• Bulletin of the Korean Chemical Society
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• 제1권4호
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• pp.126-131
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• 1980

Seventeen new $N^{6}$-aminoalkyl derivatives of 5'-adenylic acid and adenosine 5'-triphosphate (Compound I-XVII) were synthesized from 6-chloropurine ribonucleoside by reaction with appropriate diamines. This paper discusses the procedure of synthesis and the identification of the derivatives by ultraviolet spectra, high voltage electrophoresis, paper chromatography, elemental analyses, and other chemical methods.

• 한국결정성장학회지
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• 제19권3호
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• pp.130-134
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• 2009

새로운 $CaZrO_3$, 축광성 형광체를 고온의 약한 환원 분위기에서 전통적인 고상반응법으로 합성하였다 광발광 분석 결과 $Tb^{3+}$ 이온을 첨가한 $CaZrO_3$ 축광성 형광체는 $^5D_3$, $^5D_4$ 에너지 준위에서 $^7F_1{\sim}^7F_6$ 준위로의 전이에 의해 황녹색의 발광을 나타내며, 고온의 질소분위기에서 합성한 경우의 축광성 형광체에 대한 스펙트럼의 주 피크는 $^5D_4{\rightarrow}^7F_5$ 전이에 의한 542 nm의 발광 피크가 생성되었다. $CaZrO_3:Tb^{3+}$ 축광성 형광체의 잔광 발광 스펙트럼은 좁은 영역의 546 nm의 피크가 강하게 생성되었다 잔광 휘도는 254 nm 자외선을 조사하고 전원을 끈 후에 측정하였으며, 녹황색의 축광성 형광체가 사람이 어두운 곳에서 인지 가능한 $0.32\;mcd/m^2$까지 8시간 지속됨을 관찰하였다.

• Earthquakes and Structures
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• 제7권4호
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• pp.485-510
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• 2014

In performance-based seismic design procedures Peak Ground Acceleration (PGA) and pseudo-Spectral acceleration ($S_a$) are commonly used to predict the response of structures to earthquake. Recently, research has been carried out to evaluate the predictive capability of these standard Intensity Measures (IMs) with respect to different types of structures and Engineering Demand Parameter (EDP) commonly used to measure damage. Efforts have been also spent to propose alternative IMs that are able to improve the results of the response predictions. However, most of these IMs are not usually employed in probabilistic seismic demand analyses because of the lack of reliable Ground Motion Prediction Equations (GMPEs). In order to define seismic hazard and thus to calculate demand hazard curves it is essential, in fact, to establish a GMPE for the earthquake intensity. In the light of this need, new GMPEs are proposed here for the elastic input energy spectra, energy-based intensity measures that have been shown to be good predictors of both structural and non-structural damage for many types of structures. The proposed GMPEs are developed using mixed-effects models by empirical regressions on a large number of strong-motions selected from the NGA database. Parametric analyses are carried out to show the effect of some properties variation, such as fault mechanism, type of soil, earthquake magnitude and distance, on the considered IMs. Results of comparisons between the proposed GMPEs and other from the literature are finally shown.

• 한국지반환경공학회 논문집
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• 제10권7호
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• pp.111-115
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• 2009

국내에서는 지반의 설계응답스펙럼을 확률론적으로 생성한 지진재해도와 결정론적으로 유도된 지진계수를적용하여 생성한다. 지진재해도와 지진계수는 호환되지 않지만, 현 설계기준은 이런 근본적인 비호환성을 무시하고 있다. 지진재해도와 지진계수를 동일한 확률론적 기반에서 생성한다면 이와 같은 문제를 극복할 수 있지만, 기존의 방법으로는 지진계수를 확률론적으로 생성할 수 없다. 본 논문에서는 동반논문에서 신(新) PSHA의 결과물로써 생성된 지진기록을 입력지진파로 활용하여 1차원 등가선형 지반응답 해석을 수행하였으며 이의 결과를 기반으로 등재해스펙트럼을 생성하였다. 등재해스펙트럼의 또 한가지 장점은 지반물성치의 불확실성과 임의성이 과학적으로 고려되었다는 점이다. 등재해스펙트럼은 나아가 확률론적인 지진계수를 도출하는데 활용되었다. 확률론적인 지진계수를 내진설계기준에서 제시된 지진계수를 비교한 결과, 확률론적으로 계산된 지진계수는 결정론적으로 계산된 결과와 상당한 차이가 있는 것으로 나타났다.

• 천문학회보
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• 제36권2호
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• pp.73.2-73.2
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• 2011

We present a new database of absorption and emission-line measurements based on the entire spectral atlas from the Sloan Digital Sky Survey (SDSS) 7th data release of galaxies within a redshift of 0.2. Our work makes use of the publicly available penalized pixel-fitting(pPXF) and gas and absorption line fitting (gandalf) IDL codes, aiming to improve the existing measurements for stellar kinematics, the strength of various absorption-line features, and the flux and width of the emissions from different species of ionized gas. Our fit to the stellar continuum uses both standard stellar population models and empirical templates obtained by combining a large number of stellar spectra in order to fit a subsample of high-quality SDSS spectra for quiescent galaxies. Furthermore, our fit to the nebular spectrum includes an exhaustive list of both recombination and forbidden lines. Foreground Galactic extinction is implicitly treated in our models, whereas reddening in the SDSS galaxies is included in the form of a simple dust screen component affecting the entire spectrum that is accompanied by a second reddening component affecting only the ionised gas emission. Most notable of our work is that, we provide quality of the fit to assess reliability of the measurements. The quality assessment can be highly effective for finding new classes of objects. For example, based on the quality assessment around the Ha and [NII] nebular lines, we found approximately 1% of the SDSS spectra which classified as "galaxies" by the SDSS pipeline are in fact type I Seyfert AGN.

