• Title/Summary/Keyword: Nitrogen diffusion

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Soot Formation in a Double-Concentric Diffusion Flame (동축 이중 확산화염의 매연 생성 특성)

  • Jurng, Jongsoo;Lee, Gyo-Woo;Ko, Bum-Seung;Kang, Kyung-tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1355-1362
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    • 1999
  • An experimental study on a double-concentric diffusion flame(DDF) has been carried on in order to Investigate the characteristics of soot formation compared to a normal coflow diffusion flame(NDF). Laser extinction technique has been used for an ethylene($C_2H_4$) and air flame with various flow rates. Soot formation In the double-concentric diffusion flame was enhanced by the inner inverse diffusion flame due to the increase in flame temperature and also suppressed due to the nitrogen-dilution from the inner air. Soot concentration at the flame axis of DDF was higher than that of the NDF, mainly because of the increase of temperature by inner flame. However, the maximum soot volume fraction of DDF was lower than NDF at the outer side of the flame, mainly due to the effect of nitrogen-dilution from the inner air.

A Study fur Wettability of Silicate Glasses on Silicon Nitride (질화규소와 실리케이트계 유리의 젖음성에 관한 연구)

  • 안병국
    • Journal of Welding and Joining
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    • v.20 no.3
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    • pp.116-121
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    • 2002
  • For the accumulation of a fundamental knowledge about the behavior of glass solder during the joining of ceramics, the wettability of solder on silicon nitride have been measured by sessile drop method. $SiO_2-MgO-Al_2O_3$ g1ass solder and oxynitride glass solders were selected as examples while silicon nitride which were used as substrates. Contact angle of solder on silicon nitride didn't decrease with time at high nitrogen content in the solder, but low nitrogen content in solders have the time-dependent property. Reason which contact angle of low nitrogen content in solders decrease on silicon nitride was that diffusion of nitrogen take place between solder and silicon nitride.

Brain MRI Findings of Nitrogen Gas Inhalation for Suicide Attempt: a Case Report

  • Kim, Young-eun;Lee, Donghoon;Kim, Minji;Hwang, Hokyoung
    • Investigative Magnetic Resonance Imaging
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    • v.21 no.4
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    • pp.264-268
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    • 2017
  • South Korea has the highest reported suicide rate among all countries belonging to the Organization for Economic Cooperation and Development. Nitrogen is a colorless, odorless and nontoxic gas. Nitrogen gas has, however, been recently used as a method of attempted suicide, its nontoxity notwithstanding. We herein report on an unusual case involving a 30-year-old male who presented with symptoms after a suicide attempt by nitrogen inhalation. Diffusion-weighted imaging of his brain was showed curvilinear high signal intensity in the bilateral frontal and right occipital cortices, with subtle low apparent diffusion coefficient value. In addition, T2-weighted images and fluid attenuated inversion recovery images revealed subtle high signal intensity in the bilateral frontal cortices, basal ganglia and occipital cortices with contrast enhancement.

H13소재의 쇼트피닝과 이온질화에의한 표면경화

  • Jo, Gyun-Taek;Son, Seok-Won;Yu, Gwang-Chun;Lee, Yeong-Guk;Lee, Won-Beom
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.58-59
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    • 2012
  • Surface hardening mechanism of H13 steel was investigated when ion niriding after shot peening process was applied. Severe plastic deformation induced nanocrystallized grains at surface region. Higher nitrogen concentration was achieved in ion nitrided specimen with shot peening treatment than in single nitrided specimen. The elemental mapping on chromium and nitrogen by TEM-EELs showed chromium dissolved in matrix enhanced bulk nitrogen diffusion at surface region. Higher nitrogen diffusion also caused lattice distortion. Nano-sized grains, higher nitrogen concentration, and lattice diffustion contributed to the surface hardening.

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Joining of Multi Nodes of a Titanium Bicycle by the Superplastic Hydroforming and Diffusion Bonding Technology (티타늄 자전거의 다중 조인트 접합을 위한 초소성 하이드로포밍과 확산 접합 기술)

  • Yoo, Y.H.;Lee, S.Y.
    • Transactions of Materials Processing
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    • v.28 no.1
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    • pp.15-20
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    • 2019
  • The superplastic forming/diffusion bonding process has been developed to fabricate a core frame structure with joint nodes out of tubes, for the development of a titanium high performance bicycle. The hydroforming process has been applied for bulging of a tube in the superplastic condition before, and during the diffusion bonding process. In this experiment, a commercial Ti-3Al-2.5V tube was selected as raw material for the study. The forming experiment has been performed using a servo-hydraulic press with a capacity of 200 ton. Next, nitrogen gas was used to acquire necessary pressure for the bulging and bonding of the tubes to fabricate the joint nodes. The pertinent processing temperature was $870^{\circ}C$ for the superplastic hydroforming/diffusion bonding (SHF/DB) process, using the Ti-3Al-2.5V tube. The bonding quality and the progress of bulging and diffusion bonding have been observed by the investigation of the joining interfaces at the cross section of the joint structure. The control of the nitrogen pressure throughout the SHF/DB process, was an important factor to avoid any significant defects in the joint structure. The whole progress stage of the diffusion bonding could be observed at a joint interface. A core structure with 5 joint nodes to manufacture a titanium bicycle could be obtained in a SHF/DB process.

