• Title/Summary/Keyword: Nitrogen Oxide

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Selective Inhibition of Ammonia Oxidation and Nitrite Oxidation Linked to $N_2O$ Emission with Activated Sludge and Enriched Nitrifiers

  • Ali, Toor Umair;Kim, Minwook;Kim, Dong-Jin
    • Journal of Microbiology and Biotechnology
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    • v.23 no.5
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    • pp.719-723
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    • 2013
  • Nitrification in wastewater treatment emits a significant amount of nitrous oxide ($N_2O$), which is one of the major greenhouse gases. However, the actual mechanism or metabolic pathway is still largely unknown. Selective nitrification inhibitors were used to determine the nitrification steps responsible for $N_2O$ emission with activated sludge and enriched nitrifiers. Allylthiourea (86 ${\mu}M$) completely inhibited ammonia oxidation and $N_2O$ emission both in activated sludge and enriched nitrifiers. Sodium azide (24 ${\mu}M$) selectively inhibited nitrite oxidation and it led to more $N_2O$ emission than the control experiment both in activated sludge and enriched nitrifiers. The inhibition tests showed that $N_2O$ emission was mainly related to the activity of ammonia oxidizers in aerobic condition, and the inhibition of ammonia monooxygenase completely blocked $N_2O$ emission. On the other hand, $N_2O$ emission increased significantly as the nitrogen flux from nitrite to nitrate was blocked by the selective inhibition of nitrite oxidation.

LPG-DME Compression Ignition Engine with Intake Variable Valve Timing (LPG-DME 압축착화 엔진에서 흡기 가변밸브 영향)

  • Yeom, Ki-Tae;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.2
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    • pp.158-165
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    • 2008
  • The combustion and exhaust emissions characteristics of a liquefied petroleum gas-di-methyl ether compression ignition engine with a variable valve timing device were investigated under various liquefied petroleum gas injection timing conditions. Liquefied petroleum gas was used as the main fuel and was injected directly into the combustion chamber. Di-methyl ether was used as an ignition promoter and was injected into the intake port. Different liquefied petroleum gas injection timings were tested to verify the effects of the mixture homogeneity on the combustion and exhaust emission characteristics of the liquefied petroleum gas-di-methyl ether compression ignition engine. The average charge temperature was calculated to analyze the emission formation. The ringing intensity was used for analysis of knock characteristics. The combustion and exhaust emission characteristics differed significantly depending on the liquefied petroleum gas injection and intake valve open timings. The CO emission increased as the intake valve open and liquefied petroleum gas injection timings were retarded. However, the particulate matter emission decreased and the nitrogen oxide emission increased as the intake valve open timing was retarded in the diffusion combustion regime. Finally, the combustion efficiency decreased as the intake valve open and liquefied petroleum gas injection timings were retarded.

Hybrid artificial bee colony-grey wolf algorithm for multi-objective engine optimization of converted plug-in hybrid electric vehicle

  • Gujarathi, Pritam K.;Shah, Varsha A.;Lokhande, Makarand M.
    • Advances in Energy Research
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    • v.7 no.1
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    • pp.35-52
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    • 2020
  • The paper proposes a hybrid approach of artificial bee colony (ABC) and grey wolf optimizer (GWO) algorithm for multi-objective and multidimensional engine optimization of a converted plug-in hybrid electric vehicle. The proposed strategy is used to optimize all emissions along with brake specific fuel consumption (FC) for converted parallel operated diesel plug-in hybrid electric vehicle (PHEV). All emissions particulate matter (PM), nitrogen oxide (NOx), carbon monoxide (CO) and hydrocarbon (HC) are considered as optimization parameters with weighted factors. 70 hp engine data of NOx, PM, HC, CO and FC obtained from Oak Ridge National Laboratory is used for the study. The algorithm is initialized with feasible solutions followed by the employee bee phase of artificial bee colony algorithm to provide exploitation. Onlooker and scout bee phase is replaced by GWO algorithm to provide exploration. MATLAB program is used for simulation. Hybrid ABC-GWO algorithm developed is tested extensively for various values of speeds and torque. The optimization performance and its environmental impact are discussed in detail. The optimization results obtained are verified by real data engine maps. It is also compared with modified ABC and GWO algorithm for checking the effectiveness of proposed algorithm. Hybrid ABC-GWO offers combine benefits of ABC and GWO by reducing computational load and complexity with less computation time providing a balance of exploitation and exploration and passes repeatability towards use for real-time optimization.

