• Title/Summary/Keyword: Neutral loss

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A Role of Dissolved Iron ion in Combined Fenton Reaction for Treatment of TNT Contaminated Soil (오염토양처리를 위한 혼합 Fenton 공정에서 용존 철이온이 오염산화처리에 미치는 역할에 관한 연구)

  • Seo, Seung-Won;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.11 no.6
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    • pp.76-82
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    • 2006
  • Fenton's reaction are difficult to apply in the field due to the low pH requirements for the reaction and the loss of reactivity caused by the precipitation of iron (II) at neutral pH. Moreover, Fenton-like reactions using iron mineral instead of injection of iron ion as a catalyst are operated to get high removal result at low pH. Because hydroxyl radical can generate at the surface of iron mineral, there are competition with a lot of hydroxide at around neutral pH. On the other side, to operate Fenton's reaction series at neutral pH, modified Fenton reaction is suggested. The complexes, composed by iron ions (ferrous ion or ferric ion)-chelating agent, could be acted as a catalyst and presented in the solution at neutral pH. However, modified Fenton reaction requires a lot of hydrogen peroxide. Accordingly, the purpose of this experiment was to effectively combine Fenton-like reaction and modified Fenton reaction for extending application of Fenton's reaction. i.e., injecting chelating agents in Fenton-like reaction at around neutral pH is increasing the concentration of dissolved iron ion and highly promoting the oxidation effect. 2,4,6-trinitrotoluene (TNT) was used as a probe compound for comparing reaction efficiencies in this study. If the concentration of dissolved iron ion in combined Fenton process were existed more than 0.1 mM, the total TNT removal were increased. Magnetite-NTA system showed the best TNT removal (76%) and Magnetite-EDTA system indicated about 56% of TNT removal. The results of these experiments proved more promoted 40-60% of TNT removal than Fenton-like reaction's.

Hazards and Solutions of Loss of the PEN Conductor in TN-C-S System (TN-C-S계통에서 PEN도체의 단선고장의 위험성 및 보호대책)

  • Lee, Bok-Hee;Lee, Kyu-Sun;Ahn, Chang-Hwan;Kim, Han-Su
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.8
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    • pp.113-120
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    • 2007
  • This paper presents the electric shock hazards and solutions of loss of the combined protective and neutral (PEN) conductor in TN-C-S system. In order to mitigate the touch voltage on exposed-conductive-parts in a break in the PEN conductor, the touch voltages on exposed-conductive-parts in a break in the PEN conductor were experimentally investigated as a function of the ground resistances of the source grounding electrode and customer's additional grounding electrode. As a result, the equipotential bonding is one of important requirements for installations supplied by TN-C-S system. A solution of mitigating the touch voltages on exposed-conductor-parts caused by a loss of the PEN conductor would be the installation of the additional grounding electrode at the customer's service entrance. The ground resistance of additional grounding electrode necessary to limit the touch voltage to a safety voltage of less than 50[V] depends on the load and circuit parameters. In addition, the undervoltage sensing devices oner affordable solutions to detect a loss of the PEN conductor in TN-C-S system.

Competition between ICME and crustal magnetic field on the loss of Mars atmosphere

  • Hwang, Junga;Jo, Gyeongbok;Kim, Roksoon;Jang, Soojeong;Cho, Kyungsuk;Lee, Jaejin;Yi, Yu
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.62.3-63
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    • 2017
  • The Mars Atmosphere and Volatile (MAVEN) mission has been providing valuable information on the atmospheric loss of Mars since its launch in November 2013. The Neutral Gass and Ion Mass Spectrometer (NGIMS) onboard MAVEN, was developed to analyze the composition of the Martian upper atmospheric neutrals and ions depending on various space weather conditions. We investigate a variation of upper atmospheric ion densities depending on the interplanetary coronal mass ejections (ICMEs). It is known that the Mars has a very weak global magnetic field, so upper atmosphere of Mars has been strongly affected by the solar activities. Meanwhile, a strong crustal magnetic field exists on local surfaces, so they also have a compensating effect on the upper atmospheric loss outside the Mars. The weak crustal field has an influence up to 200km altitude, but on a strong field region, especially east longitude of $180^{\circ}$ and latitude of $-50^{\circ}$, they have an influence over 1,400km altitude. In this paper, we investigated which is more dominant between the crustal field effect and the ICME effect to the atmospheric loss. At 400km altitude, the ion density over the strong crustal field region did not show a significant variation despite of ICME event. However, over the other areas, the variation associated with ICME event is far more overwhelming.

