• Title/Summary/Keyword: Nitrogen Oxide

Search Result 687, Processing Time 0.028 seconds

Effect of Nitrogen Compounds and Organic Carbon Concentrations on $N_2O$ Emission during Denitrification (탈질에서 질소성분 및 유기탄소 농도가 $N_2O$ 배출에 미치는 영향)

  • Kim, Dong-Jin;Kim, Heon-Ki;Kim, Yu-Ri
    • Clean Technology
    • /
    • v.17 no.2
    • /
    • pp.134-141
    • /
    • 2011
  • The effects of the compounds and concentrations of nitrogenous electron acceptor, the ratio of electron donor/electron acceptor (C/N), and the complexity of electron donor on the emission of $N_2O$ during wastewater denitrification were quantitatively investigated in this study. The higher ${NO_3}^-$ and ${NO_2}^-$ concentrations, the more $N_2O$ emission was observed. ${NO_2}^-$ has strong effect on $N_2O$ emission as it emitted morc $N_2O$ than ${NO_3}^-$, 50 mg/L of ${NO_2}^-$-N gave the highest conversion (9.3%) and yield (9.8%) of $N_2O$ while ${NO_3}^-$-N (50 mg/L) gave 5.6% conversion and 11.0% yield. Lower C/N ratio decreases nitrogen removal efficiency, but it increases the conversion of $N_2O$ because of the incomplete denitrification by the limited organic carbon. When real domestic wastewater is used as the electron donor of the denitrification, $N_2O$ emission is reduced to 1/10 of the emission when single carbon (acetate) is used. It is thought that multiple carbon source utilizes many denitrification pathways and it seems to be helpful for the reduction of $N_2O$ emission.

A Case of Acute Respiratory Distress Syndrome Caused by Nitric Acid Inhalation (질산(Nitric Acid) 증기 흡입에 의한 급성호흡곤란증후군 1예)

  • Kim, Dae Sung;Yoon, Hye Eun;Lee, Seung Jae;Kim, Yong Hyun;Song, So Hyang;Kim, Chi Hong;Moon, Hwa Sik;Song, Jeong Sup;Park, Sung Hak
    • Tuberculosis and Respiratory Diseases
    • /
    • v.59 no.6
    • /
    • pp.690-695
    • /
    • 2005
  • Nitric acid is an oxidizing agent used in metal refining and cleaning, electroplating, and other industrial applications. Its accidental spillage generates oxides of nitrogen, including nitric oxide (NO) and nitrogen dioxide ($NO_2$), which cause chemical pneumonitis when inhaled. The clinical presentation of a nitric acid inhalation injury depends on the duration and intensity of exposure. In mild cases, there may be no symptoms during the first few hours after exposure, or the typical symptoms of pulmonary edema can appear within 3-24 hours. However, in cases of prolonged exposure, progressive pulmonary edema develops instantaneously and patients may not survive for more than 24 hours. We report a case of a 44-year-old male who was presented with acute respiratory distress syndrome after nitric acid inhalation. He complained of cough and dyspnea of a sudden onset after inhaling nitric acid fumes at his workplace over a four-hour period. He required endotracheal intubation and mechanical ventilation due to fulminant respiratory failure. He was managed successfully with mechanical ventilation using positive end expiratory pressure and systemic corticosteroids, and recovered fully without any deterioration in his pulmonary function.

Changes in Available Lysine and Extractable Nitrogen, and Extent of Browning during the Storage of Dried Fish Meat (건어육저장중의 유효 Lysine 및 Ex분질소의 변화와 갈변)

  • LEE Kang-Ho;SONG Dong-Suck;You Byeong-Jin;KIM Mu-Nam
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.15 no.4
    • /
    • pp.271-282
    • /
    • 1982
  • The browning development, mainly through the Maillard reaction, occurring in the dried fish meat products during storage causes reduction of the nutritional value due to the loss of the essential amino acid such as available lysine as well as off -flavor resulting in the deterioration of the food quality thus shortening the shelflife. In the work, the changes in the amount of available lysine, extractable nitrogenous compounds (nonprotein-N, amino-N, trimethylamine oxide, trimethylamine, and free lysine) and development of browning were measured to assess the relationship between the shelflife and the quality loss in dried filefish under the steady state conditions (35,45, and $55^{\circ}C;a_{w}'s$ of 0.44 0.52, 0.65 and 0.75 at each temperature) and fluctuating temperature condition of $35/55^{\circ}C$ will. alternating 7 day periods at each water activity. The results indicated that the amount of available lysine and extractable nitrogenous compounds except TMA decreased rapidly with increasing temperatures and water activities while the rate of available lysine and extractable nitrogenous compounds must be involved in the initial stage of brown pigment formation. The available lysine loss of the dried filefish products stored under the fluctuating temperature conditions was greater than that stored under its fixed mean temperature, $45^{\circ}C$. The activation energies for lysine loss obtained from the Arrhenius plot ranged 6.9 to 4.4 Kcal/mol and $Q_{10}$ values at $40^{\circ}C$ were 1.4 to 1.2. The values for browning were 15.7 to 14.4 Kcal/mol and 2.2 to 2.0 respectively. Shelf-life, defined as the time to reach 0.15 O. D./g solid or the limit of off-color deterioration by browning reaction, was extented longer than the halflife of Iysine loss, actually corresponding $75\%$ loss of available lysine. This suggested that the halflife of lysine loss might not be adequate to assess the shelf-life of the food system with high potential of protein, nonproteinous nitrogen compounds, and lipids.

