• 제목/요약/키워드: Nitrogen atmosphere

검색결과 540건 처리시간 0.024초

상압 플라즈마의 광 방출 스펙트럼 특성조사에 관한 연구 (The Study on Emission Spectrum Characteristics of Atmosphere Pressure Plasma)

  • 박성진
    • 조명전기설비학회논문지
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    • 제27권2호
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    • pp.77-83
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    • 2013
  • In this study, we aimed to determine the optical properties of the plasma used for the dry cleaning method. The optical properties of the atmospheric pressure plasma device were measured through the degree of ionization of hydrogen or nitrogen gas by ionized atmospheric gas. The degree of ionization of hydrogen or nitrogen is closely associated with surface modification. We observed through our experiments that argon gas, an atmospheric gas, caused an increase in the ionization of nitrogen gas, which has similar ionization energy. This type of increase in nitrogen gas ions is believed to affect surface modification. The results of our study show that the pressure of argon gas and the partial pressure of argon and nitrogen gases lead to different results. This important result shows that argon ions can affect the ionization of nitrogen gas.

질화분위기에 따른 반응결합 질화규소의 미세구조변화 (The Microstructure of the Reaction -Bonded $Si_3N_4$ Formed in the Various Atmosphere)

  • 박지연;김종희
    • 한국세라믹학회지
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    • 제23권5호
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    • pp.61-66
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    • 1986
  • The gas mixtures ($H_2$/$N_2$, He/$N_2$) having a high thermal conductivity allow the heat generated by the nitriding exotherm to be dissipated from the compact in to the nitriding atmosphere permitting a more accurate control of temperature and produces a more uniform microstructure. In order to observe the effect of the mixed gas atmosphere on the microsturcture of RBSN. the specimen was nitrided in the mixed gas atmosphere which was containe up to 50vol% $H_2$ or He for 0-12 hrs at 135$0^{\circ}C$. The addition of hydrogen to nitrogen gas resulted in the growth of a-needle at the early stage of nitrding increase of the reaction rate and a finer and more uniform microstructure. in case of the addition of helium the behaviour of reaction was similar to the one with pure nitrogen. As the amount of helium was increased a coarse microstructure was formed.

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LM3V 지면모델의 국내 적용성 평가를 위한 유출량 및 질소 모의 연구 (Study on Simulation of Runoff and Nitrogen for Application of LM3V Model in South Korea)

  • 정충길;김성준
    • 한국농공학회논문집
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    • 제59권4호
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    • pp.1-15
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    • 2017
  • Eutrophication of surface waters is of concern worldwide, because it can result in many undesirable water-quality and ecological problems, such as hypoxic 'dead' zones and harmful algal blooms, both associated with considerable economic costs. In this study, we used LSM (Land Surface Model) to simulate nitrogen in five major rivers in the Southern Korean Peninsula. The main objective of this research was to enhance nitrogen data for input of LM3V model in South Korea. Input data for nitrogen fluxes were categorized into three sections including agriculture fertilizer, livestock manure, atmosphere deposition, biological fixation, and sewage pollutants were used as the nitrogen input. For using LM3V model, the nitrogen input data were regenerated by considering states of agriculture and industry in South Korea at a $1/8^{\circ}$ resolution. Then, we simulated stream/river flows and N loads throughout the entire drainage networks in South Korea at a $1/8^{\circ}$ resolution. By using the same parameters for the entire country ($100,210km^2$), composed of 5 river basins with varying climate and land use, the model simulates spatial (11 sites) and temporal (1999~2010) patterns of flows and nitrate-N loads are resonable by comparing observed flow and nitrate-N loads. The r (Pearson's linear correlation) for water temperature, flow and nitrate-N at river were 080~0.93, 0.62~0.92 and 0.5~0.9 respectively. Based on enhanced N input data and model results, we find that LM3V model as land surface model can be applied in South Korea with interaction of atmosphere and land conditions.

