitrogen oxides and sulfur dioxide in Northeast Asia are of great concern because of their impact on air quality and atmospheric chemistry on regional and intercontinental scales. Satellite remote sensing based on DOAS (Differential Optical Absorption Spectroscopy) technique has been preferred to measure atmospheric trace species and to investigate their emission characteristics on regional and global scales. Absorption spectra obtained by the satellite-born instrument, SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric Chartography) have been utilized to retrieve the information of $SO_2$ and $NO_2$ over Northeast Asia. $SO_2$ levels over Northeast Asia were in order of East China, Yellow Sea, South Sea and Korean Peninsula with mean vertical columns of $1.78({\pm}1.0){\times}10^{16}$, $1.11({\pm}0.67){\times}10^{16}$, $0.60({\pm}0.63){\times}10^{16}$, $0.71({\pm}0.65){\times}10^{16}\;molecules/cm^2$, respectively. $NO_2$ levels were in order of East China, Yellow Sea, Korean Peninsula, and South Sea with mean vertical columns of $1.2({\pm}0.56){\times}10^{16}$, $0.38({\pm}0.19){\times}10^{16}$, $0.48({\pm}0.28){\times}10^{16}$, $0.26({\pm}0.16){\times}10^{16}\;molecules/cm^2$, respectively. High levels of $SO_2$ and $NO_2$ were observed over East China, in particular in winter by the contribution of heating fuel combustion exhausts. The $SO_2$ and $NO_2$ levels over East China were the highest in January with 34% and 42% higher over the annual means. Low levels of $SO_2$ ranged over Korean peninsula, while $NO_2$ levels were relatively high, in particular in winter. The $SO_2$ and $NO_2$ levels over Yellow Sea were relatively higher compared to those over Korean peninsula and South Sea, which could be mainly attributed to their transport from East China.

Diurnal Variations of O3 and NO2 Concentrations in an Urban Park in Summer: Effects of Air Temperature and Wind Speed (여름철 도심 공원의 O3과 NO2 농도의 일변화: 기온과 풍속의 영향)

  • Han, Beom-Soon;Kwak, Kyung-Hwan;Baik, Jong-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.5
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    • pp.536-546
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    • 2016
  • The diurnal variations of $O_3$ and $NO_2$ in an urban park and the effects of air temperature and wind speed on the diurnal variations are investigated. $O_3$ and $NO_2$ concentrations were observed at a site in an urban park of Seoul from 27 July 2015 to 9 August 2015. The $O_3$ and $NO_2$ concentrations observed in the urban park are compared to those observed at the Gangnam air quality monitoring station (AQMS). The $O_3$ concentration is higher in the urban park than at the Gangnam AQMS in the daytime because the amount of $O_3$ dissociated by NO is smaller as well as partly because the amount of $O_3$ produced in the oxidation process of biogenic volatile organic compounds (VOCs) is larger in the urban park than at the Gangnam AQMS. The $NO_2$ concentration is lower in the urban park than at the Gangnam AQMS during day and night because the observation site in the urban park is relatively far from roads where $NO_x$ is freshly emitted from vehicles. The difference in $NO_2$ concentration is larger in the daytime than in the nighttime. To examine the effects of air temperature and wind speed on the diurnal variations of $O_3$ and $NO_2$, the observed $O_3$ and $NO_2$ concentrations are classified into high or low air temperature and high or low wind speed days. The high $O_3$ and $NO_2$ concentrations in the daytime appear for the high air temperature and low wind speed days. This is because the daytime photochemical processes are favorable when the air temperature is high and the wind speed is low. The scatter plots of the daytime maximum $O_3$ and minimum $NO_2$ concentrations versus the daytime averages of air temperature and wind speed show that the daytime maximum $O_3$ and minimum $NO_2$ concentrations tend to increase as the air temperature increases or the wind speed decreases. The daytime maximum $O_3$ concentration is more sensitive to the changes in air temperature and wind speed in the urban park than at the Gangnam AQMS.

Study on Fuel Specificity and Harmful Air Pollutants Factor of Agglomerated Wood Charcoal (시중에 유통되고 있는 성형목탄의 연료특성과 유해인자에 대한 연구)

  • JEOUNG, Taek Yong;YANG, Seung Min;KANG, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.253-266
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    • 2020
  • This study selected three types of agglomerated wood charcoal (Agglomerated wood charcoal with charcoal powder, Carbonized wood briquette, Ignition-type of perforated charcoal) that are in circulation in Korea among fuel-type wood products and analyzed the fuel characteristics, harmful substance content, and emissions of air pollutants generated by combustion. The first results showed that charcoal-grilled carbon, which is the raw material of charcoal, produced higher CO than saw-billed carbon. The second result is that the emission standards of air pollutants generated by the combustion of molded wood coal are not up to the emission standards of nitrogen oxides and sulfur oxides in the entire product, compared with the emission criteria of the atmospheric environment preservation method (based on 2019, carbon monoxide: 200 ppm, nitrogen oxides, 150 ppm sulfur oxides: 100 ppm), but the carbon dioxide moulding and carbon dioxide levels were not up. Based on the analysis of combustion gas generated during combustion derived from this study, future research is needed for comparing with the emission standards of pellets, which are wood products for fuel, among the existing biomass burning standards and for reducing carbon monoxide generated during incomplete combustion of agglomerated wood charcoal.

