• Journal of the Korean institute of surface engineering
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• v.44 no.3
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• pp.75-81
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• 2011

Growth behaviors of iron-nitride on S45C steels at low pressure gas nitriding were examined. Surfaces of the steels covered with fine and porous oxide during the pre-oxidation using $N_2O$ gas. Well faceted particles connected with them were observed after 1 min nitriding. They grew steadily and filled inter-pores during additional nitriding process. From the X-ray diffraction analysis, ${\gamma}'$-iron nitride was dominantly formed at the initial stage but the amount of ${\varepsilon}$-iron nitride was rapidly increased as nitriding treatment time. The porous layer was formed on the particles and thickened up to half of nitride layer after 60 min nitriding. The observed growth behaviors were discussed in internal stress related with volume expansion involved in transforming from iron to iron-nitrides.

• Journal of the Korean institute of surface engineering
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• v.37 no.2
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• pp.119-127
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• 2004

In order to develop the corrosion and wear resistance of stainless steels, effects of plasma-nitriding on the surface characteristics of stainless steels containing Nb were investigated by utilizing a potentiostat. It was found that plasma nitriding at $350^{\circ}C$, compared with $500^{\circ}C$, produced a good corrosion resistance as nitriding time increased, whereas stainless steel containing low Nb content showed that pitting potential and corrosion potential decreased.

• Journal of ILASS-Korea
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• v.24 no.4
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• pp.203-208
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• 2019

In general, the oxi-nitriding method is well known as such a surface treatment way for substantial enhancement in corrosion resistance, even comparable to that of titanium. However, there are still lacks of information on thermal performance of the oxi-nitriding surface being of additional compound layers on the base substrate. Above all, the quantitative measurement of its thermal performance still was not evaluated yet. Thus, the present study experimentally measures the thermal resistance of the oxi-nitriding surface during droplet evaporation and then estimates heat transfer performance with the use of the onedimensional heat transfer model in vertical direction. From the experimental results, it is found that the total evaporation time slightly increased with the thermal resistance caused by the oxi-nitriding layer, showing a maximum difference of approximately 20% with that of the bare surface. Although the heat transfer performance of oxi-nitriding surface became slightly lower than that of the bare surface, the oxi-nitriding surface exhibits much better heat transfer performance compared to titanium.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.3
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• pp.157-163
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• 2006

This paper described the process of improving durability performance of the exhaust decoupler by the plasma nitriding. The properties of plasma nitriding treatment of AIS1304 stainless steel were tested using specimens before applying plasma nitriding to a mesh ring. In order to analyses the effect of plasma nitriding treatment on the mechanical properties, SEM(Scanning Electron Microscopes), roughness and hardness tester were used. Based on specimen plasma nitriding, we could find appropriate condition for application to the mesh ring of decoupler. To confirm the improved durability performance, we compared the number of cycles, which reaches to fracture, of the nitrided decoupler and that of the unnitrided decoupler by the bending cyclic test. In this test, the durability and wear resistance of the mesh ring are significantly improved by plasma nitriding treatment.

• Journal of the Korean Society for Heat Treatment
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• v.7 no.4
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• pp.318-327
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• 1994

According to conventional nitriding of tool steels, it was very difficult to produce a high surface hardness. This study has been conducted to investigate the influence of initial structures on the nitriding characteristics of tool steels in gas-nitrided for the improvement in surface hardness. The specimens (SACM645, STD61 steels) have been quenching and tempering at various temperature and then gas-nitrided for 30, 45 and 60hr at 500, 530 and $550^{\circ}C$ respectively in gasatmosphere of 30%$NH_3-70%N_2$ As hardness of initial structure was higher, the nitriding layer was deeper and hardness of the nitriding layer was higher. Deeper nitriding layers was due to higher diffusion rate by fine initial microstructure. Also the reason of high surface hardness was associated with formation of dispersed fine carbonitrides of nitrides.