Photoluminescence property of ZnO nanoparticle prepared by microwave irradiation method

  • Sakamoto, Naonori;Ishizuka, Satoshi;Wakiya, Naoki;Suzuki, Hisao
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.788-791
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    • 2008
  • ZnO nanoparticle was successfully prepared by microwave irradiation method in various oxygen/nitrogen ratio atmospheres. The product prepared in a low oxygen ratio atmosphere showed tetra pod shape with high aspect ratio, c/a. PL spectra of the products showed higher UV emission intensity than the others when it was prepared in the atmosphere oxygen/nitrogen=40/60.

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Characteristics of Atmosphere-rice Paddy Exchange of Gaseous and Particulate Reactive Nitrogen in Terms of Nitrogen Input to a Single-cropping Rice Paddy Area in Central Japan

  • Hayashi, Kentaro;Ono, Keisuke;Matsuda, Kazuhide;Tokida, Takeshi;Hasegawa, Toshihiro
    • Asian Journal of Atmospheric Environment
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    • 제11권3호
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    • pp.202-216
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    • 2017
  • Nitrogen (N) is an essential macronutrient. Thus, evaluating its flows and stocks in rice paddy ecosystems provides important insights into the sustainability and environmental loads of rice production. Among the N sources of paddy fields, atmospheric deposition and irrigation inputs remain poorly understood. In particular, insufficient information is available for atmosphere-rice paddy exchange of gaseous and particulate reactive N (Nr, all N species other than molecular N) which represents the net input or output through dry deposition and emission. In this study, we assessed the N inputs via atmospheric deposition and irrigation to a Japanese rice paddy area by weekly monitoring for 2 years with special emphasis on gas and particle exchange. The rice paddy during the cropping season acted as a net emitter of ammonia ($NH_3$) to the atmosphere regardless of the N fertilizer applications, which reduced the effects of dry deposition to the N input. Dry N deposition was quantitatively similar to wet N deposition, when subtracting the rice paddy $NH_3$ emissions from N exchange. The annual N inputs to the rice paddy were 3.2 to $3.6\;kg\;N\;ha^{-1}\;yr^{-1}$ for exchange, 8.1 to $9.8\;kg\;N\;ha^{-1}\;yr^{-1}$ for wet deposition, and 11.1 to $14.5\;kg\;N\;ha^{-1}\;yr^{-1}$ for irrigation. The total N input, 22.8 to $27.5\;kg\;N\;ha^{-1}\;yr^{-1}$, corresponded to 38% to 55% of the N fertilizer application rate and 53% to 67% of the brown rice N uptake. Monitoring of atmospheric deposition and irrigation as N sources for rice paddies will therefore be necessary for adequate N management.

백 시멘트의 백색도에 미치는 냉각분위기의 영향 (Influences of Cooling Atmosphere on the Whiteness in White Portland Cement)

  • 한기성;최상흘
    • 한국세라믹학회지
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    • 제15권2호
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    • pp.85-88
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    • 1978
  • Influence of cooling atmosphere on the whiteness in white portland cement was studied. The effective composition of gaseous medium of cooling atmosphere is desirable less than 0.5% of $O_2$ and 0.5~1.5% of CO. When theclinker is quenched in nitrogen atmosphere, the color of clinker becomes bright pink. In a weakly reducing gaseous medium or vacuum, the absence of oxygen brings defects in crystal and transformation in the coordination of iron, and as a result, whiteness is raised.