Observation of flame oscillation with changing combustor pressure (연소실 압력변동에 따른 화염 진동현상의 관찰)

  • Kim, Jong-Ryul;Choi, Gyung-Min;Kim, Duck-Jool
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.275-280
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    • 2005
  • At previous study, nitrogen oxide emission was decreased with decreasing pressure index. This tendency was explained by the flame oscillation with changing combustor pressure. In this study, the characteristics of flame oscillation with changing combustor pressure were investigated. It can be found that flame length is extended and flame width is narrowed by decreasing combustor pressure. It can be observed that pilot flame and the surrounding air converge on the inner flame in the $P^{\ast}{\geqq}1$ conditions and that surrounding air and flow pattern was widely dispersed in the $P^{\ast}<1$ conditions. In the respect of average flame length, low fluctuation was shown in the $P^{\ast}<1$ conditions. On the other hands, large fluctuation was shown in the $P^{\ast}<1$ conditions. Flame oscillation are observed from $P^{\ast}=$ 0.98 in the condition of $P^{\ast}<1$ and the amplitude of flame oscillation becomes larger when $P^{\ast}$ is lowered. These results demonstrate that low NOx phenomenon was caused by flame oscillation with changing combustor pressure.

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The Simultaneous absorption of SOX-NOX using aqueous ammonia solution (암모니아수용액을 이용한 SOX-NOX 동시 흡수에 관한 연구)

  • Kim, Jae-Gang;Lee, Ju-Yeol;Park, Byung-Hyun;Choi, Jin-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.372-376
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    • 2015
  • The experiment was performed using the cleaning precipitator To investigate the absorption efficiency of the $SO_X/NO_X$ of the aqueous ammonia solution. Concentration of the cleaning liquid is 0.1, 0.5, and 1.0% with increasing absorption efficiency has improved. However, the reaction shown only a difference in time. Absorption efficiency has improved in accordance with the gas residence time. When the direction of the same gas and the cleaning liquid is determined that there is the effect of increasing the residence time. The relative impact of $SO_X$ and $NO_X$ is this likely to react slower than $SO_X/NO_X$. The yield is determined to require adjustment of the cleaning dust collector according to the concentration of the next gas.

The Relative Importance of Indoor and Outdoor Sources for Determining Indoor Pollution Concentrations in Homes in Seoul, South Korea

  • Lee, Jae Young;Kim, Kyunghwan;Ryu, Sung Hee;Kim, Chang Hyeok;Bae, Gwi-Nam
    • Asian Journal of Atmospheric Environment
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    • v.12 no.2
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    • pp.127-138
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    • 2018
  • This study measured indoor and outdoor levels of hydrocarbon volatile organic compounds (VOCs), such as benzene, toluene, ethylbenzene, and xylene isomers (collectively referred to as BTEX), as well as 13 carbonyl compounds, at 20 homes in Seoul, South Korea. Along with the sampling of BTEX and carbonyls, indoor concentrations of the air pollutants nitrogen oxide (NO) and carbon dioxide ($CO_2$) were also measured at each home. These measurements were used to understand the characteristics of BTEX and carbonyls by calculating the various ratios and correlation coefficients between measured contaminant levels. We found that carbonyls were mostly originated from indoor sources, while BTEX were originated from both indoor and outdoor sources. A high correlation between indoor levels of NO and BTEX indicated that traffic emissions were also an important sources of BTEX.

