• Title/Summary/Keyword: Ni-Mo

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A computer simulation of the peso-scale microstructural evolution in the ternary Ni- ${Ni_3}Al-{Ni_3}V$ system (${Ni_3}Al-{Ni_3}V$ 준이원계 합금 포함 삼원계 시스템에서의 meso-scale 미세구조의 전산 모사에 관한 연구)

  • Park, Sung-Il;Lee, Hyuck-Mo
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.947-952
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    • 2001
  • The meso-scale microstructure of the $Ni-Ni_3Al- Ni_3V$ system is crucial to obtain both high strength and high toughness. Its evolution may be predicted with the aid of computer simulation of the compositional separation for heat-treated alloys. In this study, computer simulations of the hypothetical A-B-C ternary system, which is similar to the $Ni-Ni_3Al- Ni_3V$ system in terms of phase equilibria, have been performed using the kinetic modeling. Simulated morphologies were changed with nominal compositions and model parameters. It was showed the current model was useful and the more realistic model was proposed.

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A manufacturing process and characteristic observation of alloy blocks for dental CAD/CAM system (치과 CAD/CAM 가공용 합금블럭 제조 및 특성 관찰)

  • Kim, Chi-young
    • Journal of Technologic Dentistry
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    • v.40 no.3
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    • pp.125-131
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    • 2018
  • Purpose: Automatic dental prosthesis manufacturing process was accelerated by the spread of dental CAD / CAM system. The CAD / CAM system with milling alloys were needed supplement. So, sintered alloy blocks were introduced. In this study, we want to study sintered alloy block. And to evaluate the alloy block manufacture and alloy properties. Methods: The alloy powders were prepared by high pressure water dispersion method. The sintered alloy blocks were prepared by low temperature pressing method. Their components observation were EDX, and the alloy structure was observed by XRD. Results: Co-Cr alloy powders were observed to have a circle shape with an average diameter of about $100{\mu}m$ and a Ni-Cr alloy powder had a circle shape with an average diameter of about $50{\mu}m$. The Co-Cr alloy block is composed of Co (34.62 wt%), Cr (17.33 wt%), Mo (2.98 wt%), Si (0.36 wt%) and C (44.17 wt%). The Ni-Cr alloy powder was composed of Ni (40.29 wt%), Cr (19.37 wt%), Mo (3.53 wt%), Si (0.52 wt%) and C (33.18 wt%). The peak of the Co and CoCr peaks were observed in the CoCr alloy body by the means of XRD study. Cr2Ni3 of the peak was observed in the Ni-Cr alloy material. Conclusion : As a result, the following conclusions were obtained. 1. Prepared by high-pressure water-law Co-Cr alloy powder has an average diameter $100{\mu}m$, Ni-Cr alloy powder was found to have the form of sphere having an average diameter $50{\mu}m$. 2. Co-Cr alloy and Ni-Cr alloy block produced by low-temperature processing showed a certain ratio. 3. In the XRD study, Co phase appeared in Co-Cr alloy block after sintering. and Cr2Ni3 phase appeared in Ni-Cr alloy block after sintering.

Electrode properties upon the substitution of Mo for Mn in Zr-basd AB2-type Hydrogen Storage Alloys (Zr1-xTixV0.4Ni1.2Mn0.4-yMoy계 합금전극의 Mo 함량에 따른 물성 및 전극특성)

  • Seo, Chan-Yeol;Park, Choong-Nyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.11 no.4
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    • pp.189-202
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    • 2000
  • $AB_2$ type Zr-based Laves phases alloys have been studied for potential application as a negative electrode in a Ni-MH battery. The $AB_2$-type electrodes have a much higher energy density than $AB_5$-type electrodes per weight, however they have some disadvantages such as poor activation behavior and cycle life etc. Nonetheless, the $AB_2$-type electrodes have been studied very extensively due to their high energy density. In this study, in order to develop the cycle life, the Mn of $AB_2$ alloy composition was substituted partially by Mo. The alloys were melted by arc furnace and remelted 4-5 times for homogeneity. The alloy powder was used below 200-325 mesh for experiments. The structures and phases of the alloys were analyzed by XRD, SEM and EDS, and measured the curve of a pressure-composition isotherms. The electrodes were prepared by cold pressing of the copper-coated(25 wt%) alloy powders, and tested by a half cell. The results are summarized as follows. The cycle life was improved with the increase of Mo amount in $Zr_{1-x}Ti_xV_{0.4}Ni_{1.2}Mn_{0.4}Mo_y$(x=0.3, 0.4) and the activation was faster, whereas the discharge capacity decreased.

