• Title/Summary/Keyword: New Materials

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Permeation Property of Ionomer Film with New Multifunctional Ionic Site (다관능기를 도입한 아이오노머 필름의 기체투과 특성)

  • Lee, Bo-Mi;Jeong, Sam-Bong;Nam, Sang-Yong
    • Korean Journal of Materials Research
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    • v.22 no.5
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    • pp.227-236
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    • 2012
  • Ionomer is a thermoplastic that is composed of covalent bonds and ionic bonds. It is possible to use this material in processes such as injection molding or extrusion molding due to the material's high oil resistance, weatherproof characteristics, and shock resistance. In this study, a new ionomer having a multifunctional group was prepared by a stepwise neutralization system with the addition of acidic and salt additives. In step I, to increase the contents of the multifunctional group and the acid degree in ethylene acrylic acid (EAA), MGA was added to the ionomer resin (EAA). A new ionomer was prepared via the traditional preparation method of the ionic cross-linking process. In step II, metal salt was added to the mixture of EAA and MGA. The extrusion process was performed using a twin extruder (L/D = 40, size : ${\varphi}30$). Ionomer film was prepared for evaluation of gas permeability by using the compression molding process. The degree of neutralized and ionic cross-linked new ionomer was confirmed by FT-IR and XRD analysis. In order to estimate the neutralization of the new ionomer film, various properties such as gas permeation and mechanical properties were measured. The physical strength and anti-scratch property of the new ionomer were improved with increase of the neutralization degree. The gas barrier property of the new ionomer was improved through the introduction of an ionic site. Also, the ionic degree of cross-linking and gas barrier property of the ionomer membrane prepared by stepwise neutralization were increased.

The Antifungal Test: An Efficient Screening Tool for the Discovery of Microbial Metabolites with Respiratory Inhibitory Activity

  • Han, Jae Woo;Kim, Bomin;Oh, Mira;Choi, Jaehyuk;Choi, Gyung Ja;Kim, Hun
    • Mycobiology
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    • v.48 no.4
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    • pp.326-329
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    • 2020
  • Valuable natural compounds produced by a variety of microorganisms can be used as lead molecules for development of new agrochemicals. Furthermore, high-throughput in vitro screening systems with specific modes of action can increase the probability of discovery of new fungicides. In the current study, a rapid assay tested with various microbes was developed to determine the degree of respiratory inhibition of Saccharomyces cerevisiae in two different liquid media, YG (containing a fermentable carbon source) and NFYG (containing a non-fermentable carbon source). Based on this system, we screened 100 fungal isolates that were classified into basidiomycetes, to find microbial secondary metabolites that act as respiratory inhibitors. Consequently, of the 100 fungal species tested, the culture broth of an IUM04881 isolate inhibited growth of S. cerevisiae in NFYG medium, but not in YG medium. The result is comparable to that from treatment with kresoxim-methyl used as a control, suggesting that the culture broth of IUM04881 isolate might contain active compounds showing the inhibition activity for respiratory chain. Based on the assay developed in this study and spectroscopic analysis, we isolated and identified an antifungal compound (-)-oudemansin A from culture broth of IUM04881 that is identified as Oudemansiella venosolamellata. This is the first report that (-)-oudemansin A is identified from O. venosolamellata in Korea. Taken together, the development of this assay will accelerate efforts to find and identify natural respiratory inhibitors from various microbes.

A Study of New Chronological Book Numbers (새 연대순 도서기호법의 연구)

