• 제목/요약/키워드: Nitrogen (N)

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Ti 첨가강 열영향부 조직과 인성에 미치는 질소의 영향 (Effects of Nitrogen on the Microstructure and Toughness of HAZ in Ti-Containing Steel)

  • 김병철;방국수
    • Journal of Welding and Joining
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    • 제20권3호
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    • pp.91-97
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    • 2002
  • Variation of HAZ toughness of Ti-containing steel with nitrogen content was investigated and interpreted in terms of its microstructure and the amount of soluble nitrogen present. The amounts of Ti and Al combined in TiN and AlN, respectively, in HAZ at $1400^{\circ}C$ peak temperature were less than those in base plate; 55~88% in TiN and 21~28% in AlN, indicating the dissolution of nitrifies in HAZ. The calculated amounts of soluble nitrogen using the thermodynamic analysis showed a good agreement with the measured values in other experiment. Therefore, the analysis can be used to estimate the amount of soluble nitrogen in HAZ. Simulated HAZ toughness was influenced not only by its microstructure but also by the amount of soluble nitrogen present after the formation of BN during the cooling cycle of welding. It showed maximum value when the nitrogen content is in stoichiometric ratio with titanium content, showing that soluble nitrogen in HAZ is detrimental to its toughness.

반응성 스퍼터링방법으로 증착된 Ta-N 박막의 미세구조 분석 (Analysis of the microstructure of reactively sputtered Ta-N thin films)

  • 민경훈;김기범
    • 한국표면공학회지
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    • 제27권5호
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    • pp.253-260
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    • 1994
  • Ta-N films were reactively sputter deposited by dc magnetron sputtering from a Ta target with a various Ar-N, gas ratio. Electrical resistivity of pure Ta film was 150$\mu$$\Omega$cm and decreased initially with nitrogen addition, and then increased to a value of 220$\mu$$\Omega$-cm~260$\mu$$\Omega$-cm at 9%~23% nitrogen partial flow. Rutherford backscattering spectrometry(RBS) and Auger electron spectroscopy (AES) analysis show that nitrogen content in the film is increased with the nitrogen partial flow. The film contains 58at.% nitrogen at 36% nitrogen partial flow. Both the phase and the microstructure of the as-deposisted films were investigated by x-ray diffractometry(XRD) adn transmission electron microscopy (TEM) at various nitrogen content. The phase of pure Ta film is identified as $\beta$-Ta with a 200$\AA$~300$\AA$ grain size. The phase of Ta film is changed to bcc-Ta as small amount of nitrogen is added. Crystalline Ta2N film was deposited at 24at.% nitrogen content. Amorphous phase is formed over a range of nitrogen content from about 33at.% to 35at.% while crystalline fcc-TaN is observed to form at 39at.%~48at.% nitrogen content.

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미질향상을 위한 간척지 토양 염농도별 적정 질소시비량 (Nitrogen Fertilizer Management for Improving Rice Quality under Different Salinity Conditions in Tidal Reclaimed Area)

  • 최원영;이규성;고종철;박홍규;김상수;김보경;김정곤
    • 한국작물학회지
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    • 제49권3호
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    • pp.194-198
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    • 2004
  • 본 연구는 남서해안 간척지에서 토양 염농도(저염; 0.1%, 중염; 0.3∼0.4%)별로 쌀 품질 향상을 위한 적정 질소 시비량을 구명하기 위하여 시험한 결과를 요약하면 다음과 같다. 1.유추분화기의 초장은 질소 시비량이 많을수록 컸고, 토양염농도간에는 저염 토양에서 켰다. 2. 출수기는 저염 토양에서는 표준비인 N20kg/10a에 비해 N8-N16kg/10a까지는 같았으나 N24kg/10a에서는 1일 늦었고, 중염 토양에서는 N8-N16kg/10a 까지는 1일이 삘랐고 N24kg/10a에서는 같았으며, 토양 염농도간에는 저염 토양에서보다 중염 토양에서 4일 정도 늦었다. 3. 질소시비량이 많을수록 간장이 크고, 포장도복이 심했다. 4. 저염 토양에서 질소시비량이 많을수록 $\textrm{m}^2$ 당 립수는 많았으나 등숙비율이 낮아져 발 수량은 N12kg/10a이상에서는 유의차가 없었으며, N12kg/10a이하에서 현미의 완전미율이 높고 단백질 함량이 낮았다. 5.중염 토양에서는 질소시비량이 많을수록 $\textrm{m}^2$ 당 립수가 많고 등숙비율이 비슷하여 발 수량은 질소시비량이 많을수록 높았으나 N20kg/10a 이상에서는 유의차가 없었고, 현미의 완전미율과 단백질함량은 질소시비량간에 비슷하였다. 따라서 남서해안 간척지에서 쌀 수량 및 미질 등을 고려해 볼 때, 저염 토양에서는 N12kg/10a, 중염 토양에서는 N20kg/10a이 적당할 것으로 생각된다

