• Title/Summary/Keyword: Nitrogen atmosphere

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Characteristic of Tantalum Nitride Thin-films for High Precision Resistors (고정밀 저항용 질화탄탈 박막의 특성)

  • 최성규;나경일;남효덕;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.537-540
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    • 2001
  • This paper presents the characteristics of Ta-N thin-(ibm for high precision resistors, which were deposited oni substrate by DC reactive magnetorn sputtering in an argon-nitrogen atmosphere(Ar-(4∼16%)N$_2$). Sturcutural properties sutided using X-ray diffraction (XRD) indicate the presence of TaN, Ta$_3$N$\sub$5/ or a mixture of Ta-N phases in the films depending on the amount of nitrogen in the sputtering gas. The chemical composition are investigated by auger electro spectroscopy(AES). The optimized conditions of Ta-N thin-film resistors were deposited in 4 % N$_2$ gas flow ratio. Under optimum conditions, the Ta-N thin-film resistors are obtained a high resistivity, $\rho$=305.7 ${\mu}$Ωcm, a low temperature coefficient of resistance, TCR=-36 ppm/$^{\circ}C$.

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Magnetic Hardening of Nano-thick $Sm_2Fe_{17}N_x$ Films Grown by Pulsed Laser Deposition

  • Yang, Choong Jin;Wu, Jianmin
    • Journal of Magnetics
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    • v.5 no.4
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    • pp.124-129
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    • 2000
  • $Sm_2Fe_{17}N_x$ film magnets were prepared using a $Sm_2Fe_{17}$ target in a $N_2$ gas atmosphere using a Nd-YAG pulsed laser ablation technique. The effect of nitrogen pressure, deposition temperature, pulse time and film thickness on the structure and magnetic properties of $Sm_2Fe_{17}N_x$ film were studied. Increasing the nitrogen pressure up to 5 atm led to the formation of complete $Sm_2Fe_{17}N_x$ compound. Optimized magnetic properties with the nitrogenation temperature in the range 500-53$0^{\circ}C$ could be obtained by extending the nitrogenation time up to 4 hours. Relatively low coercivities of 400~600 Oe were found in $Sm_2Fe_{17}N_x$films 50~100 m thick, while a $4\piM_s$ of 10$\sim$12 kG could be achieved. In-plane anisotropy, which was the basic goal in this study, was achieved by controlling the nitrogenation parameters.

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Study on Joint Technology for HTS Field Coils (고온초전도 계자코일 제작을 위한 접합기술 연구)

  • 손명환;김석환;백승규;조영식;서무교;이언용;권영길;윤문수
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.256-258
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    • 2002
  • Six different types of joining between two parallel high Tc super-conducting tapes were prepared and I-V characteristic curves were obtained at the atmosphere of liquid nitrogen. Resistances in joint parts were estimated from I-V curves. We selected the best jointing method among these six methods and its availability for fabricating HTS field coils is discussed.

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Fabrication of AlN Whiskes by Self-propagating High-temperature Synthesis (자전 고온 합성법에 의한 질화 알루미늄 휘스커의 제조)

  • 이경재;장영섭;김석윤;김용석
    • Journal of the Korean Ceramic Society
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    • v.32 no.8
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    • pp.931-937
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    • 1995
  • AlN powder and whiskers were synthesized by direct nitridation of aluminum powder in pure nitrogen atmosphere. The nitridation reaction of aluminum powder was initiated by heating the sample to the ignition temperature and the reaction was finished in less than 3 minutes. AlN whisker-shaped morphology was observed predominantly when the sample was heated above 90$0^{\circ}C$.

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Fabrication and Properties of HTS Double Pancake Coils (고온초전도 더블 팬케이크 코일 제작 및 특성)

  • 손명환;이언용;백승규;권영길;윤문수;권용덕
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.02a
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    • pp.263-265
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    • 2003
  • A winding machine to fabricate the double pancake coils was manufactured. A race-track type double pancake coil using high temperature superconductor (HTS) tape was prepared and I-V and I-H characteristic curves were obtained at the atmosphere of liquid nitrogen. The winding method to make the double pancake coil and its properties is discussed.

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Influence of Nitrogen/Hydrogen Atmospheres on Sintered Properties of P/M Components

  • Philips, Thomas;Koh, Kyung-Sug
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.818-819
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    • 2006
  • The effect of individual gas constituents in a sintering atmosphere is examined to optimize the sintered properties of Iron-Carbon P/M components. The influence of sintered properties is reviewed as a function of hydrogen percentages and dew point in the sintering zone. Microstructures, porosity, pore morphology and dimensional changes are the subject of this review. The effects of CO containing atmospheres are compared against the non CO atmospheres in terms of hardness, carbon control and dimensional changes.

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The Impedance Properties of Poly(p-phenylene)-based Carbon/Li cell (PPP-based Carbon/Li cell의 임피던스 특성)

  • 류현옥;홍성문;김주승;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.283-285
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    • 1997
  • We have obtained disordered carbon by pyrolyzing PPP in a nitrogen atmosphere for 8 hour at 700$^{\circ}C$. AC impedance property was measured with the PPP-based carbon/EC-DEC/Li cell. The impedance spectra of the cell were measured during the 1st discharge proceed. As the result of measurement the cell resistance decreased in intial discharge, but increase in final discharge.

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Reactions of Thioxanthylium Ion with Organomercurials

  • Shin, Dong-Myung;Kim, Kyong-Tae
    • Bulletin of the Korean Chemical Society
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    • v.2 no.3
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    • pp.114-121
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    • 1981
  • Reactions of thioxanthylium ion with dimethyl-, dibenzyl-, diisopropyl-, and diphenylmercury in the air gave 9,9'-methylenedithioxanthene, 9-benzylthioxanthene, 9-acetonylthioxanthene, and 9-phenylthioxanthene, respectively, as a 9-substituted thioxanthene. In contrast with reactions with aromatics with an electron-donating group, large amount of thioxanthene and thioxanthone were obtained. However, only trace amounts of thioxanthene and thioxanthone were obtained from the reaction with dibenzylmercury under nitrogen atmosphere. In order to explain these reactions, one electron transfer between thioxanthylium ion and organomercurials was proposed.

Synthesis of Polyimide Derived from 4-Methyl-1,2-phenylene Bis(4-aminobenzoate) and 4,4'-Hexafluoroisopropylidenediphthalic Anhydride

  • Byung Hyun Ahn
    • Elastomers and Composites
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    • v.58 no.1
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    • pp.26-31
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    • 2023
  • Aromatic diamine containing ortho catenation and methyl group was synthesized from 4-methyl catechol and 4-nitrobenzoyl chloride. Subsequently, a poly(amic acid) was prepared by reacting 4-methyl-1,2-phenylene bis(4-aminobenzoate) with 4,4'-hexafluoroisopropylidenediphthalic anhydride (6FDA). The resulting poly(amic acid) was transformed into a polyimide through chemical imidization. The polyimide formed was soluble in N-methyl-2-pyrrolidone (NMP) and could be cast into a flexible, transparent film. Furthermore, the polyimide exhibited a 5% weight loss at 380 ℃ in the nitrogen atmosphere.