• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2007.04a
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• pp.27-28
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• 2007

전주는 표면코팅을 목적으로 하기보다 금속제품을 제조하기 위해 사용하는, 도금법과 유사한 기술이다. 다양한 조성의 Fe-Ni 합금들을 전주성형하여 극박형상으로 제조하였다. 2원계 Fe-Ni 합금의 결정립 크기는 10 nm 정도였으며 P 첨가에 의해 결정립 크기를 더욱 미세하게 할 수 있다. 전주한 2원계 Fe-Ni 합금들의 비저항은 전형적인 나노결정질 소재의 특성을 나타낸다.

• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1215-1218
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• 2003

An analysis of the bonding situation in CaM₂P₂ (M=Fe, Ni) with ThCr₂Si₂ structure is made in terms of DOS and COOP plots. The main contributions to covalent bonding are due to M-P and P-P interactions in both compounds. Particularly, the interlayer P-P bonding by variation in the transition metal is examined in more detail. It turns out that the shorter P-P bonds in CaNi₂P₂ form as a result of the decreasing electron delocalization into ${{\sigma}_p}^*$ of P₂ due to the weaker bonding interaction between the metal d and ${{\sigma}_p}^*$ as the metal d band is falling from Fe to Ni.

• Journal of Magnetics
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• v.4 no.3
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• pp.88-91
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• 1999

A series of NiO/NiFe bilayer films are deposited with the variation of Ar sputtering pressure for the NiO layers only. As the pressure for the NiO layers increases, the exchange anisotropy field (HEX) decreases gradually and becomes extinct at 2.5 mTorr, at which the maximum coercive force (HC) in the NiO/NiFe films is obtained. Randomly oriented columnar structures with HEX a few tens of Oe and oriented columnar structures with zero HEX are observed in the NiP layers by highvoltage hihg-resolution transmission electron microscopy. The vanishing of the HEX in the oriented structures is attributed to the lack of exchange anisotropy energy (EEX) between NiO and NiFe layers, which results in little contribution of interfacial unidirectional pinning anisotropy to the interface of NiO/NiFe bilayer.

• Korean Journal of Materials Research
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• v.10 no.6
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• pp.445-449
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• 2000

Nickel ferrite $(Ni_{0.75}Fe_{2.25}O_4$ was synthesized by co-precipitation method in order to investigate its behavior under conditions of the reactor coolant system in pressurized light water nuclear power plants. Ammonia or potassium carbonate was used as a solution pH control agent, and aqueous ammonia or potassium carbonate solution or secondary distilled water was used as a co-precipitate washing agent. The effects of the pH control agent and the co-precipitate washing agent on the production yield on the basis of the Ni/Fe molar ratio and the particle characteristics of final products were investigated by XRD, SEM, EDX and XPS. The production yield was almost congruent with that of the initial aqueous mixture in case of using potassium carbonate as a pH control agent, while in case of using ammonia, it was quite changed. The difference seemed to be due to the effects of $Ni^{2+}{\leftarrow}NH_3$complexation in the aqueous solution and of the pH of co-precipitate washing agent.

• Journal of the Korean Chemical Society
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• v.40 no.1
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• pp.50-58
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• 1996

In the presence of metal ions(Co(Ⅱ), Ni(Ⅱ), Sr(Ⅱ), Cu(Ⅱ), Fe(Ⅲ), U(Ⅵ)), the sedimentation of humic acid was increased at constant pH with increasing metal concentration and the strength was increased in the following order: Sr < Ni < Co < Cu < Fe < U. At constant metal concentration, Cu(Ⅱ), Ni(Ⅱ), and Co(Ⅱ) ions caused an increase in sedimentation of humic acid as the solution pH increased, whereas Fe(Ⅲ) and U(Ⅵ) ions caused a decrease. Sr(Ⅱ) ions did not affect the sedimentation even with the variation of pH. The analysis of FT-IR spectra for the sediments prepared from the reaction between humic acid and metal ions showed that metal ions were bound to humic acid to form complexes, suggesting that the metal complexation plays an important role in the sedimentation of humic acid.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2000.11a
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• pp.54-55
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• 2000

• Journal of the Korean Magnetics Society
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• v.12 no.6
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• pp.212-217
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• 2002