대기 산성 강하물 : 삼림의 질소 포화 (Atmospheric Acid Deposition : Nitrogen Saturation of Forests)

  • 김준호
    • Journal of Ecology and Environment
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    • 제29권3호
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    • pp.305-321
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    • 2006
  • 대기 산성 강하물 : 삼림의 질소 포화 한국의 연평균 습성 질소 강하량은 12.78(범위: $7.28{\sim}21.05)\;kgN{\cdot}ha^{-1}{\cdot}yr^{-1}$이고, 이것에 건성 질소 강하량(43%)을 합하여 추정한 총질소 강하량은 18.26(10.41-30.10) $kgN{\cdot}ha^{-1}{\cdot}yr^{-1}$이 된다. 이 질소 강하량은 유럽과 북미 북동부의 질소 강하량과 비슷한 수준이다. 대기 질소 강하량이 많은 온대 삼림은 질소로 포화된다. 질소로 포화된 삼림은 계류수와 토양에 질산이온 ($NO_3^-$)과 질산태질소/암모늄태질소이($NO_{3}^{-}-N/NH_{4}^{+}-N$)의 비가 높아지고, 잎의 질소 농도가 높아지므로 N/P비, N/K비 및 N/Mg 비가 높아지는 것으로 보아 무기 영양소 교란이 일어나며, 상해와 병해에 걸리기 쉬워지고 세근과 근균의 활성이 낮아짐으로써 생산성이 낮아진다. 그러고 혐질소성 종이 호질소성 종에 의하여 대치된다. 질소로 포화된 토양에서는 온실가스인 메탄($CH_4$)의 흡수가 감소되고 일산화질소 (NO)와 아산화질소 ($N_{2}O$)의 배출이 증가되어 지구온난화를 촉진할 수 있다. 이 종설은 한국의 33장소에서 6년 동안 ($1999{\sim}2004$) 측정한 부피가중 연평균 습성 질소 강하량이 삼림의 질소 포화 수준에 달하고, 광릉시험림분수계와 그 밖의 삼림 계류수의 $NO_3$ 유출량으로 미루어 보아 한국의 삼림에 질소 포화의 징후가 나타났음을 제시하며, 문헌 자료를 통해서 외국의 삼림에서 일어나는 질소 포화의 징후를 체계적으로 논하는 데 목적이 있다.

N, P 농도에 따른 Chlorella vulgaris의 성장 및 하수고도처리능 평가 (Advanced wastewater treatment capacity and growth of Chlorella vulgaris by nitrogen and phosphorus concentrations)

  • 한수현;이윤희;황선진
    • 상하수도학회지
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    • 제27권1호
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    • pp.77-82
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    • 2013
  • The growth and removal capacity of nitrogen and phosphorus of Chlorella vulgaris were evaluated in artificial wastewater with different nitrogen and phosphorus concentrations as element growing components for microalgae growth. The nitrogen concentration was varied in 9, 15, 30 and 60 mg-N/L with fixed phosphorus concentration of 3 mg-P/L. The growth and phosphorus removal capacity of C. vulgaris were high at initial nitrogen concentration of 15 and 30 mg-N/L, and the corresponding N/P ratios calculated were 5 and 10. In the case of varying in 1.5, 3, 6 and 10 mg-P/L of phosphorus concentration with fixed nitrogen concentration of 30 mg-N/L, the growth and removal capacity of nitrogen and phosphorus were excellent with phosphorus concentration of 3 and 6 mg-P/L. The corresponding N/P ratios were shown as 10 and 5. Therefore, the appropriate N/P ratio was concluded between 5 and 10 for wastewater treatment using C. vulgaris.

