• Title/Summary/Keyword: Ni variation

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Effect of Excess PbO Addition on Sintering and Piezoelectric Characteristics in Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3 System (PbO 과잉량이 Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3계의 소결 및 압전특성에 미치는 영향)

  • 전구락;김정주;조상희;김도연
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.568-574
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    • 1989
  • Effect of PbO addition on sintering and piezoelectric properties at 0.45Pb(Ni1/3Nb2/3)O3-0.40PbTiO3-0.15PbZrO3 composition which is tetragonal phase was investigated. In this composition, Porosity and dielectric constant were increased with excess PbO addition, but Kp and d31 was not changed. These variation of physical properties could be interpreted as composition change of solid grains from tetragonal to MPB region due to amount of PbO-rich liquid changing.

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Effects of pH variation on thermal stability of electrodeposited Ni-$TiO_2$ composite (Ni-$TiO_2$ 전기도금층의 pH에 따른 열적안정성 연구)

  • Kim, Myeong-Jin;Kim, Jeong-Su;Kim, Dong-Jin;Kim, Hong-Pyo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.133-134
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    • 2011
  • 전기도금을 이용하여 $TiO_2$ 입자들을 니켈 도금층에 넣은 Ni-$TiO_2$ 복합체를 만들때 pH, 전류형태에 따른 열적안정성에 대한 영향을 평가하였다. pH 범위는 1, 2, 3.4 였으며, 전류형태는 직류, duty cycle 50%의 펄스를 사용하였다. pH가 낮으면 도금속도는 낮아졌으나 $TiO_2$의 부피분율은 증가하였고, 펄스를 이용하면 도금속도는 증가하였으나 $TiO_2$ 부피분율은 감소하였다. 경도는 pH가 낮으면 상온에서는 낮았으나 고온에서는 상대적으로 경도값이 높았다.

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Structural and electrical properties of the NiCr thin film resistors deposited at various temperatures on $SiO_2$/Si substrate

  • Phuong, Nguyen Mai;Cuong, Nguyen Duy;Kim, Dong-Jin;Kang, Byoung-Don;Kim, Chang-Soo;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.337-338
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    • 2006
  • The 200 nm thick-NiCr films grew on $SiO_2$/Si substrates at various deposition temperatures by a dc magnetron co-sputtering technique were characterized for the variation of film texture. The resistivity of the films decreases with increasing deposition temperature and temperature coefficient of electrical resistance (TCR) varies from negative value to a positive one with increasing deposition temperature. The NiCr films deposited at $300^{\circ}C$ exhibit 4 ppm/K being near zero TCR, resulting in TCR suitable for $\pi$-type attenuator applications.

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The Variation of Mechanical Properties by Thermomechanical Treatment in Fe-30%Ni-0.1 %C Alloy (가공열처리에 의한 Fe-30% Ni-0.1%C 합금의 기계적성질 변화)

  • Ahn, H.K.;Kim, H.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.2
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    • pp.88-95
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    • 1994
  • In order to compare mechanical properties of ausformed martensite with those of marformed martemsite in Fe-30%Ni-0.1%C alloy and to investigate their strengthening mechanisms, ausformed martensite and marformed martensite were prepared by ausforming treatment and marforming treatment respectively. The microstructures were observed and the quantities of retained austenite, hardness, yield strength, ultimate tensile strength and elongation were examined. The strength of ausformed martensite was mainly increased because of the lattice defects inherited from austenite. The ductility of ausformed martensite was constant at the rate of 7-8% by ductile matrix formation of the retained austenite in spite of the increase in strength. The strength of marformed martensite was increased by the increment in dislocation density, the crossing of transformation twin with deformation twin and the mutual crossing of deformation twin. The ductility of mar formed martensite was slightly lower than that of ausformed martensite, but the strength of mar formed martensite was prominently higher.

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Complexes of Polyvalent Metal Ions (Ⅵ). Complexes of Nickel and Cadmium with Dibasic Organic Acids in Aqueous, Ethanol-Water and Acetone-Water Solutions$^*$

  • Sang-Up Choi;Joon-Kil Kang;Young-Il Pae
    • Bulletin of the Korean Chemical Society
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    • v.1 no.2
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    • pp.49-54
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    • 1980
  • Solutions of $Ni^{2+}$ and $Cd^{2+}$ were mixed with the solutions of various dibasic organic acids in the presence of cation exchange resin at room temperature. The distribution ratios of the metal ions between resin and solution were measured, using radioactive metal ions as tracer. From the observed variation of the distribution ratios with acid anion concentrations, it was concluded that $Ni^{2+}$ and $Cd^{2+}$ formed one-to-one complexes with succinate, malonate, o-phthalate and tartarate ions in aqueous, 20 % ethanol-water and 20 % acetone-water solutions. The results of the present study indicated that the relative stabilities of the complexes in solution increased generally in the order : $Ni^{2+}$ < $Cd^{2+}$ complexes. Succinate < malonate < o-phthalate < tartarate complexes. Aqueous < mixed solvent systems.

