• Title/Summary/Keyword: Nitrogen Oxide

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Removal Effect of Nitrogen Oxide Using Magnetic Field (자계를 이용한 질소산화물의 제거 효과)

  • Lee, H.S.;Park, J.Y.;Park, S.H.;Lee, D.H.
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.64-66
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    • 2002
  • This study is to develop electromagnetic plasma reactors for indoor air purification, Removal effect of nitrogen oxide using magnetic field are investigated. And AC or DC high voltage is applied for corona discharge, flow rates are 150${\sim}$1500${\ell}$/min and NO initial concentration is about 10 ppm. In the results, NOx removal rate by AC power is about 10 % higher than that by DC power under the experimental condition of 700 ${\ell}$/min, 5 magnets. When magnet is applied to the reactor, NOx removal rate increased.

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Effect of Ultra-high Injection Pressure on Combustion and Emission Characteristics in a Single-cylinder Diesel Engine (초고압 분사 압력 적용에 따른 단기통 디젤 엔진에서의 연소 및 배기 특성에 관한 연구)

  • Cho, Wonkyu;Kang, Seungwoo;Bae, Choongsik;Kim, Youngho
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.41-44
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    • 2015
  • Experimental study was conducted to investigate the effect of ultra-high injection pressure on combustion and emission characteristics in a single-cylinder diesel engine. Electronically controlled ultra-high pressure fuel injection system consistently supplied the fuel of ultra-high pressure up to 250 MPa. Various injection pressures, 40 to 250 MPa, were applied and compared. A injector with eight identical nozzle holes which have diameter of $105{\mu}m$ was used. The results showed high potential to improve the nitrogen oxide (NOx) and particulate matter (PM) trade-off relationship with an ultra-high injection pressure and the exhaust gas recirculation (EGR).

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Denitrification of Anaerobic Sludge in Hybrid type Anaerobic Reactor(I): Acetate as Substrate (Hybrid type 반응조에서의 혐기성 슬러지의 탈질(I): 초산을 기질로 사용한 경우)

  • Shin, Hang-Sik;Kim, Ku-Yong;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.4
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    • pp.35-44
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    • 1999
  • In this study, it was attempted to remove nitrate and carbon in a single-stage reactor using acetate as substrate. Hybrid type upflow sludge baffled filter reactor was adopted using anaerobic sludge. Sludge bed in the bottom of reactor was intended to remove carbon and nitrate by denitrification and methanogenesis. And floating media in the upper part of reactor were intended to remove remaining carbon which was not removed due to the inhibition of nitrogen oxide on methane producing bacteria. The reactor removed over 96% of COD and most of nitrate with volumetric loading rate of $4.0kgCOD/m^3{\cdot}day$, hydraulic retention time of 24hr, 4,000mgCOD/L, and $266mgNO_3-N/L$. Nitrate in anaerobic sludge was converted to nitrogen gas(denitrification) or ammonia (ammonification) according to pH of influent, COD removal efficiency was easily affected by the change of volumetric loading rates and nitrate concentration. And when influent pH was about 4.7, most nitrate changed to ammonia while when influent pH was about 6.8~7.0, most nitrate denitrified independent of $COD/NO_3-N$ ratio. Most granules were gray and a few were black. In gray-colored granule, black inner side was covered with gray substance and SEM illustrated Methanoccoci type microorganisms which were compact spherical shape. Anaerobic filter removed residual COD effectively which was left in sludge bed due to the inhibition of nitrogen oxide.

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Process Optimization for the Laser Cutting of Cold Rolled STS Sheet (냉연 스테인리스강판의 레이저 절단 특성)

  • 이기호;김기철
    • Journal of Welding and Joining
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    • v.14 no.5
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    • pp.59-68
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    • 1996
  • This study was aimed to characterize the laser cutting process for the cold rolled stainless steel sheet. The principal process parameters of the cutting process were applied to both the continuous wave form and the pulsed wave form for the laser output mode. The laser-oxygen cutting process and the laser-nitrogen cutting process were also considered to characterize the quality and efficiency of the cutting process. The laser-oxygen cutting process revealed the better productivity than the laser-nitrogen cutting process, since the laser energy and the exothermic oxidation energy exerted on the laser-oxygen cutting process simultaneously during the entire cutting process. However, the straightness of the cutting section, which was considered as the most important factors, was inferior to that of the laser-nitrogen cutting process due to the formation of chromum oxide on the cutting surface. Frequency and duration of the pulsed wave form act as the main factors for the better quality, When the frequency increased from 100 Hz to 200 Hz and the duty increased from 20% to 40%, the quality factors such as the height of dross and the surface roughness were improved remarkably. The increase in the frequency from 200 Hz to 300 Hz, on the other hand, revealed the less effective in the cutting quality.

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Biological Removal of Nitrogen Oxides from Combustion Flue Gases (연소배가스 중 질소산화물(NOx) 제거를 위한 생물학적 기술)

  • Lee, Ki-Say
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.243-251
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    • 2010
  • Nitrogen oxides (NOx) in combustion flue gas are currently mitigated by chemical processes such as catalytic reduction, absorption and adsorption. However, development of environmentally sustainable biological processes is necessary in the near future. In this paper, the up-to-dated R&D trend of biological methodologies regarding NOx removal was reviewed, and their advantages and disadvantages were discussed. The principles and applications of bacterial system including nitrification and denitrification and photosynthetic microalgae system were compared. In order to enhance biological treatment rate and performance, the insoluble nitric oxide (NO) should be first absorbed using a proper solubilization agent, and then microbial degradation or fixation is to be followed. The use of microalgal system has a good prospect because it can fix $CO_2$ and NOx simultaneously and requires no additional carbon for energy source.

