• Title/Summary/Keyword: Nitrogen behavior

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Cryogenic Charpy Impact Test based on GTAW Method of AISI 304 Stainless Steel for LNG Pipeline (AISI 304 스테인리스 강으로 제작된 LNG배관 용접부의 극저온 샤르피 충격시험)

  • Kim, Jeong-Hyeon;Choi, Sung-Woong;Park, Doo-Hwan;Lee, Jae-Myung
    • Journal of Welding and Joining
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    • v.32 no.3
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    • pp.89-94
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    • 2014
  • AISI 304 austenitic stainless steel is widely used for LNG pipes for LNG transmission thanks to its good metallurgical and mechanical properties. In the present research, impact toughness of a gas tungsten arc welded AISI 304 stainless steel pipe was evaluated between room and liquid nitrogen ($-196^{\circ}C$) test temperatures. In addition, a comparative study was made of the fracture behavior of FCC crystal structured stainless steel weldments and BCC crystal structured mild steels(A-grade and SS400). The results showed a slight decrease in the impact energy of the AISI 304 base metal, heat affected zone(HAZ), and welded zone with decreasing test temperature. In addition, the welded metal has the highest absorbed impact energy, followed by HAZ and the base metal.

Effect of Nitrogen Treatment on the Structure and Magnetic Properties of $RuSr_2(EuCe)Cu_2O_z$ Compound (질소 열처리에 따른 $RuSr_2(EuCe)Cu_2O_z$ 계의 구조 및 자기적 특성)

  • Lee, H.K.;Kim, Y.I.;Kim, Y.C.
    • Progress in Superconductivity
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    • v.13 no.3
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    • pp.178-183
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    • 2012
  • Two $RuSr_2(EuCe)Cu_2O_z$ samples (as prepared and after $N_2$ treatment) have been investigated by thermogravimetric (TC) analysis, high-resolution x-ray powder diffraction and magnetization measurements. TG measurements which were carried out in $H_2/Ar$ atmosphere showed that the $N_2$ treatment of the as-prepared sample at $650^{\circ}C$ for 2h leads to a decrease in the oxygen content z by about 0.25. This oxygen depletion was accompanied by an increase in the magnetic transition temperature from 54.0 K to 114.9 K. This magnetic behavior is discussed in connection with the results of Rietveld analysis of the x-ray diffraction data which showed that the $N_2$ treatment resulted in both a significant increase in the rotation angle of the $RuO_6$ octahedra and a decrease in c-lattice parameter of the sample.

A Study on the Silicon surface and near-surface contamination by $CHF_3$/$C_2$$F_6$ RIE and its removal with thermal treatment and $O_2$ plasma exposure ($CHF_3$/$C_2$$F_6$ 반응성이온 건식식각에 의한 실리콘 표면의 오염 및 제거에 관한 연구)

  • 권광호;박형호;이수민;곽병화;김보우;권오준;성영권
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.1
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    • pp.31-43
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    • 1993
  • Thermal behavior and $O_{2}$ plasma effects on residue and penetrated impurities formed by reactive ion etching (RIE) in CHF$_{3}$/C$_{2}$F$_{6}$ have been investigated using X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS) techniques. Decomposition of polymer residue film begins between 200-300.deg. C, and above 400.deg. C carbon compound as graphite mainly forms by in-situ resistive heating. It reveals that thermal decomposition of residue can be completed by rapid thermal anneal above 800.deg. C under nitrogen atmosphere and out-diffusion of penetrated impurities is observed. The residue layer has been removed with $O_{2}$ plasma exposure of etched silicon and its chemical bonding states have been changed into F-O, C-O etc.. And $O_{2}$ plasma exposure results in the decrease of penetrated impurities.

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Physicochemical Properties of Poly-γ-glutamic Acid Produced by a Novel Bacillus subtilis HA Isolated from Cheonggukjang