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Basic Study for Solvent Extraction Separation of Mo from Synthetic Leaching Solution of Inconel713C by Alamine336 (Inconel713C 모사 용액으로부터 Alamine336을 통한 Mo의 용매추출분리를 위한 기초 연구)

  • Park, Sang-ryul;Ahn, Jong-gwan
    • Resources Recycling
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    • v.27 no.4
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    • pp.16-22
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    • 2018
  • Inconel713C which of a commercial Ni super alloy have the compositions of 70 wt.% Ni, 12 wt.% Cr, 6 wt.% Al and 4 wt.% Mo. In this study, solvent extraction has been performed to separate Mo from the synthetic leaching solution, formation of Inconel713C alloy similarly and is found the optimum conditions of recovery of Mo from the leaching solution. The effects of some variables, such as the nature and concentration of the extractants, $H_2SO_4$ concentrations, and the presence of impurities were investigated. The extraction percentage of Mo by Cyanex272 is 96% in the condition of pH 1 and 4% of concentration of Cyanex272 but Alamine336 is 99% in the condition of the range of pH 1 to 4 and 1 wt.% of concentration of Alamine336. In the case of Alamine336, the extraction percentage of Mo is increased by increasing of the concentration of Alamine336. The optimum condition of this experiment is pH 1 in aqueous phase, 1% concentration of Alamine336 and activation ratio of $H_2SO_4$ 1:0.5.

Magnetic Properties of Sintered Fe-79Ni-4Mo Cores Made of Centrifugal Atomized Powders (원심분무법 제조 분말로 제작된 Fe-79Ni-4Mo 소결코아의 자기특성)

  • 김상원;양충진
    • Journal of the Korean Magnetics Society
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    • v.6 no.6
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    • pp.388-396
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    • 1996
  • Magnetic properties of sintered Fe-79Ni-4Mo cores made of centrifugal atomized powders were investigated. $H_{c}$ and $\mu_{a}$ of the cores sintered at $1350^{\circ}C$ for 2 hours measured at 60 Hz at a magnetic field of 10 Oe showed the best properties. Particularly the properties of $H_{c}$ and $\mu_{a}$ measured at low field (< 0.2 Oe) were found to increase with increasing the particle size of the core samples. It resulted from the domain wall motion depending on the grain size of sintered bodies. The best D, C magnetic properties of $H_{c}$ and $\mu_{max}$ were 0.085 Oe and 40000, respectively. A, C properties of the same cores showed the $\mu_{a}$ of 11000. The magnetic properties of sintered cores always exhibited an enhanced AC/DC performance by using the powders mixed with two different particle sizes. Those properties of cores are expected to apply for current transformer.

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Comparative Evaluation of the Characteristics of High Si-High Mo Ductile Cast Iron, High Si-High Mo C. V. Cast Iron and Ni-resist Cast Iron (고규소 고몰리브덴 구상흑연주철, 고규소 고몰리브덴 C. V. 주철 및 Ni-resist 주철 특성의 비교 평가)

  • Ju, Young-Kyu;Choe, Kyeong-Hwan;Lee, Sang-Mok;Kim, Myung-Ho;Yun, Sang-Weon;Lee, Kyong-Whoan
    • Journal of Korea Foundry Society
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    • v.29 no.3
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    • pp.120-127
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    • 2009
  • The characterestics of high Si-high Mo ductile cast iron, high Si-high Mo C.V. cast iron and Ni-resist cast iron were compared and evaluated. The nodule count of the last one was lower and the nodularity was higher than those for the first one, respectively. The first two had ferritic matrices with small amounts of molybdenum carbides. The first one had the highest tensile strength and the last one the lowest elongation. This had the highest high temperature strength and that of the second one was greatly increased from the room temperature strength. The volumes of the first two were decreased during cooling and that of the last one changed little. The thermal expansion coefficient of the last one was the highest and the first one the lowest. During high temperature oxidation, even though the volume of the first one was increased, the weight was decreased and the volume and weight of the second one were increased. The change of the increased weight of the last one was more than that of thickness.

