• Title/Summary/Keyword: NiCo

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A Study on the Magnetic Anisotrpy and Magnetoresistive Characteristics of NiFe/Cu/Co Trilayers (NiFe/Cu/Co 삼층막의 자기이방성과 자기저항 특성에 관한 연구)

  • 김형준;이병일;주승기
    • Journal of the Korean Magnetics Society
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    • v.6 no.5
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    • pp.323-328
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    • 1996
  • NiFe($60\;{\AA}$)/Cu($60\;{\AA}$)/Co($30\;{\AA}$) trilayers were formed on the $4^{\circ}$ tilt-cut Si(111) substrate by rf magnetron sputtering method. With a Cu($50\;{\AA}$) underlayer, NiFe($60\;{\AA}$)/Cu($60\;{\AA}$)/Co($30\;{\AA}$) trilayers developed in-plane magnebc anisotropy and in-plane perpendicular alignment of easy axes in two magnetic components of NiFe($60\;{\AA}$)/Cu($60\;{\AA}$)/Co($30\;{\AA}$) trilayers has been found. The easy axis of Co layer consisbng of NiFe($60\;{\AA}$)/Cu($60\;{\AA}$)/Co($30\;{\AA}$) trilayers turned out to be along $4^{\circ}$ tilt Si <112> direcbon and that of NiFe layer along Si <110> direction. [NiFe($60\;{\AA}$)/Cu($60\;{\AA}$)/Co($30\;{\AA}$)]/Cu($50\;{\AA}$)/Si(111, $4^{\circ}$ tiIt-cut) trilayers showed about 2.2 % MR ratio at room temperature and large plateau in MR curves, which are more improved MR characteristics than those in [NiFe($60\;{\AA}$)/Cu($60\;{\AA}$)/Co($30\;{\AA}$)]/Cu($50\;{\AA}$)/glass trilayers with no appreciable magnetic anisotropy.

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Effects of an Underlayer on the Development of Perpendicular Magnetic Anisotropy in Co/Ni Multilayers (Co/Ni 다층박막의 수직자기이방성 발현에 대한 하지층의 영향)

  • Lee, K.S.;Lee, K.J.;Jung, M.H.;Shin, K.
    • Journal of the Korean Magnetics Society
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    • v.18 no.3
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    • pp.94-97
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    • 2008
  • We investigated how the magnetic anisotropy in $[Co(2\;{\AA})/Ni(8\;{\AA})]{\times}N$ multilayers varied with the type and thickness of an underlayer. The magnetic measurements clearly showed that the perpendicular magnetic anisotropy could be developed in the Co/Ni multilayer by adopting an underlayer with [111] texture. The coercivity of the Co/Ni multilayer increased from 99 Oe to 430 Oe as the thickness of an Au underlayer increased from $50\;{\AA}$ to $500\;{\AA}$. The increase in coercivity is ascribed to the development of the stronger [111] texture in the Co/Ni multilayer as an Au underlayer gets thicker.

High Temperature Oxidation of NiCoCrAlY-(Ta, Re, Ir) Coatings for Gas Turbines (가스터빈 엔진부품용 NiCoCrAlY-(Ta, Re, Ir) 코팅의 고온산화특성)

  • Choi, J.H.;Lee, D.B.
    • Journal of the Korean institute of surface engineering
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    • v.39 no.3
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    • pp.129-136
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    • 2006
  • The high velocity oxy-fuel sprayed coatings of 38Ni-23Co-20Cr-11Al-3Y-5Ta, 25Ni-34Co-20Cr-11Al-3Y-2Re and 32Ni-34.5Co-22Cr-11Al-0.5Ir (in wt%) were oxidized at 1000 and $1100^{\circ}C$ in air in order to find the alloying effect of Ta, Re and Ir on the oxidation properties of the NiCoCrAlY-base coatings. The primary phase of the coatings was $Ni_3Al$. The oxides formed on the coatings consisted primarily of ${\alpha}-Al_2O_3$, together with some $CoCr_2O_4,\;CoAl_2O_4$, and $Al_5Y_3O_{12}$. Tantalum oxidized to $Ta_2O_5$ and $Ta_2O_{22}$. However, no oxides of Re and Ir were detected by XRD owing to their thermodynamic inertness and/or their small amount.

