• Title/Summary/Keyword: Nickel(I)

Search Result 214, Processing Time 0.029 seconds

Effects of Nickel Supports on Hydrogen Permeability of Vanadium based Membrane (니켈 지지체를 이용한 바나듐기 분리막의 수소 투과특성)

  • Cho, Kyoungwon;Choi, Jaeha;Jung, Seok;Kim, Raymundk.I.;Hong, Taewhan;Ahn, Joongwoo
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.24 no.3
    • /
    • pp.200-205
    • /
    • 2013
  • The separation of hydrogen depends on porosity, diffusivity and solubility in permeation membrane. Dense membrane is always showing a solution diffusion mechanism but porous membrane is not showing. Therefore, porous membrane has a good hydrogen flux due to pore is carried out transferred media. This mechanism is named as the Knudsen diffusion. Hydrogen molecules or hydrogen atoms are diffused along pore that is a mean free path. In this study, complex layer hydrogen permeation membrane was fabricated by hot press process. And then, it was evaluated and calculated to relationship between hydrogen permeability and membrane porosity.

Improved evaluation of ring tensile test ductility applied to neutron irradiated 42XNM tubes in the temperature range of (500-1100)℃

  • Gurovich, B.A.;Frolov, A.S.;Fedotov, I.V.
    • Nuclear Engineering and Technology
    • /
    • v.52 no.6
    • /
    • pp.1213-1221
    • /
    • 2020
  • Chromium-nickel alloy 42XNM (XHM-1, Bochvalloy) is considered as a promising material for future generations of nuclear reactors, primarily as a material for the fuel elements shells in the development of accident tolerant fuel. However, as with most nickel-based alloys, 42ХNМ is characterized by a sharp decrease in plastic properties in the temperature range of (500-900)℃. This effect is enhanced by neutron irradiation. Preliminary tests of ring samples of 42XNM alloy (after irradiation as a part of the VVER-1000 control system) in the temperature range of ductility failure showed that the standard technique for processing tensile diagrams does not allow to evaluate the plastic properties correctly at low strains. Therefore, in this work, the alternative method for testing ring samples from materials with low plastic characteristics was developed. It was shown that the minimum value of the permanent strain of the irradiated 42XNM alloy in the temperature range of (500-1100)℃, determined by the alternative method, was ~1.6% at 750 ℃.

Cloning and Characterization of the Urease Gene Cluster of Streptococcus vestibularis ATCC49124

  • Kim Geun-Young;Lee Mann-Hyung
    • Journal of Microbiology and Biotechnology
    • /
    • v.16 no.2
    • /
    • pp.286-290
    • /
    • 2006
  • A genomic library of Streptococcus vestibularis ATCC49124 was constructed in an E. coli plasmid vector, and the urease-positive transformants harboring the urease gene cluster were isolated on Christensen-urea agar plates. The minimal DNA region required for urease activity was located in a 5.6 kb DNA fragment, and a DNA sequence analysis revealed the presence of a partial ureI gene and seven complete open reading frames, corresponding to ureA, B, C, E, F, G, and D, respectively. The nucleotide sequence over the entire ure gene cluster and 3'-end flanking region of S. vestibularis was up to 95% identical to that of S. salivarius, another closely related oral bacterium, and S. thermophilus, isolated from dairy products. The predicted amino acid sequences for the structural peptides were 98-100% identical to the corresponding peptides in S. salivarius and S. thermophilus, respectively, whereas those for the accessory proteins were 96-100% identical. The recombinant E. coli strain containing the S. vestibularis ure gene cluster expressed a high level of the functional urease holoenzyme when grown in a medium supplemented with 1 mM nickel chloride. The enzyme was purified over 49-fold by using DEAE-Sepharose FF, Superdex HR 200, and Mono-Q HR 5/5 column chromatography. The specific activity of the purified enzyme was 2,019 U/mg, and the Michaelis constant ($K_{m}$) of the enzyme was estimated to be 1.4 mM urea. A Superose 6HR gel filtration chromatography study demonstrated that the native molecular weight was about 196 kDa.

Recent Trend of Lithium Secondary Batteries for Cellular Phones (최근 휴대폰용 배터리의 기술개발 동향)

  • Lee, H.G.;Kim, Y.J.;Cho, W.I.
    • Journal of the Korean Electrochemical Society
    • /
    • v.10 no.1
    • /
    • pp.31-35
    • /
    • 2007
  • In this review article, we are going to explain the recent development of lithium secondary batteries for a cellular phone. There are three kinds of rechargeable batteries for cellular phones such as nickel-cadmium, nickel-metal hydride, and lithium ion or lithium ion polymer. The lithium secondary battery is one of the most excellent battery in the point of view of energy density. It means very small and light one among same capacity batteries is the lithium secondary battery. The market volume of lithium secondary batteries increases steeply about 15% annually. The trend of R&D is focused on novel cathode materials including $LiFePO_4$, novel anode materials such as lithium titanate, silicon, and tin, elecrolytes, and safety insurance.