Mechanical properties of epoxy composites reinforced with ammonia-treated graphene oxides

  • Park, Mi-Seon;Lee, Sangmin;Lee, Young-Seak
    • Carbon letters
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    • v.21
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    • pp.1-7
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    • 2017
  • The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine ($C-NH_2$) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.

Influence of oxytetracycline on the fate of Nitrogen species in a recirculating aquaculture system

  • Medriano, Carl A.D.;Yoon, Hyojik;Chandran, Kartik;Khanal, Samir.K.;Lee, Jaewoo;Cho, Yunchul;Kim, Sungpyo
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.123-128
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    • 2018
  • Common aquaculture practices include the use of certain pharmaceuticals such as antibiotics in avoiding diseases and promoting a healthier growth of the culture. The aim of this study is to monitor and assess the influence of different low oxytetracycline concentrations on the transformation of nitrogen compounds under aeration condition in a lab-scale recirculating aquaculture system (RAS). Over $1mg\;L^{-1}$ dose of oxytetracycline to aquaculture had induced ammonia($NH_4-N$), nitrate($NO_3-N$), soluble COD accumulation in RAS. In addition, nitrous oxide ($N_2O$) emission from RAS was significantly reduced during the oxytetracycline dose periods. After ceasing the dose of oxytetracycline, ammonia oxidation and nitrous oxide re-emission were observed. This observation indicated that low concentrations of oxytetracycline could affect the nitrogen species in RAS. Also, the emission mechanisms of $N_2O$ may not be only dependent on nitrification process but also dependent on denitrification process in our RAS system.

Nitrogen Budget of South Korea in 2008: Evaluation of Non-point Source Pollution and $N_2O$ Emission (2008년도 대한민국 질소수지 연구: 비점오염증가 및 $N_2O$발생량산정)

  • Nam, Yock-Hyoun;An, Sang-Woo;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.2
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    • pp.103-112
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    • 2011
  • The main objective of this research was to estimate Nitrogen budget of South Korea in 2008. Input-output budgets for nitrogen fluxes were categorized into three sections: cities, agricultural area, and forest. Chemical and biological fixation, dry and wet deposition, imported food and feed were used as the nitrogen input. Crop uptake, volatilization, denitrification, leaching, runoff, and forest consumption were used as the nitrogen outputs. Annual total nitrogen input was 1,294,155 ton/yr, and output was 632,228 ton/yr. Comparison with a previous research in 2005 indicates that nitrogen input was decreased by 1.9% due to the decrease in nitrogen fertilizer while nitrogen output was decreased by 6.3%. Non-point source (NPS) pollution was also estimated by mass balance approach, which increased by 22% than the previous research in 2005. The emission of nitrous oxide ($N_2O$) caused by denitrification was newly examined in this research. About 8,289 ton/yr of $N_2O$ was released from agriculture area and domestic wastewater treatment plant.

Effects of SO2 Mixture in Inlet Air on Combustion and Exhaust Emission Characteristic in diesel engine (디젤엔진에 있어서 흡기 중에 SO2혼입이 연소 및 배기배출물 특성에 미치는 영향)

  • Yoo, Dong-Hoon
    • Journal of Power System Engineering
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    • v.19 no.2
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    • pp.64-69
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    • 2015
  • Marine diesel engines with high thermal efficiency and fuel diversity used for propulsive power have been taking charge of important position on marine transport. However, marine environment has recently focused on emissions such as nitrogen oxide and sulfur oxide which is generated from combustion of low grade fuels. EGR(Exhaust gas recirculation) system is one of effective methods to reduce the nitrogen oxide emission from marine diesel engines. In general, it is considered that recirculating gas influences fuel combustion and emissions in diesel engines. However, along with positive effects of EGR, the EGR system using fuels of including high sulfur concentration should be considered about re-combustion and activation of sulfur dioxide in recirculating gas. Therefore, in experimental study, an author investigates effects of sulfur dioxide mixture concentration in intake air on combustion and exhaust emission characteristics in a direct injection diesel engine. In results, change of sulfur dioxide concentrations in intake air had negligible impact on combustion chamber pressure, rate of heat release and emissions compared with effects of oxygen decreasing and carbon dioxide increasing of EGR.

Preparation of Boron Compounds from Calcium Borate, Colemanite : Synthesis of Hexagonal Boron Nitride from Boric Oxide(III) (Colemanite 붕산염으로부터 붕소화합물의 제조 : 무수붕산으로부터 육방정 질화붕소의 합성 (III))

  • Jee, Mi-Jung;Jang, Jae-Hun;Paik, Jong-Hoo;Lee, Mi-Jai;Lim, Hyung-Mi;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.812-818
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    • 2004
  • This study has been undertaken with objective of studying the mechanism and condition of formation of hexagonal boron nitride from reduction of boric okide in the presence of carbon under nitrogen atmosphere. It was found that the formation of hexagonal boron nitride was started at 1400$^{\circ}C$ and almost completed its conversion at 1550$^{\circ}C$. The morphology of boron nitride synthesized in this study was very fine and platelet. It was considered as reaction pathway of hexagonal boron nitride that boron oxide was reduced to born and evaporated by activated carbon, and then it was reacted with nitrogen.