Graphitic g-C3N4-WO3 Composite: Synthesis and Photocatalytic Properties

  • Doan, An Tran;Thi, Xuan Dieu Nguyen;Nguyen, Phi Hung;Thi, Viet Nga Nguyen;Kim, Sung Jin;Vo, Vien
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1794-1798
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    • 2014
  • Graphitic g-$C_3N_4-WO_3$ composite was synthesized simply by decomposing melamine in the presence of $WO_3$ at $500^{\circ}C$. The obtained material was characterized by XRD, SEM, IR and XPS. The results showed that the as-prepared composite exhibits orthorhombic $WO_3$ phase coated by g-$C_3N_4$ and the g-$C_3N_4$ decomposed completely with N-doped $WO_3$ remaining at elevated calcination temperatures. The photocatalytic activity of the composite was evaluated by the photodegradation of methylene blue under visible light. An enhancement in photocatalytic activity for the graphitic g-$C_3N_4-WO_3$ composite compared to the conventional nitrogen-doped $WO_3$ was observed, which can be attributed to the presence of g-$C_3N_4$ in the material.

An Experimental and Numerical Study on the Oxy-MILD Combustion at Pilot Scale Heating Capacity (Pilot급 산소 MILD 연소에 관한 실험 및 수치해석적 연구)

  • Cha, Chun-Loon;Lee, Ho-Yeon;Hwang, Sang-Soon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.7
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    • pp.275-282
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    • 2016
  • MILD (Moderate and Intense Low-oxygen Dilution) combustion using oxygen as an oxidizer is considered as one of the most promising combustion technologies for high energy efficiency and for reducing nitrogen oxide and carbon dioxide emissions. In order to investigate the effects of nozzle angle and oxygen velocity conditions on the formation of oxygen-MILD combustion, numerical and experimental approaches were performed in this study. The numerical results showed that the recirculation ratio ($K_V$), which is an important parameter for performing MILD combustion, was increased in the main reaction zone when the nozzle angle was changed from 0 degrees to 15 degrees. Also, it was observed that a low and uniform temperature distribution was achieved at an oxygen velocity of 400 m/s. The perfectly invisible oxy-MILD flame was observed experimentally under the condition of a nozzle angle of $10^{\circ}$ and an oxygen velocity of 400 m/s. Moreover, the NOx emission limit was satisfied with NOx regulation of less than 80 ppm.

Effective Nitridation of Compacts of Coarse Silicon Particles (조립자규소 성형체의 효과적 질화가열법에 관한 연구(Densification of Silicon Nitride 3보))

  • 박금철;최상욱
    • Journal of the Korean Ceramic Society
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    • v.21 no.1
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    • pp.33-40
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    • 1984
  • To find out the optimum heating profile for the nitridation of compacts of graded silicon grains (max 53$mu extrm{m}$) two batches with the addition of MgO and $Mg(NO_3)_3$$cdot$$6H_2O$ to silicon particles were isostatically pressed into compacts. They were nitrided under some different nitriding schedules. The properties such as bulk densitis microstructures and formed phases were measured and observed. The following results were obtained ; 1) About 10% unreacted silicon remained in specimen which was nitrided at 1, 350$^{\circ}C$ for 240hrs. 2) One of the step-heating processes 1, 150$^{\circ}C$-1, 390$^{\circ}C$ for 65hrs are then $1, 390^{\circ}C$for 50hrs was the low temperature but with that at high temperature. 3) High pressure(10.5kgf/$cm^2$) of nitrogen at 1, 390$^{\circ}C$ accelerated the $\alpha$$ ightarrow$$\beta$ transformation of silicon nitride. 4) Magnesium nitrate was superior to magnesium oxide in the role of nitriding aid and the formation of uniform microstructures.

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Characterization of the ultra thin films of silicon oxynitride deposited by plasma-assisted $N_2O$ oxidation for thin film transistors

  • Hwang, Sung-Hyun;Jung, Sung-Wook;Kim, Hyun-Min;Kim, Jun-Sik;Jang, Kyung-Soo;Lee, Jeoung-In;Lee, Kwang-Soo;Jung, Won-June;Dhungel, S.K.;Ghosh, S.N.;Yi, J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1462-1464
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    • 2006
  • Scaling rules for TFT application devices have led to the necessity of ultra thin dielectric films and high-k dielectric layers. In this paper, The advantages of high concentration of nitrogen in silicon oxide layer deposited by using $N_2O$ in Inductively Coupled Plasma Chemical Vapor Deposition (ICP-CVD) is investigated using X-ray energy dispersive spectroscopy (EDS). We have reported about Ellipsometric measurement, Capacitance - Voltage characterization and processing conditions.

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