The Formation Rate and Activation Energy of Diffusion Layer and Compound Layer in Ion-Nitriding (이온질화 에 있어 확산층 및 합성층 의 생성속도 및 질소 의 활성화에너지)

  • 성환태;유봉환;조규식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.8 no.5
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    • pp.476-480
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    • 1984
  • This paper deals with nitrogen diffusion velocity and activation energy in diffusion layer and compound layer in ion-nitriding, and presents observations on the effect of deformation according to nitriding methods. During the experiment the activation energy and diffusion velocity of nitrogen have been examined in S45C steel samples. It is found that the results of an investigation correspond with the theoretical data and the ion-nitriding method offers less deformation than conventional salt-bath method of nitriding.

The Effect of the Gas Ration on the Characteristics of Plasma Nitrided SCM440 Steel (SCM440강의 플라즈마 질화특성에 미치는 가스비율의 영향)

  • 김무길
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.5
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    • pp.712-720
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    • 1998
  • The effect of H2:N2 gas ratio on the case thickness hardness and nitrides formation in the sur-face of SCM440 machine structural steel have been studied by micro-pulse plasma process. The thickness of compound layer increased with the increase of nitrogen content in the gas com-position. The maximum thickness of compound layer the maximum case depth and the maximum surface hardness were about 15.8${\mu}m$, 400${\mu}m$ and Hv765 respectively in the nitriding condition of 250Pa and 70% nitrogen content at $520^{\circ}C$ for 7hrs. Generally only nitride phases such as ${\'{\gamma}}$($Fe_4N$)$\varepsilon(Fe_2}{_3N}$ phases were detected in compound and diffusion layer by XRD analysis. The amount of $\varepsilon(Fe_2}{_3N}$ phase increased with the increase of nitrogen content. The relative amounts and kind of phases formed in the nitrided case changed with the change of nitrogen content in the gas composition.

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Characteristics of Electomigration & Surface Hardness about Tungsten-Carbon-Nitrogen(W-C-N) Related Diffusion Barrier (W-C-N 확산방지막의 전자거동(ElectroMigration) 특성과 표면 강도(Surface Hardness) 특성 연구)

  • Kim, Soo-In;Hwang, Young-Joo;Ham, Dong-Shik;Nho, Jae-Kue;Lee, Jae-Yun;Park, Jun;Ahn, Chan-Goen;Kim, Chang-Seong;Oh, Chan-Woo;Yoo, Kyeng-Hwan;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.18 no.3
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    • pp.203-207
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    • 2009
  • Copper is known as a replacement for aluminum wire which is used for semiconductor. Because specific resistance of Cu ($1.67{\mu}{\Omega}$-cm) is lower than that of Al ($2.66{\mu}{\Omega}$-cm), Cu reduce RC delay time. Although melting point of Cu($1085^{\circ}C$) is higher than melting point of Al, Cu have characteristic to easily react with Silicon(Si) in low temperature, and it isn't good at adhesive strength with Si. For above these reason, research of diffusion barrier to prevent reaction between Cu and Si and to raise adhesive strength is steadily advanced. Our study group have researched on W-C-N (tungsten-carbon-nitrogen) Diffusion barrier for preventing diffusion of Cu through semiconductor. By recent studies, It's reported that W-C-N diffusion barrier can even precent Cu and Si diffusing effectively at high temperature. In this treatise, we vaporized different proportion of N into diffusion barrier to research Cu's Electromigration based on the results and studied surface hardness in the heat process using nano scale indentation system. We gain that diffusion barrier containing nitrogen is more stable for Cu's electromigration and has stronger surface hardness in heat treatment process.

Temperature Measurement in Concentric Diffusion Flames by Rapid Insertion Technique (급속 삽입법에 의한 화염 내부 온도 분포 측정)

  • Lee, Gyo-Woo;Chung, Young-Rok;Jurng, Jong-Soo
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.75-83
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    • 1999
  • The effect of temperature distributions on soot volume fraction in double-concentric diffusion flames have been investigated experimentally. Using fine thermocouple wires and a rapid insertion mechanism, we have measured temperature without the effect of soot particles attached to the thermocouple junction, which can lower the temperature signal about 100 K by increasing the heat loss from the junction by radiation. The temperature at the flame axis is higher in the double-concentric diffusion flames than in normal co-flow diffusion flames because of the inverse diffusion flame. However, it is almost the same as that at the periphery of normal flames, on which the inverse flame does not have an effect. Thus, the lower soot concentration found in the double-concentric diffusion flame can be explained by the effect of nitrogen diffusion from the central air jet.

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