• 제목/요약/키워드: Ni-MH

검색결과 121건 처리시간 0.022초

Screening, Characterization, and Cloning of a Solvent-Tolerant Protease from Serratia marcescens MH6

  • Wan, Mao-Hua;Wu, Bin;Ren, Wei;He, Bing-Fang
    • Journal of Microbiology and Biotechnology
    • /
    • 제20권5호
    • /
    • pp.881-888
    • /
    • 2010
  • solvent-tolerant bacterium strain, MH6, was isolated by hydrophilic organic solvent DMSO enrichment in the medium and identified as Serratia marcescens. The extracellular protease with novel organic-solvent-stable properties from strain MH6 was purified and characterized. The molecular mass of the purified protease was estimated to be 52 kDa on SDS-PAGE. The open reading frame (ORF) of the MH6 protease encoded 504 amino acids with 471 amino acid residues in the mature protease. Based on the inhibitory effects of EDTA and 1,10-phenathroline, the MH6 protease was characterized as a metalloproteinase. The enzyme activity was increased in the presence of $Ni^{2+}$, $Mg^{2+}$, and $Ca^{2+}$. The protease could also be activated by the nonionic surfactants Tween 80 (1.0%) and Triton X-100 (1.0%). The protease showed remarkable solvent stability in the presence of 50% (v/v) solutions of long-chain alkanes and long-chain alcohols. It was also fairly stable in the presence of 25% solutions of hydrophilic organic solvents. Owing to its high stability in solvents and surfactants, the MH6 protease is an ideal candidate for applications in organic catalysis and other related fields.

금속 수소화물을 이용한 수소공급시스템 (Hydrogen Supplying System using Metal Hydride)

  • 배상철;승전정문
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2007년도 춘계학술대회
    • /
    • pp.13-19
    • /
    • 2007
  • To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1 MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristics, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results are compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

  • PDF

Nafion 115를 사용한 DMFC MEA 의 성능실험 (Performance of a direct methanol fuel cell (DMFCs)Using Nation 115)

  • 최훈;황용신;차석원
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
    • /
    • pp.43-46
    • /
    • 2007
  • To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristic, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results rate compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

  • PDF

Ni-MH 2차 전지용 Zr계 수소저장합금전극의 특성에 미치는 치환원소(Co, Cr, Fe)의 영향 (The effect of substitution elements(Co, Cr, Fe) on the properties of Zr-based hydrogen storage alloy electrode for Ni-MH secondary battery)

  • 최승준;정소이;서찬열;최전;박충년
    • 한국수소및신에너지학회논문집
    • /
    • 제10권3호
    • /
    • pp.185-189
    • /
    • 1999
  • Effects of alloy modification with the $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy for an electrode use have been investigated. For the alloy composition, a part of Mn was substituted by Co, Cr and Fe. The experimental results showed that Co accelerated activation of alloy, and Fe and Cr improved the discharge capacity. These results agree with P-C-T curves of each alloy. But substituting Fe for Mn showed the decrease of the discharge capacity when discharged at high rate (60mA, about 1C rate). Considering both the discharge capacity and the high rate discharge property, $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ alloy was found to be the best alloy among the alloys subjected to the test.

  • PDF

Ni분말과 소결시킨 V0.9Ti0.1 수소저장합금의 전극특성 (The Electrode Characteristics and Modified Surface Properties of V0.9Ti0.1 Alloy Sintered with Ni Powder)

