• Title/Summary/Keyword: Ni/MSU-F

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Conversion of Cellulose over Ni Loaded Mesoporous MSU-F Catalysts via Air Gasification

  • Park, Young-Kwon;Park, Kyung Sun;Kim, Seong-Soo;Park, Sung Hoon;Jung, Sang-Chul;Kim, Sang Chai;Jeon, Jong-Ki;Jeon, Ki-Joon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3205-3208
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    • 2014
  • Catalytic gasification of cellulose was carried out in a U-type fixed reactor with Ni loaded MSU-F catalyst (Ni/MSU-F) and Ni loaded ${\gamma}-Al_2O_3$ (Ni/${\gamma}-Al_2O_3$). The characteristics of the catalysts were analyzed by using X-ray diffraction, $H_2$-temperature programmed reduction, and Brunauer-Emmett-Teller analyses. The operation conditions of catalytic gasification reactions were $750^{\circ}$ and 0.2 equivalence ratio. Air was used as gasification agent. Catalytic gasification characteristics, such as gas yield and gas composition ($H_2$, CO, $CO_2$, $C_1-C_4$), were measured and calculated. The gas yield of Ni/MSU-F was much higher than that of Ni/${\gamma}-Al_2O_3$. Especially high amount of hydrogen was produced by Ni/MSU-F.