  • Seo, Ji-Hyun;Kim, Chan-Shick;Lee, Sam-Pin
    • Preventive Nutrition and Food Science
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    • v.13 no.4
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    • pp.354-361
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    • 2008
  • A novel bacterium isolated from Cheonggukjang was identified as a glutamate-dependent Bacillus subtilis HA with 98.3% similarity to Bacillus subtilis Z99104. Optimization of poly-$\gamma$-glutamic acid ($\gamma$-PGA) production by modulating fermentation factors including carbon sources, nitrogen sources, inorganic salts and fermentation time was investigated. Optimum culture broth for $\gamma$-PGA production consisted of 3% glutamate, 3% glucose and various salts, resulting in the PGA production of 22.5 g/L by shaking culture for 72 hr at $37^{\circ}C$. Average molecular weight of $\gamma$-PGA was determined to be 1,220 kDa through MALLS analysis. The $\gamma$-PGA solution showed a typical pseudoplastic flow behavior, and a great decrease in consistency below pH 6.0 regardless of the same molecular weight of $\gamma$-PGA. The molecular weights of isolated $\gamma$-PGA were drastically decreased by heat treatment in various acidic conditions, resulting in different hydrolysis of $\gamma$-PGA. The consistency of $\gamma$-PGA solution was greatly decreased with increase heating time in acidic conditions.

Sogeunjung-tang improves depressive-like behavior decreased by forced-swimming test

  • Jeong, Hyun-Ja;Moon, A Rim;Kim, Na-Hyung;Chung, Cha-kwon
    • CELLMED
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    • v.7 no.1
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    • pp.4.1-4.4
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    • 2017
  • Sogeunjung-tang (S-tang) is a traditional Korean medicine that has been used for the therapy of anxiety disorder in a variety of clinical situations. However, no study has investigated this effect. The aim of this study was to investigate the effectiveness of S-tang for reducing depression in animal model. The anti-depressant effect of S-tang was investigated in ICR mice by using forced swimming test (FST). After FST, we analyzed the blood biochemical parameters from blood. The immobility time was significantly decreased in the S-tang oral administration or pharmaceutical acupuncture group compared with the control group at 14 days (p < 0.05). The anti-depressant effect of S-tang was higher than that of fluoxetine (a classical anti-depressant). S-tang or fluoxetine significantly decreased the creatine kinase and lactate dehydrogenase level compared with the control group (p < 0.05) but not glucose, protein, and blood urea nitrogen level. Further investigation of S-tang as a potential pharmacologic agent in the management of depression related anxiety is warranted.

Effect of Injection Hole and Needle-driven Characteristics on Pilot Spray in High Pressure Injector with Common-rail System (커먼레일 고압분사용 인젝터의 분공수 및 니들구동특성이 Pilot 분무에 미치는 영향)

  • Lee, Jin-Wook;Bae, Jang-Woong;Kim, Ha-Nul;Kang, Kern-Yong;Min, Kyung-Duk
    • Journal of ILASS-Korea
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    • v.9 no.1
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    • pp.8-14
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    • 2004
  • future exhaust emission limits for diesel-driven passenger cars will force the automotive company to significantly develop of the new technologies of diesel engine respectively of the drive assemblies. As we know, the contributions of soot and nitrogen oxide is the main problems in diesel engine. Recently, as a result, the pilot injection of common-rail fuel injection system recognizes an alternative function to solve an environmental problem. This study describes the effect of the nozzle structure and driven characteristic of injector on pilot injection fur a passenger car common-rail system. The pilot spray structure such as spray tip penetration, spray speed and spray angle were obtained by high speed images, which is measured by the Mie scattering method with optical system fur high-speed temporal photography. Also the CFD analysis was carried out for fuel behavior under high pressure in between needle and nozzle of injector for common-rail system to know the condition of initial injection at experiment test. It was found that solenoid-driven injector with 5-hole was faster than 6-hole injector in spray speed at same conditions and piezo-driven injector showed faster response than solenoid injector.

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Effect of Heat Treatment Condition on Fine Structure of High strength Polyacrylonitrile(PAN) Fibre(III) (고강력 폴리아크릴로니트릴 섬유의 열처리에 의한 미세구조 변화(III))

  • Bang, Yun Hyuk;Lee, Chun Yong;Kim, Han Do;Lee, Mun Cheul;Cho, Hyun Hok
    • Textile Coloration and Finishing
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    • v.7 no.2
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    • pp.24-31
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    • 1995
  • The properties of carbon fibers made from PAN are controlled by the heat treatment conditions. The length changes of high strength homo-PAN and co-PAN (acrylonitrile/acrylamide= 98/2wt% ) fibers under constant tensile stress during heat treatment in nitrogen gas were investigated by measuring the shrinkage behavior. In order to elucidate the relation between the length and fine structure change, the measurements of the crystalline orientation and birefringence index etc. were made for the fibers treated under linear heating up to 27$0^{\circ}C$. There are two regions in the length change with heat treatment temperature. The change in the initial period is mainaly due to the relaxation of amorphous molecular chain confined by the fiber-manufacture process. The length change in later period is considered to arise as cyclization reactions. The co-PAN fibers caused a larger shrinkage, while the onset of the shrinkage change in later period is, shifted to lower temperature. Significant morphological changes are shown to precede onset of the cyclization reactions and also during these reactions.

