• 한국재료학회지
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• 제22권8호
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• pp.426-432
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• 2012

This study involves using nickel chloride solution as a raw material to produce nano-sized nickel oxide powder with average particle size below 50 nm by the spray pyrolysis reaction. The influence of the inflow speed of raw material solution on the properties of the produced powder is examined. When the inflow speed of the raw material solution is at 2 ml/min., the average particle size of the powder is 15~25 nm and the particle size distribution is relatively uniform. When the inflow speed of the solution increases to 10 ml/min., the average particle size of the powder increases to about 25 nm and the particle size distribution becomes much more uneven. When the inflow speed of the solution increases to 20 ml/min., the average particle size of the powder increases in comparison to the case in which the inflow speed of the solution was 10 ml/min. However, the particle size distribution is very uneven, showing various particle size distributions ranging from 10 nm to 70 nm. When the inflow speed of solution increases to 50 ml/min., the average particle size of the powder decreases in comparison to the case in which the inflow speed was 20 ml/min., and the particle size distribution shows more evenness. As the inflow speed of the solution increases from 2 ml/min. to 20 ml/min., the XRD peak intensities gradually increase, while the specific surface area decreases. When the inflow speed of solution increases to 50 ml/min., the XRD peak intensities rather decrease, while the specific surface area increases.

• 한국표면공학회지
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• 제18권3호
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• pp.125-133
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• 1985

설파민산 니켈 용액으로 40~60$^{\circ}C$ 온도와 5~25 A/$dm^2$의 전류밀도 범위에서 1mm 두께까지 니켈을 전착시켰다. 1.2V 이상의 음극 과전압 크기에서 핵발생 속도의 증가에 따라 미세한 결정립 크기의 무질서 방위가 나타났고 0.63V에서 미세한 (110) 우선 방위가 나타났으며 그 사이의 크기에서는 강한(100) 우선방위가 형성되었다. (100) 우선방위는 조대한 주상정 조직을 나타냈고, 그 주상정의 폭은 전류밀도가 증가하면 감소하였다. X-ray응력 측정장치로 측정한 전착증 표면의 잔류응력 크기는 대부분 인장응력으로써 80MPa 이내였고 가끔 매우 작은 압축응력도 나타났다. 음극의 전류효율은 90% 이상이었으나 양극의 효율은 전류밀도, 온도, 특히 염화니켈의 양에 따라 50~90%의 효율을 나타냈다.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.298-300
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• 2004

An alternative molecular porphyrin-phthalocyanine aggregate was prepared and characterized with UV-visible and X-ray absorption spectroscopies. UV-visible experiments evidence 1-dimensional porphyrin-phthalo-cyanine array formed by mixing $SnTPPCl_2 ({\lambda}_{max}=429,\;{\varepsilon}=2.4{\times10^ 5 /M{\cdot}cm)\;and\;NiPc(OBu)_8({\lambda}_{max}=744 nm,\;{\varepsilon}= 2.0{\times}10^ 5 /M{\cdot}cm)$ in solution. In the UV-visible spectrum of the porphyrin-phthalocyanine array, $(SnPNiPc)_n$, a new Q-band appeared at 844 nm with decrease of the Q-band peak of $NiPc(OBu)_8$ at 744 nm. The red-shift of Q-band evidences an alternative porphyrin-phthalocyanine array formed in solution through metal-halide interaction rather than ${\pi}-{\pi}$ facial interaction, in which nickel of $NiPc(OBu)_8$ coordinates with chloride of $SnTPPCl_2$ through self assembly. Ni K-edge XANES (X-ray absorption near edge structure) spectra also support the axial ligation of nickel to chloride. The square planar structure of $NiPc(OBu)_8$ turns to an octahedral structure in (SnPNiPcSnP) by axial ligation. A higher energy-shift (0.2 eV) of the preedge peak of (SnPNiPcSnP) indicaties partial oxidation of nickel by charge transfer from NiPc$(OBu)_8$ to SnTPPCl$_2$.

• 공업화학
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• 제7권4호
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• pp.614-622
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• 1996

엣칭용 염화제2철 용액중의 효과적인 니켈제거에 관해 연구하였다. 전해철괴 또는 폐새도우마스크 철편을 사용하여 염화제2철을 염화제1철로 환원시킨후 용액중의 $Ni^{2+}$를 전해철 분말로 환원 석출시켰다. 최적의 실험조건하에서 초기 니켈의 농도가 1.0%일 때 니켈제거율은 99%이었고 초기 니켈의 농도가 0.1%일 때 니켈제거율은 98%이었다. 염화제2철의 환원반응 중에 생성된 수산화철의 종류 및 입자크기를 XRD와 SEM으로 분석하였다.