Sequential Copolypeptides (Ⅲ). Synthesis and Characterization of Poly ($\gamma$-benzyl-L-glutamyl-$\gamma$-benzyl-L-glutamyl-glycine)

  • Choi, Sang-Up;Kang, Joon-Kil
    • Bulletin of the Korean Chemical Society
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    • v.1 no.3
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    • pp.78-82
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    • 1980
  • Solutions of $Cd^{2+}$, $Co^{2+}$ and $Ni^{2+}$ were mixed with the solutions of hydroxycarboxylic acids such as salicylic, lactic and mandelic acids in the presence of cation exchange resin at room temperature. The distribution ratios of the metal ions between resin and solution were measured, using radioactive metal ions as tracer. From the observed variation of the distribution ratios with the acid anion concentrations, it was concluded that $Cd^{2+}$, $Co^{2+}$ and $Ni^{2+}$ formed the one-to-one complexes with salicylate, lactate and mandelate ions in aqueous, 20 % ethanol-water and 20 % acetone-water solutions. The results of the present study indicated that the relative stabilities of the metal-acid complexes in solution increased in the order: $Cd^{2+}$ <$Co^{2+}$ <$Ni^{2+}$ complexes. Salicylate

Nickel Substitution Effects on Nano-sized Co, Mn and MnZn Ferrites Synthesized by Sol-gel Method

  • Choi, Won-Ok;Kwon, Woo Hyun;Chae, Kwang Pyo;Lee, Young Bae
    • Journal of Magnetics
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    • v.21 no.1
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    • pp.40-45
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    • 2016
  • Nickel substituted nano-sized ferrite powders, $Co_{1-x}Ni_xFe_2O_4$, $Mn_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ($0.0{\leq}x{\leq}0.2$), were fabricated using a sol-gel method, and their crystallographic and magnetic properties were subsequently compared. The lattice constants decreased as quantity of nickel substitution increased, while the particle size decreased in $Co_{1-x}Ni_xFe_2O_4$ ferrite but increased for the $Mn_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites. For the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.2$) ferrite powders, the $M{\ddot{o}}ssbauer$ spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. However, the $M{\ddot{o}}ssbauer$ spectrum of $Mn_{0.8}Zn_{0.1}Ni_{0.1}Fe_2O_4$ consisted of two Zeeman sextets and one single quadrupole doublet due to the ferrimagnetic and paramagnetic behavior. The area ratio of the $M{\ddot{o}}ssbauer$ spectra could be used to determine the cation distribution equation, and we also explain the variation in the $M{\ddot{o}}ssbauer$ parameters by using this cation distribution equation, the superexchange interaction and the particle size. The saturation magnetization decreased in the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites but increased in the $Mn_{1-x}Ni_xFe_2O_4$ ferrite with nickel substitution. The coercivity decreased in the $Co_{1-x}Ni_xFe_2O_4$ and $Mn_{1-2x}Zn_xNi_xFe_2O_4$ ferrites but increased in the $Mn_{1-x}Ni_xFe_2O_4$ ferrite with nickel substitution. These variations could thus be explained by using the site distribution equations, particle sizes and spin magnetic moments of the substituted ions.

Current Collector Effects on High Temperature Electrolysis by NI-YSZ Cermet Supported Solid Oxide Cells (집전체에 따른 NI-YSZ Cermet 기반의 가역적 고체산화물 연료전지를 이용한 고온 수증기 전기분해 특성)

  • Shin, Eui-Chol;Ahn, Pyung-An;Seo, Hyun-Ho;Lee, Jong-Sook;Yu, Ji-Haeng;Woo, Sang-Kuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.533-539
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    • 2010
  • Ni-YSZ supported button cells were prepared by spray-coating YSZ and screen-printing YSZ-LSM powder as an electrolyte and oxygen electrode on Ni-YSZ cermet disks. In order to identify the polarization loss mechanism in high temperature electrolysis current-voltage characteristics coupled with electrochemical impedance spectroscopy were investigated as a function of temperature, current load, and the humidity. The effects of the different current collectors of platinum and silver for oxygen electrodes were compared. With Ag current collector two polarization losses were distinguished. The high frequency component was attributed to the Ni-YSZ cermet which was less susceptible to temperature variation but increasing in loss with humidity. The lower frequency component was attributed to the LSM electrode. Platinum current collector led to a much lower polarization loss.