NiO(Co0.25Mn0.75)2O3 and BaSrTiO3 thick films on alumina substrate as temperature and humidity ceramic multisensors

  • Oh, Young-Jei;Lee, Deuk-Yong
    • Journal of Sensor Science and Technology
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    • v.18 no.5
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    • pp.343-348
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    • 2009
  • $NiO{\cdot}(Co_{0.25}Mn_{0.75})_2O_3$(Mn-Ni-Co) and $Ba_{0.5}Sr_{0.5}TiO_3$(BST) thick films were screen printed on Pt patterned alumina substrate to investigate the effects of sintering temperature on humidity and temperature sensing properties of ceramic sensors. A raise in sintering temperature increased resistance and B constant of the Mn-Ni-Co temperature sensor. This may have derived from the synergic effects of the reduction in charge carriers caused by the substitution of Co for Mn as well as the formation of microcracks from the difference in thermal expansion coefficients. Dependence of resistance on humidity of the Mn-Ni-Co temperature sensor, however, was not found. BST films sintered at temperatures in the range of $1100^{\circ}C$ to $1150^{\circ}C$ showed excellent humidity sensing properties. The BST humidity sensor was faster in its response than the Mn-Ni-Co temperature sensor. The humidity sensor, however, proved to be unstable under various temperatures, suggesting a need for a temperature stabilizing device. In contrast, the Mn-Ni-Co temperature sensor was stable under humid conditions.

Preparation and cation mixing phenomena of LiCo$O_2$and $LiCo_{1-x}$$Ni_x$$O_2$ solid solutions (LiCo$O_2$$LiCo_{1-x}$$Ni_x$$O_2$고용체의 제조 및 양이온 혼합 현상)

  • 임창성;안홍주;강승민;하정수;고영신
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.6
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    • pp.601-605
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    • 1999
  • $LiCoO_2$and $LiCo_{1-x}$$Ni_x$$O_2$ solid solutions were fabricated by the solid state reaction process. The structural cation mixing phenomena were investigated using XRD, SEM, particle size analysis and $^7$Li NMR,The synthesized LiCoO$_2$ and $LiCo_{1-x}Ni_XO_2$ microcrystallines showed the hexagonal layered structures. Mean particle sizes were increased with the increase of the amount of nickel in the solid solutions. The cation mixing effects were increased as increasing the fraction of nickel(x), x = 0.3, 0.5, 0.7. the peak frequency of $^7$Li NMR was shifted to the higher frequency and the line width increased as increasing the amount of nickel in the solid solutions.

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Exchange coupling of Co/NiMn bilayer (Co/NiMn의 교환 자기결합에 관한 연구)

  • 안동환;조권구;주승기
    • Journal of the Korean Magnetics Society
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    • v.10 no.4
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    • pp.171-177
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    • 2000
  • Exchange coupling of Co/NiMn bilayers fabricated by RF magnetron sputtering method was studied. We investigated the variation of exchange coupling field (H$\sub$ex/) for different annealing temperature and time. The maximum exchange coupling field was obtained after 13hr annealing at 300 $^{\circ}C$. With respect to deposition sequence, it was demonstrated that NiMn-top bilayers had higher exchange coupling field than NiMn-bottom bilayers. Ta capping layer was shown to be essential in achieving exchange coupling and Auger Electron Spectroscopy (AES) proved that uncapped NiMn/Co bilayers did not have exchange coupling because of oxygen incorporation into film. We also observed the effect of Ta underlayer on exchange coupling. It was found that Ta underlayer had better not be used for attaining higher exchange coupling. XRD analysis showed that Ta underlayer helped bilayers develop texture, but it was not essential to exchange coupling of Co/NiMn bilayers, which is in contrast to NiFe/NiMn system. Furthermore, the NiMn and Co thickness dependence of exchange coupling has been investigated. The exchange coupling strength reached the maximum above 200 ${\AA}$ NiMn thickness and had inversely proportional relation with Co thickness.

