• Title/Summary/Keyword: Ni-$TiO_2$

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Acoustic Emission Characteristics of Ceramic Coated Steel by Plasma Spraying (플래즈머용사에 의한 세라믹 코팅 강재의 음향방출 특성)

  • Kim, G.S.
    • Journal of Power System Engineering
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    • v.2 no.3
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    • pp.49-54
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    • 1998
  • This paper is investigated of hardness and adhesiveness of plasma sprayed coating steels by AE(Acoustic Emission) testing when loading a tensile. AE Parameters used are Event, Count, Energy and Amplitude. Test specimens are carbon steel(S45C) with sprayed coating layers of Ni-4.5wt.%Al(bond coating) and $TiO_2$(top coating), and carry out heat treatment at $800^{\circ}C\;and\;1000^{\circ}C$, respectively. The micro-hardness of the heat treatment specimen have been improved more than that of non-heat treatment. On the tensile test, the process and occurence of the exfoliation of the sprayed coating layer can be estimated by AE Characteristics of AE parameters, such as event, count, amplitude and energy, on the layer exfoliation are shown the similar aspects. The exfoliation of bond coating occure at about 20% of strain and top coating is about 5% of strain.

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Dielectric and Piezoelectric Properties of PNN-PMN-PZT Ceramics for High Power Piezoelectric Transformer (고출력 압전변압기용 PNN-PMN-PZT 세라믹스의 유전 및 압전 특성)

  • 황상모;류주현;홍재일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.7
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    • pp.597-601
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    • 2002
  • In this study, the structural, dielectric and piezoelectric properties of $Pb[(Ni_{1/3}Nb_{2/3})_x-(Mn_{1/3}Nb_{2/3})_{0.09-x}-(Zn_{0.505}Ti_{0.495)_0.91]O_3$ (x=0, 0.01, 0.02, 0.03, 0.04, 0.05) system ceramics were investigated to develop the composition ceramics for piezoelectric transformer. All the specimens were sintered at $1250^{\circ}C$ and its physical properties were measured, and the results are as follows : With increasing PNN substitution for PMN-PZT system, dielectric constant was increased and electro-mechanical coupling factor($k_p$) was increased to 0.62 at 5 mol% while mechanical quality factor(Qm) was decreased.

Effect od solution composition on electroless Ni plating on PZT (PZT의 무전해 니켈도금의에 미치는 액조현성의 영향)

  • 김제경;이명훈;문경만
    • Journal of the Korean institute of surface engineering
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    • v.31 no.4
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    • pp.209-216
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    • 1998
  • It is well knownthat electroledd plating is the desirable surface treatment method which is being widely used to all kinds of material such as requiring corrosing resistance, wear resistance and conductivity, especially nonconductivity materials' surface plating. However, it is suggested that there are some problems that must be solved, for exaple, rate of plating, corrosion resistance, thickness of plating film etc. Therefore in this paper, when electroless nickel plating was performed on the PZT(Pb(Zr,Ti))with varying of solution composition such as NaOH, and $H_2NCH_2COOH$, the effect of the rate of plating and corrosion resistance were investigated.

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Microstructure and Piezoelectric Properties of PMN-PNN-PZT Ceramics (PMN-PNN-PZT 세라믹스의 미세구조 및 압전 특성)

  • Yoo, Ju-Hyun;Kim, Seung-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.8
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    • pp.496-500
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    • 2017
  • $Pb(Mn_{1/3}Nb_{2/3})_{0.07}(Ni_{1/3}Nb_{2/3})_{0.10}(Zr_{0.5}Ti_{0.5})_{0.83}O_3$ composition ceramics with high piezoelectric properties were fabricated by the columbite precursor method for ultrasonic generators, and the effects of sintering temperature on microstructure and piezoelectric properties were systematically investigated. It was found that the tetragonality of the ceramics decreased with increase in sintering temperature. Moreover, excellent physical properties such as $d_{33}=447pC/N$, ${\varepsilon}_r=1,843$, $k_p=0.641$, and $Q_m=1,207$ were obtained for an ultrasonic generator when the second calcination temperature and sintering temperature were $720^{\circ}C$ and $920^{\circ}C$, respectively.

Bending Properties of the Flexible BMNO (Bi2Mg2/3Nb4/3O7) Capacitor Using Graphene Electrode (그래핀 전극을 이용한 유연한 BMNO (Bi2Mg2/3Nb4/3O7) 캐패시터의 굽힘 특성)

  • Song, Hyun-A;Park, Byeong-Ju;Yoon, Soon-Gil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.5
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    • pp.387-391
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    • 2012
  • Graphene was fabricated onto Ni/Si substrate using a rapid-thermal pulse CVD and they were transferred onto the Ti/PES flexible substrate. For top electrode applications of the BMNO dielectric films, graphene was patterned using a argon plasma. Through an AFM image and a leakage current density of the BMNO films grown onto various bottom electrodes before and after bending test, BMNO films grown onto the graphene bottom electrode showed no change of the microstructure and the leakage current density after the bend.

