• Title/Summary/Keyword: Ni(II)

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Carbon Nanotubes Doped with Nitrogen, Pyridine-like Nitrogen Defects, and Transition Metal Atoms

  • Mananghaya, Michael R.
    • 대한화학회지
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    • 제56권1호
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    • pp.34-46
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    • 2012
  • Dopants and defects can be introduced as well as the intercalation of metals into single wall carbon nanotubes (SWCNTs) to modify their electronic and magnetic properties, thus significantly widening their application areas. Through spinpolarized density functional theory (DFT) calculations, we have systemically studied the following: (i) (10,0) and (5,5) SWCNT doped with nitrogen ($CN_xNT$), (ii) (10,0) and (5,5) SWCNT with pyridine-like defects (3NV-$CN_xNT$), and (iii) chemical functionalization of (10,0) and (5,5) 3NV-$CN_xNT$ with 12 different transition metals (TMs) (Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Pd, and Pt). Attention was done in searching for the most stable configurations, deformation, calculating the formation energies, and exploring the effects of the doping concentration of nitrogen and pyridine-like nitrogenated defects on the electronic properties of the nanotubes. Also, calculating the corresponding binding energies and effects of chemical functionalization of TMs on the electronic and magnetic properties of the nanotubes has been made. We found out that the electronic properties of SWCNT can be effectively modified in various ways, which are strongly dependent not only on the concentration of the adsorbed nitrogen but also to the configuration of the adsorbed nitrogen impurities, the pyridine-like nitrogenated defects, and the TMs absorbed; due to the strong interaction between the d orbitals of TMs and the p orbitals of N atoms, the binding strengths of TMs with the two 3NV-$CN_xNT$ are significantly enhanced when compared to the pure SWCNTs.

Nonlinear earthquake capacity of slender old masonry structures prestressed with steel, FRP and NiTi SMA tendons

  • Preciado, Adolfo;Ramirez-Gaytan, Alejandro;Gutierrez, Nayar;Vargas, David;Falcon, Jose Manuel;Ochoa, Gil
    • Steel and Composite Structures
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    • 제26권2호
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    • pp.213-226
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    • 2018
  • This paper focuses on the seismic protection of slender old masonry structures by the implementation of prestressing devices at key locations. The devices are vertically and externally located inside the towers in order to be reversible and calibrated. An extensive parametric study on a selected slender tower is carried out based on more than 100 nonlinear static simulations aimed at investigating the impact of different parameters on the seismic performance: (i) different prestressing levels; (ii) shape memory alloy superelasticity and (iii) changes in prestressing-forces in all the stages of the analysis until failure and masonry toe crushing. The tendon materials under analysis are conventional prestressing steel, fiber-reinforced polymers of different fibers and shape memory alloys. The parametric study serves to select the most suitable prestressing device and optimal prestressing level able to dissipate more earthquake energy. The seismic energy dissipation is evaluated by comparing the structural capacity curves in original state and retrofitted.

압력용기용 SA508 class3강에 대한 underclad 균열의 감수성 평가 - 입열량의 최적화 (Evaluation of Underclad Crack Susceptibility of the SA508 Class 3 Steel for Pressure Vessels -Optimization of Heat Input-)

  • 김석원;양성호;김준구;이영호
    • Journal of Welding and Joining
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    • 제13권2호
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    • pp.139-149
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    • 1995
  • Many pressure vessels for the power plants are fabricated from low alloy ferritic steels. The inner sides of the pressure vessels are commonly weld_cladded with austenitic stainless steels to minimize problems of corrosive attack. The submerged-arc welding(SAW) process is now used in preference to other processes because of the possibilities open to automation to reduce the overaII welding times. The most reliable way to avoid underclad cracks(UCC) which are often detected at the overlap of the clad beads is to use nonsusceptible steels such as SA508 class 3. At present domestically developed forging steel of SA508 cl.S is now being cladded with single layer by using 90mm wide strip, which transfers higher heat input into the base metal compared to the conventional two layers strip cladding which has been in wide use with 30-60 mm wide strip. But the current indices for the influence of heat input on crack susceptibility are not accurate enough to express the subtle difference in crack susceptibility of the steel. Therefore, the purpose of this present study is: l) To determine UCC susceptibility on domestic forging steel, SA508 cl.S cladded with single layer by using submerged arc 90mm strip and, 2) To optimize heat input range by which the crack susceptibility could be eliminated.