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Formation and Dispersion of Nitric Acid Vapor from Stack Flue Gas

  • Park, Mi Jeong;Wu, Shi Chang;Jo, Young Min;Park, Young Koo
    • Asian Journal of Atmospheric Environment
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    • v.8 no.2
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    • pp.96-107
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    • 2014
  • Extreme recovery of the thermal energy from the combustion of flue gas may bring about early gas condensation resulting in the increased formation of nitric acid vapor. The behavior of the nitric acid formed inside the stack and in the atmosphere was investigated through a computer-aided simulation in this study. Low temperatures led to high conversion rates of the nitrogen oxide to nitric acid, according to the Arrhenius relationship. Larger acid plumes could be formed with the cooled flue gas at $40^{\circ}C$ than the present exiting gas at $115^{\circ}C$. The acid vapor plume of 0.1 ppm extended to 25 m wide and 200 m high. The wind, which had a seasonal local average of 3 m/s, expanded the influencing area to 170 m along the ground level. Its tail stretched 50 m longer at $40^{\circ}C$ than at $115^{\circ}C$. The emission concentration of the acid vapor in the summer season was a little lower than in the winter. However, a warm atmosphere facilitated the Brownian motion of the discharged flue gas, finally leading to more vigorous dispersion.

Adsorption Behavior of Primary amine on Activated carbon Rayon-fiber Surfaces as Induced by Oxygen Functional Complexes (Rayon계 ACF의 표면 산소관능기 도입과 Primary amine의 흡착 거동)

  • Kim, Byeoung-Ku;Shin, Hae-Geun;Seo, Jung-Kyu;Lee, Moon-Young;Ji, Sang-Un
    • Journal of the Korean Society of Tobacco Science
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    • v.31 no.1
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    • pp.9-17
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    • 2009
  • Activated carbon fiber (ACF) was surface modified by nitric acid to improve the adsorption efficiency of the propylamine. Functional groups and textural properties of modified ACF were investigated. The total surface acidity increased about 7 times to that of as-received ACF by modification with 1 M nitric acid solution, carboxylic and phenolic groups mainly increased. However, the specific surface areas and the total pore volumes of the modified ACFs were decreased by 5-8% due to the increased blocking (or demolition) of micropores in the presence of newly introduced complexes. Despite the decrease of textural properties, it was found that the amount of propylamine adsorbed by the modified ACFs was increased by approximately 17%. The oxygen and nitrogen contents on the modified ACF increased by 1.5 and 3 times compared with the as-received ACF. From the XPS results, it was observed that propylamine reacted with strong or weak acidic groups, such as -COOH or -OH on the ACF surfaces, resulting in the formation of pyrrolic-, pyridonic- or pyridine-like structures.

Synthesis of (Ti,Al)N Powder by the Direct Nitridation(II) (직접질화법에 의한 (Ti,Al)N계 복합질화물의 합성(II))

  • Cho, Young-Soo;Lee, Young-Ki;Sohn, Yong-Un;Park, Kyong-Ho;Kim, Seok-Yoon
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.3
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    • pp.219-227
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    • 1996
  • The purpose of this research is to develop the technology for the synthesis of (Ti,Al)N powder, which shows simultaneously the excellent properties of TiN and AlN, from the Ti-Al intermetallic compounds by the direct nitriding method. The effects of variables such as temperature, Ti-Al intermetallic compounds ($TiAl_3$, TiAl and $Ti_3Al$) were investigated by TG, XRD and SEM. The (Ti,Al)N powder can be easily synthesized from the intermetallic compounds by the direct nitriding method. Among the intermetallic compounds, the nitriding behavior increased with TiAl> $Ti_3Al$ > $TiAl_3$, as the difference of diffusion coefficient for nitrogen in each materials. The ternary nitride such as $Ti_2AlN$ and $Ti_3Al_2N_2$ can be synthesized by the direct nitriding method, although the ternary nitride coexist with TiN and AlN. The ternary nitrides are stable below $1400^{\circ}C$, but these are gradually decomposed into TiN and AlN above $1400^{\circ}C$.

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