• 공업화학
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• 제3권2호
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• pp.312-317
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• 1992

디옥소우라늄(VI) (우라닐) 이온과 질산 이온과의 상호작용을 산소-17 핵자기공명분광법으로 연구하였다. $UO_2NO_3{^+}$의 우라닐 산소 원자(이후 우라닐 산소)의 산소-17 공명신호는 우라닐 이온의 그것보다 낮은 자기장에서 나타났다. $UO_2NO_3{^+}$의 안정도상수를 5, 15, 25, $35^{\circ}C$에서 질산 이온 농도에 따른 산소-17 화학적 이동의 변화로부터 구했으며, 그 값은 이온강도에 따라 달랐다. 안정도상수의 온도 의존성으로부터 계산한 열역학적 파라미터는 다음과 같다: ${\Delta}H=-(27.2{\pm}1.7)kJ\;mol^{-1}$와 ${\Delta}S=-(110{\pm}7)JK^{-1}mol^{-1}$. 우라닐 이온과 여러가지 음이온의 배위자와의 1:1 착물형성 반응에 대한 엔탈퍼와 엔트로피 사이에는 직선관계가 있었다.

• 한국안전학회지
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• 제5권2호
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• pp.40-49
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• 1990

For the determination of polluant NOx in ambient air, nitrate ion-selective electrode(ISE) was made. To comparison of NOx in each method, the nitrate-ISE, NEBA, Orion electrode were used to determinee NOx in ambient air. In this work, the concentration of NOx in ambient air was average 0.06ppm. The results were good agreement with those obtained by each method within a relative error of 3％, Absorbing efficiency of nitrogen oxides in ambient air was good for Alkali solution. The determination of nitrogen oxides in ambient air using the Aliquat 336N-PVC membrane electrode was one of the useful method. The best characteristics of the Aliquat 336N-PVC me,mbrane electrode were obtained with the ion-exchanger concentration level of 6.5-9.1 percent by weight. The optimal membrane composition, was 9.09wt.％ of ion-exchanger, 30.95wt.％ of PVC, 60.6wt.％ of plasticizer (DBP), and 0.5mm of thickness. Under the above condition, the electrode approached the Nernstian slope most closely, and the linear response ranges produced the best results.

• 한국대기환경학회지
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• 제8권1호
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• pp.68-73
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• 1992

A study on the formation of particulate nitrate$(NO_3^-)$ and gaseous nitrate$(HNO_3)$ in the atmosphere was carried out in Seoul from Oct 8 to 11 1991. To collect $NO_3^-$ and $HNO_3$ in the ambient air, dual filter pack sampler (47mm$\phi$) was used. In the dual filter pack sampler, the first filter was Teflon filter (poresize 1$\mum$) for collection of $NO_3^-$ and the second filter was Nylon filter (poresize 0.45 $\mum$) for $HNO_3$. Particulate nitrate$(NO_3^-)$ and Sulfate ions were analysed by Ion chromatography. $HNO_3$ concentration was higher in the day time $(9.93\mug/m^3)$ than the night time$(3.50\mug/m^3)$, and Particulate nitrate$(NO_3^-)$ concentration was higher in the night time and early morning$(6.21\mug/m^3)$ than the day time$(4.31\mug/m^3)$. The conversion rate of $NO_x$ to total nitrate$(NO_3^-, HNO_3)$ was 7.57%/hr in the day time and 4.79%/hr in the night time, and total average conversion rate was 5.60%/hr.

• 상하수도학회지
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• 제25권6호
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• pp.989-994
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• 2011

Nitrate contamination of groundwater is a common problem throughout intensive agriculture areas (non-point source pollution). Current processes (e.g. ion exchange and membrane separation) for nitrate removal have various disadvantages. The objective of this study was to evaluate electrochemical method such as electroreduction using bipolar ZVI packed bed electrolytic cell to remove nitrate from groundwater at field pilot. In addition ammonia stripping tower continuously removed up to 77.0% of ammonia. Bipolar ZVI packed bed electrolytic cell also removed E.coli. In the field pilot experiment for groundwater in 'I' city (average nitrate 30~35 mg N/L, pH 6.4), maximum 99.9% removal of nitrate was achieved in the applied 600 V.

• Bulletin of the Korean Chemical Society
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• 제15권5호
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• pp.341-346
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• 1994

The frameworks of $(Cu(NH_3)_3OH^+)_x(NH_4^+)_{12-x}-A{\cdot} zH_2O$ which were prepared by the ion-exchange of zeolite A with ammoniac cupric nitrate solution are more stable than those of $Cu_xNa_{12-2x} -A$ obtained by the ion exchange with aqueous cupric nitrate solution are more stable than those of $Cu_xNa_{12-2x} -A$ obtained by the ion exchange with aqueous cupric nitrate solution. An energetic calculation was made on the relatively stable $(CuOH^+)_2(NH_4^+)_{10}-A{\cdot} 2H_2O$ prepared by the partial evacuation of $(Cu(NH_3)_3OH^+)_2(NH_4^+)_{10}-A{\cdot} zH_2O$. The mean stabilization energies of water, OH-, and $NH_4^+$ ions are -30.23 kcal/mol, -60.24 kcal/mol, and -16.65 kcal/mol, respectively. The results of calculation were discussed in terms of framework stability. The $(Cu(NH_3)_3OH^+)_2(NH_4^+)_{10}-A{\cdot} zH_2O$ zeolite shows two step deammoniation reactions. The first deammoniation around 210 $^{\circ}$C (third DSC peak) was attributed to the decomposition of $[Cu(NH_3)_3OH^+]$ ion and the second one around 380 $^{\circ}$C (fourth DSC peak) was ascribed to the decomposition of $NH_4^+$ ion. The activation energies of the first and second deammoniation reactions were 99.75 kJ/mol and 176.57 kJ/mol, respectively.