Short-term Effects of Ambient Air Pollution on Emergency Department Visits for Asthma: An Assessment of Effect Modification by Prior Allergic Disease History

  • Noh, Juhwan;Sohn, Jungwoo;Cho, Jaelim;Cho, Seong-Kyung;Choi, Yoon Jung;Kim, Changsoo;Shin, Dong Chun
    • Journal of Preventive Medicine and Public Health
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    • v.49 no.5
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    • pp.329-341
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    • 2016
  • Objectives: The goal of this study was to investigate the short-term effect of ambient air pollution on emergency department (ED) visits in Seoul for asthma according to patients' prior history of allergic diseases. Methods: Data on ED visits from 2005 to 2009 were obtained from the Health Insurance Review and Assessment Service. To evaluate the risk of ED visits for asthma related to ambient air pollutants (carbon monoxide [CO], nitrogen dioxide [$NO_2$], ozone [$O_3$], sulfur dioxide [$SO_2$], and particulate matter with an aerodynamic diameter <$10{\mu}m$ [$PM_{10}$]), a generalized additive model with a Poisson distribution was used; a single-lag model and a cumulative-effect model (average concentration over the previous 1-7 days) were also explored. The percent increase and 95% confidence interval (CI) were calculated for each interquartile range (IQR) increment in the concentration of each air pollutant. Subgroup analyses were done by age, gender, the presence of allergic disease, and season. Results: A total of 33 751 asthma attack cases were observed during the study period. The strongest association was a 9.6% increase (95% CI, 6.9% to 12.3%) in the risk of ED visits for asthma per IQR increase in $O_3$ concentration. IQR changes in $NO_2$ and $PM_{10}$ concentrations were also significantly associated with ED visits in the cumulative lag 7 model. Among patients with a prior history of allergic rhinitis or atopic dermatitis, the risk of ED visits for asthma per IQR increase in $PM_{10}$ concentration was higher (3.9%; 95% CI, 1.2% to 6.7%) than in patients with no such history. Conclusions: Ambient air pollutants were positively associated with ED visits for asthma, especially among subjects with a prior history of allergic rhinitis or atopic dermatitis.

Effects of Aqueous Chlorine Dioxide Treatment on Microbial Safety and Quality of Samgae Chicken (이산화염소수 처리가 삼계용 닭의 저온저장 중 미생물학적 변화 및 품질에 미치는 영향)

  • Hong, Yun-Hee;Kim, Min-Ki;Song, Kyung-Bin
    • Food Science and Preservation
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    • v.15 no.5
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    • pp.769-773
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    • 2008
  • Aqueous chlorine dioxide ($ClO_2$) treatment of Samgae chicken was evaluated in terms of microbial safety and quality during refrigerated storage. Samgae chicken samples were treated with 0, 50, or 100 ppm of $ClO_2$ solution, and stored at $4^{\circ}C$ for 10 days. $ClO_2$ treatment significantly decreased the populations of total aerobic bacteria. One-hundred ppm $ClO_2$ treatment reduced the initial populations of total aerobic bacteria by 0.73 log CFU/g. The pH and volatile basic nitrogen values of Samgae chicken increased during storage, with no significant between-treatment difference. Sensory evaluation results showed that the quality of chicken treated with $ClO_2$ prior to refrigerated storage was better than that of the control. These results suggest that $ClO_2$ treatment could be useful in improving the microbial safety and quality of Samgae chicken.

Gas Sensing Properties of Pt Doped Fe2O3 Nanoparticles Fabricated by Sol-Gel Method (Sol-Gel 방법을 이용하여 제작된 Pt이 첨가된 Fe2O3 나노 입자의 가스 감지 특성)

  • Jang, Min-Hyung;Lim, Yooseong;Choi, Seung-Il;Park, Ji-In;Hwang, Namgyung;Yi, Moonsuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.5
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    • pp.288-293
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    • 2017
  • $Fe_2O_3$ is one of the most important metal oxides for gas sensing applications because of its low cost and high stability. It is well-known that the shape, size, and phase of $Fe_2O_3$ have a significant influence on its sensing properties. Many reports are available in the literature on the use of $Fe_2O_3$-based sensors for detecting gases, such as $NO_2$, $NH_3$, $H_2S$, $H_2$, and CO. In this paper, we investigated the gas-sensing performance of a Pt-doped ${\varepsilon}$-phase $Fe_2O_3$ gas sensor. Pt-doped $Fe_2O_3$ nanoparticles were synthesized by a Sol-Gel method. Platinum, known as a catalytic material, was used for improving gas-sensing performance in this research. The gas-response measurement at $300^{\circ}C$ showed that $Fe_2O_3$ gas sensors doped with 3%Pt are selective for $NO_2$ gas and exhibita maximum response of 21.23%. The gas-sensing properties proved that $Fe_2O_3$ could be used as a gas sensor for nitrogen dioxide.

Application of Informer for time-series NO2 prediction

  • Hye Yeon Sin;Minchul Kang;Joonsung Kang
    • Journal of the Korea Society of Computer and Information
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    • v.28 no.7
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    • pp.11-18
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    • 2023
  • In this paper, we evaluate deep learning time series forecasting models. Recent studies show that those models perform better than the traditional prediction model such as ARIMA. Among them, recurrent neural networks to store previous information in the hidden layer are one of the prediction models. In order to solve the gradient vanishing problem in the network, LSTM is used with small memory inside the recurrent neural network along with BI-LSTM in which the hidden layer is added in the reverse direction of the data flow. In this paper, we compared the performance of Informer by comparing with other models (LSTM, BI-LSTM, and Transformer) for real Nitrogen dioxide (NO2) data. In order to evaluate the accuracy of each method, mean square root error and mean absolute error between the real value and the predicted value were obtained. Consequently, Informer has improved prediction accuracy compared with other methods.