• Title/Summary/Keyword: Ni-나노 입자

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Synthesis of Pt/alloy Nanoparticles by Electrical Wire Explosion in Liquid Media and its Characteristics (액중 전기선 폭발 공정을 이용한 Pt/alloy 하이브리드 나노입자의 제조 및 그 특성)

  • Koo, Hye Young;Yun, Jung-Yeul;Yang, Sangsun;Lee, Hye-Moon
    • Particle and aerosol research
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    • v.8 no.2
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    • pp.83-88
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    • 2012
  • The electrical wire explosion process in liquid media is promising for nano-sized metal and/or alloy particles. The hybrid Pt/Fe-Cr-Al and Pt/Ni-Cr-Fe nanoparticles for exhaust emission control system are synthesized by electrical wire explosion process in liquid media. The alloy powders have spherical shape and nanometer size. According to the wire component, while Pt/Fe-Cr-Al nanoparticles are shown the well dispersed Pt on the Fe-Cr-Al core particle, Pt/Ni-Cr-Fe nanoparticles are shown the partially separated Pt on the Ni-Cr-Fe core particle. Morphologies and component of two kinds of hybrid nano catalyst particles were characterized by transmission electron microscope and energy dispersive X-ray spectroscopy analysis.

Exchange-coupling Interaction and Magnetic Properties of BaFe12O19/Ni0.5Zn0.5Fe2O4 Nanocomposite Ferrite (BaFe12O19/Ni0.5Zn0.5Fe2O4 나노복합체 Ferrite의 Exchange-coupling 상호 작용과 자기 특성)

  • Oh, Young-Woo
    • Journal of the Korean Magnetics Society
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    • v.24 no.3
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    • pp.81-85
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    • 2014
  • Nano-sized Ba-ferrite, Ni-Zn ferrite and $BaFe_{12}O_{19}/Ni_{0.5}Zn_{0.5}Fe_2O_4$ nanocomposite ferrite were prepared by sol-gel combustion method. Nanocomposite was calcined at temperature range of $600{\sim}900^{\circ}C$ for 1 h. According to the diffraction patterns, hard/soft nanocomposite was indicated to the coexistence of the magnetoplumbite structural $BaFe_{12}O_{19}$ and spinel $Ni_{0.5}Zn_{0.5}Fe_2O_4$ and agree with the standard data (JCPDS 10-0325). The particle size of nanocomposite turn out to be less than 90 nm. The nanocomposite ferrite shows a single-phase magnetization behavior, implying that the hard magnetic phase and soft magnetic phase were well exchange-coupled. The specific saturation magnetization ($M_s$) of the nanocomposite is located between hard ($BaFe_{12}O_{19}$) and soft ferrite ($Ni_{0.5}Zn_{0.5}Fe_2O_4$). The remanence (Mr) of nanocomposite ferrite is much higher than that for the individual $BaFe_{12}O_{19}$ and $Ni_{0.5}Zn_{0.5}Fe_2O_4$ ferrite. $(BH)_{max}$ is increased, generally.

Heat Conductivity Test and Conduction Mechanism of Nanofluid (나노유체의 열전도율 실험과 열전달 메커니즘의 제시)

  • Park, Kweon-Ha;Lee, Jin-A;Kim, Hye-Min
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.6
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    • pp.862-868
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    • 2008
  • Many studies have been conducted to increase heat transfer in fluid. One of the various heat transfer enhancement techniques is suspending fine metallic or nonmetallic solid powder in traditional fluid. Nanofluid is defined as a new kind of heat transfer fluid containing a very small quantity of nanometer particles that are uniformly and stably suspended in a liquid. This study investigates the effect of nanofluid containing diamond, CuNi and CuAg nanometer particles, and proposes the heat transport mechanism of nanofluid. The test result shows that the thermal conductivity of nanofluid is much higher than that of traditional fluid, and the increasing rate of the conductivity is dependent on the conductivity of the solid metal.

Synthesis and Properties of Nano-sized Ni-Fe Alloy Particle Dispersed ${Al_2}{O_3}$Nanocomposite (나노크기 Ni-Fe 합금입자 분산${Al_2}{O_3}$ 나노복합재료의 합성 및 특성)

  • Nam, Gung-Seok;O, Seung-Tak;Lee, Jae-Seong;Jeong, Yeong-Geun;Kim, Hyeong-Seop
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.986-990
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    • 2001
  • An optimum route to fabricate the $A1_2O_3/Fe-Ni$ alloy nanocomposites with sound microstructure and enhanced mechanical properties as well as magnetism was investigated. To prepare homogeneous nanocomposite powders of Fe-Ni alloy and $Al_2O_3$, the solution-chemistry routes using $Al_2O_3 \; Ni(NO_3)_2{\cdot}6H_2O$ and $Fe(NO_3)_3{\cdot}9H_2O$ powders were applied. Microstructural observation of the powder mixture revealed that the Fe-Ni alloy particles of about 20 nm in size were homogeneously surrounded $A1_2O_3$, forming nanocomposite powder. The hot-pressed composite showed improved fracture toughness and magnetic response. These results suggest that the synergy materials with an improved mechanical properties and excellent functionality can be fabricated by controlled powder preparation and consolidation processing.