수도(水稻)에서 수량(收量), 질소효율(窒素效率) 및 질소흡수량(窒素吸收量)의 상호관계(相互關係) (Relationship among Grain Yield, Nitrogen Efficiency and Nitrogen Uptake Amount in Rice Plant)

  • 박훈
    • 한국토양비료학회지
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    • 제7권3호
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    • pp.147-154
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    • 1974
  • 질소(窒素)의 정조생산효율을 높이는 방법(方法)을 찾고자 정조수량(精租收量)(Y) 질소효율(E) 및 질소흡수량(窒素吸收量)(N)간(間)의 상호관계(相互關係)를 우리나라와 일본자료(日本資料)에 의(依)하여 찾아보았다. E와 N간(間)의 관계는 수개(數個) 계층(階層)으로 구분(區分)할 수 있었으며 각계층내(各階層內)에서 Y=EN=(b-aN)N 관계(關係)가 성립(成立)되었으며 여기서 b는 E의 이론적최대치(理論的最大値)였고 a는 이론적(理論的) 최대수량(最大收量)에서의 E/N치(値)였다. 수도고수량(水稻高收量) 연구(硏究)에 있어 현재(現在)의 기술(技術)은 효율 56.8에 이르렀으며 이때 질소흡수량(窒素吸收量)은 15.5kg이었다. 장래(將來)의 목표(目標)는 질소(窒素) 흡수량(吸收量) 17kg에서 효율 63에 이르는 것으로 나타났다. 일본독농가(日本篤農家)에서는 이 수준(水準)에 이미 도달(倒達)했을 가능성이 있다. 질소효율(窒素效率)의 증가(增加)없이는 고수량(高收量)을 달성(達成)할 수 있는 질소흡수(窒素吸收)가 증가(增加)되지 않는 것으로 보였다. 토양질소(土壤窒素)의 효율(效率)과 흡수량(吸收量)의 증대(增大)가 전체질소(全體窒素)의 효율증대에 필수요건(必須要件)으로 나타났다.

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Absorption and Partition of $^{15}N-labeled$ Fertilizer in Rice under Different Nitrogen Application Time and Rate Conditions

  • Chun, Areum;Lee, Ho-Jin
    • 한국작물학회지
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    • 제51권1호
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    • pp.32-40
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    • 2006
  • The nitrogen (N) absorption and partition of the rice plants are important indicators that can be used to improve the N use efficiency (NUE) of the plants. Improving the plant NUE can help to avoid nutrient waste that may cause environmental pollution. To investigate the N absorption and partition of the rice plants, Hwaseongbyeo (Japonica) and Dasanbyeo (indica/japonica) were applied with N fertilizers at the rates of 60, 120, and 180 kg N per ha in paddy field. Also micro plots of $0.81m^2$ were established inside each plot for application of $^{15}N-labeled$ fertilizer. The differences in N utilization of the rice plants were associated with the total N absorption and partitioning after the heading stage. In the grain filling period, the increase of nitrogen content in the total and leaf blades of Dasanbyeo was higher than that of Hwaseongbyeo. Soil N was the main contributor for the increase of total N of Dasanbyeo during the grain filling period. The N fertilizer uptake rate of Hwaseongbyeo rapidly increased with the increment of N fertilization rate. In Dasanbyeo, N fertilizer uptakes were similar under all rates and times of N application. From heading stage to harvest, Dasanbyeo continued accumulating nitrogen, whereas Hwaseongbyeo had small changes. In conclusion, the difference in nitrogen absorption and partition after heading of the two cultivars was caused by the ability of Dasanbyeo to accumulate and remobilize soil nitrogen to the grains during the grain filling period.

