• Title/Summary/Keyword: Nitrogen Recycling

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Assessment of Regional-Based Nitrogen Loading and Recycling Capacity of Livestock Manure (지역별 가축분뇨의 질소부하 및 자원화 용량 평가)

  • Ryoo, Jong-Won
    • Journal of Animal Environmental Science
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    • v.18 no.3
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    • pp.235-246
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    • 2012
  • Reusing livestock manure have various advantages in securing soil organic resources. In this study, the N-loading and recycling capacity assessment of animal manure was analyzed by comparing between the cultivated areas of crops and the amount of manure units that are generated from livestock manure. From this assessment, the possibility of recycling resources of livestock manure was evaluated. The amount generated of livestock manure in Gyeonggi-do were evaluated by applying the manure units to the number of livestock manure. The analysis of manure unit per ha shows that the N loading by MU is quite different by region. When it comes to nitrogen loading, the MU per ha of cultivated land in excess of the N-amount was the highest in the Gyeonggi-do province with 2.70 MU/ha, which is higher than the appropriate level. The Chungcheongnam-do province came next with 2.31 MU. So the recycling capacity assessment was carried out mainly based on areas of forage crops, rice that can be provided by recycling livestock manure. The recycling capacity ware highest in Jeollanam-do and Jeollabuk-do. In order to properly apply the livestock manure into organic resources, the seasonal situation that effects the nitrogen demands of crops along with the regional effects crop cultivation should be seriously analyzed. In addition, a system that can effectively produce and manage fertilizer should be established.

Electrochemical Reduction of Nitrate Ion in an Aqueous Solution (수용액에서 질산성 질소의 전기화학적 환원거동)

  • Park, J.K.;Jeon, C.J.;Lee, C.K.
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.246-251
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    • 2003
  • 전기분해법을 이용하여 수용액 중의 질산성 질소의 환원거동에 대한 연구를 통하여 수용액중의 질산 함량을 제어하는 연구를 수행하였다. 촉매전극을 채택한 복극전해조에서 30분의 조업에 질산 100ppm 이하의 저농도 용액은 70%, 300ppm 이상의 고농도의 경우는 90%까지 질소를 용이하게 제거할 수 있었다. 초기 질소농도가 증가하면서 한계전류밀도도 크게 증가하였으며, pH가 감소할수록 환원전류가 증가하였다. 그리고 수용액의 pH는 질소 환원반응기구에 큰 영향을 주는 것으로 판명되었으며, 산성에서는 질소형태로 중성 혹은 염기성에서는 암모니아 형태로 환원되는 것으로 추정된다.

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Recovery of Zinc and Lead From Steel Dust by Submerged Injection Smelting Process (SUBMERGED INJECTION SMELTING PROCESS에 의한 제강분진중 유가금속의 회수)

  • 문남일;최대규;이용학
    • Resources Recycling
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    • v.1 no.1
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    • pp.37-43
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    • 1992
  • The submerged injection smelting process was performed to recover Zn and Pb from steel dust throuth vaporization and to investigate the effect of temperature, slag composition, injection time, gas flow rate, etc. on the recoveries of valuable metals. The results show that vaporation rates of zinc and lead increased at higher temperture and higher moral ratio of ferrous to ferric oxides. In the initial stage of submerged injection of nitrogen gas, the molten slags of the dust have high value of molar ratio of $Fe^{2+}$/$Fe^{3+}$ and hence zinc and lead can be effectively recovered.

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Effects of Application Amount of Organic Compound Fertilizer on Lettuce Growth and Soil Chemical properties under Plastic film house (시설재배지에서 유기복합비료 시용량에 따른 상추 생육 및 토양화학성에 미치는 영향)

  • Kim, Myeong-Suk;Park, Seong-Jin;Kim, Sung-Hyun;Hwang, Hyun-Young;Shim, Jae-Hong;Lee, Yun-Hae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.3
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    • pp.37-44
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    • 2020
  • The Project supporting organic fertilizer started in 1999 as a national policy. In farmhouse, over application of mixed organic compound fertilizer(OC) caused salt accumulation in plastic film house soil. To replace inorganic fertilizer with OC fertilizer, this study was investigated the effect of OC application on yield and soil chemical properties for lettuce cultivation in plastic film house. The OC fertilizer was applied at 50(OC50+N50), 100(OC100), and 150(OC150) % level of the basal amount of nitrogen fertilizer in soil testing recommendation. And these were compared to NPK(nitrogen, phosphat, and potash fertilizer) and PK treatment. The yield of lettuce in OC100 was similar to that of NPK treatment. In OC 50, 100 and 150 treatments, pH had a tendency to increase than that of NPK treatment. Nitrate nitrogen(NO3-N) and electrical conductivity(EC) were similar to NPK treatment. These showed that nutrients from OC fertilizer were less likely to accumulate in soil than NPK. Also, use efficiency of nitrogen in OC100 treatment were similar to NPK treatment. These results suggest that OC application as the basal dressing at the 100% level could be best to prevent a nutrient accumulation of soil and to increase the yield and commercial quality for lettuce.