  • PDF

A Study of Cold Flow Characteristics of a Flue Gas Recirculation Burner using Coanda Nozzles (코안다 노즐을 이용한 배기가스 재순환 버너의 냉간 유동 특성에 관한 연구)

  • Ha, Ji Soo;Park, Chan Hyuk;Shim, Sung Hun;Jung, Sang Hyun
    • Journal of Energy Engineering
    • /
    • v.25 no.4
    • /
    • pp.152-158
    • /
    • 2016
  • Nitrogen oxide is generated by the chemical reaction of oxygen and nitrogen in higher temperature environment of combustion facilities. The NOx reduction equipment is generally used in the power plant or incineration plant and it causes enormous cost for the construction and maintenance. The flue gas recirculation method is commonly adopted for the reduction of NOx formation in the combustion facilities. In the present study, the computational fluid dynamic analysis was accomplished to elucidated the cold flow characteristics in the flue gas recirculation burner with coanda nozzles in the flue gas recirculation pipe. The inlet and outlet of flue gas recirculation pipes are directed toward the tangential direction of circular burner not toward the center of burner. The swirling flow is formed in the burner and it causes the reverse flow in the burner. The ratio of flue gas recirculation flow rate with the air flow rate was about 2.5 for the case with the coanda nozzle gap, 0.5mm and it was 1.5 for the case with the gap, 1.0mm. With the same coanda nozzle gap, the flue gas recirculation flow rate ratio had a little increase when the air flow rate changes from 1.1 to 2.2 times of ideal air flow rate.

Effects of Lysolecithin and Sodium Stearoyl-2-lactylate on Growth Performance and Nutrient Digestibility in Broilers

  • Gheisar, Mohsen Mohammadi;Hosseindoust, Abdolreza;Kim, Hyeun Bum;Kim, In Ho
    • Korean Journal of Poultry Science
    • /
    • v.42 no.2
    • /
    • pp.133-137
    • /
    • 2015
  • We investigated the effects of supplementing low energy diets with lysolecithin and sodium stearoyl-2-lactylate on growth performance and nutrient digestibility in broilers. A total of 768 1-d-old Ross 308, mixed gender broiler chicks with an average initial body weight of 44.3 g, were used in a 35-d feeding trial. Broiler chicks were sorted into pens with 16 birds per pen and every treatment consisted of 12 pens (192 chickens per treatment). Treatments were: 1) PC: basal diet, 2) NC: PC-100 kcal, 3) T1: NC+ 0.08% lysolecithin, and, 4) T2: NC + 0.04% sodium stearoyl-2-lactylate. Body weight gain (BWG), feed intake (FI) and feed conversion ratio (FCR) were measured on a weekly basis. Chromium oxide was added to the diets at 0.2% on the last week of the experiment, as a marker for digestibility. Dietary treatments had no effect on growth performance for days 1 to 21. Low energy diet supplemented with lysolecithin and sodium stearoyl-2-lactylate in phase 2 (d 21 to 35) improved body weight gain (P<0.05). Addition of lysolecithin and sodium stearoyl-2-lactylate to the diets improved the digestibility of energy and nitrogen (P<0.05), but digestibility of dry matter was not affected. Overall, addition of an emulsifier to the diet of broiler chickens in the late growth phase enhanced growth performance and digestibility of energy and nitrogen.

