• 제목/요약/키워드: Ni variation

검색결과 407건 처리시간 0.021초

PNW-PMN-PZT 압전 세라믹의 저온소결을 위한 프리트 첨가 압전 특성평가 (Piezoelectric property variation with respect to the frit addition for lower temperature sintering in PNW-PMN-PZT ceramic system)

  • 류성림;권순용;우덕현;안상기;정지현;엄주철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.191-191
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    • 2008
  • 강유전성 세라믹스 재료로써는 PZT계열의 세라믹재료가 널리 쓰이고 있다. 이는 우수한 유전 및 압전특성을 가지고 있으나, PbO을 다량 함유하고 있어 $1000^{\circ}C$이상에서 PbO가 급격하게 휘발되는 성질 때문에 조성의 변동이 생겨 재현성이 어려우며 이를 방지하기 위하여 PbO를 과잉 첨가시키기 때문에 PbO휘발로 인한 강한 독성이 인체에 유해하고, 비환경 친화적인 물질로 최근에는 환경문제가 대두됨에 따라 대체 또는 보완 할 수 있는 방안에 검토되고 있다. 본 연구는 그 해결책의 한 방안으로 압전특성이 우수한 $(Pb_{0.94}Sr_{0.06})[(Ni_{1/2}W_{1/2})_{0.02}(Mn_{1/3}Nb_{2/3})_{0.07}(Zr_{0.51}Ti_{0.49})_{0.91}]O_3$계 조성을 설계하고 Glass frit(0~1.1 wt%)를 소량 첨가하여 액상 소결 특성을 부여하고 $1000^{\circ}C$ 이하의 저온에서 소결하여 유전 및 압전 특성을 평가하였다. 실험방법은 일반적인 세라믹스 제조공정으로 24시간 ball milling하고 $850^{\circ}C$에서 2시간 하소 후 Glass frit를 소결조제로 소랑 첨가하여 $1000^{\circ}C$ 이하 온도에서 소결을 진행하여 각 소결온도에 따른 유전 및 압전 특성을 평가하였다. 최종 소결된 시편의 밀도와 수축율을 분석하여 최적의 소결온도를 확립하였으며 XRD분석을 통해 perovskite구조를 확인하고 미세구조확인을 위해 SEM으로 관찰하였다. 압전 특성을 평가하였다.

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한국 연안산 어류의 미네랄 함량 및 영양평가 (Mineral Content and Nutritional Evaluation of Fishes from the Korean Coast)

  • 목종수;이두석;윤호동
    • 한국수산과학회지
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    • 제41권5호
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    • pp.315-323
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    • 2008
  • To measure the mineral content of fishes, we collected 177 individuals from 53 fish species from the east (Pohang), west (Gunsan), and south (Tongyeong) coasts of Korea. The mean content of the macro mineral in a 100 g sample taken from the edible portion of each fish was (in descending order): P(207.4 mg), K(169.7 mg), Na(101.6 mg), Ca(44.4 mg), and Mg(30.4 mg). In comparison, the mean content of micro mineral in the fishes was (in descending order): Zn ($8.98{\mu}g/g$), Fe ($5.03{\mu}g/g$), Cu ($0.76{\mu}g/g$), Mn ($0.43{\mu}g/g$), and Ni ($0.08{\mu}g/g$). We could not observe clear regional variation in the mineral content of fish species. With regard to minerals considered essential for humans, the amount of Ca per sample (100 g) was the highest in the Scyliorhinus torazame (465.4 mg), and than followed by Ammodytes personatus (338.0 mg), Dasyatis akajei (267.4 mg), Raja kenojei (248.1 mg), Conger myriaster (174.1 mg), Clupanodon punctatus (86.8 mg), Muraenesox cinereus (81.2 mg), and Engraulis japonica (70.4 mg). The daily average intake of the mineral through the fishes consisted of P (100.6 mg), K (82.3 mg), Na (49.3 mg), Mg (14.8 mg), Zn (0.44 mg), Fe (0.24 mg), Cu (0.04 mg) and Mn (0.02 mg). The respective intakes of macro mineral (P, Mg, Na, Ca, K) from the fishes were about 14.4, 4.2, 3.3, 3.1 and 1.8% of the dietary reference intakes for Koreans (KDRIs) set by the Korean Nutrition Society. In comparison, the respective intakes of micro mineral (Cu, Zn, Fe, Mn) from the fishes were about 4.6, 4.4, 2.4, and 0.6% of the KDRIs.