Effect of pH Adjustment by Adding Sulphuric Acid on Chemical Properties in Aerobic Liquefying Process of Co-Digestate of Swine Manure and Apple Pomace (돈분과 사과착즙박의 혼합 혐기소화액의 황산첨가 pH 조절이 호기성 액비화과정에서의 화학적 특성 변화)

  • Ryoo, Jong-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.3
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    • pp.5-14
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    • 2020
  • This study aims to survey the effect of sulphuric acid (H2SO4) treatment for pH adjustment with 6.5 and 7.0 regarding ammonia volatilization on chemical content change in the aerobic liquefying process of co-digesate swine manure and apple pomace. The digestates of swine manure was aerated with 0.3 ㎥ air/㎥·min for 60 days. The untreated digestate showed the increased pH and decreased contents of electrical conductivity (EC) and total nitrogen (T-N). The untreated digestate had a high concentration of NH3 with 172.6 mg/L, but, ammonia (NH3) concentration of H2SO4-treated digestate was significantly lower than that of untreated digestate. The H2SO4-untreated digestate for retaining aeration showed a decreased concentration of 47.2% of ammonium nitrogen. While, the H2SO4-treated digestate had a high concentration of ammonium nitrogen compared to the untreated digestate. Also, the H2SO4 treatment affected to increase the contents of nitrogen and phosphoric acid content. Therefore, the pH adjustment with H2SO4 might be a useful method for the decreased ammonia concentration and nitrogen maintenance in the aerobic liquefying process of swine manure digesate.

Estimation of Agricultural By-products and Investigation on Nutrient Contents for Alternatives of Imported Oil-cakes (수입유박 대체 비료자원 발굴을 위한 농업부산물 발생량 추정 및 양분 함량 조사)

  • An, Nan-Hee;Lee, Sang-min;Cho, Jung-Rai;Lee, Cho-Rong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.4
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    • pp.71-81
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    • 2019
  • This research was conducted to improve availability of agricultural by-products, national natural resources that could be used as fertilizer source, by estimating the amount of production and collecting main contents of fertilizer substances from previous studies and data, in order to be used as basic data to investigate national resources that could be used as alternatives for imported oil-cakes in the future. Conversion factor was used to estimate annual production of agricultural by-products for main 34 crop types in 2018. For total agricultural by-products, rice straws accounted at 50.3% for the highest proportion, followed by 8.7% of rice husks, showing that by-products from rice harvest accounted at 59.0% for all by-products. Further, there were listed the contents of fertilizer substances (nitrogen, phosphoric acid, potash) in 40 types of by-products from agricultural areas. The average contents of nitrogen, phosphoric acid, and potash in agricultural by-products were 1.43%, 0.59%, and 1.90%, respectively. As a result of estimating the annual nitrogen supply amount from 26 agricultural by-products in 2018, it was found that it could supply 44,911 tons of nitrogen. The investigated by-products contained fertilizer substances such as nitrogen, phosphoric acid, and potash, but the contents were lower compared to castor oil-cake used as main component of organic fertilizer. Therefore, resource management plan needs to be established for efficient use of by-products because time, location, and nutrient content of agricultural by-product production were extremely different. Research on fertilizer and manure using agricultural by-products need to be conducted to develop and distribute alternatives for imported oil-cakes.

Effects of biodegradable polymer coating urea to nitrogen release in the soil column (생분해성 코팅 요소 종류별 질소 용출 및 온실가스 발생량에 미치는 영향)

  • Jaeyee Choi;JoungDu Shin;HyunJong Cho;Woojin Chung;Sang Beom Lee;Seok In Yun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.1
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    • pp.49-59
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    • 2024
  • Biodegradable coating urea plays an important role in reducing the non-pollutants in agroecosystems, maximizing the plant nutrient utilization efficiency and slow-releasing nitrogen. Herein, the objective of this study was to investigate the nitrogen-releasing patterns and greenhouse gas emissions on different biodegradable coating urea. The treatments consisted of the control as an application of chemical fertilizers, NBCF as the non-biodegradable coating urea, NB60, and MDS as biodegradable coating urea. As a result of this study, the maximum accumulated total nitrogen (TN) concentration in the NBCF was higher at 33% than one in the NB60 during the precipitation periods. Its leaching period in the NCBF was prolonged for day 10 compared to the NB60. TN and NO3-N releasing patterns in the NBCF and NB60 were fitted well on linear types(R2≥0.991), but their control and MDS were fitted well on Sigmoid curves(R2≥0.994) with high releasing concentration in the MDS compared to the control during leaching periods. For the greenhouse gas emissions, CH4 emissions in the NBCF, NB60, and MDS were increased at 0.38%, 11.36%, and 5.91%, and N2O emissions were also increased at 50.5%, 32.4%, 58.8% as compared to the control, respectively. Therefore, application of biodegradable polymer coating urea might mitigate the non-point pollutants in agro-ecosystem.

