• Title/Summary/Keyword: Newtonian science

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Molecular Conformation and Non-Newtonian Viscosity Behavior of Poly(L-proline) in Various Solvent Systems

  • Jang, Chun-Hag;Kim, Hyun-Don;Lee, Jang-Oo
    • Bulletin of the Korean Chemical Society
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    • v.15 no.5
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    • pp.399-404
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    • 1994
  • The non-Newtonian viscosities (the specific or intrinsic viscosities) of poly(L-proline) (PLP, $M_v$=19,000 and 32,000) in various mixed-solvent systems like water-propanol and acetic acid-propanol of varying compositions were measured during the reverse mutarotation (Form II ${\rightarrow}$Form I) by the application of external pressure (up to 4.5 psi). The non-Newtonian viscosity effect was found to be larger in acetic acid-propanol system than in water-propanol system and to somewhat decrease during the reverse mutarotation at a given solvent system. The non-Newtonian viscosity behavior of PLP in aqueous salt ($CaCl_2$) solution was also studied, from which it was found that the degree of the non-Newtonian effect decreased with increasing salt concentration, and increased with increasing PLP molecular weight. These findings could be explained in terms of conformational changes of PLP in solution (like the helix-helix or helix-coil transition) involved.

Continuous Viscosity Measurement of Non-Newtonian Fluids over a Range of Shear Rates Using a Mass-Detecting Capillary Viscometer

  • Sehyun Shin;Keum, Do-Young
    • Journal of Mechanical Science and Technology
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    • v.16 no.2
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    • pp.255-261
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    • 2002
  • A newly designed mass-detecting capillary viscometer uses a novel concept to continuously measure non-Newtonian fluids viscosity over a range of shear rates. A single measurement of liquid-mass variation with time replaces the now rate and pressure drop measurements that are usually required by capillary tube viscometers. Using a load cell and a capillary, we measured change in the mass flow rate through a capillary tube with respect to the time, m(t), from which viscosity and shear rate were mathematically calculated. For aqueous polymer solutions, excellent agreement was found between the results from the mass-detecting capillary viscometer and those from a commercially available rotating viscometer. This new method overcomes the drawbacks of conventional capillary viscometers meassuring non-Newtonian fluid viscosity. First, the mass-detecting capillary viscometer can accurately and consistently measure non -Newtonian viscosity over a wide range of shear rate extending as low as 1 s$\^$-1/. Second, this design provides simplicity (i. e., ease of operation, no moving parts), and low cost.

Three Body Problem and Formation of Binary System (3체 문제와 연성계의 형성)

  • Jae Woo Park;Kyu Hong Choi;Kyong Chol Chou
    • Journal of Astronomy and Space Sciences
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    • v.2 no.1
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    • pp.19-33
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    • 1985
  • The singularities of differential Newtonian equation of motion in three body problem cause the loss of accuracy and the considerable increase of the computer time. These singularities could be eliminated during the process of regularization to transform the independent variables and the coordinate of Newtonian equations of motion. In this study, we calculated the positions and velocities of three body along the time scale to find out the unique solution of regularized Newtonian equations of motion with the $5^{th}$ order Runge-Kutta method by assuming the suitable initial velocities and positions. As the results of these calculations it is shown that the tripe stellar system eventually distintegrated, two of them formed a binary, and the last one escaped from this system with a hyperbolic orbit. This may suggest one possible explanation for the binary formation.

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Spreading and retraction dynamics of a liquid droplet impacting rough hydrophobic surfaces: Formation of micrometer-sized drops (거친 발수 표면에 충돌하는 유체 방울의 팽창 및 수축 역학: 미세 유체 방울의 형성)

  • Kim, Uijin;Kim, Jeong-Hyun
    • Journal of the Korean Society of Visualization
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    • v.19 no.3
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    • pp.15-21
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    • 2021
  • In this study, we investigated the dynamics of a droplet impacting rough hydrophobic surfaces through high-speed imaging. Micrometer-sized structures with grooves and pillars were fabricated on smooth Polydimethylsiloxane (PDMS) surfaces by laser ablation. We used Newtonian and non-Newtonian liquid droplets to study the drop impact dynamics. De-ionized water and aqueous glycerin solutions were used for the Newtonian liquid droplet. The solutions of xanthan gum in water were prepared to provide elastic property to the Newtonian droplet. We found that the orientation of the surface structures affected the maximal spreading diameter of the droplet due to the degree of slippage. During the droplet retraction, the dynamic receding contact angles were measured to be around 90° or less. It resulted in the formation of the micro-capillary bridges between the receding droplet and the surface structures. Then, the rupture of the capillary bridge led to the formation of micrometer-sized droplets on top of the surface structures. The size of the microdroplets was found to increase with increasing the impacting velocity and viscosity of the Newtonian liquid droplets. However, the size of the isolated microdroplets decreased with enhancing the elasticity of the droplets, and the size of the non-Newtonian microdroplets was not affected by the impacting velocity.

Laminar Heat and Fluid Flow Characteristic with a Modified Temperature-Dependent Viscosity Model in a Rectangular Duct

  • Sohn Chang-Hyun;Chang Jae-Whan
    • Journal of Mechanical Science and Technology
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    • v.20 no.3
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    • pp.382-390
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    • 2006
  • The present study proposes a modified temperature-dependent non-Newtonian viscosity model and investigates the flow characteristics and heat transfer enhancement of the viscoelastic non-Newtonian fluid in a 2:1 rectangular duct. The combined effects of temperature dependent viscosity, buoyancy, and secondary flow caused by the second normal stress difference are considered. Calculated Nusselt numbers by the modified temperature-dependent viscosity model give good agreement with the experimental results. The heat transfer enhancement of viscoelastic fluid in a rectangular duct is highly dependent on the secondary flow caused by the magnitude of second normal stress difference.

