• Title/Summary/Keyword: Newtonian

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Compressive Creep Behavior of Rice Starch Gels (쌀 전분 젤의 creep 특성)

  • Hong, Seok-In;Kim, Young-Sug;Choi, Dong-Won;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.24 no.2
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    • pp.165-170
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    • 1992
  • The creep behavior of gels made with $30{\sim}45%$ gelatinized rice starch was measured over a wide range of temperature. Compressive creep curves of rice starch gels conformed to a six element mechanical model consisting of one Hookean, two Voigt and one Newtonian component. The creep compliance of gels decreased with increasing starch concentrations. Among viscoelastic constants of the mechanical model, elastic modulus was mainly influenced by the change of starch concentrations. The concentration-invariant compliance curve was obtained by reduction to 38% using reduction parameter $a_{c}$. The creep compliance curves of 45% starch gels increased with temperature, which indicated that rice starch gels became softer and less rigid with increasing temperature. When the compliance at $20^{\circ}C$ was set as a reference curve, creep compliance data for 45% gels at various temperature could be superimposed as a continuous smooth curve. The apparent activation energies of 45% rice starch gels calculated by the modified WLF equation were not intrinsic, but decreased as temperature increased.

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Rheological Behavior of Lyotropilc Solutions of Cellulose in the $NH_3/NH_4SCN$ Solvent System

  • Jo, Jae-Jeong;Cuculo, J.A.;Theil, M.H.
    • Proceedings of the Korean Fiber Society Conference
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    • 1990.06b
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    • pp.36-37
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    • 1990
  • In the past, facile dissolution of cellulose has been hampered by the lack of suitable nondegrading solvents. Recently, this problem has been solved in our laboratory by the discovery of an inexpensive, convenient solvent system, that is the mixture of $NH_3\;and\;NH_4SCN$, for cellulose. Also, the $cellulose/NH_3/NH_4SCN$ solution system has been found to form the anisotropic, i.e., liquid crystalline phase. It is believed that both the cholesterio and the nematic phase occur. This finding has prompted extensive on-going researoh on the formation of the liquid crystalline phase from an inexpensive natural source such as cellulose since the nematic phase is envisioned as an excellent precursor sources for products with desirable properties, for example, high modulus and high strength. This interest naturally leads to a desire to understand the theological properties of the nematic phase so that the transformation of the nematic phase to the solid state with desirable properties can be efficiently accomplished, ;From this point of view, the theological behavior of the $cellulose/NH3_/NH_4SCN$ system has been studied as a function of shear rate and shear stress over a wide range of solvent compositions, cellulose concentration, centrifugation and urea contents, Results indicate that the viscosity decreases with increasing shear rate. A marked shear thinning behavior and a quasi-Newtonian behavior were observed in the low shear rate region and in the high shear rate region, respectively for all solvent compositions. The $cellulose/NH_3/NH_4SCN$ solution system only exhibited the viscosity increase with increasing cellulose concentration and failed to show the viscosity drop generally observed at the point of incipience of liquid crystal formation, This may be due to the gel-like nature of the solution by the association of the rodlike molecules into bundles which may serve as crosslinking points giving the cellulose solution a network structure. Also, simply hydrogen bonding may be so restrictive of molecular mobility that a viscosity drop is blocked. In addition to the above results, yield stress and thixotropy were also observed in the $cellulose/NH_3/NB_4SCN$ solution system which are characteristics of liquid crystal and gel, The results of the effect of centrifugation on viscosity show that viscosity decreases by the application of centrifugation. This may be explained by the change of the piled polydomain structure to the dispersed polydomain structure due to the pressure gradient generated during centrifugation.ation.