해바라기 군락의 일차생산과 질소경제 (Studies on the Nitrogen Economy and Primary Production of a Helianthus annuus Population)

  • 송승달
    • Journal of Plant Biology
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    • 제18권3호
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    • pp.101-108
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    • 1975
  • The nitrogen economy and primary production of a Helianthus annuus "Manchurian" population were studied with special reference to the pattern of seasonal changes of vertical distributions of dry matter and nitrogen quantities, and its quantitative significance was discussed in relation to the pattern of the plant population growth, distribution ratios among organs, and turnover rates of dry matter and nitrogen. The population was established in plant density of 11.1plant/$m^2$ at the experimdntal field of Kyungpook National University, Daegu. During the period of population developemnt (April-September, 1973), the annual inflow rates and outflow rates of dry matter and nitrogen were 5560 gDM/$m^2$/year and 89 gN/$m^2$/year, respectively. The distribution ratios of dry matter and nitrogen to leaves were 28% and 45%, to stems 48% and 18%, to roots 13% and 5%, and to flowers and seeds 11% and 32%, respectively. The maximum turnover rates of inflow of dry matter and nitrogen were attained in May-June, and were 216%/month and 210%/month, respectively. The amount of nitrogen demand was 52gN/$m^2$/year (58%) for the foliage growth, 13 gN/$m^2$/year(15%) for the stem growth, 20 gN/$m^2$/year(23%) for the reproductive organs, and 4 gN/$m^2$/year(4%) for the growth of the underground parts. The amount of nitrogen supply by the nitrogen withdrawn from senescing leaves and stems was 25gN/$m^2$/year(28%) and the amount of nitrogen absorption by the root from the environmental soil was 64 gN/$m^2$/year(72%). The ratiio of the a mount of produced dry matter to that of assimilated nitrogen during a year was calculated for this annual plant population as 60, which can be used as the nitrogen utility index.ity index.

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농촌유역의 질소 오염원과 기여도 해석을 위한 $\delta^{15}$N 분석(지역환경 \circled1) ($\delta^{15}$N Analysis for Interpretation of Nitrogen pollution Source and Contribution in Agricultural Watersheds)

  • 홍영진;권순국
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2000년도 학술발표회 발표논문집
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    • pp.513-518
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    • 2000
  • It has been acknowledged that fertilizer, natural soil nitrogen and animal waste, municipal waste have different mass ratio of nitrogen which is presented as a symbol of $\delta^{15}$N. and that the values of $\delta^{15}$N for fertilizer and natural soil nitrogen and animal waste are placed less than +5$\textperthousand$ and higher than +10$\textperthousand$, respectively. thus, Nitrogen pollution sources and contribution can be interpreted in watershed through $\delta^{15}$N analysis and then, analysis is performed with Kjeldhl-Dumas method. In this study, The values of $\delta^{15}$N are between +1.46$\textperthousand$ and +8.97$\textperthousand$, and the nitrate concentration is placed less than 3.31mg/L and higher than 0.19mg/L, respectively. Thus, this watershed is noncontamination area at the present time. But as a result of $\delta^{15}$N, contribution of natural soil nitrogen be discovered in this watershed, presently.

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Effect of Forms and Levels of Nitrogen Fertilizer on Plant Growth and Essential Oil Content of Agastache rugosa

  • Ohk, Hyun-Choong;Song, Ji-Sook;Chae, Young-Am
    • 한국작물학회지
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    • 제45권2호
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    • pp.128-133
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    • 2000
  • This study was carried out to investigate the effect of forms and levels of nitrogen fertilizer on plant growth and essential oil production of Agastache rugosa. Calcium nitrate had more influenced on length and width of leaves and lateral branch length than did urea. When nitrogen fertilizer level was increased from 12 kgN/I0a to 24kgN/I0a, plant growth was stimulated and dry matter of leaf and inflorescence were increased. Top dry matter of plant with calcium nitrate treatment (38.4 g) was heavier than that of urea treatment (32.8 g). Interactions among accession and nitrogen form and nitrogen rate were not significantly different for top dry matter. The forms and rate of nitrogen fertilizer did not affect estragole content. The estragole contents was higher in leaf (91.8%) than that of inflorescence (81.3%). While the essential oil content was not affected by different nitrogen forms, nitrogen level affected the essential oil contents positively by increasing dry matter. Essential oil yield was not affected by accession or nitrogen form, but by nitrogen rate. With increasing N application from 12kgN/I0a to 24 kgN/I0a, essential oil yield was increased by 95.8 %.

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