  • Lee Jai Chul
    • Journal of the Korean Society for Library and Information Science
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    • v.12
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    • pp.7-37
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    • 1985
  • In most of the modern libraries throughout the world, it is popular to adopt the author number which arranges the books or entries in alphabetical order of their author's names within the same ultimate class. However, viewed historically, that was the Western practice never used in the East before. Traditionally chronological order was followed in the East. Book number not only individualizes the books within the same class but also makes it easy for the user to choose and find out the relevant materials. In this respect, chronological book number is decidedly superior to all kinds of book number systems ever have been existed. Especially in these days of rapid obsolescence of documents and with serious problems of storage of documents, the chronological order seems to be the most modern and future-oriented of all other book number systems because it distinguishes clearly new materials from aged materials by the date of publication and controls the stack spaces mechanically and effectively. This writer devised New Chronological Book Numbers adaptable to both the Eastern and Western materials, and the system has been adopted at Yonsei University Library. The features of the system are as follows: (1) It is easy to type the call number in cataloging the Eastern and Western materials. That is because the structure of the chronological number is pure numerical notation by taking the last two figures of the year within twentieth century(e.g. 85 for AD 1985), that is 1900s, and the last three figures of the year from twenty-first century to thirtieth century, that is 2000s. (2) It does not make all classes have chronological number uniformly. Within the classes for individual biographies, genealogies and collections of biography of specific family, books about individual organization, individual literary and artistic works, philosophical works of the famous philosophers, books and its facsmile editions published before 1900, new editions, translations, commentaries, serials, chronological number is assigned to the author number as in the past. (3) It separates the Eastern materials from the Western materials and makes the typing easy in cataloging. That is because the subarrangement within the same chronological book number is made by the accession order which uses 'panjol-ponmun' or the characters of basic syllabic table of Korean alphabet in case of the Eastern materials and Roman alphabet in case of the Western materials.

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Preparation of Nanoflake Bi2MoO6 Photocatalyst Using CO(NH2)2 as Structure Orientation and Its Visible Light Degradation of Tetracycline Hydrochloride

  • Hu, Pengwei;Zheng, Dewen;Xian, Yuxi;Hu, Xianhai;Zhang, Qian;Wang, Shanyu;Li, Mingjun;Cheng, Congliang;Liu, Jin;Wang, Ping
    • Korean Journal of Materials Research
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    • v.31 no.6
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    • pp.325-330
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    • 2021
  • Bi2MoO6 (BMO) via the structure-directing role of CO(NH2)2 is successfully prepared via a facile solvothermal route. The structure, morphology, and photocatalytic performance of the nanoflake BMO are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), fluorescence spectrum analysis (PL), UV-vis spectroscopy (UV-vis) and electrochemical test. SEM images show that the size of nanoflake BMO is about 50 ~ 200 nm. PL and electrochemical analysis show that the nanoflake BMO has a lower recombination rate of photogenerated carriers than particle BMO. The photocatalytic degradation of tetracycline hydrochloride (TC) by nanoflake BMO under visible light is investigated. The results show that the nanoflake BMO-3 has the highest degradation efficiency under visible light, and the degradation efficiency reached 75 % within 120 min, attributed to the unique hierarchical structure, efficient carrier separation and sufficient free radicals to generate active center synergies. The photocatalytic reaction mechanism of TC degradation on the nanoflake BMO is proposed.

A Study on the Concentration Variations of VOCs and Formaldehyde on the Type of Interior Materials of New Vehicles by Simulation Program (시뮬레이션 프로그램을 이용한 신규 차량의 인테리어 물질에 따른 VOC와 폼알데히드의 농도 변화에 관한 연구)

  • Yi, Young-Seop;Kim, In-Bum;Ko, Won-Kyoung
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.89-95
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    • 2012
  • The concentrations of Volatile Organic Compounds(VOCs) and Formaldehyde(HCHO) for interior materials of new vehicles are estimated and recognized by using the simulation program known as IAQx. The concentrations of contaminants are estimated and evaluated by the ventilation rates of new domestic vehicles and the required ventilation rates for new vehicles are estimated through the given contaminant data. This study is conducted to compare the ventilation rates for the contaminants between the discontinuously ventilated new vehicles and the continuously ventilated new vehicles using the simulation program. The equation of ventilation rate of new vehicles is acquired to be able to lower initial concentrations below the standard level under different conditions for both business and personal commuting.

Development Smart Sensor & Estimation Method to Recognize Materials (대상물 인식을 위한 지능센서 및 평가기법 개발)

  • Hwang, Seong-Youn;Hong, Dong-Pyo;Chung, Tae-Jin;Kim, Young-Moon
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.3
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    • pp.73-81
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    • 2006
  • This paper describes our primary study for a new method of recognizing materials, which is need for precision work system. This is a study of dynamic characteristics of smart sensors, new method$(R_{SAI})$ has the sensing ability of distinguishing materials. Experiment and analysis are executed for finding the proper dynamic sensing condition. First, we developed advanced smart sensor. We made smart sensors for experiment. The type of smart sensor is HH type. The smart sensor was developed for recognition of material. Second, we develop new estimation methods that have a sensing ability of distinguish materials. Dynamic characteristics of sensor are evaluated through new recognition index$(R_{SAI})$ that ratio of sensing ability index. Distinguish of object is executed with $R_{SAI}$ method relatively. We can use the $R_{SAI}$ method for finding materials. Applications of this method are finding abnormal condition of object (auto-manufacturing), feeling of object(medical product), robotics, safety diagnosis of structure, etc.

