• Title/Summary/Keyword: Ni loss

Search Result 295, Processing Time 0.029 seconds

Composite Coating of Nickel-Boron Nitride-Phosphours and Nickel-Boron Nitride-Boron Ternary System on Aluminum (알루미늄에 니켈-질화붕소-인과 니켈-질화붕소-붕소의 3원계 복합도금)

  • Kuak Woo-Sup;Yoon, Byung-Ha;Kim, Dai-Ryong
    • Journal of the Korean institute of surface engineering
    • /
    • v.19 no.3
    • /
    • pp.83-91
    • /
    • 1986
  • Codeposited of boron nitride(BN) particle dispersed into electroless nickel-phosphours (Ni-P) and nickel-boron(Ni-B) platings were studied for the purpose of developing the wear resistance and lubricity. BN can be codeposited from electroless nickel plating bath with $NaH_2PO_2$ and $NaBH_4$ as the reducing agents. Most dispersolids were distributed uniformly in the Ni-P and Ni-B matrix. Abrasion loss decreased with increasing amount of codeposits and reached a constant value 2.4 percent by volume percent of BN particle. The wear resistance and the friction coefficient of the heat treated BN composite coatings were improved about three times than that of as-coatings. The BN composite coatings were more wear resistance than hard chromium. Ni-B-BN composite coatings showed lower wear resistance and friction coefficient than Ni-P-BN. The BN content of the deposite was found to be 2.4 v/o for these optium conditions.

  • PDF

Studies on Corrosion inhibition of 90Cu10NiFe Alloy by Eco-Friendly Organic Compound ; Sodium Diethyl Dithio Carbamate(NaDDC) (친환경 유기화합물(NaDDC)에 의한 90Cu10NiFe합금의 부식억제 연구)

  • Jung, Gil-Bong;Kim, Doo-Han;Lee, Sung-Do
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.14 no.6
    • /
    • pp.1018-1025
    • /
    • 2011
  • The improved properties of corrosion for 90Cu10NiFe alloy in natural seawater were explained by sodium diethyl dithio carbamate(NaDDC), namely organic compound, which is reagent for heavy metal extractions of waste water. The efficiency of NaDDC as corrosion inhibitor for 90Cu10NiFe alloy has been investigated in seawater after immersion in various concentrations of NaDDC solutions for 12~36hrs at pH 8.2 by weight loss test and electrochemical techniques including potentiodynamic polarization and SEM-EDS measurements. The results showed that the corrosion resistance of 90Cu10NiFe alloy improves with the increasing concentration of NaDDC but it did not improves with increasing time any more, so the highest inhibition efficiency was 93% at 100mg/L, 36hrs. The results obtained from weight losses and corrosion rates in polarization curve measurements were in good agreement. Therefore, it showed that NaDDC is a good inhibitor for copper corrosion of 90Cu10NiFe alloy.

Effects of ta-C Coatings on Surface Characteristics of Dental Ni-Ti Files (치과용 Ni-Ti파일의 표면특성에 미치는 ta-C코팅효과)

  • Sun-Kyun Park;Han-Cheol Choe
    • Corrosion Science and Technology
    • /
    • v.22 no.5
    • /
    • pp.368-376
    • /
    • 2023
  • Dental Ni-Ti files must ensure stability and resistance to fatigue fracture. DLC and ta-C were coated to remove defects on the surface and ensure stability, and the surface characteristics were investigated. When coated with DLC, it was black, and in case of ta-C coating, it was blue-black. Scratches, which are defects caused by mechanical processing, were formed on the surface of the un-coated Ni-Ti file from the end of the file along the direction of processing, with the Pro-file appearing in the vertical direction and the K-file appearing in the file direction. Scratches were reduced on the coated surface, and the surface roughness was greatly reduced after coating compared to before coating. The un-coated Ni-Ti file had the lowest hardness, the DLC-coated file had the highest hardness, and ta-C showed relatively high hardness. The elastic modulus of the DLC coating film was high, and the ta-C elastic modulus was low. The adhesion of the DLC coating film tended to be higher than that of ta-C, and the wear loss amount of DLC coating of taC was lower. The corrosion potential of the ta-C coating increased significantly, and the corrosion current density decreased.

Estimating Unsteady Soil Loss due to Rainfall Impact according to Rim Fire at California

  • Choi, Hyun;Kim, Gihong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
    • /
    • v.35 no.4
    • /
    • pp.269-280
    • /
    • 2017
  • Recently, in the United States, there has been short-term intensive rainfall due to El Ni?o and Rania. The Rim Fire was a wildland fire that was started in a remote canyon in Stanislaus National Forest in California. This portion of the central Sierra Nevada spans Tuolumne and Mariposa counties. This study is about estimating unsteady soil loss due to rainfall impact according to Rim Fire at California. It implies that caution needs to be taken in selecting the grid size for estimating soil loss using numerical modeling approach. Soil loss increased in all duration times before Rim fire. But it increased until 7 days and reduced or kept stable after that. Based on the 2014 average rainfall 1388 mm/yr, soil loss was estimated to be 247,518 ton/ha/yr before Rim Fire, and 9,389,937 ton/ha/yr after that.