Plant Uptake of Heavy Metals in Andong Serpentine Soil

  • Kim, Jeong-Myeong;Yang, Keum-Chul;Choi, Sang-Kyoo;Yeon, Myung-Hun;Shin, Jin-Ho;Shim, Jae-Kuk
    • Korean Journal of Environmental Biology
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    • v.24 no.4
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    • pp.408-415
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    • 2006
  • Serpentines soil have high values of magnesium and low values of calcium, and are usually deficient in N and P, but rich in iron, Ni, silicates. We investigated serpentine soil properties and measured the content of nutrient elements and heavy metals in shoots and root of plant species which were in common at serpentine and non-serpentine areas in Andong, Korea. The soils showed higher pH value above 6.9. The contents of Ni, Cr, Fe and Mg of serpentine soils exhibited 77, 27, 5.5 and 12.5 times more than in non-serpentine soils, respectively. The content of Na was almost same but K was two times higher in non-serpentine soil, compared with serpentine soil. The contents of nutrient element such as K, Ca, Na and P in serpentine plants did not show conspicuous differences with non-serpentine plants. On the other hand, the concentrations of Ni, Cr, Fe, Mg and Mg/Ca were very high in plant on serpentine area. The all plant species collected at the serpentine site were bodenvag plants, which are not restricted to a specific type of substrate. By the plant species and parts of plant tissues, the absorption levels and patterns showed high variation and were species-specific. Carex lanceolata, Lysimachia clethroides and Cynanchum paniculatum contained much chromium and Eupatorium chinense and C. paniculatum exhibited high contents of Ni. In leaf tissue, C. lanceolata, Rubus parvifolius, Festuca ovina, Quercus serrata, and L. clethroides took comparatively large amount of Cr in serpentine area. E. chinense contained large amount of Ni, Cr and Fe in a leaf tissue. The stem of Galium verum, Juniperus rigida included high amount of Cr, Ni and Fe. And C. paniculatum absorbed large amount of Ni and Cr in the stem.

Effect of El Niño/Na Niña on Mesozooplankton Biomass in the Northwestern Subtropical Pacific Warm Pool and the Northern East China Sea (엘니뇨/라니냐가 북서태평양 아열대 난수역과 북부동중국해의 중형동물플랑크톤 생체량에 미치는 영향)

  • Kang, Hyung-Ku;Shin, Chang-Woong;Jeon, Dongchull
    • Ocean and Polar Research
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    • v.37 no.3
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    • pp.189-200
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    • 2015
  • Mesozooplankton biomass including total biomass and size-fractionated biomass and the abundance of major taxonomic groups of copepods were studied in the Northwestern Subtropical Pacific Warm Pool (NSPWP) and the Northern East China Sea (NECS) from 2006 to 2014. Mesozooplankton biomass ranged from 0.69 to $3.08mgC/m^3$ (mean $1.12mgC/m^3$) in the NSPWP and from 10.60 to $69.10mgC/m^3$ (mean $30.33mgC/m^3$) in the NECS with higher values in spring than fall. Percent composition in the biomass of each size group of mesozooplankton varied interannually both in the NSPWP and in the NECS. The smallest size group (0.2~0.5 mm) contributed the least to total biomass in both regions, but significantly higher in the NSPWP than in the NECS. The percent composition in abundance of copepod taxonomic groups (i.e. Calanoida, Cyclopoida, and Poecilostomatoida) also fluctuated interannually. Mean composition of calanoid copepods was higher in the NECS than in the NSPWP, but the opposite pattern was observed for poecilostomatoid copepods. Mesozooplankton biomass both in the NSPWP and in the NECS was negatively correlated with Oceanic $Ni{\tilde{n}}o$ Index (ONI), indicating declines in biomass during El $Ni{\tilde{n}}o$ periods and vice versa during Na $Ni{\tilde{n}}a$ period. The effect of El $Ni{\tilde{n}}o$ on variation of mesozooplankton biomass was more prominent in the NSPWP than in the NECS. These results suggest that mesozooplankton biomass both in the NSPWP and in the NECS responded to El $Ni{\tilde{n}}o$ events, although the biological process that explain the reduced mesozooplankton biomass might be different in both regions.