• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.36 no.5
• /
• pp.458-462
• /
• 2003

This study was to survey proper condition of nitrate removal by hydraulic retention time (HRT) and measured growth of black rockfish (Sebastes schlegeli) and giant croaker (Nibea japonica) in the seawater recirculating culture system designed for nitrate removal. Nitrate conversion to nitrogen at 8 hr-HRT was higher than 16 hr-HRT, amounting to $32.2\;g/m^3/day$ in the seawater recirculating culture system. The removal efficiency of nitrate improved when dissolved oxygen was situated less than 0.5 mg/L. Daily growth rate (DGR) and feed efficiency (FE) of S. schlegeli with mean body weight of 108 g in 8 hr-HRT were significantly higher values than those in 4 hr-HRT (P<0.05). The DGR and FE of N. japonica with mean body weight of 12 g in added carbon system showed not differing in the values from N. japonica in control system (P>0.05).

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.6
• /
• pp.2904-2912
• /
• 2011

Water qualities in the decentralized water treatment plants do not frequently satisfy the water standard limit, in particular, fluoride and nitrate are notorious for the poor removal. In this study, an electro-adsorption equipped with carbon nonotube (CNT) electrodes were carried out to effectively remove the nitrate and fluoride in the decentralized water treatment plants. Two types of CNT electrodes, coating and sintering electrodes were applied. Coating electrodes were made based on different kinds of binder and sintering electrodes were made based on different sintering temperature. Removal of fluoride and nitrate when the coated electrodes with organic binder were used for electro-adsorption were 46 and 99.9% respectively, which were better performances than the coated electrodes with inorganic binder were used. On the other hand, removal of fluoride and nitrate when the electrodes sintered at higher temperature ($1,000^{\circ}C$) were 77 and 87% respectively, which were better performances than the electrodes sintered at lower temperature ($850^{\circ}C$). As a consequences, the electro-adsorption equipped with a CNT electrodes could be an potential alternative process for the removal of fluoride and nitrate in a decentralized water treatment plants if proper current density and contact time were applied.

• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.2
• /
• pp.155-160
• /
• 2008

In this study, the nitrate removal efficiency was examined under a variety of operating conditions, such as different doses of the reducing agent, different electrode types, different HRTs(hydraulic retention times), and different current densities, using the multistep electrochemical process. The nitrate removal efficiency increased and the input energy decreased when the reducing agent was used, and almost no difference was found between the electrode types in terms of their nitrate removal efficiency and current efficiency. So that the Zn reducing agent could be recovered, though, the B-type electrode was chosen(step 1: Pt-Zn; step 2: Pt-Zn; step 3: Pt-Zn; step 4: Pt-Zn). HRT experiments were carried out on constant electric current density unrelated HRTs and various electric current density related HRTs: the constant amount of electric current per unit volume. As a result, HRT and the electric current density caused concentration polarization and the lack of an applied current. That is to say,the lower the HRT, the greater the decrease in concentration polarization and in the amount of applied current per unit volume. Therefore, optimal conditions were found through the experiments that were conducted on HRT and electric current density. When a spacer was installed in the process, the nitrate removal efficiency and energy efficiency increased even more because the diffusion likewise increased.

• Korean Chemical Engineering Research
• /
• v.53 no.3
• /
• pp.269-275
• /
• 2015

The adsorption characteristics of ions were evaluated for the nitrate-selective carbon electrode (NSCE) in accordance with power supply methods. The NSCE was fabricated by coating the surface of a carbon electrode with anion-exchange resin powders with high selectivity for the nitrate ion. Capacitive deionization (CDI) experiments were performed on a mixed solution of nitrate and chloride ion in constant voltage (CV) and constant current (CC) modes. The number of total adsorbed ions in CV mode was 15% greater than that in CC mode. The mole fraction of adsorbed nitrate ion showed the maximum 58%, though the mole fraction was 26% in the mixed solution. This indicates that the fabricated NSCE is highly effective for the selective adsorption of nitrate ions. The mole fraction of adsorbed nitrate was nearly constant value of 55-58% during the adsorption period in CC mode. In the case of CV mode, however, the values increased from the initial 30% to 58% at the end of adsorption. We confirmed that the current supplied to cell is important factor to determine the selective removal of nitrate.