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Synthesis of Ni nanopowder by wire explosion in liquid media (액중 전기폭발법을 이용한 니켈 나노분말 제조)

  • Cho, Chu-Hyun;Jin, Yun-Sik;Ha, Yoon-Cheol;Lee, Kyung-Ja;Rhee, Chang-Kyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.61-61
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    • 2010
  • 니켈 니켈 와이어를 증류수 및 에탄올 등의 유기용매 중에서 펄스파워 기술을 이용하여 전기적으로 폭발 시켰다. 폭발에 의하여 생성된 입자들은 직경이 수 마이크로미터 에서 수 십 나노미터에 이르는 넓은 입도분포를 보였다. 본 연구에서는 원심분리기술을 이용하여 입자의 크기별로 분리 회수가 가능함을 증명하였다. 또한 유기용매 중에서 제조된 니켈분말에 탄소가 포함되어 있으며, 열처리를 통하여 제거가 가능함을 실험을 통하여 밝혔다.

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Fabrication of Al2O3/Fe-Ni Nanocomposites by Pressureless Sintering and their Magnetic Properties (상압소결에 의한 Al2O3/Fe-Ni 나노복합재료의 제조 및 자기적 특징)

  • Lee, Hong-Jae;Jeong, Young-Keun;NamKung, Seok;Oh, Sung-Tag;Lee, Jai-Sung
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.769-774
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    • 2002
  • The powder mixture in which Fe-Ni alloy particles of 20 nm were homogeneously dispersed on $Al_2O_3$ particle surfaces was prepared by hydrogen reduction of $Al_2O_3$ and metal oxide powders. $Al_2O_3$/Fe-Ni nanocomposites fabricated by pressureless sintering were only composed of $Al_2O_3$ and ${gamma}$-Fe-Ni phases and achieved over 98% of the theoretical density at the sintering temperature above $1350^{\circ}C$. The highest strength and toughness of the composites were 574 MPa and 3.9 MP$a{\cdot}m1/2$, respectively. These values were about 20% higher than these of monolithic $Al_2O_3$ sintered at the same conditions. Nanocomposites showed ferromagnetic properties and coercive force was increased with decrease of the average particle size of dispersions.

Improved Ethanol Gas Sensing Performance of α-Fe2O3 Nanoparticles by the Addition of NiO Nanoparticles (NiO의 첨가에 따른 α-Fe2O3 나노입자 센서의 에탄올 가스 검출 특성 향상)

  • Park, Sunghoon;Kang, Wooseung
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.69-74
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    • 2016
  • In order to investigate the effect of NiO on the ethanol gas sensing performance of ${\alpha}-Fe_2O_3$ nanoparticles, NiO and ${\alpha}-Fe_2O_3$ nanoparticles are synthesized by hydrothermal method. The sensor with ${\alpha}-Fe_2O_3$ and NiO nanoparticles mixed at an optimum ratio of 7:3 showed 3.8 times improved sensing performance for 200ppm ethanol gas at $200^{\circ}C$. The enhanced gas sensing performance can be considered to be caused by pn heterojunction at the grain boundaries of ${\alpha}-Fe_2O_3$ and NiO nanopartcles.

Microstructure and Properties of Nano-Sized Ni-Fe Alloy Dispersed Al2O3 Composites (Ni-Fe 합금입자 분산 Al2O3 나노복합재료의 미세조직 및 특성)

  • 남궁석;정재영;오승탁;이재성;이홍재;정영근
    • Journal of Powder Materials
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    • v.9 no.3
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    • pp.161-166
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    • 2002
  • Processing and properties of $Al_2O_3$ composites with Ni-Fe content of 10 and 15 wt% were investigated. Homogeneous powder mixtures of $Al_2O_3$/Ni-Fe alloy were prepared by the solution-chemistry route using $Al_2O_3$, $Ni(NO_3)_2{\cdot}6H_2O$ and $Fe(NO_3)_3{\cdot}9H_2O$ powders. Microstructural observation of composite powder revealed that Ni-Fe alloy particles with a size of 20nm were homogeneously dispersed on $Al_2O_3$ powder surfaces. Hot-pressed composites showed enhanced fracture toughness and magnetic response. The properties are discussed based on the observed microstructural characteristics.

One-pot Synthesis of Nickel and Tungsten Carbide Nanoparticles Supported Mesoporous Carbon Electrocatalyst for Oxygen Reduction Reaction (산소환원반응을 위한 니켈-텅스텐 카바이드 나노입자 담지 메조포러스 카본 촉매의 단일 합성 및 그 특성 평가)

  • Kim, Hyemin
    • Journal of the Korean institute of surface engineering
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    • v.51 no.3
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    • pp.179-184
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    • 2018
  • In this study, Ni and tungsten carbide (WC) nanoparticles are simultaneously synthesized with the mesoporous carbon nanoparticles (CNP) using a solution plasma processing (SPP) in the benzene. The Ni and WC nanoparticles were formed through the sputtering effect of electrodes during discharge, and mean time CNP were formed through reduction reaction. TEM observation showed that loaded Ni and WC nanoparticles were evenly dispersed on the CNP. The results of electrochemical analysis demonstrated that an introduction of Ni nanoparticles promoted to improve catalytic activity for oxygen reduction reaction (ORR). Moreover, Ni-WC/CNP lead to fast electron transfer process compared to that of WC/CNP. Therefore, the inexpensive Ni-WC/CNP might be a promising as catalytic material for cathodes in fuel cell applications.