• Journal of the Korean Society for Heat Treatment
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• v.22 no.5
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• pp.298-306
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• 2009

Gas nitriding and post oxidation were performed on stainless steels and SACM 645 steel. With increasing gas nitriding time, the increasing rate of nitrided layer was most rapid on SACM 645 steel and the nitriding depth of nitrided layer was most narrow on STS 304 steel among three steels. Corrosion resistance was increased with post oxidation on stainless steels and with increasing time the effect of corrosion resistance was decreased to compare with relatively short gas nitriding time. An improvement effect of corrosion resistance was consisted of predominantly on austenitic stainless steel by post oxidation after gas nitriding among three steels and it was relatively less influenced on martensitic stainless steel.

• Journal of the Korean Society for Heat Treatment
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• v.16 no.6
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• pp.315-319
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• 2003

Effect of nitriding on fatigue crack initiation and growth rate has been studied in Ni-Cr-Mo steel. Specimens were nitrided at $860^{\circ}C$ for 15 hr. The fatigue limit of nitrided specimens were superior to those ofannea1ed($860^{\circ}C$, 15 hr) specimens. Based on detailed observations of slip band and micro crack initiation, it is concluded that the excellent fatigue limit of nitrided specimens is attributed to improved slip initiation resistance by nitriding. The characteristic of fatigue crack growth rate of nitrided specimens was investigated by comparing with those of annealed specimens. It was found that the crack growth rate was markedly decreased and the threshold stress intensity factor range was improved by nitriding. It is concluded that the excellent fatigue limit of nitrided specimens is also attributed to improved fatigue crack growth rate and threshold stress intensity factor range by nitriding.

• Journal of Computational Design and Engineering
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• v.3 no.1
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• pp.71-90
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• 2016

Steel nitriding is a thermo-chemical process leading to surface hardening and improvement in fatigue properties. The process is strongly influenced by many different variables such as steel composition, nitrogen potential, temperature, time, and quenching media. In the present study, the influence of such parameters affecting physic-chemical and mechanical properties of nitride steels was evaluated. The aim was to streamline the process by numerical-experimental analysis allowing defining the optimal conditions for the success of the process. Input parameters-output results correlations were calculated through the employment of a multi-objective optimization software, modeFRONTIER (Esteco). The mechanical and microstructural results belonging to the nitriding process, performed with different processing conditions for various steels, are presented. The data were employed to obtain the analytical equations describing nitriding behavior as a function of nitriding parameters and steel composition. The obtained model was validated, through control designs, and optimized by taking into account physical and processing conditions.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.5
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• pp.702-711
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• 1998

The characteristics of corrosion resistance for the surface of medium high carbon steels and low alloy steels utilizing as manufacturing the machinery structures and machining tools and treating by plasma/ion nitriding process have been studied in terms of electrochemical polarization behav-iors including corrosion potential(Ecorr) anodic polarization trends and polarization resistance(Rp) The seven base materials showed a clear passivation behavior for the polarization tests in the ASTM standard solution 1N ${H_2){SO_4}$ Although the treated surface by plasma nitriding for the seven test materials showed a significant increase in hardness the treatment gave a detri-mental effect in corrosion resistance. The various characteristics including corrosion potential polarization curves microstructures corrosion current polarization resistance among non-treat-ed nitriding and/or soft-nitriding treated specimens have been investigated and some of the mechanisms discussed.

• Journal of the Korean Society for Heat Treatment
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• v.23 no.3
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• pp.142-149
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• 2010

Austenitic stainless steel is more or less difficult with conventional gas nitriding treatment, but it can be nitrided after appropriate pre-heat treatment. The pretreatment was more effective upon nitriding for austenitic stainless steel than martensitic stainless steel. Both thickness and microhardness measurements indicated that effect of the nitriding treatment was more sensitive in austenitic stainless steel than martensitic stainless steel with nitriding time. Fatigue strength was most increased with SACM 645 steel among three steels.