• 대한화학회지
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• 제32권5호
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• pp.409-415
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• 1988

In this study, an aniline modified Bakelite-A resine was synthesized by polymerizing phenol, formaldehyde and aniline. Structural properties of the polymer were examined by IR spectroscopy, elemental analysis and vapour pressure osmometry. By visible spectroscopy, it was found that nitrogens of amine groups in the polymer are strongly coordinated to Ni(Ⅱ). Also a nitrate ion-selective PVC membrane electrode based on the polymer-Ni(Ⅱ) complex as ion carrier was preparaed. The electrode gave a linear response with a Nernstian slope within the concentration range $10^{-1}$ M∼$10^{-4}$M $KNO_3$.

• Bulletin of the Korean Chemical Society
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• 제11권2호
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• pp.124-126
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• 1990

The potentiometric response behavior of a polypyrrole(PPy) coated Pt electrode to nitrate ion has been studied. The electrode shows a nernstian behavior with a slope of 59 mV over 0.50 M to $1.0{\times}10^{-3}M\;NO_3\;^-$ and a detection limit of $1.0{\times}10^{-4}M\;NO_3\;^-$. The response of the electrode is fast and the selectivities for $I^-,\;ClO_4\;^-,\;and\;IO_4\;^-$ are found to be improved. The effect of pH on the potential response to $NO_3\;^-$ is compared with the existing nitrate ion selective electrodes.

• 한국환경과학회지
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• 제14권10호
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• pp.919-928
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• 2005

This study introduces the development of new supercritical water oxidation(SCW)(multiple step oxidation) to destruct recalcitrant organic substances totally and safely by using sodium nitrate as an oxidant. This method has solved the problems of conventional SCW, such as precipitation of salt due to lowered permittivity, pressure increase following rapid rise of reaction temperature, and corrosion of reactor due to the generation of strong acid. Destruction condition and rate in the supercritical water were examined using Polyvinyl Chloride(PVC) and ion exchange resins as organic substances. The experiment was carried out at $450^{\circ}C$ for 30min, which is relatively lower than the temperature for supercritical water oxidation $(600-650^{\circ}C)$. The decomposition rates of various incombustible organic substances were very high [PVC$(87.5\%)$, Anion exchange resin$(98.6\%)$, Cationexchange resin$(98.0\%)$]. It was observed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium (salt formation). However, relatively large amount of sodium nitrate (4 equivalent) was required to raise the decomposition ratio. For complete oxidation of PCB was intended, the amount of oxidizer was an important parameter.

• 생명과학회지
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• 제7권2호
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• pp.73-78
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• 1997

시판되고 있는 강염기성 $Cl^{-}$형의 음이온 교환수지를 사용하여 회분식 질산성 질소 제거 실험을 행하여 다음과 같은 결과를 얻었다. 수지의 종류에 따라 제거특성은 달랐다. 수지의 량이 많을수록, 계의 온도가 톡을 수록 질산성 질소이 제거효율은 높아졌다. 원수의 농도는 낮을수로그 원수의 공급유속은 느릴수록 질산성 질소의 제거효율이 좋았다. 음이온에 디한 겔형 이온교환수지인 SA 10A의 선택성은 ${SO_4}^{2-}>{No_3}^->NO_{2-}>{HCO_3}^-$로써 이온가 수가 높은 이온일수록 선택성이 증가하고 은 이온가인 경우에는 원자번호가 클수록 그리고 수화반경이 작을수록 선택성이 증가하였다. 증가하였다.

• 한국초지조사료학회지
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• 제20권4호
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• pp.265-274
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• 2000

To investigate the effects of anion replacement on NO3- concentration in Italian ryegrass. Plants weregrown hydroponically to the full vegetative stage. NO3 supply(control) was replaced with SO1- (Tl), C1-(T2) and water (T3) to during 14 days. The determination of inorganic nutrient uptake and quantification ofprincipal metabolites (nitrate. protein and sugar) followed. Relatively high uptake of ~ a a'n d Ca" for controlplants, K+ and POJ- for T2 plants, and C 1 for TI plants was observed, respectively. Proteins in shoot andstubble were relatively higher in control and TI plants, which coupled N source. In root proteins largelydecreased (especially in T3 plants) during experimental period. Sugars in shoot of all four treatments tendedto decrease during the first 7 days and recovered afterward. Sugars in stubble also markedly decreased duringthe first 7 days, while those in root was much less varied during experimental period. After 14 days oftreatment, nitrate concentration in shoot of control plants was 13mgIg FW. Comparing to control: nitrate inshoot reduced by 27%, 46% and 50% in TI, T2 and T3 plants, respectively. Dry weight was slightlyincreased or not significantly changed in control, T1 and T2 plants, while a significant decrease(31.3% ofcontrol) occurred in T3 plants.(Key words : Italian ryegrass, Anion replacement, Ion uptake, Protein, Sugar, Nitrate)ptake, Protein, Sugar, Nitrate)