보수용접 모사 방법에 따른 원자로 배관 이종금속 맞대기 용접부 응력 분포 (Stress Distribution in the Dissimilar Metal Butt Weld of Nuclear Reactor Piping due to the Simulation Technique for the Repair Welding)

  • 이휘승;허남수;김진수;이진호
    • 대한기계학회논문집A
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    • 제37권5호
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    • pp.649-655
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    • 2013
  • 이종금속용접부에 대한 실제 용접 공정 중 용접부에서 결함이 발견되면 이를 제거하고 보수용접이 수행된다. 일반적으로 보수용접을 수행하면 용접부에서 인장 잔류응력이 크게 증가될 수 있는 것으로 알려져 있다. 따라서 Alloy 82/182를 사용하여 보수용접이 수행된 이종금속용접부의 일차수 응력부식 균열 현상을 평가하기 위해서는 보수용접에 의한 용접부의 응력 변화를 정확하게 평가해야 한다. 본 논문에서는 비선형 유한요소해석을 수행하여 보수용접에 의한 원자력 이종금속 맞대기 용접부의 응력 분포를 평가하였다. 특히 보수용접 공정 모사를 위한 여러 유한요소 해석방법이 이종금속용접부의 응력분포에 미치는 영향을 평가하였다.

월악산화강암(月岳山花崗岩)의 접촉변성(接觸變成)에 관(關)하여 (Study on The Contact Metamorphism of Weolagsan Granite)

  • 이대성;강준남
    • 자원환경지질
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    • 제11권4호
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    • pp.169-182
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    • 1978
  • The Weolagsan area consists of four units; (1) Low grade meta-sediments of the upper members of Ogcheon age unknown group such as Changri (mainly black slate and phyllitic rock), Majeonri (mainly alternation of slate, limestone and chert) and Hwanggangri Formation (pebble bearing phyllitic sediments); (2) Samtaesan Formation of Chosun System of Ordovician; (3) So called meta-volcanics and (4) Weolagsan Granite and its associations which intruded above mentioned meta-sediments and meta-volcanics. This study was focused to know the Woelagsan granite and its metasomatic effects to the country rocks petrographically and petrochemically. According to the field survey, microscopic work and some chemical analysis, the granite is a "normal granite" based on the Streckeisen's classification and belongs to a mass of the Central-zone younger group in Ogcheon geosynclinal belt. The granite metasomatized the country rocks along its northern contact zone. Zone of calcareous and cherty rocks (Majeonri formation) was silicified partly and skarned locally at the contact with the granite. The chemical analysis of the zone show no difinite variations in contents of $SiO_2$ and CaO with the distance from the granite. It seems to be indicated that the silicification of this part was not so metasomatized by the granite body, but thermally affected as much as to be partially remelted in the specific parts of the formations. Meta-volcanic rock zone was slightly chloritized near contact with the granite. Limestone of Samtaesan Formation was silicified and skarned along the contact zone by the granite body. The chemical analysis of the zone show some noticiable changes in compositions of $SiO_2$ and CaO with distance from the granite boundary. It can be imagined that the silicification of this zone was metasomatically originated by Woelagsan Granite. According to chemical analysis on several trace elements, the ratio of Zn/Cr and Ni/Cr are relatively higher than that of Cu/Cr in the above mentioned silicified zones. Generally the variation of these metal elements in the zones tend to be regular with distance from the granite body.

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경험적 모드분해법을 이용한 기상인자와 우리나라 강수 및 기온의 상관관계 분석 : II. 상관관계 분석 (Correlation analysis between climate indices and Korean precipitation and temperature using empirical mode decomposition : II. Correlation analysis)

  • 안시권;최원영;신홍준;허준행
    • 한국수자원학회논문집
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    • 제49권3호
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    • pp.207-215
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    • 2016
  • 본 연구에서는 우리나라 강수 및 기온과 다양한 기상인자와의 교차상관관계 분석을 통해 대규모 기후변동이 우리나라에 어떠한 영향을 주는지를 분석하였다. 강수 및 기온자료의 경우 앞선 연구인 "경험적 모드분해법을 이용한 기상인자와 우리나라 강수 및 기온의 상관관계 분석 : I. 자료의 분해 및 특성분석"의 연구결과를 통해 주기성, 경향성에 따라 분해한 강수 및 기온자료의 내재모드함수를 사용하여, 자료의 변동이 심하고 잡음이 포함된 원 자료를 통한 상관관계 분석보다 좀 더 명확한 상관계수를 계산하였다. 이렇게 분해된 기상자료와 기상인자간의 교차상관관계 분석을 통해 그 시간차와 상관계수를 계산하여, 주기성과 경향성 측면에서 어떠한 상관관계가 있는지를 분석하였다. 그 결과 주기성 측면에서 엘니뇨현상에 의한 기후변동이 우리나라 기상현상과 밀접한 관련이 있으며, 경향성 측면에서 기후변화로 인한 해수면 온도 증가추세가 우리나라 기상현상과 밀접한 연관이 있음을 알 수 있었다.