• 한국표면공학회지
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• 제36권6호
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• pp.455-460
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• 2003

Microstructural and magnetic properties of nanocrystalline Fe-46 wt%Ni and Fe-36 wt%Ni alloys were investigated. Alloys were prepared by the electrodeposition process. The electrolytes were iron sulfate/nickel chloride-based and iron chloride/nickel sulfamate-based solutions. Fe-46 wt%Ni alloy was FCC structure with grain size of 10 nm, but FCC and BCC phases were found in Fe-36 wt%Ni alloy and its grain size was smaller. Effective permeability of Fe-36 wt%Ni alloy was higher than that of Fe-46 wt%Ni alloy in the high frequency range because of large electrical resistivity and small eddy current loss resulted from grain size decrease. Up to $300^{\circ}C$ of annealing temperature, grain growth of Fe-Ni alloys slowly occured. Conversely, annealing above $450^{\circ}C$ led to a drastic grain growth. In that case, effective permeability was decreased at the temperature lower than $300^{\circ}C$ but at $300^{\circ}C$ or higher effective permeability was increased. At the high frequency of 1 MHz, electrodeposited Fe-Ni alloys had higher effective permeability with an decrease in the grain size.

• Membrane and Water Treatment
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• 제1권1호
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• pp.39-47
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• 2010

Using a conventional two-compartment cell with stirrers the separation of an aqueous solution of HCl-$NiCl_2$ by an anion-exchange membrane Neosepta-AFN was investigated. The dialysis process was characterized by the permeability coefficient of the membrane towards to $Cl^-$ ions. This quantity was determined by the numerical integration of equations, which describe the time dependence of the total concentration of $Cl^-$ ions in compartment initially filled with stripping agent (water), combined with an optimizing procedure. The analysis of the experimental results showed that this permeability coefficient is a satisfactory characteristic for the process studied. It can be graphically correlated with the initial acid and initial salt concentrations in the compartment initially filled with acid+salt mixture.

• 전기학회논문지
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• 제56권8호
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• pp.1436-1440
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• 2007

Beryllium copper has been known to be an important material for the various fields of industry because it can be used for mechanical and electrical/electronic components that are subjected to elevated temperatures (up to $400^{\circ}C$ for short times). Blade type tip for probing the cells of liquid crystal display(LCD) was fabricated using beryllium copper foil. The dry film resist was employed as a mask for patterning of the blade type tip. The beryllium copper foil was etched using hydrochloric acidic iron-chloride solution. The concentration, temperature, and composition ratio of hydrochloric acidic iron-chloride solution affect the etching characteristics of beryllium copper foil. Nickel with the thickness of $3{\mu}m$ was electroplated on the patterned copper beryllium foil for enhancing its hardness, followed by electroplating gold for increasing its electrical conductivity. Finally, the dry film resist on the bridge was removed and half of the nickel was etched to complete the blade type tip.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.281-285
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• 2001

This technology Provides an economical Production of high value added goods applicable to electro chemicals by recycling of waste products in EGL(Electro Galvanizing Line). The waste products produced in EGL contain potassium chloride (KCI), nickel and zinc. Highly pure KCI and Zinc Chloride which are raw material of electro plating, can be produced by the development of the recycling process. The scope of this study ranges from laboratory experiments to pilot test in plant. We have developed the whole process of recycling technology such as purification method of waste products, fabrication methods of electro chemicals, basic design of plant, pilot scale production and evaluation of pilot goods, Developed electro chemicals were pure enough to satisfy the specification of steel company.

• 한국표면공학회지
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• 제37권2호
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• pp.76-79
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• 2004

Nickel chloride coated protein chip plate was developed by using a spin coating method. The ability of histidine tagged protein adsorption was investigated at various solvents. The surface of plate has a large aggregated nickel complex with high density in water. However, the surface of plate has a very small size of aggregated nickel complex with low density in isopropanol. The ability of protein adsorption decreased as increasing the size of alkyl chain in various alcohol solvents. The mechanism on the ability of protein adsorption at the plate surface is discussed.

• 한국표면공학회지
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• 제32권3호
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• pp.219-223
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• 1999

A new additive for semi-brightness finish in nickel electroplating, having a quarternary ammonium salt structure, has been developed in this study. The effectiveness of the new additive was tested in laboratory-scale eletroplating tests as well as in a full-scale factory plating line. An examination of the plated surface showed that the new additive is as good as the one produced by the most commonly used additive in the nickel plating industry. The plated surface was examined by SEM, EPMA, and Reflectance Spectroscopy, and was found to be compatible to the one obtained with commercial additives. The new additive has a shelf life comparable with those of other commercially available additives. The additive developed in this study has an excellent potential to be used commercially.