• Journal of Korean Society on Water Environment
• /
• v.20 no.6
• /
• pp.571-576
• /
• 2004

Since anaerobic/anoxic/oxic process, which is a typical mainstream biological nitrogen and phosphorus removal process, utilizes influent organic matter as an external carbon source for phosphorus release in anaerobic or anoxic stage, influent COD/T-P ratio gives a strong influence on performance of phosphorus removal process. In this study, a bench scale experiment was carried out for SBR process to investigate nitrogen and phosphorus removal at various influent COD/T-P ratio and nitrate loadings of 23~73 and 1.6~14.3g $NO_3{^-}-N/kg$ MLSS, respectively. The phosphorus release and excess uptake in anoxic condition were very active at influent COD/T-P ratios of 44 and 73. However, its release and uptake was not obviously observed at COD/T-P ratio of 23. Consequently, phosphorus removal efficiency was decreased. In addition, the phosphorus release and uptake rate in anoxic condition increased as the nitrate loading decreased. Specific denitrification rate had significantly high correlation with organic materials and nitrate loadings of the anoxic phase too. The rate of phosphorus release and uptake in the anoxic condition were $0.08{\sim}0.94kg\;S-P/kg\;MLSS{\cdot}d$ and $0.012{\sim}0.1kg\;S-P/kg\;MLSS{\cdot}d$, respectively.

• Journal of Microbiology and Biotechnology
• /
• v.18 no.11
• /
• pp.1826-1835
• /
• 2008

An autotrophic denitrification reactor (ADR-l) and a heterotrophic denitrification reactor (HDR-2) were operated to remove nitrate and nitrite in an anoxic environment in raw sewage. The $NO_3$-N removal rate of ADR-l was shown to range from 52.8% to 78.7%, which was higher than the $NO_3$-N removal rate of HDR-2. Specific denitrification rates (SDNR) of ADR-l and HDR-2 were 3.0 to 4.0 and 1.1 to $1.2\;mgNO_3$-N/gVSS/h, respectively. From results of restriction fragment length polymorphism (RFLP) of the 16S rRNA gene, Aquaspirillum metamorphum, Alcaligenes defragrans, and Azoarcus sp. were $\beta$-Proteobacteria that are affiliated with denitritying bacteria in the ADR-l. Specifically, Thiobacillus denitrificans was detected as an autotrophic denitrification bacteria. In HDR-2, the $\beta$-Proteobacteria such as Denitritying-Fe-oxidizing bacteria, Alcaligenes defragrans, Acidovorax sp., Azoarcus denitrificans, and Aquaspirillum metamorphum were the main bacteria related to denitrifying bacteria. The $\beta$-and $\alpha$-Proteobacteria were the important bacterial groups in ADR-l, whereas the $\beta$-Proteobacteria were the main bacterial group in HDR-2 based on results of fluorescent in situ hybridization (FISH). The number of Thiobacillus denitrificans increased in ADR-l during the operation period but not in HRD-2. Overall, the data presented here demonstrate that many heterotrophic denitritying bacteria coexisted with autotrophic denitrifying bacteria such as Thiobacillus denitrificans for nitrate removal in ADR-l. On the other hand, only heterotrophic denitritying bacteria were identified as dominant bacterial groups in HDR-2. Our research may provide a foundation for the complete nitrate removal in raw sewage of low-COD concentration under anoxic condition without any external organic carbon or the requirement of post-treatment.