Die Bestimmung von Spurenelementen in Naurlichen Wassern durch Rontgenfluoreszenzspektrometrie nach Konzentration durch Verdampfen (Ⅰ) (X-線螢光分析에 依한 天然水中의 微量金屬定量 [I] 蒸發濃縮에 依하여)

  • Yung Kyu Park
    • Journal of the Korean Chemical Society
    • /
    • v.13 no.1
    • /
    • pp.41-44
    • /
    • 1969
  • Eine neuentwickelte Methode zur Herstellung von Me${\ss}$praparaten wird fur die Bestmmung der Spurenelemente in Wasser Rontgenfluroreszspektrometrie angewendet. Supuren von Kupfer, Blei, Zink, Nickel, Kobalt und Eisen werden aus großen Mengen von naturlichem Wasser durch Verdampfen konzentriert. Aus der konzentrierten Losung werden die Spurenelemente durch Einleitung von Schwefelwasserstoff bei pH 8 unter Zusatz von Aluminiumsulfat-Trager ausgefallt. Die Niederschlage der Metallsulfide werden durch Membranfilter filtriert, mit Gelatine fixiert und ihre Absolutmengen durch Rontgenfloreszenzanalyze bestimmt. Kupfer, Blei, Zink, Nickel, Kobalt und Eisen werden bei einer Konzentration von 2.5 bis 50.0 p.p.b. mit einer relativen Standardabweichung 14.0% gemesser.

  • PDF

Crystal Structure of Three-Dimensional Nickel(II) Tetraaza Macrocyclic Complex Linked by Hydrogen-Bonds (수소 결합에 의한 이차원의 Nickel(II) Tetraaza 거대 고리 착물 결합구조)

  • Park, Ki-Young;Choo, Geum-Hong;Suh, Il-Hwan
    • Korean Journal of Crystallography
    • /
    • v.13 no.1
    • /
    • pp.12-16
    • /
    • 2002
  • The complex [Ni(L)](BDC)·4H₂O (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[16,4,O/sup 1.18/,O/sup 7.12/] docosane; BDC = 1,3-benzenedicarboxylate) has been synthesized and characterized by X-ray crystallography. Compound 1 crystallizes in the orthorhombic space group Pcnb, with a = 8.764(2) , b = 17.687(2) , c = 19.475(1) , V = 3018.7(8) ³, Z = 4, R₁, (wR₂) for 2148 observed reflections of [1>2σ(I) was 0.0822 (0.2236). Compound 1 is interconnected to give a three-dimensional network through weak hydrogen-bonding interactions.

En-masse retraction with a preformed nickel-titanium and stainless steel archwire assembly and temporary skeletal anchorage devices without posterior bonding

  • Jee, Jeong-Hyun;Ahn, Hyo-Won;Seo, Kyung-Won;Kim, Seong-Hun;Kook, Yoon-Ah;Chung, Kyu-Rhim;Nelson, Gerald
    • The korean journal of orthodontics
    • /
    • v.44 no.5
    • /
    • pp.236-245
    • /
    • 2014
  • Objective: To evaluate the therapeutic effects of a preformed assembly of nickel-titanium (NiTi) and stainless steel (SS) archwires (preformed C-wire) combined with temporary skeletal anchorage devices (TSADs) as the sole source of anchorage and to compare these effects with those of a SS version of C-wire (conventional C-wire) for en-masse retraction. Methods: Thirty-one adult female patients with skeletal Class I or II dentoalveolar protrusion, mild-to-moderate anterior crowding (3.0-6.0 mm), and stable Class I posterior occlusion were divided into conventional (n = 15) and preformed (n = 16) C-wire groups. All subjects underwent first premolar extractions and en-masse retraction with preadjusted edgewise anterior brackets, the assigned C-wire, and maxillary C-tubes or C-implants; bonded mesh-tube appliances were used in the mandibular dentition. Differences in pretreatment and post-retraction measurements of skeletal, dental, and soft-tissue cephalometric variables were statistically analyzed. Results: Both groups showed full retraction of the maxillary anterior teeth by controlled tipping and space closure without altered posterior occlusion. However, the preformed C-wire group had a shorter retraction period (by 3.2 months). Furthermore, the maxillary molars in this group showed no significant mesialization, mesial tipping, or extrusion; some mesialization and mesial tipping occurred in the conventional C-wire group. Conclusions: Preformed C-wires combined with maxillary TSADs enable simultaneous leveling and space closure from the beginning of the treatment without maxillary posterior bonding. This allows for faster treatment of dentoalveolar protrusion without unwanted side effects, when compared with conventional C-wire, evidencing its clinical expediency.