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Flow Visualization in the Branching Duct by Using Particle Imaging Velocimetry (입자영상유속계를 이용한 분기관내 유동가시화)

  • No, Hyeong-Un;Seo, Sang-Ho;Yu, Sang-Sin
    • Journal of Biomedical Engineering Research
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    • v.20 no.1
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    • pp.29-36
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    • 1999
  • The objective of this study is to analyse the flow field in the branching duct by visualizing the flow phenomena using the PIV system. A bifurcation model is fabricated with transparent acrylic resin to visualize the whole flow field with the PIV system. Water was used as the working fluid and the conifer powder as the tracer particles. The single-frame and two-frame methods of the PIV system and 2-frame of the grey level correlation method are applied to obtain the velocity vectors from the images captured in the flow filed. The velocity distributions in a lid-driven cavity flow are compared with the so-called standard experimental data, which was obtained from by 4-frame method in order to validate experimental results of the PIV measurements. The flow patterns of a Newtonian fluid in a branching duct were successfully visualized by using the PIV system and the sub-pixel and the area interpolation method were used to obtain the final velocity vectors. The velocity vectors obtained from the PIV system are in good agreement with the numerical results of the 3-dimensional branch flow. The results of numerical analyses and the PIV experiments for the three-dimensional flows in the branch ing duct show the recirculation zone distal to the branching point and the sizes of the recirculation length and height of the tow different methods are in good agreement.

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Comparison of Volume of Fluid (VOF) type Interface Capturing Schemes using Eulerian Grid System (오일러 격자체계에서 유체율 함수에 기초한 경계면 추적기법의 비교)

  • Kim, Do-Sam;Kim, Tag-Gyeom;Shin, Bum-Shick;Lee, Kwang-Ho
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.32 no.1
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    • pp.1-10
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    • 2020
  • The application of multiphase flows is increasingly being applied to analyze phenomena such as single phase flows where the fluid boundary changes continuously over time or the problem of mixing a liquid phase and a gas phase. In particular, multiphase flow models that take into account incompressible Newtonian fluids for liquid and gas are often applied to solve the problems of the free water surface such as wave fields. In general, multi-phase flow models require time-based the surface tracking of each fluid's phase boundary, which determines the accuracy of the final calculation of the model. This study evaluates the advection performance of representative VOF-type boundary tracking techniques applied to various CFD numerical codes. The effectiveness of the FCT method to control the numerical flux to minimize the numerical diffusion in the conventional VOF-type boundary tracking method and advection calculation was mainly evaluated. In addition, the possibility of tracking performance of free surface using CIP method (Yabe and Aoki, 1991) was also investigated. Numerical results show that the FCT-VOF method introducing an anti-diffusive flux to precent excessive diffusion is superior to other methods under the confined conditions in this study. The results from this study are expected to be used as an important basic data in selecting free surface tracking techniques applied to various numerical codes.

Emulsifying and Rheological Properties of the Pine Nut's Extracts (잣 구성 성분의 유화 및 유동특성)

  • Lee, Seog-Won;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.32 no.5
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    • pp.1093-1101
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    • 2000
  • The effects of concentration and pH on the emulsifying and rheological properties of the pine nut's protein extract(PNPE) and carbohydrate extract(PNCE) were investigated. Emulsifying activity index(EAI) of sample containing PNPE was minimal at pH 4.0 and the alteration of pH from 4 to 3 or 8 increased EAI regardless of concentration. The most EAI(about 6.44 $m^2/g$ solid) significantly(p<0.05) observed in solution containing 1% PNPE at pH 8.0, but that of 3% PNPE(0.10 $m^2/g$ solid) was minimal at pH 4.0. The emulsion stability exhibited maximum value(about 20) in 3% PNPE emulsion at pH 8.0. However, EAI of samples containing PNCE increased gradually with the increase of pH, but it had lower value than that of samples containing PNPE. At pH 7.0 and 8.0, the rheological behavior of emulsion solutions showed Newtonian fluid(n=1, $r^2>0.99$) regardless of concentration in all samples containing PNPE, but the samples containing PNCE showed pseudoplastic behavior(n<1) in all conditions. The sample with the better emulsion stability index(ESI) significantly(p<0.05) exhibited the higher L, b, and ${\delta}E$, however, lower a value.