  • 김동명;이한호;이기영;이재영
    • 한국수소및신에너지학회논문집
    • /
    • 제6권1호
    • /
    • pp.1-9
    • /
    • 1995
  • $V_{0.9}Ti_{0.1}$ 합금은 많은 양의 수소를 흡수할 수 있으나 KOH 전해질내에서 방전이 되지 않기 때문에 Ni-MH 전지의 음극재료로 사용할 수 없었다. 이와 같은 $V_{0.9}Ti_{0.1}$ 합금을 전해질내에서 수소흡수/방출에 대한 촉매효과를 갖도록 Ni 분말과 소결하였다. Ni 분말과 소결한 모든 시편은 KOH 전해질내에서 10 Cycle 이내에 활성화 되었다. 방전용량은 소결시 첨가된 Ni 분말의 양에 따라 maximum 거동을 보였다. 가장 높은 방전용량을 보여준 전극의 경우는 소결시 첨가된 Ni 분말의 양이 25wt.%이며 그 방전용량은 302mAh/g이었다. SEM과 EDS 그리고 XRD 분석결과 소결시 $VNi_3$가 형성됨을 알 수 있었다. $V_{0.9}Ti_{0.1}$ 합금의 표면에 형성된 $VNi_3$는 전극의 최적방전조건과 밀접한 관련이 있음을 알 수 있었다. Brewer-Engel 이론에 의하면 $VNi_3$는 수소의 evolution에 대한 전기적 촉매효과가 매우 높다고 보고하고 있으며, 이러한 효과는 본 실험결과 교환전류밀도의 증가와 방전시 과전압의 감소로써 나타났다. 본 연구에서는 수소의 저장용량은 크나 KOH 전해질내에서 방전되지 않는 합금을 사용하여 Ni-MH 전지용 음극개발을 하기 위해 Ni분말과 소결하여 합금의 표면을 변화시키는 새로운 방법을 제안하고자 한다.

  • PDF

Ni-MH 2차 전지용 ZrV0.1Mn0.7Ni1.2 수소저장합금의 전극특성에 미치는 Mo의 부분치환과 열처리의 영향 (The Effects of Partial Substitution of Mo and Heat Treatment on the Electrode Characteristics of ZrV0.1Mn0.7Ni1.2 Hydrogen Storage alloy)

  • 한동수;오명학;정치규;정원섭;김인곤
    • 한국수소및신에너지학회논문집
    • /
    • 제9권1호
    • /
    • pp.16-24
    • /
    • 1998
  • 최근 Ni-MH 전지의 고성능화를 위해 방전용량이 높은 Zr기 $AB_2$ 형의 수소 흡장 합금이 주목받고 있다. 본 연구에서는 이 중에서 $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ 합금을 선택하여 합금의 열처리 그리고, Mn 대신 Mo의 부분치환이 전극의 특성에 미치는 영향을 조사하였다. 합금은 먼저 아크 용해로를 사용하여 제작하였으며, 이 합금 중 일부를 $1,100^{\circ}C$에서 가열 후 각각 서냉과 급냉 처리를 행하였다. 이 세 가지 종류의 합금들을 이용하여 활성화 거동, 고율 방전 특성, 자기 방전 특성 등의 전극특성을 평가하였다. 그 결과 합금은 열처리에 의해서 방전용량이 감소하고 고율 방전율 또한 감소하였다. 그러나, 전기 화학적으로 구한 압력-조성 등온곡선의 평탄구역의 기울기를 감소시켰다. 또한 $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ 합금의 Mn을 Mo으로 부분 치환함에 의해서 방전용량의 감소 없이 자기방전특성을 크게 개선할 수 있었다.

  • PDF

UPS 기능을 가지는 배터리 기반의 삼상 전력 평준화 시스템 (Three-phase Power Equalizing System with UPS Function based on Battery Storage)

  • 권정민
    • 전력전자학회논문지
    • /
    • 제17권4호
    • /
    • pp.353-358
    • /
    • 2012
  • In this paper, three-phase power equalizing system (PES) with UPS function is proposed. This system is based on NiMH battery with battery management system. The power conversion circuit is composed with the three-phase converter/inverter, the bi-directional converter, and the thyristor switches. The three-phase converter/inverter provides the power to the grid or get the power from the grid. Also, it operates as a UPS. The bi-directional converter charges or discharges the battery. The thyristor switches are used for connecting/disconnecting with the grid and the load. A 15 kW prototype is implemented for the verifying the performance of the proposed system.

Ni-MH 2차 전지의 충전 방식에 관한 연구 (A Study on the Charging Method of Ni-MH Rechargeable Battery)

  • 이인호;황보민;김성환;유지윤;박귀태
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1993년도 하계학술대회 논문집 A
    • /
    • pp.464-466
    • /
    • 1993
  • In this paper, a peak detection algorithm having high reliability is proposed. The peak detection algorithm is implemented to a charger and power control system which is applicable to home appliances or notebook PC directly. The charger and power control system is controlled by a microprocessor, M50927 (Mitzubishi), to improve cost to performance ratio. The charger algorithm is designed to be operated under optimal charge node and various protections are added tn improve the reliability of the charger.

  • PDF