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Recoverty of Lithium Carbonate and Nickel from Cathode Active Material LNO(Li2NiO2) of Precursor Process Byproducts (전구체 공정부산물 LNO(Li2NiO2)계 양극활물질로부터 탄산리튬 및 니켈 회수연구)

  • Pyo, Je-Jung;Wang, Jei-Pil
    • Resources Recycling
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    • v.28 no.4
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    • pp.30-36
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    • 2019
  • In this study, Li powder was recovered from the by-product of LNO ($Li_2NiO_2$) process, which is the positive electrode active material of waste lithium ion battery, through the $CO_2$ thermal reaction process. In the process of recovering Li powder, the $CO_2$ injection amount is 300 cc/min. The $Li_2NiO_2$ award was phase-separated into the $Li_2CO_3$ phase and the NiO phase by holding at $600^{\circ}C$ for 1 min. After this, the collected sample:distilled water = 1:50 weight ratio, and after leaching, the solution was subjected to vacuum filtration to recover $Li_2CO_3$ from the solution, and the NiO powder was recovered. In order to increase the purity of Ni, it was maintained in $H_2$ atmosphere for 3 hours to reduce NiO to Ni. Through the above-mentioned steps, the purity of Li was 2290 ppm and the recovery was 92.74% from the solution, and Ni was finally produced 90.1% purity, 92.6% recovery.

Analysis of Dopant Dependency and Improvement of Thermal stability for Nano CMOS Technology (Nano-CMOS에서 NiSi의 Dopant 의존성 및 열 안정성 개선)

  • 배미숙;오순영;지희환;윤장근;황빈봉;박영호;박성형;이희덕
    • Proceedings of the IEEK Conference
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    • 2003.07b
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    • pp.667-670
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    • 2003
  • Ni-silicide has low thermal stabiliy. This point is obstacle to apply NiSi to devices. So In this paper, we have studied for obtain thermal stability and analysis of dopant dependency of NiSi. And then we applied Ni-silicide to devices. To improvement of thermal stability, we deposit Ni70/Co10/Ni30/TiN100 to sample. Co midlayer is enhanced thermal stability of NiSi. Co/Ni/TiN, this structure show very difference between n-poly and p-poly in sheet resistance. But Ni/Co/Ni/TiN, structure show less difference. Also junction leakage is good.

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The Electrical Properties and Aging Effects on the Composition of Mn-Co-Ni NTC Thermistors (Mn-Co-Ni 산화물계 NTC 서미스터의 조성에 따른 전기적 특성과 경시변화)

  • 권정범;정용근;엄우식;송준광;유광수
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1174-1179
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    • 2001
  • Mn-Co-Ni oxide system has been used as the NTC thermistors for normal temperature applications. Mn-Co-Ni oxide-based thermistors with various compositions were sintered at 1250$^{\circ}C$ for 3 hours and then maintained at 1000$^{\circ}C$ for 3 hours. The electrical properties of the thermistors fabricated were measured. In particular the MCN622 composition (Mn$_3$O$_4$60 wt%, Co$_3$O$_4$20 wt%, NiO 20wt%) exhibited the lowest resistivity and relatively high B constant. The MCN721 composition (Mn$_3$O$_4$70wt%, Co$_3$O$_4$20wt%, NiO 10 wt%) showed the higher resistivity than any other compositions. The aging properties of each composition showed comparatively stable characteristics within ${\pm}$2%.

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$CO_2$ Laser Weldability Between Sintered Co, Co+Ni alloy and Carbon Steel (Co/Co+Ni 성분의 분말 소결 금속과 탄소강의 레이저 용접성에 대한 고찰)

  • 박종원;이창희
    • Laser Solutions
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    • v.3 no.2
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    • pp.13-24
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    • 2000
  • The weldability of dissimilar materials between sintered materials which are consisted of Co, Co+Ni and carbon steel has been investigated using CO$_2$ laser. Autogeneous CO$_2$ laser welding were run along the butt between two alloys using sets of parameters variation-power and travel speed. In order to study weldability, mechanical tests (bending strength test, microhardness test) and metallurgical analyses (microstructure, phase transformation, fracture mode) were carried out. From the results obtained, it was found that the porosity which exists in a weld metal greatly affects the soundness of the weld. The optimum energy input to have a proper strength over than the requirement by a specification, found to be around 0.3-0.35kJ/m. There are two kinds of fracture mode in the weld metal, depending upon alloy combination, brittle fracture in the case of Co-carbon steel and a ductile fracture in the case of Co+Ni-carbon steel. In general, Co+Ni sintered material showed a better weld properties as compared to the Co sintered material.

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