• Korean Journal of Soil Science and Fertilizer
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• v.31 no.1
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• pp.39-45
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• 1998

As a basic research for developing a sludge application technique in forestry, this study was conducted to investigage a reasonable amount and period of sludge to be applied onto forest nursery of Acer palmatum Thunb. The paper mill sludge was used for the study, and ammonium nitrate was treated to some of them to reduce the C/N ratio lower than 40. The maximum amount of applied sludge was 7ton/ha/year, and they were spread on spring and on late summer. The sludge application did not stimulate early growth of the trees during a year. Since there was no significant changes in soil chemical properties, the amount of applied sludge was thought to be too little to result in a significant role for tree growth. However, the soil water showed significant increase of Cu when the activated sludges were applied during late summer. Thus, the time of application need to be determined cautiously with considering the risk of ground water contamination. In conclusion, if we set a goal from the view point of long-term concept such as forest productivity rather than to get a short-term product, the uncomposted sludge in small amount during growing season might be considered to be applied on forest nursery.

• The Journal of Engineering Geology
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• v.13 no.2
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• pp.239-256
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• 2003

The purpose of this study is to investigate the hydrochemical characteristics of emergency-use groundwater in the Daejeon area, and to elucidate the contamination source of $NO_3-N$ and the origin of sulfate in the groundwater. The groundwater shows weak acidic pH, the electrical conductivity ranging from 142 to $903{\;}\mu\textrm{S}/cm$, and the hydrochemical types of $Ca-HCo_3$ and $Ca-Cl(SO_4,{\;}NO_3)$. The Box-Whisker analysis and the Krigging analysis of chemical data of groundwater were made to demonstrate the concentration distribution of hydrochemical composition, and to compare the trend of hydrochemical data. The groundwater in the area of Dong-gu, Jung-gu and Daeduk-gu, where are old town, shows higher electrical conductivity, nitrate content, sulfate and $EpCO_2$ levels than groundwater in new town area of Seo-gu and Yusung-gu. ${\delta}^{15}N$ of groundwater in the area of Seo-gu and Yusung-gu ranges from +7.4 to $+9.6{\textperthousand}$, indicating that major contamination source of $NO_3-N$ is the leakage from municipal sewage pipe lines. ${\delta}^{15}N$ of groundwater in the old town area of Tong-gu, Jung-gu and Daeduk-gu shows the range between +10.2 and $+23.5{\textperthousand}$, meaning that major contamination source is leakage of septic tank. ${\delta}^{34}S$ of groundwater shows the range of $+3~13.4{\;}{\textperthousand}$. Sulfur isotope indicates the possibility of a sulfate reduction and the input of anthrophogenic source.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.499-502
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• 2004

Groundwater chemistry in a coastal region having complex contaminant sources was investigated. Water analysis data for 197 groundwater samples collected from the uniformly distributed sixty-six wells were used. Chemical analysis rand results indicate that groundwaters show wide concentration ranges in major inorganic ions, reflecting complex hydrochemical processes of pollutants. Due to the complexity of groundwater chemistry, Results illustrate that thirty five percent of the wells do not fit for drinking based on nitrate and chloride concentration in the study area. the samples were classified into four groups based on Cl and NO$_3$ concentrations and the processes controlling water chemistry were evaluated based on the reaction stoichiometry. The results explained the importance of mineral weathering, anthropogenic activities (nitrification and oxidation of organic matters), and Cl-salt inputs (seawater, deicer, NaCl, etc.) on groundwater chemistry. It was revealed that mineral dissolution is the major process controlling the water chemistry of the low Cl and NO$_3$ group (Group 1). Groundwaters high in NO$_3$ (Groups 2 and 4) are acidic in nature, and their chemistry is largely influenced by nitrification, oxidation of organic matters and mineral dissolution. In the case of chloride rich waters (Group 3), groundwater chemistry is highly influenced by mineral weathering and seawater intrusion associated with cation-exchange reactions.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.35-37
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• 2001