Behaviors of Anisotropic Fluids in the Vicinity of a Wedge

  • Kim, Youn-J.
    • Journal of Mechanical Science and Technology
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    • v.14 no.6
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    • pp.690-698
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    • 2000
  • The laminar boundary layer flow and heat transfer of anisotropic fluids in the vicinity of a wedge have been examined with constant surface temperature. The similarity variables found by Falkner and Skan are employed to reduce the stream wise-dependence in the coupled nonlinear boundary layer equations. The numerical solutions are presented using the fourth-order Runge - Kutta method and the distribution of velocity, micro-rotation, shear and couple stresses and temperature across the boundary layer are plotted. These results are also compared with the corresponding flow problems for Newtonian fluid over wedges. It is found that for a constant wedge angle, the skin friction coefficient is lower for micropolar fluid, as compared to Newtonian fluid. For the case of the constant material parameter K, however, the magnitude of velocity for anisotropic fluid is greater than that of Newtonian fluid. The numerical results also show that for a constant wedge angle with a given Prandtl number, Pr = I, the effect of increasing values of K results in increasing thermal boundary layer thickness for anisotropic fluid, as compared with Newtonian fluid. For the case of the constant material parameter K, however, the heat transfer rate for anisotropic fluid is lower than that of Newtonian fluid.

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Thixotropic Equation and Rheological Parameters on Non-Newtonian Flow Mechanism (비 뉴톤 유동 메카니즘에서 틱소트로피 식과 유변 파라메타)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.386-393
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    • 2015
  • The rheological properties of complex materials such as colloid dispersion show complicated non-Newtonian flow phenomena when they are subjected to shear flow. These flow properties are controlled by the characteristics of flow units and the interactions among the flow segments. The rheological parameters of relaxation time $({\beta}_2)_0$, structure factor $C_2$ and shear modulus $X_2/{\alpha}_2$ for various thixotropic flow curves was obtained by applying thixotropic equation to flow curves. The variations of rheological parameters are directly related to non-Newtonian flows, viscosities and activation energies of flow segments.

Development of Equilibium Flow Calculation Program Using a Modified Newtonian Method (수정 뉴토니안 방법을 이용한 평형유동 해석 프로그램 개발)

  • Choi, Jaehyeok
    • Journal of the Korea Institute of Military Science and Technology
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    • v.19 no.4
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    • pp.483-491
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    • 2016
  • A simple aerodynamic calculation program for high Mach number flow is developed by combining the modified Newtonian method with Tannehill's curve fits for the thermodynamic properties of air in equilibrium state. Aerodynamic characteristics for a parabolic nose are predicted and compared with CFD(Computational Fluid Dynamics) analysis results. Comparison shows good agreements, and the developed program is expected to be a practical tool for slender body aerodynamic calculation for high Mach number flow.

Non-Newtonian Characteristics of Gochujang and Chogochujang at Different Temperatures

  • Choi, Ji Eun;Lee, Jun Ho
    • Preventive Nutrition and Food Science
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    • v.22 no.1
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    • pp.62-66
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    • 2017
  • This study was conducted to determine the rheological properties of gochujang and chogochujang at different temperatures (25, 35, and $45^{\circ}C$). Rheological properties of the samples were determined using a rotational rheometer at a shear range of 1 to $40s^{-1}$. Gochujang and chogochujang were found to be non-Newtonian fluids according to the Herschel-Bulkley model. Yield stress and consistency coefficient of gochujang at different temperatures were higher than those of chogochujang, whereas the opposite was observed for flow behavior index. Moreover, all rheological properties of gochujang and chogochujang decreased with increasing temperature. The consistency coefficient was related to temperature using an Arrhenius-type relationship. Gochujang (14.48 kJ/mol) had slightly higher activation energy than chogochujang (14.03 kJ/mol).

Physical Properties of Freeze-Dried Powder of Aloe Vera Gel with Respect to the Concentrating Degree as Pre-Treatment (전처리 농축 정도에 따른 Aloe Vera gel의 동결건조분말의 물성)

  • Lee, Nam-Jae;Lee, Seung-Ju
    • Korean Journal of Food Science and Technology
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    • v.41 no.1
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    • pp.32-36
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    • 2009
  • The physical properties of freeze-dried Aloe vera gel powders were examined according to the influence of the concentration degrees of the gel solutions as raw materials during freeze-drying. As a pre-treatment prior to freeze-drying, the gel solutions were vacuum-concentrated at three concentration levels (g water/g solids): high (H), 76; medium (M), 119; and low (L), 159. The water contents of the three powder samples were almost the same. For their viscosity measurements, non-Newtonian fluid behavior with shear thinning was observed in samples H and M, whereas Newtonian liquid behavior was found in sample L. In electrical conductivity measurements, sample H showed the highest conductivity upon dissolving the powder in water. For their water sorption isotherms, sample H was analyzed to have the least amount of bound water. Finally, it was determined that the degree of concentration caused only slight differences in the physical properties of freeze-dried Aloe gel powders.