Electrical Characteristics of Piezoelectric Transformer for Driving A 28W Fluorescent Lamp (28W(T5) 형광등 구동용 압전트랜스포머의 전기적 특성)

  • 류주현;황상모;윤광희;김종선;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.847-851
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    • 2000
  • In this study, contour-vibration-mode Pb($Ni_{1/2}$,$W_{1/2}$)$O_3$-Pb(Zr,Ti)$O_3$ piezoelectric transformers for driving a 28W(T5) fluorescent lamp were fabricated to the modified filter structure with ring and dot electrodes which has been developed for application in 455kHz AM radios. The piezoelectric transformers were fabricated to the size of $31.5$\times$31.5$\times$2.5$mm^3$ with the variations of ring/dot electrode area ratio. Driving of piezoelectric transformer was carried out with input region for the ring electrode and output region for the dot electrode. The electrical properties and characteristic temperature rises caused by the vibration were measured at various load resistances. A 28 W fluorescent lamp, T5, was successfully driven by the fabricated transformer. The transformer with ring/dot electrode area ratio of 1.83 exhibited the best properties in terms of output power, efficiency and characteristic temperature rise, 30.95 W, 97.57% and8.3$^{\circ}C$ respectively.

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Preliminary Study on the Ultramafic Rocks from the Chungnam Province, Korea (충남지역에 분포하는 초염기성암의 기원규명을 위한 기초연구)

  • Wee, Soo-Meen;Choi, Seon-Gyu;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.27 no.2
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    • pp.171-180
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    • 1994
  • Several ultramafic bodies and ultramafic origin talc deposits are distributed in Chungnam province near the contact zone with Ogchun fold belt They occur as discontinued belt form with northeast trending, and most of them are more or less sepentinized. Major, trace, and rare earth elements analyses were made of the ultramafics from the study area to constrain their origin and genetic relationships. Compared to the primitive mantle estimates of privious workers, the correlations defined by the studied rock samples indicate similar Ni but very lower $Al_{2}O_{3}$, CaO and $TiO_{2}$ contents. It is inferred that source material of the studied rocks might be residual mantle which had undergone a large degree of partial melting event. The REE patterns show relatively flat to enriched in LREE (chondrite normalized La/Yb and Sm/Yb ratios are 1.1-5.2 and 1.2-1.6). Several alternative explaination are possible for LREE enrichment patterns in the studied ultramafic rocks such as 1) enrichment due to late stage alteration, 2) enriched pre-melting composition, and 3) mixing of two components. Based on the result, the LREE enrichment characteristic of the studied rocks might be result from the mixture of two geochemically distinct components; one is depleted residual mantle and the other component which determine the abundances of incompatible elements and responsible for the LREE enrichment.

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산화공정을 통해 제작 된 전이금속산화물 박막의 저항변화 특성 연구

  • Seong, Yong-Heon;Go, Dae-Hong;Kim, Sang-Yeon;Do, Gi-Hun;Seo, Dong-Chan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.30.1-30.1
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    • 2009
  • 정보화가 급속히 진전됨에 따라 보다 많은 양의 정보를 전송, 처리, 저장하게 되면서 이를 위해 대용량, 고속, 비휘발성의 특징을 갖는 차세대 메모리의 개발이 절실히 요구되고있다. 이 중 저항 변화 메모리(ReRAM)는 일반적으로 TiO2, Al2O3, NiO2, HfO2, ZrO2 등의 전이금속산화물을 이용한 MIM 구조로서 적당한 전기 신호를 가하면 저항이 높아서 전도되지 않는 상태(Offstate)에서 저항이 낮아져 전도가 가능한 상태(On state)로 바뀌는 메모리 특성을가진다. ReRAM은 비휘발성 메모리이며 종래의 비휘발성 기억소자인 Flash memory 보다 access time 이105 배 이상 빠르고, 5V 이하의 낮은 전압에서도 동작이 가능하다. 또한 구조가 간단하여 공정 단순화가 가능하고 소자의 집적화도 쉽다는 점 등 많은 장점들이 있어서 Flash memory를 대체할 수 있는 유력한 후보로 여겨지고 있다. 본연구에서는 DC-magnetron Sputtering 방법으로 전이금속 박막을 증착하고, Dry furnace로 산화시켜 전이금속산화물 박막을 제작한 후 저항변화 특성을 연구하였다. 두 개의 전이금속산화물 박막을 dual-layer로 형성시켜 저항변화특성을 관찰하였으며 또한, 전이금속산화물 박막의 조성을 달리 하여 저항변화를 관찰 하였다. 전이금속산화물 박막의 전기적 특성을 알아보기 위해 Si(100) wafer 위에 Pt를 이용 MIM 형태로 capacitor 시편을 제작 하여, probe station으로 I-V 측정을 하였고 조성 및 표면 분석을 위해서는 AES와 AFM을, 미세구조를 분석을 위해서는 TEM과 SEM 을 사용하였다.

