• Title/Summary/Keyword: Ni alloys

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Fabrication of Ni-Nb-Ti-Zr Amorphous Alloys with Wide Supercooled Liquid Region (넓은 과냉각 액체영역을 가지는 Ni-Nb-Ti-Zr계 비정질 합금의 제조)

  • Kim, Sung-Gyoo
    • Journal of Korea Foundry Society
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    • v.22 no.5
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    • pp.252-256
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    • 2002
  • Ni-Nb-Ti-Zr amorphous alloys were manufactured using melt-spinning methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The value of the reduced glass transition temperature and the supercooled liquid region of $Ni_{62}Nb_{10}Ti_{13}Zr_{15}$ alloy were relatively high and were 0.612 and 76 K respectively. However, amorphous bulk alloy rod was not formed using the Cu-mold die casting. The mechanical properties were in the range of $800{\sim}900DPN$ of hardness and $2.5{\sim}2.8$ GPa of tensile strength in the whole composition range.

Cu-based Bulk Amorphous Alloys in the Cu-Zr-Ti-Ni-Pd System (Cu-Zr-Ti-Ni-Pd계 비정질 벌크합금의 형성과 성질)

  • Kim, Sung-Gyoo;Bae, Cha-Hurn
    • Journal of Korea Foundry Society
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    • v.22 no.6
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    • pp.304-308
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    • 2002
  • The new Cu-Zr-Ti-Ni-Pd amorphous alloy system has been introduced and manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties of the alloys were examined. The reduced glass transition temperature(Trg = Tg/Tm) and the supercooled liquid region(${\Delta}$Tx = Tx-Tg) of $Cu_{49}Zr_{30}Ti_{10}Ni_5Pb_6$ alloy were 0.620 and 57 K respectively. $Cu_{49}Zr_{30}Ti_{10}Ni_5Pb_6$ amorphous alloy was produced in the rod shape with 2mm diameter using the Cu-mold die casting. The hardness value of the amorphous bulk alloy was 432 DPN.

Fabrication and Mechanical Properties of Ni-based Amorphous Bulk Alloys (Ni기 비정질 벌크합금의 제조와 기계적 성질)

  • Kim, Sung-Gyoo
    • Journal of Korea Foundry Society
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    • v.22 no.6
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    • pp.288-292
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    • 2002
  • Ni-base amorphous alloys were manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The reduced glass transition temperature and the supercooled liquid region of $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$alloy were 0.621 and 46 K respectively. $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$ alloy was produced in the rod shape 3mm diameter using the Cu-mold die casting. Hardness, compression strength, elongation and elastic modulus of the alloy were 850 DPN, 2.75 GPa, 1.8% and 150 GPa respectively. Moreover, compression strength of 2.75 GPa was the highest value in the amorphous bulk alloy produced up to now.

The electrode characteristics of non-stoichiometric Zr-based Laves phase alloys (Non-Stoichiometric Zr-Based 라베스상 수소저장합금의 방전특성)

  • Kim, Dong-Myung;Jung, Jai-Han;Lee, Han-Ho;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.1
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    • pp.11-18
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    • 1996
  • The Laves phase alloy hydrides have some promising properties as electrode materials in reversible metal hydride batteries. In this work, the hydrogen storage performance, crystallographic parameters, surface morphology, surface area and electrochemical characteristics of the non-stoichiometric $ZrMn_{0.3}V_{0.7}Ni_{1.4+{\alpha}}$, $ZrMn_{0.5}V_{0.5}Ni_{1.4+{\alpha}}$($\alpha$ =0.0, 0.2, 0.4, 0.6) alloys were examined. These as-cast alloys were found to have mainly a cubic C15-type Laves phase structure by X -ray diffraction analysis. The equilibrium pressure of the alloy were increased as $\alpha$ increased in both two types alloy. In case of $ZrMn_{0.5}V_{0.5}Ni_{1.4+{\alpha}}$ alloys, discharge efficiency and the rate capability of the alloy were decreased as $\alpha$ increased but, these values were increased in case of $ZrMn_{0.3}V_{0.7}Ni_{1.4+{\alpha}}$ alloys. The differences of these electrode properties observed were dependent on the reaction surface area and the catalytic activity of unit area of the each electrode.

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