• Title/Summary/Keyword: Nitrate nitrogen concentration

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Effect of Loading Rate in the Operation of DEPHANOX and Modified-DEPHANOX Processes (유입부하가 DEPHANOX 및 Modified-DEPHANOX 공정에 미치는 영향)

  • Ryu, Hong-Duck;Min, Kyung-Kook;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.24-31
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    • 2004
  • This study was initiated to evaluate the efficiencies of DEPHANOX and Modified-DEPHANOX, which were devoloped to enhance nitrogen removal efficiency in municipal wastewater treatment. In the results, removal efficiency of organic matters was not affected much by increased loading rate of organic matters which is contained in influent. The nitrogen removal efficiencies according to the loading rate of influent TN was decreased drastically in conditions of over $0.2kg/m^3{\cdot}day$, which is T-N loading rate, and the DEPHANOX process was affected more sensitively than the M-DEPHANOX was. When the temperature was altered from $25^{\circ}C$ to $16^{\circ}C$ at HRT 6hrs, the removal efficiency of ammonia nitrogen was still over 90% and it was concluded that both DEPHANOX and M-DEPHANOX were strong enough to endure temperature variation. Moreover, both processes showed over 90% in ammonia removal efficiencies in over HRT 5hrs, so it was concluded that they were strong in HRT variation. M-DEPHANOX process showed a higher value than DEPHANOX did in T-N removal efficiency to the extent of 4~21 %, which resulted from differency of denitrification rates and the biosorption efficiency of organic matter in both processes. In the condition of HRT less than 4hrs, concentrations of ammonia nitrogen contained in effluents and nitrification reactors, might be sensitively affected by biosorption efficiency of organic matters in first separation tank. In the effect of effluent nitrate concentration in phosphorus removal, the more effluent nitrate concentration was decreased, the more phosphorus removal efficiency was increased. This result is related to the decrease of concentration of effluent nitrate which resulted from nitrification inhibition by decreased HRT.

Effect of the Organic and Nitrogen Removal and Electricity Production on Changing the External Resistor and the Inflow Loading in the Biocathode Microbial Fuel Cell (생물환원전극 미생물연료전지에서 외부저항 및 유입부하에 따른 유기물 및 질소 제거와 전기생산에 미치는 영향)

  • Kim, Jiyeon;Kim, Byunggoon;Kim, Hongsuck;Yun, Zuwhan
    • Journal of Korean Society on Water Environment
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    • v.31 no.5
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    • pp.556-562
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    • 2015
  • In order to remove the organic substances and the nitrate-nitrogen contained in wastewater, some researchers have studied the simultaneous removal of organics and nitrogen by using different biocathode microbial fuel cells (MFCs). The operating conditions for removing the contaminants in the MFCs are the external resistances, HRTs, the concentration of the influent wastewater, and other factors. This study aimed to determine the effect of the external resistors and organic loading rates, from the changing HRT, on the removal of the organics and nitrogen and on the production of electric power using the Denitrification Biocathode - Microbial Fuel Cell (DNB-MFC). As regards the results of the study, the removal efficiencies of $SCOD_{Cr}$ did not show any difference, but the nitrate-nitrogen removal efficiencies were increased by decreasing the external resistance. The maximum denitrification rate achieved was $129.2{\pm}13.54g\;NO_3{^-}-N/m^3/d$ in the external resistance $1{\Omega}$, and the maximum power density was $3,279mW/m^3$ in $10{\Omega}$. When the DNB-MFC was operated with increasing influent organic and nitrate loading by reducing the HRTs, the $NO_3{^-}-N$ removal efficiencies were increased linearly, and the maximum nitrate removal rate was $1,586g\;NO^3{^-}-N/m^3/d$ at HRT 0.6 h.

Cucumber Growth and Nitrogen Uptake as Affected by Solution Temperature and NO3-:NH4+ Ratios during the Seedling

  • Yan, Qiu-Yan;Duan, Zeng-Qiang;Li, Jun-Hui;Li, Xun;Dong, Jin-Long
    • Horticultural Science & Technology
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    • v.31 no.4
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    • pp.393-399
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    • 2013
  • The effect of solution temperature and nitrogen form on cucumber (Cucumis sativus L.) growth, photosynthesis and nitrogen metabolism was investigated in hydroponic culture. Cucumber plants were grown for 35 days in a greenhouse at three constant solution temperatures ($15^{\circ}C$, $20^{\circ}C$, and $25^{\circ}C$) within a natural aerial temperature ($15-30^{\circ}C$). Four nitrate:ammonium ($NO{_3}^-:NH{_4}^+$) ratios (10:0, 8:2, 5:5, and 2:8 $mmol{\cdot}L^{-1}$) at constant nitrogen (N) concentration of $10mmol{\cdot}L^{-1}$ were applied within each solution temperature treatment. Results showed an increasing solution temperature enhanced plant growth (height, dry weight, and leaf area) in most N treatments. Dry weight accumulation was greatest at the 10:0 $NO{_3}^-:NH{_4}^+$ ratio in the $15^{\circ}C$ solution, the 5:5 ratio in the $20^{\circ}C$ solution and the 8:2 ratio in the $25^{\circ}C$ solution. Photosynthetic rate (Pn) response to solution temperature and $NO{_3}^-:NH{_4}^+$ ratio was similar to that of plant growth. Probably, the photosynthate shortage played a role in the reduced biomass formation. Increasing solution temperature enhanced the nitrate reductase (NR) activity, and further reduced shoots nitrate content. Our results indicate that the optimal ratio of nitrate to ammonium that promotes growth in hydroponic cucumber varies with solution temperature.