The pseudo spin valve with a structure of Tl/CoFe(t $\AA$)/Cu(30 $\AA$)/NiFe(50 $\AA$)/Ta, showing giant magnetoresistance properties by utilizing coercivity difference between only two soft ferromagnetic layers were produced by d.c UHV magnetron sputtering system. In pseudo spin valve Ta/CoFe/Cu/NiFe/Ta, the magnetic and magnetoresistance properties with change of CoFe thickness were investigated. When the thickness of CoFe was 60 $\AA$, a typical MR curve of pseudo spin valve structure was obtained, showing MR ratio of 3.8 cio and the coercivity difference of 27.4 Oe with a sharp change of hard layer switching. When the CoFe thickness was varied from 20 to 100 $\AA$, coercivity difference between two layers was increased to 40 $\AA$. and decreased to 100 $\AA$ gradually. It is thought the change in coercivity of hard layer was due to the crystallinity and magnetostriction of thin CoFe layer. In order to improve the MR property in CoFe/Cu/NiFe trier layer structure, CoFe layer with change of 2-20 $\AA$ thick was inserted between Cu and NiFe. When the thickness of CoFe was 10 $\AA$, MR ratio was 6.7％, showing excellent MR property. This indicates 50 ％ higher than that of CoFe/Cu/NiFe pseudo spin valve.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.6
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• pp.549-558
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• 2018

The overall efficiency depend on the overpotential of the oxygen evolution reaction in alkaline water electrolysis. Therefore, it is necessary to research to reduce the oxygen evolution overpotential of electrodes. In this study, Ni-Zn-Fe electrodes were prepared by electroplating and the surface area was increased by Zn leaching process. Electroplating variables were studied to optimize the plating parameters(electroplating current density, pH value of electroplating solution, Ni/Fe content ratio). Ni-Zn-Fe electrode, which is electroplated in a modified Watts bath, showed 0.294 V of overpotential at $0.1A/cm^2$. That result is better than that of Ni and Ni-Zn plated electrodes. As the electroplating current density of the Ni-Zn-Fe electrode increased, the particle size tended to increase and the overpotential of oxygen evolution reaction decreased. As reducing pH of electroplating solution from 4 to 2, Fe content in electrode and activity of oxygen evolution reaction decreased.

• Journal of the Korean Chemical Society
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• v.30 no.5
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• pp.456-464
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• 1986

The complex formation of branched poly(ethylene imine) (BPEI) with bivalent transition metal ions, such as Fe(II), Co(II), Ni(II) and Cu(II), have been investigated in terms of visible absorption and pH titration methods in an aqueous solution in 0.1M KCl at 30${\circ}$. The stability constants for M(II)-BPEI complexes was calculated with the modified Bjerrum method. The formation curves of M(II)-BPEI complexes showed that Fe(II), Co(II), Ni(II) and Cu(II) ions formed coordination compounds with four, two, two, and two ethylene imine group, respectively. In the case of Cu(II)-BPEI complex at pH 3.4 ∼ 3.8, ${\lambda}_{max}$ was shifted to the red region with a decrease in the acidity. The overall stability constants (log $K_2$) increased as the following order, Co(II) < Cu(II) < Ni(II) < Fe(II).

• Korean Journal of Environment and Ecology
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• v.12 no.1
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• pp.22-29
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• 1998

This study is investigated for the trace element concentration in the soils derived from different parent rocks, which are serpentinites, metamorphic rocks and black shales, and the absorption of the trace element by Pinus rigida in Hongseong and Keumsan, Chungnam, respectively. The concentrations of nickel, chrominium and cobalt are high in the serpentinites, whereas the concentrations of zinc, molybdenium and iron are high in the metamorphic rocks. These elements in black shale are lower than those in serpentinites and metamorphic rocks. The serpentine soils show high nickel, chrominium and cobalt content, while zinc and iron content are high in the mixed soils(serpentinites + metamorphic rocks) and black shales. Comparing with parent rocks, all of trace elements in their weathered soils are low. The pH of serpentine soil is high, 7.73~9.55 and that of black shale soil in 5.61. In serpentine area, the absorptions of chrominium by P. rigida is lower than its in the soils. The absorption of zinc by P. rigida is high relative to zinc concentration in soils. The Co/Ni and Fe/Ni quotient in P. rigida over serpentine soils are considerably lower than those growing over other soils tpes.