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Recycling of Plant Fiber Resources: Enhanced Hydration of Newspaper Stock for Decrease of Deinking Reject (식물유래 섬유자원의 재활용: 탈묵 수율 개선을 위한 신문 지료의 수화 촉진 방안)

  • Chung, Sung-Hyun;Kim, Joong-Ho;Joo, Jong-Hun;Bang, Jae-Wook
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.39-41
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    • 2011
  • The recycling rate of recovered paper in Korea is the highest in the world, 92%, but remanufacturing yield is low due to the extremely poor quality of the paper. The poor quality, in turn, influences to the reject amount in deinking process. To increase the yield of old newspaper recycling process, hydrophobic degree of inorganic pigments of deinking stock must be reduced. To determine the hydrophobicity, Pitch Potential Deposit Tester (PDT) was newly designed and applied with respect to the SB latex property of various quality used in Korea; its hydrophobic degree according to Tg, gel content, charge and particle size of latex and optimum designing condition of SB latex. And below are the conclusions: 1. The reason of excessive reject from old newspaper deinking process for total amount of printed ink is loss of inorganic pigments. When lipase, a biochemical catalyst, was applied with the purpose of preventing inorganic pigments loss about more than 70% of total reject weight and promoting hydration of pulp for deinking, deinking process yield of pre flotation secondary stage increased remarkably without any changes of deinking efficiency. 2. Lipase improved deinking stock by cutting ester linkage on surface of hydrophobic materials to promote its hydration. From this, it reached the conclusion that hydration degree of stock exercises significant effect on flotation deinking process yield. 3. Inorganic alkali promotes hydration of deinking stock. But there have been needs for more fundamental measures other than inorganic alkali of promoting hydration for yield improvement. For this, this study intended to find out reasons of chemical properties change on surface of hydrophobic material by change of pH. 4. Pitch Deposit Test (PDT) was performed for understanding principle of why surface of coating flake from OMG is hydrophobic and why it becomes hydrophilic when pH of stock is alkaline. As a result of this test, it is determined that swelling property by change of pH of latex film, which were used as coating adhesive is the reason for hydrophobic change. 5. Hydrophilicity of coating flake increased with hydrophilic pigments. And as more of SB Latex adhesive was used and higher of calcium hardness of stock became, its hydrophilicity decreased. SB Latex adhesive film is reformed by mechanical friction. For having hydrophilicity under neutral pH, strong bruising action such as kneading is required. 6. Because swelling of adhesive film decreases as Tg of SB latex gets lower and mean diameter gets smaller, it shows hydrophobicity under neutral pH. This lowers hydrophilicity of coating flake, which leads to easy elimination with flotation reject on DIP process. Therefore, for improving future flotation yield, it is necessary to develop to use eco-friendly clean SB latex by raising Tg and increasing mean diameter for recycling, and as a result, to reduce excessive loss of coating flake as a reject from deinking process.

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Eliminating the Third Harmonic Effect for Six Phase Permanent Magnet Synchronous Generators in One Phase Open Mode

  • Liu, Jian;Yang, Gui-Jie;Li, Yong;Gao, Hong-Wei;Su, Jian-Yong
    • Journal of Power Electronics
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    • v.14 no.1
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    • pp.92-104
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    • 2014
  • To insure stable operation and eliminate twice torque ripple, a topology for a six phase permanent magnet synchronous generator (SP-PMSG) with a neutral point connected together was analyzed in this paper. By adopting an extended transformation matrix, the mathematic model of the space vector control was established. The voltage and torque equations were deduced while considering the third harmonic flux and inductance. In addition, the suppression third harmonic method and the closed loop control strategy were proposed. A comparison analysis indicates that the cooper loss minimum method and the current magnitude minimum method can meet different application requirements. The voltage compensation amount for each of the methods was deduced which also takes into account the third harmonic effect. A simulation and experimental result comparison validates the consistency through theoretical derivation. It can be seen that all of the two control strategies can meet the requirements of post-fault.

The influence of Advanced Adult Periodontitis on the pulp (진행성 치주염이 지수 조직에 미치는 영향)

  • Lee, Kang-Woon;Lee, Chel-Woo;Han, Soo-Boo
    • Journal of Periodontal and Implant Science
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    • v.29 no.1
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    • pp.95-102
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    • 1999
  • The purpose of this study was to observe histopathologically the influence of advanced periodontitis on pulp tissue, and to conclude the correlation between the results with clinical manifestations. The samples were teeth with over 7mm pocket depth and over 50% radiographic bone loss. These were diagnosed to have very poor prognosis and thus planned to be extracted. Those with any of following conditions were excluded from the samples, loss of vitality, periapical pathology, restoration or prosthesis, dental caries, and attrition or abrasion. It was because these conditions could affect pulp without any correlation with periodontal disease. For the experiment, 17 teeth from 11 patients were selected. Average age of patient was 47. Each tooth was examined for following categoris; pocket depth, gingival recession, electric pulp test, mobility, percussion test, sensitivity test. The extracted teeth were fixed buffered neutral formalin solution. It was decalcified using 4% nitric acid. Sliced histological samples observed using light microscope, for pulp status, and severeity of inflammation. 4 samples were excluded due to histologic sample discrepency. Thus 13 samples were subject to observation. 4 showed normal conditions. Focal reversable pulpitis was shown in 5 samples. Chronic pulpitis was observed 1 sample. Pulpal abscess was observed in 3 samples.