Effects of Residual Food Fermentation Solution on the production of Lettuce(Lactuca sativa L.) (상추에 대한 남은 음식물 혐기 발효액의 시용 효과)

  • Chang, Ki-Woon;Yu, Young-Seok;Jung, Yun-Kyoung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.4
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    • pp.111-116
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    • 2001
  • As part of the recycling methods, residual food through the anaerobic fermentation process was decomposed into methane gas and fermentation liquid. The research was conducted to measure the effect of application of fermentation liquid on chemical properties of soil and plant growth according to application rate and separate manure at the base of nitrogen in fermentation liquid. The fermentation liquid contained 0.52% nitrogen was applied in treatments by standard fertilizer. The treatments were composed of the control only with chemical fertilizer and N-50, N-100-4, N-100-8 were each of applied with 50, 100(6 times), 100(3 times)% of fermentation liquid contrast to standard fertilizer. Properties of fermentation liquid was high EC because of waster soluble organic compounds as well as much of salts and also contained a lot of suspended solid. The changes of soil chemical properties little occurred in before and after of experiment but EC and content of ex. Ca in soil were increased. Fresh weigh in treatments applied with fermentation is high than that of control but the difference between treatments little showed. The above result means if fermentation liquid be used instead of chemical fertilizer the volume of used fermentation liquid will be reduced by 50% of present standard fertilizer.

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Simultaneous Removal of Carbon and Ammonia Nitrogen from Recirculation Water in High Density Seawater Aquaculture Farm (고밀도 해산어 양식장 순환수로부터 유기물 및 암모니아질소 동시 제거)

  • 정병곤;김문태;이헌모
    • Journal of environmental and Sanitary engineering
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    • v.18 no.1
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    • pp.15-22
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    • 2003
  • Treatability tests were conducted using EMC process to study the feasibility of applying this process as recycling-water treatment system in high density seawater aquaculture farm. To study the effect of organic and ammonia nitrogen loading on system performance, hydraulic retention time of reactor was reduced gradually from 12hr to 10min. The conclusions are can be summarized as follows. When the system HRT was reduced from 12hr to 10 min gradually, there was little noticeable change(reduction) in ammonia nitrogen removal efficiencies until 2hr of HRT, however, removal efficiencies were decreased dramatically when the system was operated under the HRT of less than 2hr. In case of organics(COD), there was no dramatic deterioration in removal efficiencies depending on HRT reduction. More than 90% of removal efficiencies were maintained successfully when the system was operated at the HRT of 10 min. In case of system performance depending on media packing ratio in reactor, there was little difference in each reactor performance depending on media packing ratio in reactor when the reactors were operated under the HRT of longer than 1hr, however, differences in reactor performances were considerably evident when the reactors were operated under the HRT of shorter than 1hr. That is, the more reactor was packed, the better reactor performed. When comparing reactor performance among 25%, 50%, 75% packed reactor, it can be judged that media packing ratio more than 50% plays no significant role in increasing reactor performance. For this reason, packing the media less than 50% is more reasonable way in view of economic. Such a tendency well agreed with the variation of ammonia-nitrogen removal efficiencies according to the media packing ratio in reactors at each HRT. Difference in effluent ammonia-nitrogen concentration between 50% media packing reactor and 75% media packing reactor was negligible. When comparing with the results of 25% packing reactor, difference was not so great.

The Nitrogen Behavior in the Continuous Inflow SBR according to Variations of Internal Recycling Rate (반송률 변화에 따른 연속 유입식 SBR 공정의 질소 거동)

  • Kim, Su-Yeon;Choi, Yong-Bum;Jo, You-Na;Han, Dong-Joon;Kwon, Jae-Hyouk
    • Clean Technology
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    • v.25 no.3
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    • pp.231-237
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    • 2019
  • The BOD removal efficiency according to HRT of the continuous inflow SBR process was decreased from 92.1 ~ 96.0% at HRT 9 ~ 15 h to 86.9 ~ 90.7% at HRT 6 h, but a stable removal efficiency was shown up to HRT 6 h. The T-N removal rate was decreased to 80.1 ~ 87.9% at HRT 12 ~ 15 h, to 71.9 ~ 87.0% at HRT 9 h, and to 60.1 ~ 65.7% at HRT 6 h. As a result of the test of removing organic matter and nitrogen, the optimum HRT of the continuous inflow SBR reactor is determined as 9 h. The TCODcr removal efficiency was 88.4 ~ 96.0% and the TBOD removal efficiency was 92.1 ~ 98.1% as a result of examination of organic matter removal efficiency according to a change in the recycling rate (1 ~ 5Q) at HRT 9 h, suggesting that the a change in the recycling rate has a minimal effect on the removal of organic matter. The T-N removal efficiency was 70.3 ~ 80.4% at 1 ~ 2Q, 77.2 ~ 85.6% at 3Q and 61.5 ~ 80.8% at 4 ~ 5Q according to a change in the recycling rate. The TP removal efficiency was reduced to 75.0 ~ 84.6% at 1 ~ 4Q and to 63.3 ~ 72.4% at 5Q. This is presumably because the release and ingestion of phosphorus (P) by microorganisms is not performed smoothly at 5Q or more. Therefore, the optimum recycling rate for removing organic matter and nutrients was found to be 3Q.