Determination of moisture threshold for solution sampling in different soil texture (토양용액 채취를 위한 토성별 한계수분함량 설정)

  • Lee, Chang Hoon;Kim, Myung Sook;Kong, Myung Seok;Kim, Yoo Hak;Oh, Taek-Keun;Kang, Seong Soo
    • Korean Journal of Agricultural Science
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    • v.41 no.4
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    • pp.399-404
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    • 2014
  • Soil moisture is an important factor for the availability and circulation of nutrients in arable soil. The purpose of this study was to set thresholds moisture content on soil nitrate concentration in the solution for real-time diagnosis. Sandy loam, silt loam, and sandy loam was filled with $1.2g\;cm^{-3}$ at Wagner pots, 0, 100, and $200mg\;L^{-1}$ of $KNO_3$ was saturated. Nitrate in standard solution was recovered about 95% by passing the porous cup. Nitrate concentrations in sampling of soil solution were examined by using a porous cup. The soil solution was higher in accordance with sandy loam> silt loam> clay loam, limited water filled pore space for sampling soil solution was 33.7, 56.4, and 62.2%, respectively. Nitrate concentration in the soil solution was negligible at sandy loam and silt loam during sampling periods, which was decreased about 50~82% in clay loam compared to the initial $NO_3$-N concentration in the saturated $KNO_3$ solution. Over limitation of soil solution sampling, soil EC and $NO_3$-N content were increased with the saturated $NO_3$-N concentration, regardless of soil texture (p<0.05). Conclusively, soil solution by using a porous cup was possible, regardless of the soil texture, which was useful for the diagnosis in nitrate concentration of soil solution. However, because nitrate concentration of soil solution in a clay loam changes, it was necessary for careful attention in order to take advantage for the real-time diagnosis of nitrogen management in soil.

Effect of Total Nitrogen on the Nitrate Content of Crisp Lettuce Leaf in Deep Flow Culture (결구상추의 수경재배시 배양액내 전질소량 조절이 엽중 nitrate 함량에 미치는 효과)

  • 김혜진;김영식
    • Journal of Bio-Environment Control
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    • v.8 no.3
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    • pp.216-221
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    • 1999
  • To reduce leaf nitrate content, lettuce plants(Lactuca sativa var. capitata) were grown in deep flow culture. Nitrogen concentrations were controlled to 1 (6.Sme/$\ell$), 3/4 (4.9me/$\ell$), 2/4 (3.3me/$\ell$), and 1/4 strength(1.6me/$\ell$) of Yamaziki's nutrient solution from 7 days before harvest. The pH of nutrient solution was maintained at high level between 7.2 and 8.4. The values of pH and EC were increased with the nitrogen concentration in the nutrient solution. The nitrate contents were lowest at the treatment of 1/4 strength, but not significantly different among other treatments. The nitrate content was lower in outer leaves than in head leaves. The weight and diameter of head and shoot weight were lowest at the treatment of 1/4 strength.

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A Study on Photosynthesis and Nitrogen Assimilation in Cactus -Portulaca oleracea L.- (Cactus의 광합성과 질소동화작용에 관한 연구 - 한국산 쇠비름(Portulaca oleracea L.) -)

  • 장남기;김희백
    • Asian Journal of Turfgrass Science
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    • v.10 no.2
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    • pp.125-142
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    • 1996
  • Crassulacean acid metaholism (CAM) was investigated in leaves and stems of the succulent $C_4$dicot Portulaca oleracea L. Under 14-hour days, stem tissues showed much greater fluctuation of acidity than leaf tissues. But leaf and stem tissues showed almost same CAM-like pattern of acid fluctuation under 8-hour days. Stem tissues of R oleracea grown under the naturai environment showed high CAM activity, but no CAM activity was seen in leaves of those plants. In the naturally growing plants, the rapid acidification was seen in intact stems at dawn, but defoliated stems showed only a gradual increase. RuBP carlboxylase activity was very high at 2:00 P.M. in both leaves and stems. However, its activity at 1:00 A.M. and 5:30 AM. was hardly detected. particularly, activity of PEP carboxylase in leaves was very high in the early morning, though that in stem tissues was little. These results indicate that $CO_2$ passed through open stomata at dawn may be assimilated by PEP carboxylase in leaves, and then $C_4$ products move to stems. The levels of nitrate concentration and of nitrate reductase were higher in stems than in leaves. The levels were also higher in the light than in the dark. It would be suggested that considerable amount of nitrate absorbed from roots ho assimilated in stems, and nitrate transferred to leaves via stem tissues be reduced there. Key words: Portalaca oleracea, Cactus, Photosynthesis, Nitrogen assimilation, Crassulacean acid metabolism (CAM).