Determination of Macronutrients, Micronutrients and Heavy Metals Present in Spilanthes acmella Hutch and Dalz: Possible Health Effects

  • Singh, Salam Bhopen;Singh, Kamal;Butola, Sandeep Singh;Rawat, Suraj;Arunachalam, Kusum
    • Natural Product Sciences
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    • 제26권1호
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    • pp.50-58
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    • 2020
  • The study was conducted for quantitive determination of macronutrients, micronutrients and heavy metals present in Spilanthes acmella Hutch and Dalz, a traditionally used important medicinal plant. The results illustrated the presence of substantial amounts of essential nutrient elements in different parts of the plant. K and Mg were detected in the range between 36.35 ± 1.01 to 67.78 ± 1.33 g/kg and 2.17 ± 0.13 to 7.02 ± 0.84 g/kg of DWS respectively. While the essential micronutrients Fe, Na, Mn, Zn and Cu were detected in the range between 62.62 ± 12.72 to 856.95 ± 76.61 mg/kg, 365.47 ± 23.84 to 633.03 ± 38.12 mg/kg, 51.66 ± 7.77 to 186.33 ± 13.92 mg/kg, 41.87 ± 2.85 to 53.89 ± 3.79 mg/kg and 18.49 ± 2.07 to 48.71 ± 4.89 mg/kg of DWS respectively. Besides, heavy metals (Cd, Ni and Pb) detected in some of the plant samples were beyond the maximum permissible limit (MPL) of FAO/WHO for herbal medicines. The concentrations of the essential nutrient elements except zinc were significantly different in different parts of the plant (p < 0.001). Further variation in the concentrations of the elements in the plant was observed with respect to seasonal changes and geographical conditions. Nevertheless the findings corroborate ethnomedicinal significance of the plant and signify the possibilibity of utilizing its standardized products for preparation of food supplements as well as multidimensional therapeutic herbal medicines.

Geochemistry of Pb in Surface Sediments of the Yellow Sea: Contents and Speciation

  • Kim, Kyung-Tae;Lim, Chae-Reol;Cho, Yeong-Gil;Hong, Gi-Hoon;Lim, Suk-Hyun;Yang, Dong-Beom;Choi, Man-Sik
    • Journal of the korean society of oceanography
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    • 제35권4호
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    • pp.179-191
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    • 2000
  • Both acid-leached and residual Pb in surface sediments of the Yellow Sea are analyzed in order to explain the spatial distribution of Pb contents and to determine a major controlling factor of its geographical distribution. Leached and residual Pb contents in surface sediments, which may have a different origin, show mirrored geographical distribution. Sediments with high residual Pb ( ${\sim}$20 ${\mu}$g/g; northeastern sand) contain low leached Pb (6-8 ${\mu}$g/g) while sediments with high leached Pb ( ${\sim}$20 ${\mu}$g/g; central mud) contain low residual Pb. As a result, total Pb shows little variation spatially. The mirrored distribution of both species also leads the grain-size dependence of Pb contents to be unclear although the grain-size dependence of other trace metals (Cr, Co, Ni etc.) has been well reported in this shelf. High leached Pb contents (>15 ${\mu}$g/g) were also observed in sediments off the Changjiang River mouth and off the Kyunggi Bay where they can be interpreted as the results of diagenetic accumulation and anthropogenic pollution, respectively. Residual Pb enriched in sands of the northeastern area might be from K-feldspar, which in turn allows the suggestion that northeastern sands may have originated from coastal erosion of granitic landmass or directly from nearby rivers.

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KODOS-89 지역 망간단괴의 성인과 분포 (Origin of Manganese Nodules and Their Distribution in the KODOS-89 Area, Northeastern Equatorial Pacific.)