• Journal of Korean Society on Water Environment
• /
• v.20 no.1
• /
• pp.24-31
• /
• 2004

This study was initiated to evaluate the efficiencies of DEPHANOX and Modified-DEPHANOX, which were devoloped to enhance nitrogen removal efficiency in municipal wastewater treatment. In the results, removal efficiency of organic matters was not affected much by increased loading rate of organic matters which is contained in influent. The nitrogen removal efficiencies according to the loading rate of influent TN was decreased drastically in conditions of over $0.2kg/m^3{\cdot}day$, which is T-N loading rate, and the DEPHANOX process was affected more sensitively than the M-DEPHANOX was. When the temperature was altered from $25^{\circ}C$ to $16^{\circ}C$ at HRT 6hrs, the removal efficiency of ammonia nitrogen was still over 90% and it was concluded that both DEPHANOX and M-DEPHANOX were strong enough to endure temperature variation. Moreover, both processes showed over 90% in ammonia removal efficiencies in over HRT 5hrs, so it was concluded that they were strong in HRT variation. M-DEPHANOX process showed a higher value than DEPHANOX did in T-N removal efficiency to the extent of 4~21 %, which resulted from differency of denitrification rates and the biosorption efficiency of organic matter in both processes. In the condition of HRT less than 4hrs, concentrations of ammonia nitrogen contained in effluents and nitrification reactors, might be sensitively affected by biosorption efficiency of organic matters in first separation tank. In the effect of effluent nitrate concentration in phosphorus removal, the more effluent nitrate concentration was decreased, the more phosphorus removal efficiency was increased. This result is related to the decrease of concentration of effluent nitrate which resulted from nitrification inhibition by decreased HRT.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2003.09a
• /
• pp.78-82
• /
• 2003

Development of hematite-coated sand was evaluated for the application of the PRB (permeable reactive barrier) in the arsenic-contaminated subsurface of the metal mining areas. The removal efficiency of As(III) and As(V), the effect of anion competition and the capability of arsenic removal in the flow system were investigated through the experiments of adsorption isotherm, arsenic removal kinetics against anion competition and column removal. Hematite-coated sand followed a linear adsorption isotherm with high adsorption capacity at low level concentrations of arsenic (< 1.0 mg/l). When As(III) and As(V) underwent adsorption reactions in the presence of anions (sulfate, nitrate and bicarbonate), sulfate caused strong inhibition of arsenic removal, and bicarbonate and nitrate caused weak inhibition due to specific and nonspecific adsorption onto hematite, respectively. In the column experiments, high content of hematite-coated sand enhance the arsenic removal, but the amount of the arsenic removal decreased due to the higher affinity of As(V) than As(III) and reduced adsorption kinetics in the flow system, Therefore, the amount of hematite-coated sand, the adsorption affinity of arsenic species and removal kinetics determined the removal efficiency of arsenic in the flow system. arsenic, hematite-coated sand, permeable reactive barrier, anion competition, adsorption.

• Proceedings of the KIEE Conference
• /
• 1997.11a
• /
• pp.709-712
• /
• 1997

Selective removal of NOx by binary oxide systems of Ba-Cu and Mn-Zr was investigated. These mixed oxides were effective in removing NOx at $400^{\circ}C$ by absorption in or on the solid as nitrate. The reaction was investigated by oxidation of NO which was promoted in the presence of $O_2$ on Mn or Cu sites. Then, the oxidized species were stored in the solid as nitrate ions on Ba or Zr sites.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.32 no.1B
• /
• pp.79-84
• /
• 2012

Nitrate is a common contaminant in groundwater aquifer. The present study investigates the performance of the bipolar zero valent iron (ZVI, $Fe^0$) packed bed electrolytic cell in removing nitrate in different operating conditions. The packing mixture consists of ZVI as electronically conducting material and silica sand as non-conducting material between main cathode and anode electrodes. In the continuous experiments for the simulated wastewater (contaminated groundwater, initial nitrate about 30 mg/L as N and electrical conductivity about 300 ${\mu}S/cm$), over 99% removal of nitrate was achieved in the applied voltage 600 V and at the flow rate of 20 mL/min. The optimum packing ratio (v/v) and flow rate were determined to be 1:1~2:1 (silica sand to ZVI), 30 mL/ min respectively. Effluent pH was proportional to nitrate influx concentration, and ammonia which is the final product of nitrate reduction was about 60% of nitrate influx. Magnetite was observed on the surface of the used ZVI as major oxidation product.