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RHEOLOGICAL PROPERTIES OF RESIN COMPOSITES ACCORDING TO THE CHANGE OF MONOMER AND FILLER COMPOSITIONS (단량체 및 무기질 filler 조성 변화에 따른 복합레진의 유변학적 특성)

  • Lee In-Bog;Lee Jong-Hyuck;Cho Byung-Hoon;Son Ho-Hyun;Lee Sang-Tag;Um Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.29 no.6
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    • pp.520-531
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    • 2004
  • The aim of this study was to investigate the effect of monomer and filler compositions on the rheological properties related to the handling characteristics of resin composites. Methods. Resin matrices that Bis-GMA as base monomer was blended with TEGDMA as diluent at various ratio were mixed with the Barium glass (0.7 um and 1.0 um), 0.04 um fumed silica and 0.5 um round silica. All used fillers were silane treated. In order to vary the viscosity of experimental composites, the type and content of incorporated fillers were changed, Using a rheometer, a steady shear test and a dynamic oscillatory shear test were used to evaluate the viscosity ($\eta$) of resin matrix, and the storage shear modulus (G'), the loss shear modulus (G"), the loss tangent ($tan{\delta}$) and the complex viscosity (${\eta}^*$) ofthe composites as a function of frequency ${\omega}{\;}={\;}0.1-100{\;}rad/s$. To investigate the effect of temperature on the viscosity of composites, a temperature sweep test was also undertaken. Results. Resin matrices were Newtonian fluid regardless of diluent concentration and all experimental composites exhibited pseudoplastic behavior with increasing shear rate. The viscosity of composites was exponentially increased with increasing filler volume%. In the same filler volume, the smaller the fillers were used, the higher the viscosities were. The effect of filler size on the viscosity was increased with increasing filler content. Increasing filler content reduced $tan{\delta}$ by increasing the G' further than the G". The viscosity of composites was decreased exponentially with increasing temperature.

Improvement of Rheological and Functional Properties of Salmon FPC by Enzymatic Partial Hydrolysis 1. Production of Salmon FPC Hydrolysates and Their General Properties (효소적 부분 가수분해에 의한 연어 FPC(Fish Protein Concentrates)의 물성 및 기능성 개선 1. 연어 FPC의 가수분해물 제조와 일반적인 성상)

  • LEE Jong-Ho;LEE Keun-Tai;PARK Seong-Min;PARK Chan-kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.1
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    • pp.132-138
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    • 1998
  • To improve functional properties and enhance application of FPC in food industry, modified salmon FPC with enzyme treatment was produced and its general properties were investigated. Salmon FPC has over $84\%$ of protein and less than $0.18\%$ of lipid. Solubilities of FPC extracted with IPA and ethanol were very poor as less than $3\%$ in every pH range. In case of enzyme : substrate ratio of 1 : 100, degree of hydrolysis significantly increased until 4 hours and then slightly increased. No considerable differences were observed in general components of hydrolysates. Results of SDS-PAGE showed one unique band in each case and their molecular weight was less than 6,500. The flow properties of hydrolysates showed newtonian flow. Whiteness of hydrolysates were higher than that of salmon FPC as $5\~7$. There was no significant differences in the amount of peptide, but that of free amino acid slightly increased from 0.17 to 0.21 mg/ml.