This study has investigated the chemical characteristics and the contamination of groundwater in relation to land use in Daejeon Metropolitan City. An attempt was made to distinguish anthrophogenic inputs from the influence of natural chemical weathering on the chemical composition of groundwater at Taejon. Groundwater samples collected at 170 locations in the Taejon area show very variable chemical composition of groundwater, e.9. electrical conductance ranges from 65 to 1,290 S/cm. Most groundwater is weakly acidic and the groundwater chemistry is more influenced by land use and urbanization than by aquifer rock type. Most of groundwater from green areas and new town residential districts has low electrical conductance, and is of Ca-HC $O_3$ type, whereas the chemical composition of groundwater from the old downtown and industrial district is shifted towards a Ca-Cl (N $O_3$+S $O_4$) type with high electrical conductance. A number of groundwater samples in the urbanized area are contaminated by high nitrate and chlorine, and exhibit high hardness. The Ep$CO_2$, that is the $CO_2$ content of a water sample relative to pure water, was computed to obtain more insight into the origin of $CO_2$ and bicarbonate in the groundwater. Factor analysis of the chemical data shows that the HC $O_3$ and N $O_3$ concentrations have the highest factor loadings on factor 1 and factor 2, respectively. Factors 1 and 2 represent major contributions from natural processes and human activities, respectively. The results of the factor analysis indicate that the levels of $Ca^{2+}$, $Mg^{2+}$, N $a^{+}$, Cl and SO4$^2$ derive from both pollution sources and natural weathering reactions.ons.

• Journal of Preventive Medicine and Public Health
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• v.7 no.2
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• pp.327-332
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• 1974

Wells are perticularly able to be a source of water-borne infections disease in the army society. Owing to untreated drinking water, high indidence of water-borne diseases are encounted in Korea. This study was carried out to evaluate the physicochemical and bacteriological states of 298 wells in army camps around Daegu city during a year from January to November, 1974. Main findings are summerized as follows: 1. Turbidity, Colorness & odor was within normal range in all samples. 2. Reaction of pH, cnsumption of KMnO4, total hardness and chlorine ion as over almost within normal range. 3. Free Ammonia was detected to 33.2% positive, and nitrite, 45.5% positive. 4. In the bacteriological test 40.3% of all samples were over the standard limit on E. Coli. 5. In comparison of nitrate and E. Coli detection, 60.1% of nitrite was over the standard limit out of the positive cases detected E. Coli. and all of E. Coli were over the standard limit out of the positive cases of nitrite. 6. The contamination was very remarkable in the spring and summer, and very diminished in the autumn and winter.

• The Korean Journal of Mycology
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• v.28 no.2
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• pp.93-96
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• 2000

To investigate the effect of inorganic nutrient supplement in oyster mushroom (Pleurotus ostreatus), we have conducted some study on cultural and growth characteristics of fruitbody formation and chemical composition of media and fruitbody. When supplemented with slow releasing fertilizer, contamination rate was not different from non-supplemented medium, days for incubation time and first pinhead were faster than non supplemented medium. And fruitbody yield and biological efficiency were increased $10{\sim}28%,\;7{\sim}20%$ respectively, but biological efficiency was decreased when increased supplement ratio. The chemical compositions (total carbon, total nitrogen, ammonia nitrogen, nitrate nitrogen, potassium and phosphate) of slow releasing fertilizer supple mented medium and fruitbody were compared with non-supplemented.

• Journal of Soil and Groundwater Environment
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• v.26 no.1
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• pp.65-75
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• 2021

We investigated hydrochemical and stable isotope characteristics of groundwater in a large agricultural plain, the Honam plain, to evaluate the adequacy of agricultural water supply. For preliminary assessment for the area, we collected 23 groundwater samples from domestic wells and conducted hydrochemical and water stable isotope analysis. Groundwater in the study area is mainly Ca-HCO3 type resulting from water-rock interactions. Stable oxygen and hydrogen isotopic compositions indicated that recharge water is derived from precipitation while some sampling sites had evaporation signatures. Irrigation water quality using sodium absorption ratio and salinity hazard showed most of the groundwater samples were found to be suitable for irrigation. The groundwater in the southwestern part of the study area was affected by both seawater intrusion and agricultural activities, indicating a higher possibility of groundwater contamination near the coastal areas. Elevated concentrations of nitrate and phosphate ions in the groundwater are considered to be influenced by anthropogenic activities such as fertilizer application. It is expected that this study would be able to provide preliminary information on groundwater quality for agricultural water supply in the Mangyeong-Dongjin watershed.