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Surface Defects States on a SiO2/Si Observed by REELS

  • Kim, Juhwan;Kim, Beomsik;Park, Soojeong;Park, Chanae;Denny, Yus Rama;Seo, Soonjoo;Chae, Hong Chol;Kang, Hee Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.271-271
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    • 2013
  • The defect states of a Ar-sputtered SiO2 surface on Si (001) were investigated using Auger electron spectroscopy (AES) and reflection electron energy loss spectroscopy (REELS). The REELS spectra at the primary electron energy of 500 eV showedthat three peaks at 2.5, 5.1, and 7.2 eV were found within the band gap after sputtering. These peaks do not appear at the primary electron energies of 1,000 and 1,500 eV, which means that the defect states are located at the extreme surface of a SiO2/Si thin film. According to the calculations, two peaks at 7.2 and 5.1 eV are related to neutral oxygen vacancies. However, the third peak at 2.5 eV has never been previously reported and the theories proposed that this defect state may be due to Si-Si bonding. Our Auger data showed that a peak for Si-Si bonding at 89 eV appears after Ar ion sputtering on the surface of the sample, which is consistent with the theoretical models.

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Development of Simple Bimodal Model for Charged Particle Coagulation (Bimodal 방법을 이용한 하전입자 응집 모델링)

  • Kim, Sang Bok;Song, Dong Keun;Hong, Won Seok;Shin, Wanho
    • Particle and aerosol research
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    • v.10 no.1
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    • pp.27-31
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    • 2014
  • A simple bimodal model has been developed to analyze charged particle coagulation by modifying previously suggested bimdal model for evolution of particle generation and growth. In the present model, two monodisperse modes are used and 40 charge nodes are assigned to each mode to account both change of the particle size and charge distribution. In addition, we also implemented the effect of electrostatic dispersion loss in the present model. Based on the developed model, we analyzed coagulation of asymmetric bipolar charged particles by computing evolutions of particle number concentration, geometric mean diameter of particles, charge asymmetric ratio and geometric standard deviation of particle size distribution for various initial charge asymmetric ratios. The number concentration of asymmetric bipolar charged particles decreases faster than that of neutral particles but that does not give faster growth of particles since the electrostatic dispersion loss overwhelms particle growth by coagulation.

A PWM Control Strategy for Low-speed Operation of Three-level NPC Inverter based on Bootstrap Gate Drive Circuit (부트스트랩 회로를 적용한 3-레벨 NPC 인버터의 저속 운전을 위한 PWM 스위칭 전략)

  • Jung, Jun-Hyung;Ku, Hyun-Keun;Im, Won-Sang;Kim, Wook;Kim, Jang-Mok
    • The Transactions of the Korean Institute of Power Electronics
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    • v.19 no.4
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    • pp.376-382
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    • 2014
  • This paper proposes the pulse width modulation (PWM) control strategy for low-speed operation in the three-level neutral-point-clamped (NPC) inverters based on the bootstrap gate drive circuit. As a purpose of the cost reduction, several papers have paid attention to the bootstrap circuit applied to the three-level NPC inverter. However, the bootstrap gate driver IC cannot generate the gate signal to the IGBT for low-speed operation, because the bootstrap capacitor voltage decreases under the threshold level. For low-speed operation, the dipolar and partial-dipolar modulations can be the effective solution. However, these modulations have drawbacks in terms of the switching loss and THD. Therefore, this paper proposes the PWM control strategy to operate the inverter at low-speed and to minimize the switching loss and harmonics. The experimental results are presented to verify the validity on the proposed method.

Comparative performance evaluation of 10kV IGCTs in 3L NPC and ANPC Converter in PMSG MV Wind Turbines (PMSG 풍력발전기용 3L NPC와 ANPC 컨버터에서의 10kV IGCT 성능 비교 평가)

  • Lyngdoh, Amreena Lama;Suh, Youngsug;Park, Byoung-Gun;Kim, Jiwon
    • Proceedings of the KIPE Conference
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    • 2018.11a
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    • pp.86-88
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    • 2018
  • The three level(3L) neutral point clamped (NPC) voltage source converter (VSC) topology is widely used for grid interface in high power wind energy due to its superior performance as compared to the two level(2L) VS. However, one of the major drawbacks of this topology is the unequal dispersion of loss and therefore the junction temperature among the power devices. The 3L ANPC topology derived from the NPC topology was proposed to resolve this drawback of unequal loss profile of 3L NPC. The 3L ANPC can work under various switching strategies. In this paper a comparative study of the various switching strategies of 3L ANPC using the recently developed 10kV IGCTs which has the capability to raise the current and voltage rating of the wind turbines is carried out. The comparison is performed using ABB make 10kV IGCT 5SHY17L9000 and PLECs simulations.

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