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3D numerical modeling of impact wave induced by landslide using a multiphase flow model (다상흐름 모형을 이용한 산사태 유발 수면충격파 3차원 수치모의)

  • Kim, Byungjoo;Paik, Joongcheol
    • Journal of Korea Water Resources Association
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    • v.54 no.11
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    • pp.943-953
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    • 2021
  • The propagation of impact wave induced by landslide and debris flow occurred on the slope of lake, reservoir and bays is a three-dimensional natural phenomenon associated with strong interaction of debris flow and water flow in complex geometrical environments. We carried out 3D numerical modeling of such impact wave in a bay using a multiphase turbulence flow model and a rheology model for non-Newtonian debris flow. Numerical results are compared with previous experimental result to evaluate the performance of present numerical approach. The results underscore that the reasonable predictions of both thickness and speed of debris flow head penetrating below the water surface are crucial to accurately reproduce the maximum peak height and free surface profiles of impact wave. Two predictions computed using different initial debris flow thicknesses become different from the instant when the peaks of impact waves fall due to the gravity. Numerical modeling using relatively thick initial debris flow thickness appears to well reproduce the water surface profile of impact wave propagating across the bay as well as wave run-up on the opposite slope. The results show that the maximum run-up height on the opposite slope is not sensitive to the initial thickness of debris flows of same total volume. Meanwhile, appropriate rheology model for debris flow consisting of inviscid particle only should be employed to more accurately reproduce the debris flow propagating along the channel bottom.

Research on the Rheological Properties of Aqueous Film Forming Foam to Respond to Ship Oil Fires (함정 유류화재 대응을 위한 수성막포의 유변학적 특성 연구)

  • Kil-Song Jeon;Hwi-Seong Kim;Jung-Hoon You;Yong-Ho Yoo;Jin-Ouk Park
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.603-607
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    • 2023
  • Aqueous film forming foam (AFFF) is a critical fire suppression agent used in combating hydrocarbon fires. This type of fire suppressant is highly effective due to its ability to form a protective film, dissipate heat, inhibit combustion, and utilize a blend of chemical substances to extinguish fires. While these properties offer significant advantages in responding to hydrocarbon fires, AFFF is distinct in its deployment as it is dispensed in the form of foam. Therefore, the rheological analysis of AFFF foam using a rheometer plays a crucial role in predicting the spray characteristics of AFFF for combating hydrocarbon fires, and this is closely associated with effective fire suppression. In this study, we conducted rheometer experiments to confirm the non-Newtonian behavior (shear-thinning) of AFFF foam and obtained data on the form's stability. These experimental data are expected to contribute to enhancing the efficiency of fire suppression systems utilizing AFFF.

Qualities and Anti-inflammatory Activity of Kyungokgos Sold in Local Markets (국내 시판 경옥고 제품의 품질 특성 및 항염증 활성)

  • Lee, Ka-Soon;Kim, Gwan-Hou;Kim, Hyun-Ho;Seong, Bong-Jae;Kim, Sun-Ick;Han, Seung-Ho;Kang, Eun Ju;Yoo, Yung Choon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.3
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    • pp.335-341
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    • 2013
  • Kyungokgos purchased in local markets in Korea vary in their combination and mixing ratios during processing. This study was investigated qualities of Kyungokgos manufactured traditionally to evaluating its qualities. The general components of Kyungokgos were moisture (18.62~49.78%), ash (0.198~1.211%), protein (0.89~3.58%), lipid (0.16~1.14%) and carbohydrates (47.95~77.08%). The color values of L, a, and b were 26.49~73.87, 16.51~38.64, and 45.41~88.94, respectively. The viscosity was classified into three non-Newtonian type groups: high, medium, and non-dilatant, according to the increase of loop execution times. Three extracts (KOG-1, -7, and -8, in a 30-fold dilution) showed no cytotoxicity toward RAW 264.7 cells, while the extracts of KOG-2, -4, and -5 showed a low cytotoxic effect. KOG-1 and -2 extracts with low cytotoxicity markedly inhibited the production of the inflammatory mediators-nitric oxide (NO) and tumor necrosis factor-alpha (TNF-${\alpha}$) in LPS-stimulated RAW 264.7 cells. These results indicate that KOG-1 and -2 extracts have anti-inflammatory activity in LPS-stimulated RAW 264.7 macrophages.