• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 C
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• pp.1599-1601
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• 2000

To study invar alloy as a core material for large ampacity over-head transmission line which have high strength and low thermal expansion coefficient simultaneously, thermal expansion coefficient, physical properties and hardness of Fe-Ni-Co-xC alloy have been studied. It is necessary that invar alloy possess low thermal expansion coefficient and high strength for increased capacity over-head transmission line. In this paper we tried to find out the effect of carbon addition related with mechanical and physical properties. It was found that the thermal expansion coefficient and hardness were increased with carbon addition for whole composition range but the saturation magnetization was decreased except for the range of 0.1$\sim$0.4%C.

• 한국주조공학회지
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• 제25권6호
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• pp.259-264
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• 2005

The copper clad steel wire is used extensively as lead wires of electronic components such as capacitors, diodes and glass sealing lamp because the wire combines the strength and low thermal expansion characteristic of Fe-Ni steel with the conductivity and corrosion resistance of copper. In order to fabricate the copper clad steel wire, several processes including electro-plating, tubecladding extrusion process and dip forming process have been introduced and applied. The electroplating process for the production of copper clad steel wire shows poor productivity and induces environmental load generation such as electroplating solution. The dip forming process is suitable to mass production of copper clad steel such as trolley wire. and need expensive manufacturing facilities. The present paper describes the improvement of the conventional continuous casting process to fabricate copper clad steel wire, which its core metal is low thermal expansion Fe-Ni alloy and its sheath material is copper. In particular, the formation of intermetallic compound at interface between core and sheath was investigated in order to introduce optimum continuous casting process parameter for fabrication of copper clad steel wire with higher electrical conductivity. The mechanical strength of copper clad steel wire was also investigated through wiredrawing process with of 95% in total reduction ratio.

• 한국분말재료학회지
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• 제23권3호
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• pp.207-212
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• 2016

In this study, Fe-Cu-Ni-Mo-C low alloy steel powder is consolidated by spark plasma sintering (SPS) process. The internal structure and the surface fracture behavior are studied using field-emission scanning electron microscopy and optical microscopy techniques. The bulk samples are polished and etched in order to observe the internal structure. The sample sintered at $900^{\circ}C$ with holding time of 10 minutes achieves nearly full density of 98.9% while the density of the as-received conventionally sintered product is 90.3%. The fracture microstructures indicate that the sample prepared at $900^{\circ}C$ by the SPS process is hard to break out because of the presence of both grain boundaries and internal particle fractures. Moreover, the lamellar pearlite structure is also observed in this sample. The samples sintered at 1000 and $1100^{\circ}C$ exhibit a large number of tiny particles and pores due to the melting of Cu and aggregation of the alloy elements during the SPS process. The highest hardness value of 296.52 HV is observed for the sample sintered at $900^{\circ}C$ with holding time of 10 minutes.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1997년도 한국재료학회 추계학술발표회
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• pp.173-173
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• 1997

• 한국재료학회지
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• 제15권12호
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• pp.773-779
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• 2005

Properties of Ni-base superalloys of Nimonic 80A alloy system were investigated by the observation of microstructures, precipitates ana hardness as a function of the chemical compositions ana the paths of heat treatment. The higher hardness values showed, the higher Ti/Al ratio among high compositions of Cr and Co element. The lower (Ti+Al) and Fe contents decreased in the same Ti/Al ratio, the higher hardness values showed. This results are considered that coherent deformation was increased with increasing Ti/Al ratio. Hardness showed higher value when Cr contents was $18 wt\%$ less than $21wt\%Cr$. In $3.15 wt\%$Co alloy, $\gamma'$ phase was very fine as around 50nm and, its volume fraction and hardness showed the highest value by 2step-aging treatment.

• 대한금속재료학회지
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• 제48권6호
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• pp.523-532
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• 2010

Co-application of organic coating and cathodic protection has not provided enough durability to low-alloyed steels inseawater ballast tank (SBT) environments. An attempt has made to study the effect of alloy elements (Al, Cr, Cu, Mo, Ni, Si, W) on general and localized corrosion resistance of steels as basic research to develop new low-allowed steels resistive to corrosion in SBT environments. For this study, we measured the corrosion rate by the weigh loss method after periodic immersion in synthetic seawater at $60^{\circ}C$, evaluated the localized corrosion resistance by an immersion test in concentrated chloride solution with the critical pH depending on the alloy element (Fe, Cr, Al, Ni), determined the permeability of chloride ion across the rust layer by measuring the membrane potential, and finally, we analyzed the rust layer by EPMA mapping and compared the result with the E-pH diagram calculated in the study. The immersion test of up to 55 days in the synthetic seawater showed that chromium, aluminium, and nickel are beneficial but the other elements are detrimental to corrosion resistance. Among the beneficial elements, chromium and aluminium effectively decreased the corrosion rate of the steels during the initial immersion, while nickel effectively decreased the corrosion rate in a longer than 30-day immersion. The low corrosion rate of Cr- or Al-alloyed steel in the initial period was due to the formation of $Cr_2FeO_4$ or $Al_2FeO_4$, respectively -the predicted oxide in the E-pH diagram- which is known as a more protective oxide than $Fe_3O_4$. The increased corrosion rate of Cr-alloyed steels with alonger than 30-day exposure was due to low localized corrosion resistance, which is explained bythe effect of the alloying element on a critical pH. In the meantime, the low corrosion rate of Ni-alloyed steel with a longer than 30-day exposure wasdue to an Ni enriched layer containing $Fe_2NiO_4$, the predicted oxide in the E-pH diagram. Finally, the measurement of the membrane potential depending on the alloying element showed that a lower permeability of chloride ion does not always result in higher corrosion resistance in seawater.