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The Effect of Kovar(Fe-29Ni-l7Co) Oxidation Atmosphere on the Kovar-to-Glass Seal

  • Kim, Buoung-Soo;Kim, Min-Ho;Park, Duck-Kyun;Son, Yong-Bei
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2000년도 Proceedings of 5th International Joint Symposium on Microeletronics and Packaging
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    • pp.111-111
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    • 2000
  • In order to form a uniform oxidation layer and spinel crystalline phase that has been help strong bonding in Kovar(Fe-29Ni-17Co)-to-glass sealing, the humidified nitrogen and nirtogen/hydrogen mixture was used as an oxidation atmosphere. Kovar oxidation was diffusion-controlled reaction and the activation energy was 25~32 kcal/mol at $600~900^{\circ}C.$ After oxidation at $600^{\circ}C, $ the oxidation layer was under 1 $\mu\textrm{m}$ thickness and crystalline phase was spinel which was found to be suitable for the Kovar-to-glass sealing. The Kovar-to-glass seal was carried out at $1010^{\circ}C$ and humidified nitrogen/hydrogen mixture atmosphere. Sealing properties were tested by Leak tester and SEM.

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쾌속 금형 제작을 위한 텅스텐 카바이드와 코발트 혼합물의 선택적 레이저 소결 (Selective Laser Sintering of WC-Co Mixture for Rapid Tooling)

  • 김광희;조셉비만
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2002년도 금형가공 심포지엄
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    • pp.187-194
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    • 2002
  • This paper describes the experimental results on direct selective laser sintering of WC-Co mixture for rapid tooling. The experiments were carried out within an air, argon and nitrogen atmosphere. Coupons of single layer were sintered at various laser powers, scanning speeds and scan spacings. As the energy density (energy per unit scanned area) is increased, the thickness of coupons is increased. The main problem took place during sintering within an air atmosphere was severe oxidation of WC-Co mixture. As the laser power is increased and/or scanning speed is decreased, more severe oxidation occurred. Within an argon and nitrogen atmosphere the oxidation is reduced significantly. Experiments on multi-layer sintering were also carried out.

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$ZrO_2$ 의 입자크기과 상분포에 미치는 소결분위기 영향 (Sintering Atmosphere Effect on the Grain Size and Phase Distribution of a Zirconia)

  • 백용균;안중호
    • 한국세라믹학회지
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    • 제36권11호
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    • pp.1198-1204
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    • 1999
  • The effect of sintering atmosphere on the grain sizes and phase distributions in 3Y-ZrO2 and 8Y-ZrO2 was investigated O2 and N2 were used as sintering atmospheres. In the case of 3Y-ZrO2 the sintered density was higher in N2 than in O2 while in the case of 8Y-ZrO2 contrary results were obtained. The observation can be explained by the nitrogen solubility into the zirconia lattice. That is nitrogen gas can behave as a diffusive gas contrary to the behavior in other oxides depending on the amount of Y2O3. In 3Y-ZrO2 tetragonal phase was retained at room temperature irrespective of sintering atmospheres. Grain sizes of two specimens were below 2㎛ and larger in O2 thin in N2 Under a given stress the transformability of tetragonal phase into monoclinic phase was higher in O2 than N2. The results are discussed on the basis of an effect of the grain size and non-transformable ttragonal(t') phase.

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쾌속 금형 제작을 위한 텅스텐 카바이드와 코발트 혼합물의 선택적 레이저 소결 실험 (Experiments on Selective Laser Sintering of WC-Co Mixture for Rapid Metal Tooling)

  • 김광희;조셉비만
    • Journal of Advanced Marine Engineering and Technology
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    • 제26권6호
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    • pp.661-669
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    • 2002
  • Rapid tooling technique enables us to make dies and molds that produce prototype parts with the correct material at a substantially reduced cost and time. In this study, experiments on selective laser sintering of tungsten carbide-cobalt mixture were carried out to find optimal sintering conditions that will be applied to rapid metal tooling. The experiments were carried out within an air, an argon and a nitrogen atmosphere. Coupons of single layer were sintered at various laser powers, scanning speeds and scan spacings. Very severe oxidation took place within an air atmosphere. The oxidation is reduced significantly within an argon and a nitrogen atmosphere. The thickness of the sintered coupons is increased as the energy density, the laser energy Per unit scanned area, is increased. Several multi-layer sintering experiments were also carried out.