Physiological Factors Depressing Feed Intake and Saliva Secretion in Goats Fed on Dry Forage

  • Sunagawa, K.;Ooshiro, T.;Nakamura, N.;Ishii, Y.;Nagamine, I.;Shinjo, A
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.20 no.1
    • /
    • pp.60-69
    • /
    • 2007
  • Ruminants eating dry forage secrete large volumes of saliva which results in decreased plasma volume (hypovolemia) and the loss of $NaHCO_3$ from the blood. The present research investigated whether or not hypovolemia and the loss of $NaHCO_3$ from the blood in goats brought about by dry forage feeding actually depresses feed intake and saliva secretion, respectively. The present experiment consisted of three treatments (NI, ASI, MI). In the control treatment (NI), a solution was not infused. In the ASI treatment, i.v. infusion of artificial parotid saliva was initiated 1 h before feeding and continued for the entire 2 h feeding period. In the MI treatment, iso-osmotic mannitol solution was infused. The NI treatment showed that hematocrit and plasma total protein concentration were increased due to decreased circulating plasma volume brought about by feeding. In the ASI treatment, the fluid and $NaHCO_3$ that were lost from the blood because of a feeding-induced acceleration of saliva secretion was replenished with an intravenous infusion of artificial parotid saliva. This replenishment lessened the levels of suppression on both feeding and parotid saliva secretion. When only the lost fluid was replenished with an intravenous infusion of iso-osmotic mannitol solution in the MI treatment, the degree of feeding suppression was lessened but the level of saliva secretion suppression was not affected. These results indicate that the marked suppression of feed intake during the initial stages of dry forage feeding was caused by a feeding-induced hypovolemia while the suppression of saliva secretion was brought about by the loss of $NaHCO_3$ from the blood due to increased saliva secretion during the initial stages of feeding.

Electromagnetic Wave Absorption Properties of NiCuZn Ferrite (NiCuZn 페라이트의 전자파 흡수특성)

  • Park, Chan-Kyu;Kim, Ki-Tae;Chang, Sang-Mok;Lee, Sang-Rok
    • Applied Chemistry for Engineering
    • /
    • v.20 no.5
    • /
    • pp.500-504
    • /
    • 2009
  • NiCuZn Ferrites, known as preventing EMI/EMC, were prepared and their properties were investigated based on the chemical composition ratio, sintering temperature, and mean particle size. The NiCuZn ferrite made of $Fe_2O_3$ 49.0 mol%, NiO 9.0 mol%, CuO 8.0 mol%, ZnO 34.0 mol% could be applied at the largest range of electromagnetic wave. The optimal calcination and sintering temperature were $900^{\circ}C$ and $1080^{\circ}C$, respectively. The electromagnetic wave loss capacity of its mean particle size $1.12{\mu}m$ was superior to others examined.

Manufacturing of Ni-Cr-B-Si + WC/12Co Composite Coating Layer Using Laser Cladding Process and its Mechanical Properties (레이저 클래딩 공정을 이용한 Ni-Cr-B-Si + WC/12Co 복합 코팅층의 제조 및 기계적 특성)

  • Ham, Gi-Su;Kim, Chul-O;Park, Soon-Hong;Lee, Kee-Ahn
    • Journal of Powder Materials
    • /
    • v.24 no.5
    • /
    • pp.370-376
    • /
    • 2017
  • In this study we manufacture a Ni-Cr-B-Si +WC/12Co composite coating layer on a Cu base material using a laser cladding (LC) process, and investigate the microstructural and mechanical properties of the LC coating and Ni electroplating layers (reference material). The initial powder used for the LC coating layer is a powder feedstock with an average particle size of $125{\mu}m$. To identify the microstructural and mechanical properties, OM, SEM, XRD, room and high temperature hardness, and wear tests are implemented. Microstructural observation of the initial powder and LC coating layer confirm the layer is composed mainly of ${\gamma}-Ni$ phases and WC and $Cr_{23}C_6$ carbides. The measured hardness of the LC coating and Ni electroplating layers are 653 and 154 Hv, respectively. The hardness measurement from room up to high temperatures of $700^{\circ}C$ result in a hardness decrease as the temperature increases, but the hardness of the LC coating layer is higher for all temperature conditions. Room temperature wear results show that the wear loss of the LC coating layer is 1/12 of the wear level of the Ni electroplating layer. The measured bond strength is also greater in the LC coating than the Ni electroplating.