• 청정기술
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• 제13권4호
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• pp.274-280
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• 2007

본 연구에서는 염화 제2철 수용액의 재생 공정에 주로 쓰이고 있는 철환원법을 대체하기 위한 방법으로, 액-액 용매 추출법을 사용하여 수용액 내에 잔존해 있는 중금속인 Fe와 Ni을 분리 회수하는 공정을 개발하였다. Lab 실험을 통해 우선 염화 제2철 수용액으로부터 선택적으로 염화 제2철만을 추출할 수 있는 용매조건을 개발하였고, 그 결과를 사용하여 액-액 추출공정의 상업화 추진을 위한 pilot 공정 및 장치를 개발하였다. 또한 pilot test를 통하여 추출단과 역추출단의 단수를 결정할 수 있었고, 양산 공정에 적용할 수 있는 공정 데이터를 확보하였다.

• 한국응용과학기술학회지
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• 제24권4호
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• pp.427-435
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• 2007

에너지원으로서 수소를 생산하기 위하여 하니컴 구조를 갖는 모노리스에 10 wt% $Ni/CeO_2-ZrO_2$ 촉매를 담지한 후 메탄의 수증기 개질 실험을 수행하였다. 다른 $CeO_2/ZrO_2$ 몰비를 갖는 촉매들 중에서, $Ni/CeO_2-ZrO_2(CeO_2/ZrO_2=4/1)$촉매가 $700-800^{\circ}C$에서 높은 메탄의 전환율을 보여 주었다. 10wt% $Ni/CeO_2-ZrO_2$ 촉매가 담지된 금속 모노리스 촉매체는 높은 열전도도와 비표면적들로 인하여 좋은 촉매 특성을 보여줌을 확인할 수 있었다. 또한, 금속모노리스 촉매체는 반응물에서 과다의 수증기에 의한 수소 수율에서 크게 영향을 받지 않음을 알 수 있었다. $GHSV=30,000h^{-1}$, 반응물 비$(H_2O/CH_4=3.0)$ 반응온도 $800^{\circ}C$에서 금속모노리스 촉매체는 98%이상의 메탄의 전환율을 보여주었다. 생성물 가스에서 $CO_2/CO$의 비는 수증기/메탄의 반응물비가 증가할수록 수성가스화 반응에 의하여 증가됨을 알 수 있었다.

• 한국분말재료학회지
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• 제15권4호
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• pp.292-296
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• 2008

The electromagnetic (EM) wave absorption properties of the $Fe_{73}Si_{16}B_7Nb_3Cu_1$ nanocrystalline powder mixed with 5 to 20 vol% of Ni-Zn ferrites has been investigated in a frequency range from 100MHz to 10GHz. Amorphous ribbons prepared by a planar flow casting process were pulverized and milled after annealing at 425 for 1 hour. The powder was mixed with a ferrite powder at various volume ratios to tape-cast into a 1.0mm thick sheet. Results showed that the EM wave absorption sheet with Ni-Zn ferrite powder reduced complex permittivity due to low dielectric constant of ferrite compared with nanocrystalline powder, while that with 5 vol% of ferrite showed relatively higher imaginary part of permeability. The sheet mixed with 5 vol% ferrite powder showed the best electromagnetic wave absorption properties at high frequency ranges, which resulted from the increased imaginary part of permeability due to reduced eddy current.

• 전자공학회논문지
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• 제51권1호
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• pp.211-218
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• 2014

본 논문에서는 NFC 나 핸드폰, 컴퓨터 등의 정보통신기기에 사용하기 위한 높은 주파수 대역의 전자파 차폐 필름을 개발하기 위하여, 주로 자계를 차폐할 수 있는 니켈 및 실리콘과 철의 합금의 연자성 특성을 연구함에 있어 최적의 합금조성으로 Fe-Si-Cr 합금과 Fe-Ni-Cr 합금의 자성특성에 대하여 연구하였고, 그 결과에 의하여 결정된 합금의 조성비에 따라 각 합금을 용융상태에서 수분산시켜 원형 편상의 연자성 합금분말을 만들었으며, 그들을 수지에 함침시키고 가열 회전 롤러를 이용한 캘린더 가공법으로 두께 0.1 mm 및 1 mm 의 필름을 만든 다음, 저주파에서부터 10GHz 마이크로파대역까지의 전자파에 대한 투자율과 차폐율에 대하여 연구하였다. 또한 본 논문에서는 합금 분말입자의 제조에 앞서, 합금의 투자율을 예측할 수 있는 식을 제안하였으며, 그 식의 합리성을 증명하기 위해 MATLAB을 이용하여 기 발표된 합금들의 투자율과 주파수 특성을 비교적 정확하게 기술하고 있음을 보였고, 그로부터 가장 이상적인 합금의 조성비를 결정하고, 분말입자가 수지에 함침된 필름의 투자율 역시 계산하였다. 전자파 차폐 수지 필름의 차폐율(Shielding Effectiveness)에 대한 시뮬레이션은 HFSS를 이용하였다.