Heavy Metal Pollution in Soil and Vegetation near the Closed Daeseong Coal Mine in Keumsan, Chungnam (충남 금산 폐탄광지역의 토양 및 식물체내 중금속 오염)

  • 민일식;송석환;김명희
    • Journal of Korea Soil Environment Society
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    • v.3 no.2
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    • pp.41-51
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    • 1998
  • The research was conducted to measure the heavy metal pollution of soils and vegetations adjacent to the closed Daeseong coal mine in Keumsan, Chungnam. The studied area was divided into two sites ; the coal-bearing polluted and the non-polluted without coal. The samples of the weathered soils and vegetations(Miscnthus sinenis(MS) and Pinus rigida(PR)) were collected from both area. Cr, Mo, Ni, and Fe concentrations were high in the polluted soils, whereas Co, Sc, and Zn concentrations were high in the non-polluted soils. In the vegetations, Co, Cr, Sc, and Fe concentrations in the roots of MS and PR growing on the polluted sites were higher than the above-ground. However, on the non-polluted sites, Mo and Ni concentrations had an opposite trend. In the above-ground parts, high heavy metal concentrations (except Cr) were shown in MS of the non-polluted sites, whereas in the roots, heavy metal concentrations (except Zn) were high in the polluted sites. In the average heavy metal concentrations of two plants, most elements (except Zn) were lower in the plants than the soils. Comparing with vegetations and adjacent forest soils, heavy metal concentrations of the MS were similar to those of soil concentrations relative to the PR, suggesting that absorptions of the elements were higher in the MS than the PR.

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Dispersion of Toxic Elements in the Area Covered with Uranium-Bearing Black Shales in Korea (함(含)우라늄 흑색(黑色)세일 분포지역(分布地域)에서의 유독성원소(有毒性元素)들의 분산(分散)에 관한 지구화학적(地球化學的) 연구(硏究))

  • Chon, Hyo-Taek;Jung, Myung-Chae
    • Economic and Environmental Geology
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    • v.24 no.3
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    • pp.245-260
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    • 1991
  • Surficial dispersion patterns of heavy metals and toxic elements (U, Mo, Cu, Zn, Fe, Mn, Co, Cr, V, Ni, Pb, and Cd) were investigated in the Dukpyungri, Goesan area covered with low grade uranium-bearing black shales. Maximum abundance of U in the black shale was 455ppm. Radioactivity was counted at a maximum of 7cps in black shales, and was less than 0.5cps in shales, slates, and oil shales of the control areas. Enrichment of Mo, V, Cu, Zn, Cd, and Pb in black shales is particularly characteristic compared with shales, slates, and oil shales of the control areas, whereas contents of Mn, Cr, Co, and Th in all rock samples tend to be almost similar. Residual top soils (0~15cm depth) over black shales show high contents of Mo, Cu, Zn, Ni, Cd, and V in comparison with the control areas. Contents of trace elements in subsoils (15~30cm depth) were higher about one and half times than those in topsoils. Average contents of Mo, Cu, Pb, Zn, Cd and V in garden soil and playground soil of an elementary school in Dukpyungri, Goesan area, were high about two to fifteen times compared with the control areas. Contents of trace elements in stream sediments were higher from two to eight times than those in residual soils. Sodium, AI, K, V, Cr, and Fe were more enriched in the roots of pine than in the twigs of pine. Contents of Li, AI, V, Ni, Cd, Fe, and Co were higher in the roots of azalea than in the twigs of azalea. Enrichment of P, Ca, and Mg was remarkable in the twigs of both pine and azalea. Biological absorption coefficients for essential elements (Zn, P, Mn, Ca and K)tend to be high, whereas those for the non-essential elements.(Ba, Ti, V, and Mo) and toxic elements(Cr, Co, Pb and Ni) be low. Less mobile elements (Pd, Cd, and Co) tend to show anomalies with higher contrast than more mobile elements(Mo, V, Zn, Cu and Ni) in the area covered with black shales.

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