  • 정회수;정갑식
    • 한국해양학회지
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    • 제25권4호
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    • pp.189-204
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    • 1990
  • 태평양 클라리온-클리퍼톤 균열대 서부의 KODOS(Korea Deep Ocean Study)지역에 분포하는 망간단괴의 성인과 분포, 그리고 분포 원인을 규명하기 위하여 망간단괴와 퇴적물을 채취하여 화학 및 광물학적 분석을 하였다. 이 지역의 망간단괴는 Mn/Fe 비 가 크고 구리, 니켈, 아연, 마그네슘, 토도로카이트 함량이 높으며 표면조직이 거친 속성기원의 망간단괴(S-형 망간단괴)와 철, 코발트, 버나다이트 함량이 높고 표면조직 이 매끈한 수성기원의 망간단괴(S-형 망간단괴) 그리고 화학 및 광물조성과 표면조직 이 두 기원의 중간성격을 띄는 망간단괴(R-S-형 망간단괴)로 구분된다. 성인 및 부존 밀도 등의 특성에 따라 KODOS-89 지역은 크게 4지역으로 구분된다. 즉, 부존밀도가 10 kg/m$^2$이하이고 수성기원의 망간단괴가 분포하는 최북단지역, 부존밀도가 1 kg/m$^2$ 내 외이고 속성기원의 망간단괴가 분포하는 남부 지역, 그리고 부존밀도가 10 kg/m$^2$ 이 상으로 높고 수성기원의 망간단괴가 분포하는 해저산지역으로 구분된다. 이러한 망간 단괴의 분포특성은 주로 위도에 따른 수층의 생산성 및 해저지형의 차이에 의해 기인 되었다고 생각된다.

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Experimental Study of Adaptive Sliding Mode Control for Vibration of a Flexible Rectangular Plate

  • Yang, Jingyu;Liu, Zhiqi;Cui, Xuanming;Qu, Shiying;Wang, Chu;Lanwei, Zhou;Chen, Guoping
    • International Journal of Aeronautical and Space Sciences
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    • 제16권1호
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    • pp.28-40
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    • 2015
  • This paper aims to address the intelligent active vibration control problem of a flexible rectangular plate vibration involving parameter variation and external disturbance. An adaptive sliding mode (ASM) MIMO control strategy and smart piezoelectric materials are proposed as a solution, where the controller design can deal with problems of an external disturbance and parametric uncertainty in system. Compared with the current 'classical' control design, the proposed ASM MIMO control strategy design has two advantages. First, unlike existing classical control algorithms, where only low intelligence of the vibration control system is achieved, this paper shows that high intelligent of the vibration control system can be realized by the ASM MIMO control strategy and smart piezoelectric materials. Second, the system performance is improved due to two additional terms obtained in the active vibration control system. Detailed design principle and rigorous stability analysis are provided. Finally, experiments and simulations were used to verify the effectiveness of the proposed strategy using a hardware prototype based on NI instruments, a MATLAB/SIMULINK platform, and smart piezoelectric materials.

수원지역 강하분진의 화학조성및 공간분포 분석 (Chemical Compositions and Spatial Distribution Analysis of Fall-Out Particles in Suwon Area)

  • 김현섭;이태정;김동술
    • 한국대기환경학회지
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    • 제15권1호
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    • pp.23-32
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    • 1999
  • Deposition is one of the important removal mechanisms for the ambient aerosol, and it also leads to adverse environmental and economic impacts. The purpose of this study was to investigate chemical compositions and spatial distributions of fall-out aerosols. A total number of 340 samples were collected at 35 sampling sites in Suwon area from January to November, 1996. Twelve inorganic elements (Al, Ba, Cd, Cr, K, Pb, Sb, Zn, Cu, Fe, Ni, and V) and eight ionic components ($F^-$, Cl, $NO_3^-$, $SO_4^{2-}$, $Na^+$, $NH_4^+$, $Mg^{2+}$, and $Ca^{2+}$) were analyzed by AAS and IC, respectively. The monthly variation showed that the flux of fall-out particles was increased in the spring season(March, April, and May) and decreased from August to October. Arithmetic mean flux of fall-out particles was 176.8 kg/$ extrm{km}^2$/day during the study period. The fluxes of each chemical species were $SO_4^{2-}$ 12.414, $Ca^{2+}$ 7.369, $NO_3^-$ 5.812, $Cl^-$ 3.566, $NH_4^+$ 3.176, Fe 3.107 kg/$\textrm{km}^2$/day, and so on. By using a kriging analysis, spatial distribution pattern of those fluxes was intensively studied. Total fluxes estimated in Suwon city were 8424.72t/y of fall-out particles, 519.27t/y of $SO_4^{2-}$, 336.79t/y of $Ca^{2+}$,267.34 t/y of $NO_3^+$, 155.36t/y of $Cl^-$, 147.79t/y of Fe.

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