The Study on the Cavitation Erosion Behavior of Hardfacing Alloys for Nuclear Power Plants (원전 밸브용 경면처리 합금의 캐비테이션 에로젼 (cavitation erosion) 거동에 관한 연구)

  • O, Yeong-Min;Kim, Yun-Gap;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.12 no.4
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    • pp.308-316
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    • 2002
  • The cavitation erosion behavior of wear-resistant hardfacing alloys such as Co-base Stellite 6, Fe-base Norem 02 and new Fe-base alloy were investigated up to 50 hours by using a 20kHz vibratory cavitation erosion test equipment. The crack, initiated easily at the interfaces between matrix and hard second phase, was repressed effectively in Stellite 6 because the matrix was hardened by phase transformation. For this reason, Stellite 6 showed an excellent cavitation erosion resistance compared to Norem 02. The phase transformation also occurred in Norem 02, but the increase of volume fraction of the interfaces caused the crack to be initiated frequently, thus resulting in a 1arge material loss. The matrix of NewAlloy was hardened effectively by vlongrightarrow$\alpha$' phase transformation and the volume fraction of the interfaces was very small compared to Norem 02. This caused the propagation of crack to the matrix to be repressed effectively. Therefore, NewAlloy showed a very excellent cavitation erosion resistance. It wasn't considered that the cavitation erosion resistance of NewAlloy was influenced the temperature of the bath filled with a distilled water up to $80^{\circ}C$.

Design of Nickel Alloys Using the Theoretical Values Calculated from the Electronic State Energies (에너지 전자상태 계산으로 도출된 이론값을 이용한 니켈 합금 설계)

  • Baek, Min-Sook;Kang, Pub-Sung;Baek, Kyeong-Cheol;Kim, Byung-Il;Yoon, Dong-Joo
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.642-646
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    • 2015
  • Super alloys, which can be divided into three categories, i.e. Ni-base, Co-base, and Fe-base alloys, are widely used for high temperature applications. Since superalloys contain many alloying elements and precipitates, their chemistry and processing parameters need to be carefully designed. In this study, we designed a new Ni alloy to prevent corrosion due to water vapor and gases at high temperatures. The new alloy was designed using the theoretical value of the resulting energy electronic state calculation($DV-X{\alpha}$ method). The components that were finally used were Cr, Mo, and Ti, with Ni as a base. For these alloys, elements were selected in order to compare their values with that of the average theoretical basis for an Inconel 625 alloy. Finally, two kinds of Ni alloy were designed: Ni-28Cr-4Mo-2Ti and Ni-20Cr-10Mo-1Ti.

Corrosion Mechanisms of New Wrought Mg-Zn Based Alloys Alloying with Si, Ca and Ag

  • Ben-Hamu, G.;Eliezer, D.;Shin, K.S.;Wagner, L.
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.152-157
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    • 2008
  • New wrought magnesium alloys have increasingly been developed in recent years for the automotive industry due to their high potential as structural materials for low density and high strength/weight ratio demands. However, their poor mechanical properties and low corrosion resistance have led to a search for new kinds of magnesium alloys with better strength, ductility, and high corrosion resistance. The main objective of this research is to investigate the corrosion behaviour of new magnesium alloys: Mg-Zn-Ag (ZQ), Mg-Zn-Mn-Si (ZSM) and Mg-Zn-Mn-Si-Ca (ZSMX). These ZQ6X, ZSM6X1, and ZSM651+YCa alloys were prepared using hot extrusion. AC, DC polarization and immersion tests were carried out on the extruded rods. Microstructure was examined using optical and electron microscopy (SEM) and EDS. The addition of silver decreased the corrosion resistance. The additions of silicon and calcium also affected the corrosion behaviour. These results can be explained by the effects of alloying elements on the microstructure of Mg-Zn alloys such as grain size and precipitates caused by the change in precipitation and recrystallisation behaviour.