• Structural Engineering and Mechanics
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• 제59권3호
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• pp.455-473
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• 2016

Methods for the seismic demands evaluation of structures require iterative procedures. Many studies dealt with the development of different inelastic spectra with the aim to simplify the evaluation of inelastic deformations and performance of structures. Recently, the concept of inelastic spectra has been adopted in the global scheme of the Performance-Based Seismic Design (PBSD) through Capacity-Spectrum Method (CSM). For instance, the Modal Pushover Analysis (MPA) has been proved to provide accurate results for inelastic buildings to a similar degree of accuracy than the Response Spectrum Analysis (RSA) in estimating peak response for elastic buildings. In this paper, a simplified nonlinear procedure for evaluation of the seismic demand of structures is proposed with its applicability to multi-degree-of-freedom (MDOF) systems. The basic concept is to write the equation of motion of (MDOF) system into series of normal modes based on an inelastic modal decomposition in terms of ductility factor. The accuracy of the proposed procedure is verified against the Nonlinear Time History Analysis (NL-THA) results and Uncoupled Modal Response History Analysis (UMRHA) of a 9-story steel building subjected to El-Centro 1940 (N/S) as a first application. The comparison shows that the new theoretical approach is capable to provide accurate peak response with those obtained when using the NL-THA analysis. After that, a simplified nonlinear spectral analysis is proposed and illustrated by examples in order to describe inelastic response spectra and to relate it to the capacity curve (Pushover curve) by a new parameter of control, called normalized yield strength coefficient (${\eta}$). In the second application, the proposed procedure is verified against the NL-THA analysis results of two buildings for 80 selected real ground motions.

• Bulletin of the Korean Chemical Society
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• 제12권2호
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• pp.130-137
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• 1991

The following new cryptand 221 complexes of lanthanides(Ⅲ) and dioxouranium(Ⅵ) nitrate have been synthesized: $(Ln(C_{16}H_{32}N_2O_5)(H_2O)_2(NO_3)_3\ and \((UO_2)_2(C_{16}H_{32}N_2O_5)(H_2O)_4(NO_3)_4$. These complexes have been identified by elemental analysis, moisture titration, conductivity measurements and various spectroscopic techniques. The proton and carbon-13 NMR as well as calorimetric measurements were used to study the interaction of cryptand 221 with La(Ⅲ), Pr(Ⅲ ), Ho(Ⅲ) and $UO_2(Ⅱ)$ ions in nonaqueous solvents. The bands of metal-oxygen atoms, metal-nitrogen atoms and O-U-O in the IR spectra shift upon complexation to lower frequencies, and the vibrational spectra ({\delta}NMN$) of metal-amide complexes in the crystalline state exhibit lattice vibrations below 300 $cm^{-1}$. The NMR spectra of the lanthanides(Ⅲ) and dioxouranium(Ⅵ) nitrate complexes in nonaqueous solvents are quite different, indicating that the ligand exists in different conformation, and also the $^1H$ and $^{13}C-NMR$ studies indicated that the nitrogen atom of the ring has greater affinity to metal ions than does the oxygen atom, and the planalities of the ring are lost by complexation with metal ions. Calorimetric measurements show that cryptand 221 forms more stable complexes with $La^{3+}$ and $Pr^{3+}$ ions than with $UO^{22+}$ ion, and $La^{3+}/Pr^{3+}$ and $UO^{22+}/Pr^{3+}$ selectivity depends on the solvents. These changes on the stabilities are dependent on the basicity of the ligand and the size of the metal ions. The absorption band (230-260 nm) of the complex which arises from the direct interaction of macrocyclic donor atoms with the metal ion is due to n-{\delta}*$ transition and also that (640-675 nm) of $UO^{22+}$-cryptand 221 complex, which arises from interaction between two-dioxouranium(Ⅵ) ions in being out of cavity of the ligand ring is due to d-d* transition.

• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.875-883
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• 2013

Ten new derivatives of 1,3-diazabicyclo[3.1.0]hex-3-enes linked via ether linkage to chalcones were synthesized and characterized by UV, FT-IR, $^1H$ NMR and $^{13}C$ NMR spectral techniques. The spectra of all synthesized compounds, confirmed structure-photochromic behavior relationships (SPBR) both in solution or in solid state by irradiation under UV light at 254 nm. In other efforts for first time photochromic behavior of ketoaziridines has been investigated.

• Natural Product Sciences
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• 제9권4호
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• pp.220-222
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• 2003

Two new abietane diterpenes with rearranged skeleton; aegyptinol and aegyptinone C; have been isolated and identified for the first time from the anti-microbial petroleum ether extract of the roots of Salvia aegyptiaca L. Their chemical structures have been elucidated by interpretation of the detailed 1D-and 2D-NMR spectra, as well as other spectroscopic tools. In addition, full assignment of $^{13}C-NMR$ of aegyptinone B was also conducted for the first time.

• 천문학회지
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• 제15권1호
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• pp.37-39
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• 1982

High spatial and spectral resolution observations have been made over a sunspot (SPO 6403) with the Echelle Spectrograph at the Vacuum Tower Telescope, Sacramento Peak Observatory. Our observed spectra, scanned with SPO's fast microdensitometer, clearly show strengthening of $C_2$ lines in the penumbra relative to the photosphere and much weakening in the umbra in agreement with the predictions made by our molecular equilibrium calculations (Lee et al. 1981).