• Journal of Soil and Groundwater Environment
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• v.13 no.6
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• pp.72-84
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• 2008

This study was carried out to provide proper management plans for small portable water supply system in the Nonsan area through water quality monitoring, hydrogeochemical investigation and multivariate statistical analyses. Nonsan area is a typical rural area heavily depending on small water supply system for portable usage. Geology of the area is composed of granite dominantly along with metasedimentary rocks, gneiss and volcanic rocks. The monitoring results of small portable water supply system showed that 13-21% of groundwaters have exceeded the groundwater standard for drinking water, which is 5 to 8 times higher than the results from the whole country survey (2.5% in average). The major components exceeding the standard limits are nitrate-nitrogen, turbidity, total coliform, bacteria, fluoride and arsenic. High nitrate contamination observed at southern and northern parts of the study area seems to be caused by cultivation practices such as greenhouses. Although Ca and $HCO_3$ are dominant species in groundwater, concentrations of Na, Cl and $NO_3$ have increased at the granitic area indicating anthropogenic contamination. The groundwaters are divided into 2 groups, granite and metasedimentary rock/gneiss areas, with the second principal component presenting anthropogenic pollution by cultivation and residence from the principal components analysis. The discriminant analysis, with an error of 5.56% between initial classification and prediction on geology, can explain more clearly the geochemical characteristics of groundwaters by geology than the principal components analysis. Based on the obtained results, it is considered that the multivariate statistical analysis can be used as an effective method to analyze the integrated hydrogeochemical characteristics and to clearly discriminate variations of the groundwater quality. The research results of small potable water supply system in the study area showed that the groundwater chemistry is determined by the mixed influence of land use, soil properties, and topography which are controlled by geology. To properly control and manage small water supply systems for central and local governments, it is recommended to construct a total database system for groundwater environment including geology, land use, and topography.

• Economic and Environmental Geology
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• v.38 no.4 s.173
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• pp.435-450
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• 2005

The purpose of the study is to analyze the hydrogeochemical characteristics by multivariate statistical method, to interpret the hydrogeochemical processes for the new variables calculated from principal components analysis (PCA), and to infer the groundwater flow and circulation mechanism by applying the geostatistical methods for each element and principal component. Chloride and nitrate are the most influencing components for groundwater quality, and the contents of $NO_3$ increased by the input of agricultural activities show the largest variation. The results of PCA, a multivariate statistical method, show that the first three principal components explain $73.9\%$ of the total variance. PC1 indicates the increase of dissolved ions, PC2 is related with the dissolution of carbonate minerals and nitrate contamination, and PC3 shows the effect of cation exchange process and silicate mineral dissolution. From the results of experimental semivariogram, the components of groundwater are divided into two groups: one group includes electrical conductivity (EC), Cl, Na, and $NO_3$, and the other includes $HCO_3,\;SiO_2,$ Ca, and Sr. The results for spatial distribution of groundwater components showed that EC, Cl, and Na increased with approaching the coastal line and nitrate has close relationship with the presence of agricultural land. These components are also correlated with the topographic features reflecting the groundwater recharge effect. The kriging analysis by using principal components shows that PC 1 has the different spatial distribution of Cl, Na, and EC, possibly due to the influence of pH, Ca, Sr, and $HCO_3$ for PC1. It was considered that the linear anomaly zone of PC2 in western area was caused by the dissolution of carbonate mineral. Consequently, the application of multivariate and geostatistical methods for groundwater in the study area is very useful for determining the quantitative analysis of water quality data and the characteristics of spatial distribution.

• Economic and Environmental Geology
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• v.42 no.3
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• pp.217-234
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• 2009

This study characterized groundwater quality and the influence of agrochemicals in a part of Ilgwang-Myeon agricultural area in Gijang-Gun, Busan Metropolitan City, using factor analyses. From the 1st, 2nd, and 3rd analyses of groundwater samples, the mean concentrations of $Ca^{2+}$, $Na^+$, $Mg^{2+}$, $K^+$, $Zn^{2+}$, $Cu^{2+}$, $Fe^{2+}$, $Al^{3+}$, $NO_3\;^-$, $Cl^-$, $SO_4\;^{2-}$, $F^-$, and $SiO_2$ were higher in the 2nd analysis than the other analyses. Pesticide carbofuran and herbicide alachlor were detected at the wells more than a half of all the wells in the 2nd analysis but not in the 4th analysis. This fact may be explained by that a higher precipitation induced higher infiltration rate of contaminants into groundwater during the 2nd survey. According to R- and Q-mode factor analyses, and chemical composition, inorganic constituents excepting $SiO_2$, $HC0_3\;^-$-, and $F^-$ may be influenced by anthropogenic sources (manures, synthetic fertilizers, and domestic wastes), seawater as well as water-mineral interaction. A typical indicator of groundwater contamination, nitrate, exceeds around 4-5 times over the Korean standard for drinking water. Additionally, the influence of seawater diminishes from the seaside to inland.