The Effect of Substrate Temperature on the Electrical, Electronic, Optical Properties and the Local Structure of Transparent Nickel Oxide Thin Films

  • Lee, Kangil;Kim, Beomsik;Kim, Juhwan;Park, Soojeong;Lee, Sunyoung;Denny, Yus Rama;Kang, Hee Jae;Yang, Dong-Seok
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.397-397
    • /
    • 2013
  • The electrical, electronic, optical properties and the local structure of Nickel Oxide (NiO) thin film have been investigated by X-ray photoelectron spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), UV-spectrometer,Hall Effect measurement and X-ray absorption spectroscopy (XAS). The XPS results show that the Ni 2p spectra for all films consist of $Ni2p_{3/2}$ at around 854.5 eV which indicate the presence of Ni-O bond from NiO phase and for the annealed film at temperature above $200^{\circ}C$ shows the coexist Ni oxide and Ni metal phase. The REELS spectra showed that the band gaps of the NiO thin films were abruptly decreased with increasing temperature. The values of the band gaps are consistent with the optical band gaps estimated by UV-Spectrometer. The optical transmittance spectra shows that the transparency of NiO thin films in the visible light region was deteriorated with higher temperature due to existence of $Ni^0$. Hall Effect measurement suggest that the NiO thin films prepared at relatively low temperatures (RT and $100^{\circ}C$) are suitable for fabricating p-type semiconductor which showed that the best properties was achieved at $100^{\circ}C$, such as a low resistivity of $7.49{\Omega}.cm$. It can be concluded that the annealing process plays a crucial role in converting from p type to n type semiconductor which leads to reducing electrical resistivity of NiO thin films. Furthermore, the extended X-ray absorption fine structure (EXAFS) spectrum at the Ni K-edge was used to address the local structure of NiO thin films. It was found that the thermal treatments increase the order in the vicinity of Ni atom and lead the NiO thin films to bunsenite crystal structure. Moreover, EXAFS spectra show in increasing of coordination number for the first Ni-O shell and the bond distance of Ni-O with the increase of substrate temperature.

  • PDF

Sliding Wear and Friction Behavior of Electro-Pressure Sintered Co-Fe and Co-Ni Compacts (통전가압 소결된 Co-Fe, Co-Ni 소결체의 미끄럼 마찰 및 마멸거동)

  • Kwon Yong Jin;Kim Tai-Woung;Kim Yong-Suk
    • Journal of Powder Materials
    • /
    • v.11 no.6 s.47
    • /
    • pp.451-461
    • /
    • 2004
  • Dry sliding wear behavior of electro-pressure sintered Co-Fe and Co-Ni compacts was investigated. Pin-on-disk wear tests were performed on the sintered Co-Fe, Co-Ni disks against alumina $(Al_2O_3)$ and silica $(SiO_2)$ balls at various loads ranging from 3N to 12N. A constant sliding speed of 0.1m/sec was employed. Wear rate was calculated by dividing the weight loss of a specimen by the measured specific gravity and sliding dis-tance. Worn surfaces and cross-sections of the specimens were examined using an SEM and EDS to investigate wear mechanism of the compacts. The wear behavior of the compacts were discussed as a function of their com-position. Effects of mechancial properties of the compact as well as oxide layers formed on wearing surface on the wear were also discussed.

A Study on Hot Ductility Behavior of Ni-based Superalloys (니켈기 초내열합금의 고온연성거동에 관한 연구)

  • Lee, Choung-Rae;Um, Sang-Ho;Kim, Sung-Wook;Choi, Cheol;Lee, Chang-Hee
    • Journal of Welding and Joining
    • /
    • v.22 no.2
    • /
    • pp.59-68
    • /
    • 2004
  • Plasma transferred arc welding (PTAW) has been taken into consideration for repairing Ni-based superalloy components used gas turbine blades. Various cracks has been generally reported to be found in the base metal heat affected zone(HAZ) along grain boundary. Thus, hot cracking susceptibility of Ni-based superalloys was evaluated according to heat treatments. Hot ductility test was conducted on specimens with solution treated at 112$0^{\circ}C$ for 2 hours and aging treated at 845$^{\circ}C$ for 24hours after solution treatment. The results of the hot ductility test appeared that solution treated specimens were the highest ductility recovery rate among three conditions. The loss of ductility at high temperature in Ni-based superalloy was mainly controlled by the degree of pain boundary wetting due to constitutional liquation of MC carbide precipitates. Meanwhile, the highest ductility recovery rate in solution-treated alloys seems to be lack of M23C6, which can be dissolved during heating and then result in the local enrichment of Cr in the vicinity of the grain boundary.