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중탄소 저합금강의 인장성질에 미치는 템퍼링의 영향 (Effects of Tempering on Tensile Properties of Medium-Carbon Low-Alloy Steels)

  • 이영국
    • 열처리공학회지
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    • 제12권4호
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    • pp.327-337
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    • 1999
  • A series of Ni-Cr-Mo alloy steels were austenitized, quenched to martensite, and tempered at various temperature and time conditions. Tensile testing was conducted at room temperature with cylindrical specimens, and hardness was measured using Rockwell hardness tester. In the tempering stage I, high strain hardening and yield strength accounted for the high ultimate strength and hardness. In the tempering stage II, strengths and hardness linearly decreased with increasing tempering temperature. Specimens tempered in the temperin stage III showed incipient discontinuous yielding and tensile strengths only slightly higher than yield strengths. Ductilities decreased slightly in specimens tempered in the tempered martensite embrittlement range, and severely decreased in specimens tempered for 10 hours at $500^{\circ}C$ in the temper embrittlement range. Specimens tempered at $600^{\circ}C$ for 10 hours showed recrystallized microstructures, a number of fine dimples, and increased strain hardening, probably due to the precipitation of alloy carbides. The simple formulae for the mechanical properties of these steels were suggested as a function of carbon content and Hollomon-Jaffe tempering parameter.

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Co-Re-based alloys a new class of material for gas turbine applications at very high temperatures

  • Mukherji, D.;Rosler, J.;Wehrs, J.;Eckerlebe, H.;Gilles, R.
    • Advances in materials Research
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    • 제1권3호
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    • pp.205-219
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    • 2012
  • Co-Re alloy development is prompted by the search for new materials for future gas turbines which can be used at temperatures considerably higher than the present day single crystal Ni-based superalloys. The Co-Re based alloys are designed to have very high melting range. Although Co-alloys are used in gas turbine applications today, the Co-Re system was never exploited for structural applications and basic knowledge on the system is lacking. The alloy development strategy therefore is based on studying alloying additions on simple model alloy compositions of ternary and quaternary base. Various strengthening possibilities have been explored and precipitation hardening through fine dispersion of MC type carbides was found to be a promising route. In the early stages of the development we are mainly dealing with polycrystalline alloys and therefore the grain boundary embrittlement needed to be addressed and boron addition was considered for improving the ductility. In this paper recent results on the effect of boron on the strength and ductility and the stability of the fine structure of the strengthening TaC precipitates are presented. In the beginning the alloy development strategy is briefly discussed.

한국 염장 발효식품으로부터 분리한 호염성 세균의 분리ㆍ동정 및 염요구성 (Identification and Salt Requirement of Halophilic Bacteria isolated from Korean Salt-Fermented Sen Foods.)

  • Bae, Moo;Song, Kyoung-Sook
    • 한국미생물·생명공학회지
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    • 제15권5호
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    • pp.301-305
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    • 1987
  • 염장 식품인 젓갈류 15종류에서 호염성 세균을 분리하여 그들이 성장할 수 있는 NaCl 농도에 따라, 5-10% NaCl에서 잘 자라는 18균수와 10-20% NaCl 에서 더욱 잘 자라는 35균주를 구분하여, 이들을 moderate halophiles로 분류하였다. 분리한 moderate halophiles중에는 Flavobacterium-group I과 II 그러고 Pseudomonas sp.에 속하는 균주들이 있으며 이들은 3$0^{\circ}C$에서 10% NaCl을 첨가했을 때 가장 잘 성장하였다. Na 이온 대신 K 이온을 대치시켰을 때 1.5M에서는 대치가 가능하였으나 그보다 높은 농도인 2.5M 내지 3.5M에서는 대치될 수 없음을 확인하였고 Na 이온 대신 Li 이온이나 mg 이온은 생장에 적합하지 않았다.

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MULTISPECTRAL REMOTE SENSING ALGORITHMS FOR PARTICULATE ORGANIC CARBON (POC) AND ITS TEMPORAL AND SPATIAL VARIATION

  • Son, Young-Baek;Wang, Meng-Hua;Gardner, Wilford D.
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume I
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    • pp.450-453
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    • 2006
  • Hydrographic data including particulate organic carbon (POC) from the Northeastern Gulf of Mexico (NEGOM) study were used along with remotely sensed data obtained from NASA's Sea-viewing Wide Field-of-view Sensor (SeaWiFS) to develop POC algorithms to estimate POC concentration based on empirical and model-based principal component analysis (PCA) methods. In Case I and II waters empirical maximized simple ratio (MSR) and model-based PCA algorithms using full wavebands (blue, green and red wavelengths) provide more robust estimates of POC. The predicted POC concentrations matched well the spatial and seasonal distributions of POC measured in situ in the Gulf of Mexico. The ease in calculating the MSR algorithm compared to PCA analysis makes MSR the preferred algorithm for routine use. In order to determine the inter-annual variations of POC, MSR algorithms applied to calculate 100 monthly mean values of POC concentrations (September 1997-December 2005). The spatial and temporal variations of POC and sea surface temperature (SST) were analyzed with the empirical orthogonal function (EOF) method. POC estimates showed inter-annual variation in three different locations and may be affected by El $Ni{\tilde{n}}o/Southern$ Oscillation (ENSO) events.