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A Study on the Biological Treatment of Acid Pickling Wastewater Containing a High Concentration of Nitrate Nitrogen (고농도 질산성 질소를 함유한 산세폐수의 생물학적 처리에 관한 연구)

  • Park, Sang Jin;Lee, Sang Houck
    • Journal of Korean Society on Water Environment
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    • v.31 no.3
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    • pp.253-261
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    • 2015
  • The purpose of this study is the efficient biological treatment of highly concentrated nitrate nitrogen by calcium ion control present within the pickling wastewater. In laboratory scale's experiments research was performed using a sequencing batch reactor and the evaluation of denitrification reaction in accordance with the injection condition of calcium ions, the surface properties of microorganisms, and the evaluation of sludge precipitability were performed. Results of the study showed that the denitrification reaction was delayed when injecting more than 600 mg/L of the calcium ion within the denitrification process. In addition, we observed the absorption form of calcium ions absorbed on the surface of microorganisms following an increase in the calcium ion dose. It was found that as the calcium ion dose increased the sludge precipitability also increased continuously and it is judged that a smooth denitrification induction is possible when treating the nitrate nitrogen by the calcium ion control of pickling waste water and the shortening of precipitation time enables a liquid operation to increase the reaction time.

Nitrification of low concentration ammonia nitrogen using zeolite biological aerated filter (ZBAF)

  • Kim, Jin-Su;Lee, Ji-Young;Choi, Seung-Kyu;Zhu, Qian;Lee, Sang-Ill
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.554-560
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    • 2020
  • This study focuses on nitrification through a biological aerated filter (BAF) that is filled with a zeolite medium at low concentrations of ammonia. The zeolite medium consists of natural zeolite powder. The BAF is operated under two types of media, which are a ball-type zeolite medium and expanded poly propylene (EPP) medium. Nitrification occurred in the zeolite BAF (ZBAF) when the influent concentration of ammonia nitrogen was 3 mg L-1, but the BAF that was filled with an EPP medium did not experience nitrification. The ammonia nitrogen removal efficiency of ZBAF was 63.38% and the average nitrate nitrogen concentration was 1.746 mg/L. The ZBAF was tested again after a comparison experiment to treat pond water, and municipal wastewater mixed pond water. The ZBAF showed remarkable ammonia-nitrogen treatment at low concentration and low temperature. During this period, the average ammonia nitrogen removal efficiency was 64.56%. Especially, when water temperature decreased to 4.7℃, ammonia nitrogen removal efficiency remained 79%. On the other hand, the chemical-oxygen demand (COD) and phosphorus-removal trends were different. The COD and phosphorus did not show as efficient treatment as the ammonia-nitrogen treatment.

Nitrogen Removal by Electrochemical Oxidation Using the Tube Type Electrode (튜브형 전극을 이용한 전기화학적 산화에 의한 질소제거에 관한 연구)

  • Cho, Jae-Jun;Jeong, Jong-Sik;Lee, Jae-Bok
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.5
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    • pp.580-587
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    • 2004
  • The objective of this research is to investigate the electrochemical oxidation process for nitrogen removal in wastewater involving chloride ion and nitrogen compounds. The process experiment of electrochemical oxidation was conducted by using the stainless steel tube type reactor and the $Ti/IrO_2$ as anode. Free chlorine production and current efficiency variation for total nitrogen removal was compared depending on whether electrolyte is added, and the nitrogen type distribution under an operating condition. When chloride was added as electrolyte, it was found that production of free chlorine increased and the concentration of the chloride decreased as retention time passed. The concentration of chloride in influent decreased from 1,660 to 1,198 mg/L at the current density of $6.7A/dm^2$, while concentration of free chlorine increased to 132 mg/L. Current efficiency in removal of ammonium nitrogen was increased when chloride was dosed as electrolyte. It was observed that ammonium nitrogen was oxidized to nitrite and nitrate through electrochemical oxidation and that the concentration of total nitrogen in influent was reduced from 22.58 to 4.00 mg/L at the short retention time of 168 seconds through the electrochemical oxidation of nitrogen.

Study of Factors Influenced on denitrification in wastewater treatment (폐수처리 탈질 공정에 미치는 인자 연구)

  • Jeong, Gwi-Taek;Park, Seok-Hwan;Park, Jae-Hee;Bhang, Sung-Hun;Lim, Eun-Tae;Park, Don-Hee
    • KSBB Journal
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    • v.23 no.6
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    • pp.535-540
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    • 2008
  • In this study, the effects of several factors such as initial nitrate concentration, C/N ratio, biomass amount and external carbon source on denitrification process were investigated using synthetic wastewater and sludge obtained from wastewater treatment facility. As a result, the condition of lower initial nitrate concentration was increased to the removal rate of nitrate than that of high concentration. The increases of C/N ratio and initial biomass amount were linearly enhanced the removal rate. The use of ethanol as external carbon source was shown the highest removal yield than that of others.