A Study on Electroless Ni-B Plating with DMAB as Reducing Agent. I. The Electrochemical Behavior of Precipitation Reaction on Austenite Stainless Steel Substrates (DMAB를 사용한 무전해 Ni-B 합금 도금 I. 오스테나이트 스텐레스강 상의 석출반응에 대한 전기화학적 거동)

  • 이창래;박해덕;강성군
    • Journal of the Korean institute of surface engineering
    • /
    • v.32 no.2
    • /
    • pp.172-181
    • /
    • 1999
  • The effect of the DMAB concentration, temperature, deposition time, and stabilizer concentration on the precipitation reaction of the electroless nickel plating using dimethylamine borane (DMAB) as reducing agent was investigated to by the weight gain and electrochemical method. The deposition rate was dependent with DMAB concentration. The polarization resistance of the precipitation reaction was reduced with DMAB concentration. The precipitation reaction rate of Ni-B deposits was controlled by the oxidation rate of DMAB as the source of electron. The boron content of the deposit was constant at about 5.5wt%, even when DMAB concentration in the solution was increased. The effect of temperature and stabilizer ($Pb(NO_3)_2$) concentration on deposition rate was shown to have co-dependent behaviors.

  • PDF

Effect of Reinforcement Content on Damping Capacities for Castable Aluminum Matrix Composites Reinforced with SiC and Graphite Particles (SiC와 흑연 입자 강화 주조용 Al기지 복합재료의 진동감쇠능에 미치는 강화입자조성의 효과)

  • 최유송
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.7 no.1
    • /
    • pp.47-58
    • /
    • 2004
  • Loss factors of A356, Mn-Cu alloy and aluminum matrix composites reinforced with $SiC_p$ and Ni-coated graphite particles at various contents have been investigated using clamped-free cantilever beam method. The loss factors of half-power bandwidth of the specimens were measured over a wide range of frequencies from 50 to 3300Hz. Among the specimens, Al-10%$SiC_p$-10%$C_p$ showed the highest loss factor at the mode I, while Mn-Cu alloy showed the highest loss factors at the modes II and III. Consequently, at the mode I the Al-10%$SiC_p$--10%$C_p$ showed the loss factor of 0.00093, which is 2.64 and 1.58 times higher than those of A356 and Mn-Cu alloy, respectively.

A Study on the Heavy Metals Concentrations in the Air of the Dental Laboratories, in the Blood and Urine of Dental Laboratory Technicians (치과기공실 공기중 및 치과기공사의 혈액, 요중 중금속 함량에 관한 연구)

  • Cha, Sung-Soo
    • Journal of Technologic Dentistry
    • /
    • v.10 no.1
    • /
    • pp.11-24
    • /
    • 1988
  • The purpose of this study was to determine the concentration of cadmium, nickel and chromium in the air of the work-place, blood of and urine of workers and compare the level of those heavy metals by the duration of work, work-place, process of work, smoking and other factors. In this study, 48 male dental laboratory technicans and 72 office workers as the control group were subjected. The concentration of cadmium, nickel and chromium in their blood sand urine, and that of heavy metals in the air of their work-rooms were examined and analyzed from June I 1987 to September 30, 1987. The results were as follows : 1. The concentration of cadmium in the air was the highest in the porcelain part, $0.0087{\pm}0.0016mg/m^3$, that of nickel was the highest in the crown bridge part, $0.4253{\pm}0.0052mg/m^3$, and that of chrnmium was highest in the partial denture part, $0.1063{\pm}0.0024mg/m^3$. 2. cadmium, nickel and chromium concentrations in the blood and urine of dental laboratory techincians were higher that in the office workers'. Especially the concentration of cadmium in the blood($1.92{\pm}1.23{\mu}g$/100ml) of th dental laboratory techician was about two times as high as that in the office workers'($0.90{\pm}0.73{\mu}g$/100ml), and the concentration of nickel in the urine($48.53{\pm}38.83{\mu}g$/e) of the dental laboratory thchnician was about two times as high as that in the office worker's($20.24{\pm}15.35{\mu}g$/e). 3. there was no difference in the concentration of cadmium, nickel and chromium in the blood and urine with a longer duration of work. 4. The concentration of cadmium and chromium in the blood and urine differed significantly depending upon the place of work. The concentration of cadmium was the highest in the blood of dental laboratory technicians working kin the poreclain part marking at $2.53{\pm}1.08{\mu}g$/100ml. The chromium level was the heighest in the blood of partial denture park workers with a concentration of $3.60{\pm}1.02{\mu}g$/100ml. Concerning the level of cadmium in urine, it was the highest in the porcelain part workers with a concentration of $3.41{\pm}3.15{\mu}g$/e. 5. The concentration of cadmium in the urine of metal trimming and polishing group($2.64{\pm}2.41{\mu}g$/e) was higher than that of non-metal trimming and polishing group($1.39{\pm}1.18{\mu}g$/e). 6. The concentration of chromium in the blood of smoking group($2.46{\pm}1.54{\mu}g$/100ml)was higher than that lf non-smoking group($1.54{\pm}1.25{\mu}g$/100ml). 7. The height positive correlation coefficient was shown between the concentration of nickel and chromium in the blood among the all correlations between 3metals(Cd, Ni, Cr) in the blood and those in urine. The correlation coefficient was relatively high(r=0.605,,p<0.01). In general, the higher the concentration of heavy metals in the air of work places the higher the concention lf them in the blood and urine of workers, mere attention should be paid to the working environment of dental laboratory workers, Furthermore, continuous biological monitoring and further research are required for an efficient health management for dental laboratory workers.

  • PDF