Fabrication and characterization of $WSi_2$ nanocrystals memory device with $SiO_2$ / $HfO_2$ / $Al_2O_3$ tunnel layer

  • Lee, Hyo-Jun;Lee, Dong-Uk;Kim, Eun-Kyu;Son, Jung-Woo;Cho, Won-Ju
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.02a
    • /
    • pp.134-134
    • /
    • 2011
  • High-k dielectric materials such as $HfO_2$, $ZrO_2$ and $Al_2O_3$ increase gate capacitance and reduce gate leakage current in MOSFET structures. This behavior suggests that high-k materials will be promise candidates to substitute as a tunnel barrier. Furthermore, stack structure of low-k and high-k tunnel barrier named variable oxide thickness (VARIOT) is more efficient.[1] In this study, we fabricated the $WSi_2$ nanocrystals nonvolatile memory device with $SiO_2/HfO_2/Al_2O_3$ tunnel layer. The $WSi_2$ nano-floating gate capacitors were fabricated on p-type Si (100) wafers. After wafer cleaning, the phosphorus in-situ doped poly-Si layer with a thickness of 100 nm was deposited on isolated active region to confine source and drain. Then, on the gate region defined by using reactive ion etching, the barrier engineered multi-stack tunnel layers of $SiO_2/HfO_2/Al_2O_3$ (2 nm/1 nm/3 nm) were deposited the gate region on Si substrate by using atomic layer deposition. To fabricate $WSi_2$ nanocrystals, the ultrathin $WSi_2$ film with a thickness of 3-4 nm was deposited on the multi-stack tunnel layer by using direct current magnetron sputtering system [2]. Subsequently, the first post annealing process was carried out at $900^{\circ}C$ for 1 min by using rapid thermal annealing system in nitrogen gas ambient. The 15-nm-thick $SiO_2$ control layer was deposited by using ultra-high vacuum magnetron sputtering. For $SiO_2$ layer density, the second post annealing process was carried out at $900^{\circ}C$ for 30 seconds by using rapid thermal annealing system in nitrogen gas ambient. The aluminum gate electrodes of 200-nm thickness were formed by thermal evaporation. The electrical properties of devices were measured by using a HP 4156A precision semiconductor parameter analyzer with HP 41501A pulse generator, an Agillent 81104A 80MHz pulse/pattern generator and an Agillent E5250A low leakage switch mainframe. We will discuss the electrical properties for application next generation non-volatile memory device.

  • PDF

Taste Compounds of Fresh-Water Fishes 6. Taste Compounds of Korean Catfish Meat (담수어의 정미성분에 관한 연구 6. 메기의 정미성분)

  • YANG Syng-Taek;LEE Eung-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.16 no.3
    • /
    • pp.202-210
    • /
    • 1983
  • In order to elucidate the taste compounds of Korean catfish, Parasilurus asotus, free amino acids, nucleotides and their related compounds, organic bases, sugars, organic acids and minerals in the extracts of Korean catfish were analyzed, and then evaluated by sensory test of synthetic extract prepared on the basis of the analytical data. Taste panel assessments of synthetic extracts prepared with each extractive component omitted were carried out by a triangle difference test, and changes in taste profile were assessed. In free amino acid composition, glycine was dominant occupying $25\%$ of total free amino acids. The other abundant free amino acids were lysine, taurine and alanine. Judging from the result of analysis of nucleotides, IMP was dominant showing about $70\%$ of total nucleotides while ATP, ADP, AMP, inosine and hypoxanthine were low in content. Among organic bases, total creatinine was abundant and its nitrogen content occupied more than $50\%$ of the total extractive nitrogen. The amount of betaine was 18mg/100g and trace amount of trimethylamine and trimethylamine oxide were detected. The main organic acids were succinic, butyric, propionic and valeric acid. On the other hand, oxalic, fumaric, maleic, tartaric and citric acids were analyzed in trace. As for the sugars, glucose was found to be the most abundant monosaccharide. Extremely small amounts of fructoae, inositol were also detected and ribose and arabinose were trace in content. $K^+,\;Na^+,\;PO_{4}^{3-}$ and $Cl^-$ were found to be the major ions and small amount of $Ca^{2+}$ were defected. The synthetic extract, prepared with about 40 pure chemicals based on the analytical data satisfactorily revealed the natural taste of the original extract except slight difference in meaty taste and mildness. From the results of omission test the major components which contribute to produce the taste were serine, IMP, succinic acid and $PO_{4}^{3-}$.