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Porphyromonas gingivali의 열충격단백-특이성 단클론항체의 개발 (Development of monoclonal antibody against Porphyromonas gingivalis heat shock protein)

  • 이니나;이주연;김성조;최점일
    • Journal of Periodontal and Implant Science
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    • 제37권1호
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    • pp.11-21
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    • 2007
  • Heat shock protein (HSP) is one of cellular protein commonly present in major periodontopathogenic bacteria as well as mammalian cells. The protein may play a role in the immunopathogenesis by modulating autoimmune reaction due to its high level of sequence homology between bacteria and human counterpart. Hence, identifying immunodomiant epitope of bacteria HSP that is cross-reactive to periodontopathogenic bacteria with a specificity to human HSP may comprise a critical strategy for development of a periodontal vaccine. The present study was performed to establish clones producing monoclonal antibody reactive to Porphyromonas gingivalis (p. gingivalis) HSP with a specificity to human HSP. 4 different hybridomas were cloned producing monoclonal IgG antibodies to P, gingivalis HSP and evaluated for their reactivity and specificity to other periodontopathogenic bacteria as well as to human HSP. These four monoclonal antibodies reacted with p. gingivalis HSP only with specificities to other bacteria tested and human HSP as well. The antigenic epitopes producing the 4 monoclonal antibody may be potentially developed as vaccine candidates. Further investigations are under way to identify more clones producing monoclonal antibodies reactive to P, gingivalis HSP and to other periodontopathogenic bacteria as well, while maintaining specificities to human counterpart.

경사기능성 세라믹/금속 복합재료의 열응력해석 (Thermal Stress Analysis of Functuonally Graded Ceramic/Metal Composites(II))

  • 임재규;송준희
    • 대한기계학회논문집A
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    • 제21권10호
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    • pp.1571-1579
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    • 1997
  • The development of a new material which should be continuously use under severe environment of very high temperature has been urgently requested. For the development of such super-heat resistant materials, the main problem is not only to make the superior thermal barrier properties but also to actively release thermal stress. So, a new concept of functionally graded material(FGM) has been proposed to overcome this problem. A composition and microstructure of FGM are varied continuously from place to place in ways designed to provide it with the maximum function of mitigating the induced thermal stress. So, FGM can be applied in the aerospace, the electronic and the medical field, etc.. In this study, thermal stress analysis of sintering PSZ/NiCrAlY graded material was conducted theoretically using a finite-element program. The temperature condition was sintering temperature assuming a cooling-down process up to room temperature. Fracture damage mechanism was anlayzed by the parameters of residual stress. It could be known that FGM provided with the function of mitigating the induced thermal stress.

Structural health monitoring of the Jiangyin Bridge: system upgrade and data analysis

  • Zhou, H.F.;Ni, Y.Q.;Ko, J.M.
    • Smart Structures and Systems
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    • 제11권6호
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    • pp.637-662
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    • 2013
  • The Jiangyin Bridge is a suspension bridge with a main span of 1385 m over the Yangtze River in Jiangsu Province, China. Being the first bridge with a main span exceeding 1 km in Chinese mainland, it had been instrumented with a structural health monitoring (SHM) system when completed in 1999. After operation for several years, it was found with malfunction in sensors and data acquisition units, and insufficient sensors to provide necessary information for structural health evaluation. This study reports the SHM system upgrade project on the Jiangyin Bridge. Although implementations of SHM system have been reported worldwide, few studies are available on the upgrade of SHM system so far. Recognizing this, the upgrade of original SHM system for the bridge is first discussed in detail. Especially, lessons learned from the original SHM system are applied to the design of upgraded SHM system right away. Then, performance assessment of the bridge, including: (i) characterization of temperature profiles and effects; (ii) recognition of wind characteristics and effects; and (iii) identification of modal properties, is carried out by making use of the long-term monitoring data obtained from the upgraded SHM system. Emphasis is placed on the verification of design assumptions and prediction of bridge behavior or extreme responses. The results may provide the baseline for structural health evaluation.