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In Situ Spectroscopy in Condensed Matter Physics

  • Noh, Tae Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.92-92
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    • 2014
  • Recently, many state-of-art spectroscopy techniques are used to unravel the mysteries of condensed matters. And numerous heterostructures have provided a new avenue to search for new emergent phenomena. Especially, near the interface, various forms of symmetry-breaking can appear, which induces many novel phenomena. Although these intriguing phenomena can be emerged at the interface, by using conventional measurement techniques, the experimental investigations have been limited due to the buried nature of interface. One of the ways to overcome this limitation is in situ investigation of the layer-by-layer evolution of the electronic structure with increasing of the thickness. Namely, with very thin layer, we can measure the electronic structure strongly affected by the interface effect, but with thick layer, the bulk property becomes strong. Angle-resolved photoemission spectroscopy (ARPES) is powerful tool to directly obtain electronic structure, and it is very surface sensitive. Thus, the layer-by-layer evolution of the electronic structure in oxide heterostructure can be investigated by using in situ ARPES. LaNiO3 (LNO) heterostructures have recently attracted much attention due to theoretical predictions for many intriguing quantum phenomena. The theories suggest that, by tuning external parameters such as misfit strain and dimensionality in LNO heterostructure, the latent orders, which is absent in bulk, including charge disproportionation, spin-density-wave order and Mott insulator, could be emerged in LNO heterostructure. Here, we performed in situ ARPES studies on LNO films with varying the misfit strain and thickness. (1) By using LaAlO3 (-1.3%), NdGaO3 (+0.3%), and SrTiO3 (+1.7%) substrates, we could obtain LNO films under compressive strain, nearly strain-free, and tensile strain, respectively. As strain state changes from compressive to tensile, the Ni eg bands are rearranged and cross the Fermi level, which induces a change of Fermi surface (FS) topology. Additionally, two different FS superstructures are observed depending on strain states, which are attributed to signatures of latent charge and spin orderings in LNO films. (2) We also deposited LNO ultrathin films under tensile strain with thickness between 1 and 10 unit-cells. We found that the Fermi surface nesting effect becomes strong in two-dimensions and significantly enhances spin-density-wave order. The further details are discussed more in presentation. This work was collaborated with Hyang Keun Yoo, Seung Ill Hyun, Eli Rotenberg, Ji Hoon Shim, Young Jun Chang and Hyeong-Do Kim.

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Catalytic Oxidation of Methane Using the Manganese Catalysts (망간촉매를 이용한 메탄의 산화반응)

  • Peng, Meimei;Lee, Joo-Bo;Lee, Sung-Yong;Jeong, Ui-Min;Han, Seung-Dong;Jang, Hyun-Tae
    • Proceedings of the KAIS Fall Conference
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    • 2010.05b
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    • pp.1233-1236
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    • 2010
  • 본 연구에서는 메탄을 물질로 산화실험을 수행하였다. 메탄의 발화온도가 탄화수소 중에 가장 높으며, 대부분의 전이금속촉매 활성온도가 가장 높게 나타나는 물질이므로 메탄의 연소가 일어날 경우 대부분의 탄화수소류는 연소가 일어날 수 있으므로 메탄의 산화반응을 연구하였다. 메탄의 산화를 위한 전이금속 촉매중 망간을 산화물형태로 $Al_2O_3$, $TiO_2$에 담지하여 메탄에 대한 활성능을 측정하였으며, 조촉매로 금속산화물을 이용하여 활성능의 변화를 연구하였다. 또한 자연에 존재하는 천연망간광석과 금속산화물을 담지하여 최적의 메탄에 대한 활성능을 지닌 촉매를 선별하였다. 조촉매로는 Ce, Sn, Ni, Co, Mo 등을 이용하였다. 또한 본 연구에서는 촉매 제조는 과잉용액함침법을 사용하여 담지체에 촉매물질을 분산하였으며, 온도와 유량에 대한 각 조성 촉매의 활성능을 측정하여 활성화에너지 및 $T_{50}$, $T_{90}$을 도출하였다.

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