  • PDF

The Realization on GAS Sensor Module for Inteligent Wireless Communication (지능형 무선통신용 가스 센서 모듈 구현)

  • Kim, Hyo-Chan;Weon, Young-Su;Cho, Hyung-Rae
    • The Journal of The Korea Institute of Intelligent Transport Systems
    • /
    • v.11 no.6
    • /
    • pp.123-132
    • /
    • 2012
  • Gas sensors has been used very differently that depending on following purposes; Automotive (exhaust gas, fuel mixture gas, oxygen, particulates), agriculture / food industry (fresh, stored, CO2, humidity, NH3, nitrogen oxide gas, organic gas, toxic gas emitted from pesticides and insecticides), industrial / medical (chemical gas, hydrogen, oxygen and toxic gases), military (chemical weapon), environmental measurements (CO and other air pollution consisting of sulfur and nitrogen gas), residential (LNG, LPG, butane, indoor air, humidity). The types of industrial toxic substances are known about 700 species and many of these exist in gaseous form under normal conditions. he multi-gas detection sensors will be developed for casualties that detect the most important and find easy three kinds of gases in marine plant; carbon dioxide(CO2), carbon(CO), ammonia(NH3). Package block consists of gas sensing device minor ingredient, rf front end, zigbee chip. Develope interworking technology between the sensor and zigbee chip inside a package. Conduct a performance test through test jig about prototype zigbee sensor module with rf output power and unwanted emission test. This research task available early address when poisonous gas leaked from large industrial site and contribution for workers' safety at the enclosed space.

Study on the On-Board Test of After-Treatment Systems to Reduce PM-NOx in Low-Speed Marine Diesel Engine (선박용 저속디젤엔진 적용을 위한 PM-NOx 동시저감 배출저감설비 해상실증 연구)

  • Dong-Kyun Ko;Suk-Young Jeong;In-Seob Kim;Gye-Won An;Youn-Woo Nam
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.29 no.5
    • /
    • pp.497-504
    • /
    • 2023
  • In this study, Selective catalytic reduction (SCR) + Diesel particulate filter (DPF) system was installed on a ship with a low-speed engine to conduct the on-board test. The target ship (2,881 gross tons, rated power 1,470 kW@240 rpm ×1) is a general cargo ship sailing in the coastal area. Drawing development, approvals and temporary survey of the ship were performed for the installation of the after-treatment system. For performance evaluation, the gaseous emission analyzer was used according to the NOx technical code and ISO-8178 method of measurement. The particulate matter analyzer used a smoke meter to measure black carbon, as discussed by the International Maritime Organization (IMO). Tests were conducted using MGO (0.043%) and LSFO (0.42%) fuels according to the sulfur content. The test conditions were selected by considering the engine rpm (130, 160 and 180). Gaseous emission and particulate matter (smoke) were measured according to the test conditions to confirm the reduction efficiency of the after treatment system. The results of NOx emission and particulate matter (smoke) revealed that reduction efficiency was more than 90%. The exhaust pressure met the allowable back pressure (less than 50 mbar). This study confirms the importance of the on-board test and the potential of SCR + DPF systems as a response technology for reducing nitrogen oxides and particulate matter.

Influence of N Fertilization Level, Rainfall, and Temperature on the Emission of N2O in the Jeju Black Volcanic Ash Soil with Carrot Cultivation (당근 재배 화산회토양에서 질소시비 수준 및 강우, 온도 환경 변화에 따른 N2O 배출 특성)

  • Yang, Sang-Ho;Kang, Ho-Jun;Lee, Shin-Chan;Oh, Han-Jun;Kim, Gun-Yeob
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.45 no.3
    • /
    • pp.459-465
    • /
    • 2012
  • This study was conducted to obtain investigated characteristic factors which has an influence on nitrous oxide ($N_2O$) emissions related to the environment change of nitrogen application level, rainfall and temperature. It was done by the carrot cultivation at black volcanic ashes soil in the experimental field of Jeju Special Self-governing Province Agricultural Research and Extension Services from 2010 to 2011. During the carrot cultivation period, the more amount of nitrogen fertilizer applied, the more amount of $N_2O$ emissions were released. Generally $N_2O$ emissions were so deeply released to climate as that in the first and middle of cultivation with heavy rainfall released amount is high, otherwise it was released very low at the end of cultivation and drought season. $N_2O$ emissions type was considered to relate with the rainfall pattern and soil water content. We obtained the result correlated with $N_2O$ emissions, in 2010, as the soil water and soil temperature were significant to $0.5718^{**}$ ($r$) and $0.4908^{**}$ ($r$) respectively, but soil EC was not significant to 0.2704 ($r$). In 2011, soil water was significant to $0.3394^*$ ($r$), but soil temperature and soil EC were not significant to 0.2138 ($r$) and 0.2462 ($r$) respectively. Also, $NO_3$-N and soil nitrogen ($NO_3-N+NH_4-N$) were not significant to 0.0575 ($r$) and 0.0787 ($r$) respectively. During the carrot cultivation period, the average emissions factor released by the nitrogen fertilizer application for 2 years was presumed to be 0.0025 $N_2O$-N kg / N kg. This factor was 4 times than the IPCC (0.0100 $N_2O$-N kg / N kg) factor.